CHEMICAL RESISTANCE TABLE
CHEMICAL RESISTANCE TABLE The following table gives qualitative information as to the resistance of PVDF (polyvinylidene fluoride), PP (polypropylene), and HDPE (high density polypropylene) to specific chemicals under various conditions. The values given correspond to the most accurate information available from raw materials suppliers of the specific resins, based upon testing results and other relevant literature. It should be emphasized that this data has been compiled for initial consultation purposes. The information is in no way intended to replace testing based on actual conditions. Also, the user should contact a competent corrosion expert (certified by NACE or with sufficient experience in these materials) to verify any recommendation or to interpret the tables. Furthermore, any special or unusual factors, including the length of time or level of stress in the system, should be taken into consideration. In all circumstances, the Engineering Department of Asahi /America, Inc. should be consulted to review and verify final recommendations.
CHEMICAL RESISTANCE The following abbreviations are used for concentrations in some cases where a specific numeric value is not given. VL — aqueous solution, percentage of mass less than 10% L — aqueous solution, percentage of mass higher than 10% GL — aqueous solution, saturated at 68° F (20° C) TR — minimum technically pure concentration H — commercially available concentration The following footnotes are used in the body of the table: 1. Penetration of HCI possible 2. Oxidizing 3. Penetration of HF possible 4. Medium might cause stress cracking 5. Penetration of HBr possible
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The following symbols are used in the table: –––––––––––
RESISTANT SYMBOL On the basis of the data, little or no effect on the material has been evident within the given range of pressure and temperature limits.
• • • • • • • CONDITIONALLY RESISTANT SYMBOL Suitability has to be checked in each individual case. Further testing may have to be performed to offer a specific recommendation. Please consult with the Engineering Department of Asahi /America for a specific recommendation. 0
NON-RESISTANT SYMBOL The material is generally regarded to be unsuitable. Therefore, the application is not recommended.
ASAHI /AMERICA Rev. EDG– 02/A
P.O. Box 653 • 35 Green Street, Malden, MA 02148 • Tel: (800) 343-3618, (781) 321-5409 Fax: (800) 426-7058 • Internet: http://www.asahi-america.com • Email:
[email protected]
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Disclaimer Asahi/America, Inc. provides this guide to assist engineers in the design of systems, installers in the installation and owners in the operation. This guide is designed to provide the best possible recommendations known at the time of printing. Each and every type of piping system is different and no one recommendation can cover all conditions. This guide is made available to assist in the design and installation, but in no way should be construed as a written recommendation on any system. Each system should be individually designed and installed based on the responsibility and decisions of the purchaser. This guide is not a substitute for contacting Asahi/America for specific recommendations on a system. In addition, Asahi/America is not responsible for items not appearing in the guide or recommendations that may have changed after the printing of this guide. It is recommended in each case to consult Asahi/America for specific recommendations on each system. Copyright 2002 Asahi /America, Inc. All rights reserved.
Printed in U.S.A.
CHEMICAL RESISTANCE ConcenMedium
40
100 Acetaldehyde and Acetic acid
90/10
Acetic acid aqueous
10
Acetic acid aqueous (glacial acetic acid) min 96 Acetic acid - ethyl ester (ethyl acetate)
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Temperature ° F
tration Material
Acetaldehyde
Acetic acid - methyl ester (methyl acetate) Acetic anhyhrid
TR
TR
TR Acetone GL
100 Acetophenone TR Acrylic acid ethylic ester
100
Acrylonitrile TR Adipic acid aqueous
GL
Air * TR Allyl alcohol (2-propen -1- ol)
96
Aluminium chloride GL Aluminium fluoride GL Aluminium sulphate GL Alums (metal(l)-and metal (III)-sulphates)
GL
CHEMICAL RESISTANCE TABLE
PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
68
104 140 176 212 248
0 ---------------------------------0 •••• •••• 0 •••• •••• --------------------------------------------------------------------------------------------- • • • • • • --------- • • • • • • • • --------- • • • • • • • • •••••••• --------- • • • • • • • • --------- • • • • • • • • ---------------------------------0 --------- • • • • • • • • ------------------• • • • 0 --------------------------------------------------0 ------------------------------------------------------------------- • • • • • • • • --------••••
•••• --------- • • • • ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
ConcenMedium
tration
Ammonia gas TR Ammonia liquid TR Ammonia solution aqueous (ammonia water) Ammonia aluminium sulphate (ammonia alum) Ammonia carbonate and ammonium hydrogen carbonate Ammonium chloride
33
L
GL
GL Ammonium iron (III) sulphate (iron alum)
L
Ammonium fluoride L Ammonium nitrate GL Ammonium phosphate
GL
Ammonium sulphide
L
Ammonium sulphate
GL
Amyl acetate TR Aniline hydrochloride aqueous Aniline pure
GL
TR Anone
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
TR Anthraquinone sulphone acid
GL
Anti-freezers (motor vehicles)
H
Antimony chloride aqueous
90
Aqua regia (HCI/HNO2)
75/25
Temperature ° F Material PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
68
104 140 176 212 248
---------------------- • • • • • • • • • • --------------------------------------------------0 ---------------------------------0 -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------•••• ----------------- • • • • ------------------------------------------------------------------••••••••••••
•••••••••••• ----------------- • • • • ----------------- • • • • • • • • ---------------------------------------------------------------------------------------------------------------------------------------------------------•••• 0 0
* Compressed air is not recommended for any system except Air-Pro.
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P.O. Box 653 • 35 Green Street, Malden, MA 02148 • Tel: (800) 343-3618, (781) 321-5409 Fax: (800) 426-7058 • Internet: http://www.asahi-america.com • Email:
[email protected]
ASAHI /AMERICA Rev. EDG– 02/A
CHEMICAL RESISTANCE TABLE
ConcenMedium Arsenic acid aqueous
tration
80
Barium carbonate GL Barium chloride GL Barium hydroxide GL Barium salts GL Barium sulphate GL Beater glue H Beer H Beer dye (sugar dye)
VL
Bees-wax H Benzaldehyde GL Benzene TR Benzine H Benzine - benzole mixture .
80/20
Benzoic acid GL Benzoyl chloride TR Benzyl alcohol TR Bisulphite lye containing SO2 Bleaching solution (sodium hypochloride) Boric acid aqueous
GL
20
GL
ASAHI /AMERICA Rev. EDG– 02/A
CHEMICAL RESISTANCE
Temperature ° F Material PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
68
104 140 176 212 248
-------------------------- • • • • • • • • ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------0 ---------------------------------------------------
ConcenMedium Borax, aqueous (sodium tetraborate) Bromine liquid
tration
GL
TR Bromine fumes TR Bromine5 (bromine water)
GL
Butadiene gas ---------------------------------------------------------------------
TR Butane gas
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
TR Butanediol aqueous
L
Butanediol TR Butanol (butyl alcohol)
TR
1,2,4-Butanetriol --------- • • • • • • • • ------------------ • • • • --------- • • • • • • • • • • • • ------------------------------------------- • • • • --------- • • • • • • • • •••• •••• --------------------------––––––– •••• --------- • • • • • • • •
TR 2-Butene-1,4-diol TR Butindiol TR Butyric acid (and isobutyric acid)
TR
Butylacetate •••• --------- • • • • • • • • --------------------------–––––––––––––– -----------------------------------------------------------• • • • • • • • • •••• ••••••••••••• ------------–––-• • • • • • • • • ---------• • • • • • • • • --------------–-- • • • • • ----------------------------------••••••••••••••••• ••••••••••••• •••• ------------------------------------------------------------------------------------------------------------------
TR Butylene liquid TR Butylene glycol (1,4-butanediol) aqueous Butylene glycol (ethylene glycol monobutyl ether) Butylphenol
TR
TR
GL Butylphenone GL Butylphthalate (dibutyphthalate)
TR
Temperature ° F Material PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
68
104 140 176 212 248
-------------------------------------------------------------------------------------------------------------------------------------------------0 0 -------------------------------------------0 0 -------------------------------------------•••• -------•••• •••• ---------------------------------
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------------------------------------------------------------------------------------------------------------ • • • • -----------------------------------------------------------------------------------------------------------------------••••••••••••••••• ------------------------ • • • • •••• •••• ••••
--------• • • • • • • • • ------------------------------------------------------------------------------0 --------- • • • • • • • • • • • • • • • • --------- • • • • • • • •
P.O. Box 653 • 35 Green Street, Malden, MA 02148 • Tel: (800) 343-3618, (781) 321-5409 Fax: (800) 426-7058 • Internet: http://www.asahi-america.com • Email:
[email protected]
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CHEMICAL RESISTANCE ConcenMedium
tration
Calcium carbonate
GL
Calcium chlorate GL Calcium chloride aqueous
GL
Calcium hydroxide GL Calcium hypochlorite (chloride of lime), aqueous Calcium nitrate aqueous
E
L
GL
Calcium sulphate GL Calcium sulphide VL Camphoric oil (Camphor oil)
TR
Carbolineum H Carbon monoxide gas
TR
Carbonic disulphide
TR
Carbon dioxide gas
TR
Carbonic acid aqueous
GL
Carbonic acid dry H Carbonic acid wet H Castor oil TR Caustic Lye aqueous 50 Caustic lye aqueous
L
Caustic soda (sodium hydroxide)
60
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CHEMICAL RESISTANCE TABLE
Concen-
Temperature ° F Material PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
68
104 140 176 212 248
-------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------• • • • • • • • • • • • • • • • • • •• ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------•••••••••••• ••••••••••••
Medium Chloracetic acid (mono), aqueous
L
Chloracetic acid (mono), aqueous
85
Chloral (trichlor acetaldehyde)
TR
Chloral hydrate TR Chloramine aqueous
H Chloroethane (ethyl chloride) 2-Chlorethanol (ethylenechlorohydrin)
TR
TR
1 Chloric acid aqueous
------------------------------------------------0 •••• --------------------------------------------------------------------------------------------------
L
Chlordiphenyl
0 0 ---------------
tration
10
20 Chloride or lime (slurry in water)
any
Chlorine liquid TR Chlorine gas, wet
--------------------------------
0.5
-------------------------------------------------
1 Chlorine gas, dry
-------------------------------------------------------------------------------------------------
TR Chlorine water (chlorine)
GL
Chlormethyl -----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
100 Chlorobenzene .
TR
Chloroform (trichloromethane)
TR
P.O. Box 653 • 35 Green Street, Malden, MA 02148 • Tel: (800) 343-3618, (781) 321-5409 Fax: (800) 426-7058 • Internet: http://www.asahi-america.com • Email:
[email protected]
Temperature ° F Material PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
68
104 140 176 212 248
----------------------------------------------------------------------------------------------------•••••••••• --------------------------------------------------•••• -----------------------------------------------------0 •••• ------------------------------------------------------------------------------------------–– --------- • • • • • • • • -----------------------------------------------------------------–– --------- • • • • • • • • ---------------------------------
----------------------------------------------------------------------0 0 ••••••••••••••••• •••• •••• ••••••••••••••••• 0 0 ----------------------------------0 •••• --------------------••••
0 --------------------• • • • • • • • • • • •••• •••• --------------------•••• ••••
ASAHI /AMERICA Rev. EDG– 02/A
CHEMICAL RESISTANCE TABLE
ConcenMedium
TR
Chrome alum aqueous
GL
TR
Chrome acid4) (chrome (VI)-oxide4)-) aqueous
20
40 Chromosulphuric acid Chromic acid/ sulphuric acid Citric acid
15/35/50
GL Citric acid aqueous VL Coconut butter alcohol
TR
Common salt aqueous
VL
Common salt (natrium chloride)
GL
Copper (II)-chloride GL Copper (II)-cyanide GL Copper fluoride aqueous
GL
Copper (II)-nitrate aqueous
30
Copper (II)-nitrate GL Copper (II)-sulphate GL Copper sulphate aqueous
GL
Cotton seed oil TR Cresol aqueous 32 Hydrocyanic acid
-------------------------------------––––––––– -------- • • • • • • • • -------- • • • • • • • • -------- • • • • • • • • ---------------- • • • •
L Hydrocyanic acid aqueous Hydrofluoric acid aqueous3)4)
TR
4
-------------------------------
40
---------------------------------------–-------------------------
60
-------- • • • • • • • • ---------------- • • • • ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------–– ----------------------------------------–-----------------------------------------–------------------------–– ----------------------------------------–------------------––––––––––––– --------------------------------------------------------------–-------------------------–------------------------–------------------------------------------------- • • • • • • • • -----------------------------------------------------------------------––––––– ----------------------------------------------------------------------- • • • • • • • • -------- • • • •
70 Hydrofluosilicic acid aqueous
32
40 Hydrogen bromide gas5) Hydrogen chloride gas wet and dry2)
TR
TR
Hydrogen gas TR Hydrogen peroxide aqueous
30
90 Hydrogen sulphide aqueous
Temperature ° F
tration Material
GL
PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
68
104 140 176 212 248
---------------------------- • • • • • • • • -------- • • • • • • • • -------------------------– ------------------------–••••••••••• -------------------------------------------------------------------------------- • • • • • • • • ------------------------------------------------------------------– ------------------------–- • • • • -------------------------– --------------------------------------–----------- • • • • • • • • • • • • --------------------------------------------------------------–----------------------------------------------------
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-----------------------------------------------------------------–--------------------------------------------------------------------------------------–----------------------------------- • • • • • • • • ---------------––––--------------------- • • • • -------- • • • • • • • • --------------------––––-------- • • • • • • • • -------- • • • • • • • • -------------------------------------------------------------------------------
---------------------------------------------------------------------------------------------------
-------------------------------------------------------- • • • • • • • • •••• •••• •••• -------------------------------------------------
P.O. Box 653 • 35 Green Street, Malden, MA 02148 • Tel: (800) 343-3618, (781) 321-5409 Fax: (800) 426-7058 • Internet: http://www.asahi-america.com • Email:
[email protected]
E-13
CHEMICAL RESISTANCE ConcenMedium Hydrogen sulphide gas, dry Hydrogenhyposulphite aqueous Hydroquinone
VL
L Hydroquinone GL Hydroxylamine sulphate aqueous
≥12
Iodine, tincture H
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Iron (II)-chloride GL Iron (III)-chloride GL Iron (III)-nitrate L Iron (II)-sulphate GL Iron (III)-sulphate GL Isobutanol TR Isobutyric acid TR Isooctane TR Isopropyl alcohol TR Lactic acid TR Lactic acid aqueous
90
Lanolin (wool oil) H
:
Lead acetate aqueous
GL
Lead tetraethyl (tetraethyl lead)
TR
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Temperature ° F
tration Material
TR
CHEMICAL RESISTANCE TABLE
PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
68
104 140 176 212 248
ConcenMedium Light liquid paraffin
-------------------------------------------------
TR Lighting gas
-------------------------------------------------
H Linseed oil
--------------- • • • • --------------- • • • • -------------------------------------------------------------------------- • • • • • • • • ----------------- • • • • --------------------------------------–-----------------------------––––––– -----------------------------------------------------------------–------------------------------––––––– -----------------------------------------------------------------–------------------------------––––––– -----------------------------------------------------------------–-----------------------------–––––– -------------------------------------------------------------------------------------------------------------------–––––––------------------------------------------ • • • • • • • • • • • • • • • • ------------------------••••••••••••• --------------- • • • • • • • • --------––––––––––––––––––––––––– -------- • • • • • • • • -------- • • • • • • • • -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
H Liquid ammonia (ammonia water)
GL
Magnesium carbonate
GL
Magnesium chloride aqueous
GL
Magnesium hydroxide
GL
Magnesium hydroxide carbonate
GL
Magnesium nitrate GL Magnesium salts GL Magnesium sulphate aqueous
GL
Maize seed oil TR Malic acid aqueous GL Menthol TR Mercury TR Mercury (II)-chloride GL Mercury (II)-cyanide GL Mercury (II)-nitrate
-------- • • • • • • • • -------- • • • • • • • • -------------------------------------------------------------------- • • • • • • • • ---------------------------------------
L Mercury salts GL Methane bromide (methyl bromide)
Temperature ° F
tration Material
TR
PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
P.O. Box 653 • 35 Green Street, Malden, MA 02148 • Tel: (800) 343-3618, (781) 321-5409 Fax: (800) 426-7058 • Internet: http://www.asahi-america.com • Email:
[email protected]
68
104 140 176 212 248
-------- • • • • • • • • -------- • • • • • • • • -----------------------------------------------------–---------------------------------------------------0 ---------------------------------------------------------------------------------------–------------------------------------------–------------------------------------------------------------------–----––––––– ---------------------------------------------------------------------------------------–--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------–--------------------------------------------------------------------------------------------------------– ------------------------------------------------------------------ • • • • • • • • --------------------------------------------------– –––––– -------------------------------------------------------- • • • • • • • • ----------------- • • • • ------------------------------------------- • • • • -------------------------------------------------------------------------------------------– -------------------------------------------------------------------------------------------– -----------------------------------------------------------------------------------------–------------------------------------------------------------------------------------------------------------------------------------------–-0 0
ASAHI /AMERICA Rev. EDG– 02/A
CHEMICAL RESISTANCE TABLE
ConcenMedium
Methanesulphonic acid (methylsulphuric acid), aqueous
TR
≥50
>50 Methyl alcohol (methanol)
5%
Methylamine aqueous 32 Methoxybutanol TR Methoxybutyl alcohol TR Melhylbenzoin acids (Toluene acids)
GL
Methyl bromide TR Methyl chloride TR Methylene chloride (dichloromethane)
TR
Methyl ethyl ketone TR Milk H Mineral oil H Mineral water H Molasses H Naptha H Natural gas TR N,N-Dimethalformamide
TR
Nickel (II)-chloride GL
ASAHI /AMERICA Rev. EDG– 02/A
Temperature ° F
tration Material
Methanol (methyl alcohol)
CHEMICAL RESISTANCE
PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE PVDF PP HDPE
68
104 140 176 212 248
-------- • • • • • • ----------------------–-------------------------–-----------------------–--•••••••••••••••• -----------------------------–--•••• •••• -------–––––––- • • • • • • • • • • • • ------------------------------------------------•••• ---------------
ConcenMedium Nickel (II)-nitrate GL Nickel salts GL Nickel (II)-sulphate GL Nicotinic acid VL Nitric acid aqueous
VL
10-50
-------- • • • • • • • • -------- • • • • • • • •
>50