Twinning Project IL/11 Implementation and Strengthening the Environmental Framework for IPPC, Resource Efficiency and Eco-Management in Israel
Excel Template for EN 14181
Dr. Joachim Peschke, HH-HU Dr. Dominik Wildanger, HLNUG
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Twinning Project IL/11 Implementation and Strengthening the Environmental Framework for IPPC, Resource Efficiency and Eco-Management in Israel
Scope • Excel Template for Calculations that are part of EN 14181 • The template is not a report! An EN 14181 report has to provide additional information • The following calculations are featured: • • • • •
Determination of the best sampling point according EN 15259 QAL2 – Determination an validation of the calibration function AST – Verification of the calibration function AST – Linearity check of the AMS QAL3 – Shewart Card
• Goal: Comparison with lab’s template 2
Twinning Project IL/11 Implementation and Strengthening the Environmental Framework for IPPC, Resource Efficiency and Eco-Management in Israel
Determination of the best sampling point Best available measurement point in the measurement plane for the AMS (8.4, EN 15259) Industrial Site: Emission Source: Date :
Powerplant
Oxygen content
NO x Axis ‐ depth
Axis 1 ‐ 0,16 m Axis 1 ‐ 0,47 m Axis 1 ‐ 0,78 m Axis 1 ‐ 1,09 m Axis 2 ‐ 0,16 m Axis 2 ‐ 0,47 m Axis 2 ‐ 0,78 m Axis 2 ‐ 1,09 m Axis 3 ‐ 0,16 m Axis 3 ‐ 0,47 m Axis 3 ‐ 0,78 m Axis 3 ‐ 1,09 m Axis 4 ‐ 0,16 m Axis 4 ‐ 0,47 m Axis 4 ‐ 0,78 m Axis 4 ‐ 1,09 m Min value Mean value
Temperature
Velocity
c grid
c ref
o grid
o ref
T grid
T ref
v grid
v ref
F rep
Info profile 1
mg/m³
mg/m³
%
%
°C
°C
m/s
m/s
%
abs (deviation)
516,0 542,0 540,0 554,0 429,0 497,0 505,0 480,0 440,0 467,0 492,0 496,0 460,0 445,0 466,0 447,0
492,0 501,0 499,0 504,0 493,0 489,0 486,0 463,0 468,0 474,0 472,0 474,0 467,0 447,0 455,0 445,0
7,8 7,6 7,9 7,9 10,5 8,6 8,3 8,3 9,4 9,2 8,6 8,7 9,4 9,1 9,0 9,0
8,6 8,7 8,8 8,8 8,9 8,8 8,8 8,7 8,7 8,9 8,8 8,9 8,9 8,8 8,8 8,8
362 373 380 376 343 355 373 364 332 339 364 361 333 335 347 341
346 346 346 346 346 344 344 344 342 343 342 342 341 341 341 341
27,2 28,9 29,3 30,3 16,9 29,0 30,3 27,1 5,7 21,5 31,2 29,7 7,1 20,0 28,3 27,2
20,3 20,5 19,9 23,1 19,6 19,5 20,5 20,5 20,3 23,0 21,0 21,2 21,7 21,0 20,6 20,8
126,2% 129,9% 135,1% 123,6% 87,2% 144,1% 136,1% 125,4% 28,8% 95,6% 143,2% 136,6% 34,4% 98,9% 140,6% 133,5%
486,0
476,8
8,7
8,8
354,9
343,4
24,4
20,8
114%
0,12 0,16 0,21 0,10 0,26 0,30 0,22 0,12 0,85 0,18 0,29 0,23 0,79 0,15 0,27 0,20 0,10 28%
Results Best sampling point Axis 1 ‐ 1,09 m Frep at the best available sampling point
123,6%
Ratios of measured values at the best available sampling point to mean value of all grid measurements for: NOx Oxygen content Temperature
o grid / o grid mean
90,7%
T grid / T grid mean
106,0%
Velocity
v grid / v grid mean
124,4%
c grid / c grid‐mean
114,0%
Basic data of the emission source Traverse points checked Measurement results and reference values Determination of the best sampling point 3
Twinning Project IL/11 Implementation and Strengthening the Environmental Framework for IPPC, Resource Efficiency and Eco-Management in Israel
QAL2 – Calibration Function QAL2 according EN 14181:2014 Component
NOx
SRM/AMS data ‐ AMS‐Conditions 350,00
Emission Limit Value (ELV) 300 mg/m³ 20 % of ELV 10,20 % of ELV
0 0
30,61 mg/m³ 6 vol.‐%
Reference oxygen
300,00
SRM‐value [mg/m³]
ELV and uncertainty
ELV (long‐term) Max. Uncertainty @ 95% confidence p
250,00 200,00
Diagrams
150,00 100,00
Standard Reference Method (SRM) 50,00
Method Chemiluminescence EN 14792 Standard 17 Number of measurements N 0,98 k ‐ value (App. I, EN 14181) t 0,95 (N ‐1) (App. I, EN 14181)
0,00 4,00
6,00
10,00
12,00
14,00
16,00
18,00
20,00
350
400
AMS‐signal [mA]
Automated Measurement System (AMS)
Calibration function
Reference Material
SRM/AMS data ‐ ELV‐Conditions
Type of Analyzer ENOX II AMS CEMS Serial No. 0815 Output Signal from 4,00 mA to 20,00 mA Measurement range from 0 mg/m³ to 405 mg/m³ Zero Offset (only Type B calibration) Z 4 mA Linear Regression
400 350
SRM‐value [mg/m³]
Analyzer data
8,00
SRM/AMS Pair
1,746
300 250 200 150 100 50
Calibration function and variability Reference material data pairs
Method Slope b Offset a Calibration Range from to Std. dev. calibration function s D
1
s D ≤k ∙ 0
Type A 22,53 (mg/m³)/(mA) ‐63,58 mg/m³ 0 mg/m³ 362,94 mg/m³ 26,23 mg/m³
0 0
50
100
150
200
250
300
AMS‐signal [mg/m³] SRM/AMS Pair
Calibration Function
Reference Material
Yes AMS / SRM Data pairs
xi
AMS measurements ŷi ŷ i,S
AMS cond. AMS cond.
No. i 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Date Start End [mA] [mg/m³] 27.09.2016 08:00 08:30 15,51 285,95 27.09.2016 10:00 10:30 8,46 127,04 27.09.2016 12:00 12:30 7,96 115,79 27.09.2016 13:30 14:00 10,52 173,38 27.09.2016 15:30 16:00 8,17 120,46 28.09.2016 08:30 09:00 6,45 81,79 28.09.2016 10:30 11:00 6,94 92,82 28.09.2016 12:30 13:00 11,00 184,37 28.09.2016 14:30 15:00 14,78 269,43 28.09.2016 16:30 17:00 8,73 133,09 01.10.2016 08:00 08:30 10,99 184,05 01.10.2016 09:30 10:00 11,76 201,48 01.10.2016 11:00 11:30 14,00 251,79 01.10.2016 12:30 13:00 14,60 265,31 01.10.2016 14:00 14:30 12,99 229,15 01.10.2016 15:00 15:30 11,42 193,68 01.10.2016 16:30 17:00 7,72 110,43
AMS conditons / determined by AMS T p c H2O c O2
Std. cond. + O2 reference
[mg/m³] 329,94 145,46 133,60 200,05 136,89 93,65 107,10 214,38 310,89 152,39 209,14 232,47 290,53 301,49 262,39 223,48 125,48
yi
SRM measurements y i,sz y i,S
AMS cond.
[°C] 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00
Std. cond.
AMS conditions / determined by SRM T p c H2O c O2
Std. cond. + O2 reference
[hPa] [vol.‐%] [vol.‐%] [mg/m³] [mg/m³] [mg/m³] 1013,25 0,00 8,00 287,00 287,00 333,72 1013,25 0,00 7,90 132,00 132,00 151,15 1013,25 0,00 8,00 147,00 147,00 170,93 1013,25 0,00 8,00 154,00 154,00 175,00 1013,25 0,00 7,80 123,00 123,00 141,92 1013,25 0,00 7,90 87,00 87,00 98,86 1013,25 0,00 8,00 67,00 67,00 76,72 1013,25 0,00 8,10 192,00 192,00 218,18 1013,25 0,00 8,00 298,00 298,00 338,64 1013,25 0,00 7,90 123,00 123,00 141,92 1013,25 0,00 7,80 139,00 139,00 157,95 1013,25 0,00 8,00 172,00 172,00 200,00 1013,25 0,00 8,00 256,00 256,00 286,57 1013,25 0,00 7,80 247,00 247,00 289,45 1013,25 0,00 7,90 266,00 266,00 302,27 1013,25 0,00 8,00 187,00 187,00 214,12 1013,25 0,00 7,80 143,00 143,00 165,00
[°C] 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00
[hPa] [vol.‐%] [vol.‐%] 1013,25 0,00 8,10 1013,25 0,00 7,90 1013,25 0,00 8,10 1013,25 0,00 7,80 1013,25 0,00 8,00 1013,25 0,00 7,80 1013,25 0,00 7,90 1013,25 0,00 7,80 1013,25 0,00 7,80 1013,25 0,00 8,00 1013,25 0,00 7,80 1013,25 0,00 8,10 1013,25 0,00 7,60 1013,25 0,00 8,20 1013,25 0,00 7,80 1013,25 0,00 7,90 1013,25 0,00 8,00
SRM / AMS data pairs
AMS / Reference material Data pairs ‐ Only Type C calibration!
xi
AMS measurements ŷi ŷ i,S
AMS cond. AMS cond.
No. i Date R1 R2
Start End
[mA]
[mg/m³]
AMS conditons / determined by AMS T p c H2O c O2
Std. cond. + O2 reference
[mg/m³]
yi
Reference Material y i,sz y i,S
AMS cond.
[°C]
Std. cond.
[hPa] [vol.‐%] [vol.‐%] [mg/m³] [mg/m³]
AMS conditions / determined by SRM T p c H2O c O2
Std. cond. + O2 reference
[mg/m³]
[°C]
[hPa] [vol.‐%] [vol.‐%]
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Twinning Project IL/11 Implementation and Strengthening the Environmental Framework for IPPC, Resource Efficiency and Eco-Management in Israel
AST Check of the calibration function AST according EN 14181:2014 Component
SRM/AMS data ‐ AMS‐Conditions
Emission Limit Value (ELV) ELV (long‐term) Max. Uncertainty @ 95% confidence p
350,00
300 mg/m³ 20 % of ELV 10,20 % of ELV
0 0
30,61 mg/m³ 6 vol.‐%
Reference oxygen
300,00
SRM‐value [mg/m³]
ELV and uncertainty
Nox
Diagrams
250,00 200,00 150,00 100,00
Standard Reference Method (SRM) 50,00
Method Standard Number of measurements N k ‐ value (App. I, EN 14181)
6 0,92
t 0,95 (N ‐1) (App. I, EN 14181)
2,132
0,00 4,00
6,00
10,00
12,00
14,00
16,00
18,00
20,00
300
350
400
AMS‐signal [mA] SRM/AMS Pair
Automated Measurement System (AMS)
Calibration function
SRM/AMS data ‐ ELV‐Conditions 400
Type of Analyzer Serial No. Output Signal from to Measurement range from to Zero Offset (only Type B calibration) Z
350
mA mA mg/m³ mg/m³ mA
Linear Regression
SRM‐value [mg/m³]
Analyzer data
8,00
300 250 200 150 100 50
Calibration function an variability
Slope b Offset a Calibration Range from to Std. dev. calibration function s D
22,53 (mg/m³)/(mA) ‐63,58 mg/m³ 0 mg/m³ 362,94 mg/m³ 94,87 mg/m³
s D ≤ 1.5 ∙ k ∙ 0
NO
|Ḋ |≤ t 0,95 (N ‐1) ∙ s D /√N + 0
Yes
0 0
50
100
150
200
250
AMS‐signal [mg/m³] SRM/AMS Pair
Calibration Function
AMS / SRM Data pairs
xi
AMS measurements ŷi ŷ i,S
AMS cond. AMS cond.
No. i
Date 1 2 3 4 5 6 7 8 9
Start End
[mA] [mg/m³] 5,60 62,61 8,54 128,86 11,23 189,48 5,78 66,67 6,78 89,20 15,00 274,43
AMS conditons / determined by AMS T p c H2O c O2
Std. cond. + O2 reference
[mg/m³] 62,61 128,86 189,48 66,67 89,20 274,43
yi
SRM measurements y i,sz y i,S
AMS cond.
[°C] 0,00 0,00 0,00 0,00 0,00 0,00
Std. cond.
AMS conditions / determined by SRM T p c H2O c O2
SRM / AMS data pairs
Std. cond. + O2 reference
[hPa] [vol.‐%] [vol.‐%] [mg/m³] [mg/m³] [mg/m³] 1013,25 0,00 6,00 112,61 112,61 112,61 1013,25 0,00 6,00 28,86 28,86 28,86 1013,25 0,00 6,00 289,48 289,48 289,48 1013,25 0,00 6,00 16,67 16,67 16,67 1013,25 0,00 6,00 189,20 189,20 189,20 1013,25 0,00 6,00 174,43 174,43 174,43
[°C] 0,00 0,00 0,00 0,00 0,00 0,00
[hPa] [vol.‐%] [vol.‐%] 1013,25 0,00 6,00 1013,25 0,00 6,00 1013,25 0,00 6,00 1013,25 0,00 6,00 1013,25 0,00 6,00 1013,25 0,00 6,00
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Twinning Project IL/11 Implementation and Strengthening the Environmental Framework for IPPC, Resource Efficiency and Eco-Management in Israel
AST – Linearity Check AST Linearity check according EN 14181:2014 Automated Measurement System (AMS) PG‐350E (Horiba 2) Type of analyzer G8UX9Y4U Serial number Raum 259 Place of installation 10.03.2016 Date of test 09:56 ‐ 11:18 Start and end time of test Fr Person in charge mg/m³ Measurement unit 300 Upper measurement range limit [mg/m³]
ID Konzentration
Reference Material Concentration yi
i
[mg/m³]
1 2 3 4 5 6 7 8 9 10 11 12
0 80 20 40 60 0
Average y z
Specs of the analyzer
AMS Average Readings Auxilliary Reading x i,1 Reading x i,2 Reading x i,3 ẋc S[Y i,j *(X i ‐X z )] [mg/m³] 0,30 76,00 23,00 46,00 48,00 1,70
[mg/m³]
[mg/m³]
[mg/m³]
0,30 78,00 23,00 54,00 49,00 2,10
33,33
Auxilliary (X i ‐X z )^2
[mg/m³]
0,40 67,00 22,00 48,00 45,00 2,20
0,33 73,67 22,67 49,33 47,33 2,00 ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐
‐33,33 10313,33 ‐906,67 986,67 3786,67 ‐200,00 0,00 0,00 0,00 0,00 0,00 0,00
Residuum dc
rel. Residuum d c,rel
Okay?
[mg/m³]
[%]
d c,rel
