THE MACROPOROUS CERAMIC MATERIALS AS CARBON CAPTURE STORAGE (CCS)
GOH KEAT BENG
UNIVERSITI TEKNIKAL MALAYSIA MELAKA
THE MACROPOROUS CERAMIC MATERIALS AS CARBON CAPTURE STORAGE (CCS)
GOH KEAT BENG
This report is submitted in fulfillment of the requirement for the award of Bachelor of Degree of Mechanical Engineering with Honours (Structure & Materials)
Faculty of Mechanical Engineering Universiti Teknikal Malaysia Melaka
MAY 2013
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DECLARATION
“I hereby declare that the work in this report is my own except for summaries and quotations which have been duly acknowledged.”
Signature: Author: Date:
...................................... GOH KEAT BENG ......................................
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This project is dedicated to my loving mother who has always giving me moral support during the times I was developing the material and finishing the project. She has never failed to constantly encourage me even when she was busy with her own agenda. I would also like to dedicate this work to my brother for the financial supports he had given to me. Last but not least, I would like express a token of appreciation to my supportive friends who had provided me with useful advises to accomplish the project. Thanks to them for their love and patience they had given to me in achieving my goal.
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ACKNOWLEDGEMENT
I wish to express my thanks and appreciation to my supervisor, Dr. Hady Efendy for his guidance and unfailing patience. He has contributed towards my understanding and knowledge in the field of macroporous ceramic materials. I am also most grateful for his advices and motivation.
I would like to express my gratitude to the panels of this project, Dr. Haryanti Samekto and Mr.Kamarul Ariffin bin Zakaria for their feedback regarding this project. I would also like to express my appreciation to the technicians involved in assisting the practical experiments in the process of developing macroporous ceramic materials. Without their time, the macroporous porous ceramic materials would not have been accomplished.
I would like to express a special word of thanks to my friends who providing cooperation and transport during the lab and experimental session. Last but not least, I wish to express an appreciation to my beloved parents and family for their financial and moral support.
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ABSTRAK
Pemanasan global merujuk kepada peningkatan purata suhu di atmosfera permukaan bumi. Salah satu punca yang mencetuskan pemanasan global adalah kandungan karbon dioksida (CO2) yang berlebihan di atmosfera. Maka, objektif projek ini adalah menghasilkan bahan seramik berongga sebagai carbon capture storage (CCS) untuk menapis CO2. Akan tetapi, sifat-sifat seperti ketumpatan dan kekuatan mampatan bahan seramik berongga masih tidak diketahui. Bahan seramik berongga diperbuat daripada campuran komposisi simen, serbuk aluminum, alumina (Al2O3), kalsium oksida (CaO), gipsum (kalsium sulfat dihidrat, CaSO4.2H2O), serbuk silika dan air suling (H2O) yang sesuai. Komposisi bahan seramik berongga yang berlainan telah dihasilkan iaitu 2wt%, 3wt% dan 4wt% serbuk aluminium. Sifat mekanikal dan struktur keronggaan makro bahan seramik berongga tersebut dianalisis dan dibanding. Sifat-sifat optimum bahan seramik berongga telah ditentukan pada 3wt% serbuk aluminium dan menurun secara drastik pada 4wt%. Fenomena ini disebabkan oleh tindak balas kimia antara serbuk aluminium dan air suling di mana aluminium oksida yang meningkatkan kekuatan bahan seramik berongga terhasil, walau bagaimanapun pada masa yang sama, kuantiti liang yang tinggi juga terbentuk pada kadar tindak balas yang tinggi antara kedua-dua bahan asas tersebut.
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ABSTRACT
Global warming refers to the increase in average temperature of the atmosphere near the earth’s surface. One of the main causes that trigger global warming is the excessive content of carbon dioxide (CO2) in the atmosphere. Therefore, the objective of this project is to produce a porous ceramic material as a carbon capture storage (CCS) to adsorb CO2. However, the properties such as density and compressive strength of the porous ceramic material are unknown. The porous ceramic material is developed by mixing an appropriate composition of cement, aluminum powder (Al), alumina (Al2O3), calcium oxide (CaO), gypsum (calcium sulfate dehydrate, CaSO4.2H2O), silica powder and deionized (DI) water. Different compositions of porous ceramic were produced at 2wt%, 3wt% and 4wt% of aluminium powder. Their mechanical properties and macroporosity structural of the porous ceramic material were analyzed and compared. It is determined that the optimal properties of porous ceramic material were found at 3wt% of aluminium powder and degraded drastically at 4wt%. This phenomenon is due to the chemical reaction between the aluminium powder and DI water in which they form aluminium oxide that promotes the strength of the material but at the same time, more pores are created at higher reaction rate between these two fundamental materials.
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TABLE OF CONTENTS
CHAPTER
CHAPTER 1
CHAPTER 2
CONTENT
PAGE
DECLARATION
ii
DEDICATION
iii
ACKNOWLEDGEMENT
iv
ABSTRAK
v
ABSTRACT
vi
TABLE OF CONTENT
vii
LIST OF TABLES
x
LIST OF FIGURES
xi
LIST OF SYMBOLS
xiv
LIST OF APPENDICES
xv
INTRODUCTION
1
1.0
Introduction
1
1.1
Problem Statement
3
1.2
Objectives
3
1.3
Scope of Research
4
LITERATURE REVIEW
5
2.0
Literature Review
5
2.1
Porous Ceramics
6
2.2
The Mechanical Properties of Macroporous Ceramic Material Fabrication of Macroporous Materials
7
2.3
8
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2.3.1 The Replica Technique
2.4
2.5
CHAPTER 3
9
2.3.1.1 Natural Replica Templates
9
2.3.1.2 Synthetic Replica Templates
10
2.3.2 Sacrificial Template Technique
10
2.3.3 Direct Forming Technique
11
Applications of Macroporous Ceramic Materials As Carbon Capture 2.4.1 Carbonation Process
11
2.4.2 Calcination Process
13
Determination of Raw Materials
14
2.5.1 Alumina
14
12
2.5.1.1 Elastic Properties of Alumina
15
2.5.1.2 Thermal Properties of Alumina
16
2.5.2 Cement
16
2.5.3 Aluminum Powder
17
2.5.4 Calcium Oxide
18
2.5.5 Gypsum
19
2.5.6 Silica Powder
21
2.5.7 Deionized (DI) Water
21
METHODOLOGY
22
3.0
Methodology
22
3.1
Problem Identification
23
3.2
Materials Research
23
3.3
Raw Materials Preparation
24
3.4
Development of Macroporous Ceramic Material Characterization of Macroporous Ceramic Material Analysis of Micro and Macrostructure of Porous Ceramic Material
24
3.5 3.6
26 28
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CHAPTER 4
RESULTS
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4.0
Results
29
4.1
Determination of Density of Macro Porous Ceramic Material Analysis of Micro and Macro Structure of Macro Porous Ceramic Material Compressive Strength Testing of Macro Porous Ceramic Material
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4.2 4.3
CHAPTER 5
CHAPTER 6
32 35
DISCUSSION
41
5.0
Discussion
41
5.1
Density
42
5.2
Macro and Micro Structure
43
5.3
Compressive Strength Testing
45
CONCLUSION AND RECOMMENDATION
48
6.0
Conclusion
48
6.1
Recommendation
49
REFERENCES
50
APPENDICES
54
x
LIST OF TABLES
TITLE
TABLE
2.1
Typical Values of Elastic Properties at Room Temperature for
PAGE
15
Engineering Alumina Ceramics According to Porosity Level 2.2
Typical Values of Thermal Expansion Coefficient, Specific Heat,
16
Enthalpy and Thermal Conductivity at Room Temperature 3.1
Compositions of Raw Materials
25
4.1
Density of Porous Ceramic Material in 2%wt, 3%wt and 4%wt of
31
Aluminium Powder. 4.2
Average Compressive Strength (MPa) for 2wt%, 3wt% and 4wt% of Aluminium Powder by Calculation.
40
xi
LIST OF FIGURES
FIGURE
2.1
TITLE
Three Possible Techniques for Making Macro Porous Materials: The
PAGE
8
Replica, The Sacrificial Template and The Direct Forming 2.2
Processing Steps to Transform Cellular Wood Structures into Porous
9
Ceramics 2.3
Operate Modes of the Swing Adsorption Process
12
2.4
Equilibrium of Pure CaCO3 above CO2 Partial Pressure as a
13
Function of the Temperature 2.5
Alumina Powder
15
2.6
Cement Powder
17
2.7
Aluminum Powder
18
2.8
Calcium Oxide
18
2.9
Projection of the γ-CaSO4 structure Illustrating the Sulfate
19
Tetrahedral and the Channels Developed Parallel to c 2.10
Projection of the γ-CaSO4 Structure Illustrating the Relationship
20
between the Hexagonal and Monoclinic (γ = 90°) Unit Cells of γCaSO4 and Hemihydrates 2.11
Gypsum Powder
20
2.12
Silica Powder
21
3.1
Flow Chart of Methodology
22
3.2
Deposited Mixture in Mold Containers
25
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3.3
Measuring The Diameter of Macro Porous Ceramic Material Using
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Digital Vernier Caliper 3.4
Measuring The Height of Macro Porous Ceramic Material Using
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Digital Vernier Caliper 3.5
Weighing Macro Porous Ceramic Material Using Digital Weighing
27
Scale 4.1
Graph of Density of Porous Ceramic at 2wt%, 3wt% and 4wt% of
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Aluminium Powder 4.2
Top Surface for 3wt% Aluminium Powder at 50x Magnification
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4.3
Side Surface for 3wt% Aluminium Powder at 50x Magnification
33
4.4
Bottom Surface for 3wt% Aluminium Powder at 50x Magnification
33
4.5
2wt% Aluminium Powder at 200x Magnification
33
4.6
3wt% Aluminium Powder at 200x Magnification
34
4.7
4wt% Aluminium Powder at 200x Magnification
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4.8
Comparison of Average Compressive Strength (MPa) Vs Average
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Compressive Extension (mm) for Porous Ceramic Material between 2wt%, 3wt% and 4wt% of Aluminium Powder 4.9
Graph of Compressive Load (N) Against Compressive Extension
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(mm) for 2wt% Aluminium Powder Sample 1 4.10
Graph of Compressive Load (N) Against Compressive Extension
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(mm) for 2wt% Aluminium Powder Sample 2 4.11
Graph of Compressive Load (N) Against Compressive Extension
36
(mm) for 2wt% Aluminium Powder Sample 3 4.12
Graph of Compressive Load (N) Against Compressive Extension
37
(mm) for 3wt% Aluminium Powder Sample 1 4.13
Graph of Compressive Load (N) Against Compressive Extension
37
(mm) for 3wt% Aluminium Powder Sample 2 4.14
Graph of Compressive Load (N) Against Compressive Extension
37
(mm) for 3wt% Aluminium Powder Sample 3 4.15
Graph of Compressive Load (N) Against Compressive Extension (mm) for 4wt% Aluminium Powder Sample 1
38
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4.16
Graph of Compressive Load (N) Against Compressive Extension
38
(mm) for 4wt% Aluminium Powder Sample 2 4.17
Graph of Compressive Load (N) Against Compressive Extension
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(mm) for 4wt% Aluminium Powder Sample 3 4.18
Graph of Average Compressive Load (N) Against Average
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Compressive Extension (mm) 5.1
Influence of Sintering Temperature on Porosities and Density
43
5.2
Pore Size Distribution of the Samples Sintered at 1300 ˚C, 1400 ˚C
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and 1500 ˚C 5.3
Influence of Sintering Temperature on Compressive Strength
47
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LIST OF SYMBOLS
KIC
-
Fracture Toughnessm Mpa.m1/2
E
-
Young Modulus, Gpa
σ
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Compressive Strength, Mpa
P
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Compressive Load, N
A
-
Cross-Sectional Area, m2
T
-
Temperature, °C
D
-
Diameter, m
h
-
Height, m
V
-
Volume, m3
ρ
-
Density, kgm-3
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LIST OF APPENDICES
APPENDIX
TITLE
PAGE
1
PSM 2 Gantt Chart
54
2
Porous Ceramic Material
55
3
Dino Lite Digital Microscope
55
4
Universal Strength Test Machine Instron 5585
56
1
CHAPTER 1
INTRODUCTION
1.0
INTRODUCTION Carbon dioxide (CO2) is a colorless and odorless gas found within the earth’s
atmosphere. It is a product of combustion and of respiration in which it is exhaled for the exchange of oxygen (O2) and is also an important gas utilized in the process of photosynthesis in plants. It is also very useful in extinguishing flames. CO2 is the most important greenhouse gases. It is emitted into the atmosphere whenever organic matter such as fuel is burned. The carbon in the organic matter reacts with air to produce CO2 and energy (Scottish Carbon Capture & Storage, 2012). One of the largest sources of CO2 emission are from fossil fuel powered power stations. According to recent studies, approximately 40% of all CO2 emission comes from power plants. Three types of polluting power plants are natural gas, coal and oil. Second largest CO2 contributor is the pollution emitted from cars. Traffic jam is the one of the simplest example to describe the large amount of CO2 emission into the atmosphere by cars. Longer traffic will cause higher CO2 emission into the atmosphere as the cars stay longer idly on the road. Third largest pollution comes from truck. It is less in volume compared to cars, but it makes up for a large portion of the earth’s pollution with each truck’s individual output of pollutants. The difference between cars and trucks is the type of fuel used to run. Trucks and other vehicles that carry large loads use diesel as their standard fuel, which is known to be less clean than gasoline (Christodoulou, G., 2007).
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Photosynthesis CO2 + H2O + sunlight CH2O + O2
O2 + CH2O
O2 + hydrocarbons
Respiration energy + H2O + CO2 Combustion energy + H2O + CO2
(Source: “The Greenhouse Effect and Global Warming”, The Columbia University) However, excessive CO2 in atmosphere can lead to undesired phenomenon called global warming. CO2 contributes as one of the greenhouse gases in the atmosphere that contribute the greenhouse effects around the globe. The largest contributing source of greenhouse gas is the burning of fossil fuels which leads to the emission of CO2. When sunlight propagates to the earth’s surface, some of the energy is absorbed and provides warmth that sustains life in the earth and most of the rest is radiated back to the atmosphere at a longer wavelength than the sun light. Some of these longer wavelengths are absorbed by the greenhouse gases in the atmosphere before they are lost to space. These greenhouse gases acts like a mirror and reflect some of the heat energy back to the earth. This reflective phenomenon is called the “greenhouse effect” (Time for change – Cause and effect of global warming, 2007). The phenomenon affects the comfort of human lives as well as raises the average temperature of the earth that results in flooding of low level areas. Therefore, preventive action should be taken to avoid the occurrence of this phenomenon. Porous ceramic materials can be used as carbon capture storage (CCS) by adsorbing carbon dioxide (CO2) and carbon monoxide (CO). The initial use of ceramic was originated from the Greek word “keramikos”, meaning fired clay. During the olden days, pores have been avoided to increase crack resistance, but as an increasing number of application that require porous ceramic have emerged in the last decades (Andersson, L., 2011).
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The efficiency of adsorbing CO2 and CO is highly dependent of the material composition used to form the porous ceramic material. Aluminum powder with addictive can absorb CO2 and CO at normal temperatures. Alumina will be formed by the reaction between aluminum and oxygen at high temperatures and thus the porous ceramic material can be used at high temperatures since the melting point of alumina product is extremely high. Calcium oxide (CaO) can be utilized to absorb CO2 at high temperature (600°C - 700°C) through carbonation reaction (Yin, J, et al. 2012).
1.1
PROBLEM STATEMENT Excessive carbon dioxide (CO2) in the atmosphere can lead to global warming
through increased greenhouse effect. Thus, macro porous ceramic material is introduced to filter the CO2 emitted by power plants and vehicles. It has a high potential in absorbing CO2 in a wide range of temperature and it is able to withstand corrosive environment (Yin, J, et al. 2012). However, the sustainability of the ceramic material to endure physical and mechanical failures in term of stresses is still unidentified. Pores are also necessary for the ceramic material to absorb CO2 effectively. Therefore, the purpose of this project is to determine the optimum properties in between the mechanical properties and microstructure of the macro porous ceramic material for its application in CO2 absorption.
1.2
OBJECTIVES The objectives in this project are to research an alternative solution to solve the
phenomenon of global warming. Therefore, the three main objectives of the project are: 1. To produce a porous ceramic material. 2. To test and determine the mechanical properties of porous ceramic product. 3. To analyze a macro and micro structure of porous ceramic material.
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1.3
SCOPE OF RESEARCH This research is to establish suitable characterization methods for the macro
porous aluminum materials. It is conducted to study how macro and micro-porosity can be combined as ceramic bulk materials and how these materials can be used as hierarchically structure absorbents for carbon dioxide (CO2) separation.
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CHAPTER 2
LITERATURE REVIEW
2.0
LITERATURE REVIEW This chapter describes the research conducted via sources from journals which
includes a brief introduction of porous ceramics, fabricating process of macroporous ceramic material, properties of the ceramic and effectiveness of the material in CO2 absorption application as well as appropriate mixture of raw materials to obtain the optimum properties of the ceramic material. There are three distinctive techniques in fabricating the porous ceramics in which they are replica method, sacrificial template and direct foaming. The strength and the efficiency of the porous ceramic material in CO2 absorption are highly dependent on its microstructure. Pores are required in CO2 absorption but it also determines the strength of the ceramic material. Therefore, the mechanical properties of the porous ceramic are to be experimented thoroughly to establish a favourable relationship in between the porosity and the density in order to obtain the optimum strength of the porous ceramic material.
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2.1
POROUS CERAMICS Porous ceramics are recently being studied for its application in various
industries such as filters, high-temperature thermal insulation, supports for catalysts and bone substitutes (Khattab, R.M. et. al. 2012). The application of porous ceramics depends on its characteristics and permeability. It usually has low density due to the pores distribution in the structure of ceramics which contributes to its high permeability. There are two types of pores in porous ceramic material. One of them is reticulate or open-celled structure, where the structure consists of interconnected voids surrounded by a web of ceramic. The other one is called foam or closed-cell structure, where the voids are closed and there no is linkage within the continuous ceramic matrix (Surabhi, S., 2012). According to IUPAC, ceramics can be divided into three categories based on the pore sizes. They are micro, meso and macro. The size of pores for microporous ceramics is less than 2 nm, mesoporous ceramics within the range of 2 nm to 50 nm and macroporous ceramics with pores greater than 50 nm (Pekor, C.M., 2003). One of the basic materials in forming porous ceramics is alumina (Al2O3). Alumina is generally chosen as a basic material because it possesses good mechanical and thermal properties, as well as inert to most chemical attacks. Porous alumina materials are used in various forms. For example, polymeric foams are used for packing and porous ceramics are used in water purification (Surabhi, S., 2012). Traditionally, pores are avoided in ceramic materials because they reduce the material’s strength due to their brittleness. However, in the past few decades, applications that require porous ceramics have surfaced where aggressive environment such as corrosive and high temperatures which induce excessive wear are involved (Surabhi, S., 2012). Porous ceramics which contain alumina are usually used in situations that engage with harsh environments due to its high stability to acidic or alkaline conditions. Its inert nature provides a high corrosion resistance; enabling the porous ceramic materials in application that involves chemical reactions. Alumina based porous ceramics also possesses high melting point. Therefore, it has not only relatively good mechanical properties and chemical stability; it is also applicable in mechanism that involves extreme temperature such as high-temperature thermal insulation, filtration
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of gases from vehicle exhausts and filtration in hot corrosive gases in various industrial applications ( Surabhi, S., 2012).
2.2
THE MECHANICAL PROPERTIES OF MACROPOROUS CERAMIC MATERIAL Compared to metal and polymer foams, macroporous ceramics are lightweight
materials with high specific strength. In the ceramic materials, the components can be classified into struts and vertices. Struts are the walls separating the pore space either the pores are interconnected or isolated. Vertices are the spots where the struts join (Andersson, L., 2011). According to Gaiye Li, Yiqun Fan, Yuan Zheng and Yuping Wu, 2010, the fracture toughness, KIC for alumina ceramics is generally within the range of 0.3 – 0.5 Mpa.m1/2. It is dependent of the contents of pores or pore distribution per unit area. Therefore, addictives such as aluminum powder or Yttria-Stabilized Zirconia powder (YSZ) with suitable portions can be added to improve the fracture toughness. By directed metal oxidation method, Al/Al2O3 exhibits a fracture toughness of 9.5 Mpa.m1/2. Fracture toughness of 5.8 Mpa.m1/2 and bending strength of 760 Mpa are shown by Al/Al2O3 through gas pressure metal infiltration method. According to Linnea Andersson, 2011, the strength of macroporous ceramic materials increases with increasing density. This statement can be represented by the models developed by Gibson and Ashby, 1988: =C This experimental model indicates that the Young Modulus E of a macroporous material is related to the apparent density. Es denotes the modulus of the solid material, C denotes a constant and n represents an empirically determined exponent. The models are capable to predict the mechanical properties and behavior of macroporous materials (Andersson, L., 2011).
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2.3
FABRICATION OF MACROPOROUS CERAMICS Porous ceramics which are usually more durable in harsh environments have
triggered a new challenge to several industries in the development of porous ceramic materials. As the demand for porous ceramics in industrial applications keep emerging, several technologies have developed to fabricate these porous ceramics. It is critical to identify which method to be used to fabricate porous ceramic materials as their properties and pore characteristics are generally dependent of fabrication techniques. There are three different fabrication methods for producing highly porous macroporous ceramics which are the replica technique, the sacrificial template and direct foaming methods (Andersson, L.,2011).
Figure 2.1: Three Possible Techniques for Making Macro Porous Materials: The Replica, The Sacrificial Template and The Direct Forming. (Source: Andersson, L., 2011)