Chemical resistance of low density polyethylene (LDPE) Introduction The table in this document summarises data contained in technical report ISO/TR10358:1993 (E/F) (Plastic pipes and fittings – chemical-resistance classification table) (the Technical Report) issued by the International Organisation for Standards (ISO). The data were obtained from both practical experience and laboratory test results on the probable chemical resistance performance under normal conditions of low density polyethylene (LDPE). As noted in the Technical Report, the data in the table are based on values obtained by exposing the polyethylene test specimens in the relevant chemicals at 20C and 60C (at atmospheric pressure), followed by a determination of the tensile characteristics of the polyethylene and polypropylene test specimens. A “standardised” classification has been adopted in many countries, which are explained below in the “Symbols used to describe the chemicals” section. Based on the Technical Report, this document suggests the chemical resistance of low density polyethylene (LDPE). The information and data contained in this document should be used only as a general guideline on the possible use of the chemicals in contact with the specified polymers under normal conditions as detailed in the table. The data presented are not intended as guidance for any specific application, purpose or use. Normal conditions include the following: a) Temperatures of 20C and 60C; b) The absence of internal and external mechanical stress; and c) Good manufacturing principles and procedures. Symbols used for the chemical resistance of the materials S = Satisfactory L = Limited NS = Not Satisfactory Symbols used to describe the chemicals The chemicals are listed by their most customary names, including common and trade names, in alphabetical order. The concentration and/or the purity of each chemical is indicated in the table using the following symbols: Sat. sol. = Saturated aqueous solution, prepared at 20C. Sol. = Aqueous solution at a concentration higher than 10%, but not saturated. Dil. sol. = Dilute aqueous solution at a concentration equal to or less than 10 %. Work. Sol. = Working solution of the concentration usually used in the industry concerned, Susp. = Suspension of solid in a saturated solution at 20°C. tg = At least technical grade purity. tg-s = Technical grade, solid. tg-l = Technical grade, liquid. tg-g = Technical grade, gas. The concentrations are expressed as a percentage by mass at 20°C, unless otherwise stated.
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Chemical resistance of low density polyethylene (LDPE)
Chemical Acetaldehyde
Concentrations % 40 tg-l
Acetic_Acid
Up_to_10 10_to_40 50 40_to_60
Acetic_acid,_glacial
80 >_96
Acetic_anhydrique
tg-l
Acetone
tg-l
Acetophenone
tg-s
Acrylonitrile Adipic_acid Air Allyl_alcohol
tg-l Sat._sol._(1.4%) tg-g tg-l
Aluminum_chloride
Sat._sol.
Aluminum_fluoride
Susp.
Aluminum_hydroxide
Susp.
Aluminum_nitrate Aluminum_oxychloride
Sat._sol. Susp.
Aluminum_Potassium sulphate Aluminum_sulphate
Sat._sol. Sat._sol.
Ammonia,_acqueous
Sat._sol.
Ammonia,_dry_gas
tg-g
Ammonia,_liquid
tg-g
T°C 20 60 20 60 20 60 20 60 20 60 20 60 60 60 20 20 60 20 60 20 60 20 60 20 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S L S L S S S S S S S S L S L L L
S S S S S S S S S S S S S S S S S S S S S S S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Ammonium_acetate
Concentrations % Sat._Sol.
Ammonium_carbonate
Sat._Sol.
Ammonium_chloride
Sat._Sol.
Ammonium_fluoride
Up_to_20
Ammonium_hydrogen_carbonate
Sat._Sol.
Ammonium_metaphosphate
Sat._Sol.
Ammonium_nitrate
Sat._Sol.
Ammonium_persulphate
Sat._Sol.
Ammonium_phosphate
Sat._Sol.
Ammonium_sulphate
Sat._Sol.
Ammonium_sulphide
Sat._Sol.
Ammonium_thiocyanate
Sat._Sol.
Amyl_acetate
tg-l
Amyl_alcohol
tg-l
Amyl_chloride
tg-l
Aniline
Sat._Sol. tg-l
Antimony_(III)_chloride Apple_juice Aqua_regia
Sat._Sol. Work._Sol. HCl/HNO3_(3/1)
Arsenic_acid
Sat._Sol.
Barium_bromide
Sat._Sol.
Barium_carbonate
Susp.
Barium_chloride
Sat._Sol.
Barium_hydroxide
Sat._Sol.
Barium_sulphate
Susp.
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE
S S S S S S S S S S S S S S
S S S S S S S L S L
S L S S S NS NS S S S S S S S S S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Barium_sulphide Beer
Concentrations % Sat._Sol. Work._Sol.
Benzaldehyde
tg-l
Benzene
tg-l
Benzoic_acid
Sat._Sol.
Benzoyl_chloride
tg-l
Benzyl_alcohol
tg-l
Bismuth_carbonate Borax
Sat._Sol. Sol. Sat._Sol.
Boric_acid
Dil._Sol. Sat._Sol.
Boron_trifluoride Bromine,_gas Bromine,_liquid Butane,_gas
Sat._Sol. tg-g tg-l tg-g
n-Butanol
tg-l
Butyl_acetate
tg-l
Butyl_glycol
tg-l
Butylphenols
Sat._Sol.
Butyl_phtalate
tg-l
Butyric_acid
tg-l
Calcium_carbonate
Susp.
Calcium_chlorate
Sat._Sol.
Calcium_chloride
Sat._Sol.
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S S S S L L L S S
S S S S S S S S S S S NS NS NS NS S S S S
S L S S S S S S
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Chemical resistance of low density polyethylene (LDPE)
Chemical Calcium_hydroxide
Concentrations % Sat._Sol.
Calcium_hypochlorite_Sol. Calcium_nitrate
Sat._Sol.
Calcium_sulphate
Susp.
Calcium_sulphide
Dil._Sol.
Calcium_hydrogen_sulphide Camphor_oil
Sol. tg-l
Carbon_dioxide,_tg-g dry_gas Carbon_dioxide,_tg-g wet_gas Carbon_disulphide
tg-l
Carbon_monoxide,_tg-g gas Carbon_tetrachloride
tg-l
Castor_oil
tg-l
Chlorine,_dry_gas Chlorine_water Chloroacetic_acid
tg-g Sat._Sol. Sol.
Chlorobenzene
tg-l
Chloroethanol
tg-l
Chloroform
tg-l
Chloromethane,_gas
tg-g
Chlorosulphonic_acid
tg-s
Chrome_alum (chromium_Potassium_sulphate)
Sol.
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S S S S S S S L L S S
S S S S L NS S S L NS
L NS L NS S S
NS NS L NS NS S S
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Chemical resistance of low density polyethylene (LDPE)
Chemical Chromic_acid
Concentrations % Sat._Sol. 20 40 50
Citric_acid Coconut_oil
Sat._Sol. Work._Sol.
Copper_(II)_chloride
Sat._Sol.
Copper_(II)_cyanide
Sat._Sol.
Copper_(II)_fluoride
Sat._Sol. 2
Copper_(II)_nitrate
Sat._Sol.
Copper_(II)_sulphate
Sat._Sol.
Corn_oil
Work._Sol.
Cottonseed_oil
Work._Sol.
Cresols
tg-l
Cresylic_acid
Sat._Sol.
Crotonaldehyde
Sat._Sol.
Cyclohexane Cyclohexanol
tg-l Sat._Sol. tg-s
Cyclohexanone
tg-l
Decalin
tg-l
Developers_(photographic)
Work._Sol.
Dextrin
Sol.
Dextrose
Sol.
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE
S L
S L S S
S S S S
S S S S S S
L
S S S L S L S S S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Dichloroacetic_acide
Concentrations % tg-l
Dichloroethylenes
tg-l
Diethylene_glycol
tg-l
Diisooctyl_phtalate
tg-l
Dimethylamine,_gas
tg-g
Dimethylformamide
tg-l
Dioctyl_phtalate
tg-l
Dioxane
tg-l
Ethanol
40 95 tg-l
Ethanolamine Ethyl_acetate Ethyl_chloride,_gas
tg-l tg-l tg-g
1,1_Ethylene_dichloride
tg-l
Ethylene_glycol
tg-l
Ethyl_ether
tg-l
Ferric_chloride
Sat._Sol.
Ferric_nitrate
Sat._Sol.
Ferric_sulphate
Sat._Sol.
Ferrous_chloride
Sat._Sol.
Ferrous_sulphate
Sat._Sol.
Fluorine_gas,_dry
tg-g
Fluorine_gas,_wet
tg-g
Fluosilicic_acid Formaldehyde
40 30_to_40
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE
S L S S S L L L
S NS
S S L S S S S S S S S S S NS NS NS NS S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Formic_acid
Concentrations % 10 40 50
Formic_acid
85_to_tg-l
Freon_-_F12
Work._Sol.
Fructose_Sol. Fruit_juice Furfuryl_alcohol
Work._Sol. tg-l
Gas,_manufactured
tg-g
Gas,_Natural,_dry
tg-g
Gas,_natural,_wet
tg-g
Gasoline_(fuel)
Work._Sol.
Gelatine_Sol. Glucose_Sol. Glycerine Glycolic_acid
tg-l Sol. 30
Grapefruit_juice Heptane Hexane
Work._Sol. tg-l tg-l
Honey
Work._Sol.
Horseradish
Work._Sol.
Hydrobromic_acid
Up_to_20 Up_to_48 50 tg-g
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S S S S S S S
S L S S S S S L S S S S S S S S
S S NS
S S S S S S S S S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Hydrochloric_acid
Concentrations % Up_to_10 20 10_to_20 Up_to_25 30 >_30 36 Conc.
Hydrochloric_acid,_wet_gas
tg-g
Hydrochloric_acid,_wet_gas
tg-g
Hydrocyanic_acid
10
Hydrofluoric_acid
Up_to_10 40
Hydrogen Hydrogen_peroxide
tg-g Up_to_10 30
Hydrogen_peroxide Hydrogen_sulphide,_dry_gas
90 tg-g
Hydroquinone
Sat._Sol.
Iodine_(in_potassium_iodide)
Sat._Sol.
Iodine,_in_alcohol
Work._Sol.
Isooctane
tg-l
Isopropyl_alcohol
tg-l
Isopropyl_ether
tg-l
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 60 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S S S S S S S S S S S S S S S
S S S S
S L S S S S S S S NS S S S S NS NS NS NS
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Chemical resistance of low density polyethylene (LDPE) Chemical Lactic_acid
Concentrations % 10
Magnesium_sulphate
Sat._Sol.
Maleic_acid
Sat._Sol.
Mayonnaise Mercuric_chloride
Work._Sol. Sat._Sol.
Mercurous_nitrate
Sol.
Mercurous_nitrate
Sol. Sat._Sol.
Mercury
tg-l
Methyl_acetate
tg-l
Methyl_alcohol
5 65
Methylamine Methyl_ethyl_ketone Methylene_chloride
Up_to_32 tg-l tg-l
Milk
Work._Sol.
Mineral_oils
Work._Sol.
Molasses
Work._Sol.
Mustard,_aqueous Naphtha
Work._Sol. Work._Sol.
Nickel_chloride
Sat._Sol.
Nickel_nitrate
Sat._Sol.
Nickel_sulphate
Sat._Sol.
Nicotinic_acid Nitric_acid
Susp. 5 10 20
T°C 20 100 20 60 20 60 20 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 20 60 20 60 20 60 20 60 20 60 20 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S S S S S S S S S S S S S S S
S S
S S S L S S S
S S S S S S S S S S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Nitric_acid
Concentrations % 25 30 35 40 Up_to_45 50 >_50
Nitric_acid,_fuming Nitrobenzene
tg-l
Oils_and_fats
tg-l
Oleic_acid
tg-l
Oleum Olive_oil Oxalic_acid
Work._Sol. Sat._Sol.
Oxygen,_gas
tg-g
Ozone,_gas
tg-g
Paraffin_oil_(F65)
tg-l
Peanut_oil
Work._Sol.
Peppermint_oil Perchloric_acid_(2N) Petroleum_ether_(ligroin)
Work._Sol. 20 Work._Sol.
Phenol
Sol. 5 90
Phosphine Phosphoric_acid
tg-g Up_to_50
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 20 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S
L NS NS NS NS NS
S L S S NS NS
S S S L L NS
S S
S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Phosphoric_acid
Concentrations % 50_to_75 25_to_85
Phosphorus_(III)_chloride
tg-l
Phosphorus_oxychloride
tg-l
Picric_acid
Sat._Sol.
Potassium_bicarbonate
Sat._Sol.
Potassium_bisulphate
Sat._Sol.
Potassium_borate
Sat._Sol.
Potassium_bromate
Sat._Sol. Up_to_10
Potassium_bromide
Sat._Sol.
Potassium_carbonate
Sat._Sol.
Potassium_chlorate
Sat._Sol.
Potassium_chloride
Sat._Sol.
Potassium_chromate
Sat._Sol. 40
Potassium_cyanide
Sol. Sat._Sol.
Potassium_dichromate
Sat._Sol. 40
Potassium_ferricyanide
Sat._Sol.
Potassium_fluoride
Sat._Sol.
Potassium_(II)_ferrocyanide
Sat._Sol.
Potassium_hydrogen
sulphite_Sol.
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE
S L
S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Potassium_hydroxide
Concentrations % Sol. 10
Potassium_hydroxide
20 Up_to_50
Potassium_hypochlorite
Sol.
Potassium_iodide
Sat._Sol.
Potassium_nitrate
Sat._Sol.
Potassium_orthophosphate
Sat._Sol.
Potassium_perchlorate
Sat._Sol.
Potassium_permanganate
20
Potassium_persulphate
Sat._Sol.
Potassium_sulphate
Sat._Sol.
Potassium_sulphide
Sat._Sol.
Potassium_sulphite
Sat._Sol.
Potassium_thiosulphate
Sat._Sol.
Propane,_gas Propionic_acid
tg-g 50 >_50 tg-l
Pyridine Salicylic_acid Silicne_oil
tg-l Sat._Sol. tg-l
Silver_acetate
Sat._Sol.
Silver_cyanide
Sat._Sol.
Silver_nitrate
Sat._Sol.
Sodium_acetate
Sat._Sol.
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 20 60 20 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S S S
S L
S S S S S S S S S S S S S S S S S S S S S L S L S S
S S S S S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Sodium_antimonate
Concentrations % Sat._Sol.
Sodium_arsenite
Sat._Sol.
Sodium_benzoate
Sat._Sol.
Sodium_bicarbonate
Sat._Sol.
Sodium_bisulphate
Sat._Sol.
Sodium_bromide
Sat._Sol.
Sodium_carbonate
Sat._Sol. 25 Up_to_50
Sodium_chlorate
Sat._Sol.
Sodium_chloride
Sat._Sol. 10
Sodium_chlorite
2 20
Sodium_chromate
Dil._Sol.
Sodium_cyanide
Sat._Sol.
Sodium_dichromate
Sat._Sol.
Sodium_ferricyanide
Sat._Sol.
Sodium_ferrocyanide
Sat._Sol.
Sodium_fluoride
Sat._Sol.
Sodium_hydrogen_sulphite
Sat._Sol.
Sodium_hydroxide
Sol. Sat._Sol. 1 10_to_35
T°C 20 60 20 60 20 60 35 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S S S S S S S S S S S S S S S S S S S S S S S S
S S S S S S S S S S S S S S S S
S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Sodium_hydroxide
Concentrations % 40 10_to_60
Sodium_hypchlorite
5 10_to_15
Sodium_hypchlorite
12.5%_Cl
Sodium_metaphosphate Sodium_nitrate
Sol. Sat._Sol.
Sodium_nitrite
Sat._Sol.
Sodium_perborate Sodium_phosphate,_acid
Sat._Sol. Sat._Sol.
Sodium_phosphate,_neutral
Sat._Sol.
Sodium_silicate
Sat._Sol.
Sodium_sulphate
Sat._Sol. 0,1
Sodium_sulphide
Sat._Sol.
Sodium_sulphite
Sat._Sol. 40
Sodium_thiosulphate Soybean_oil
Sat._Sol. Work._Sol.
Sulphur_dioxide,_dry_gas Suphur_dioxide,_wet_gas Sulphur_trioxide Sulphuric_acid
tg-l Up_to_10 15 10_to_30 10_to_50 50
T°C 20 60 20 60 20 60 20 60 20 60 20 20 60 20 60 20 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20
LLDPE S S
S S S S S S S S S S S S S S S S S S S S S S S S
S S
NS NS S S S S S S S S S
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Chemical resistance of low density polyethylene (LDPE) Chemical Sulphuric_acid
Concentrations % 50_to_75 50_to_90 75_to_90 95 96 98 Fuming
Sulphurous_acid
Up_to_30
Tannic_acid
Sol.
Tartaric_acid
Sol. Fuming
Tetrahydrofuran
tg-l
Tetralin
tg-l
Thionyl_chloride
tg-l
Tiophene
tg-l
Tin_(II)_chloride Tin_(IV)_chloride Toluene Trichloroacetic_acid
Sat._Sol. Sol. tg-l Up_to_50
Trichlorobenzene
Work._Sol.
Trichloroethylene
tg-l
Triethanolamine
Sol. tg-l
Turpentine
tg-l
T°C 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S S
S NS NS NS S S S S S S S S
NS NS
S S S S L NS
NS NS S L
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Chemical resistance of low density polyethylene (LDPE) Chemical Urea
Concentrations % Sol. Sat._Sol.
Urine Vegetable_oils Vinegar
tg-l Work._Sol.
Water Water,_brackish Water,_distilled Water,_fresh Water,_mineral
Work._Sol.
Water,_potable
Work._Sol.
Water,_sea Whiskey
Work._Sol.
Wine
Work._Sol.
Wines_and_spirits
Work._Sol.
Xylenes
tg-l
Yeast
Susp.
Zinc_carbonate
Susp.
Zinc_chloride
Sat._Sol. 58
Zinc_nitrate Zinc_oxide Zinc_sulphate
Sat._Sol. Susp. Sat._Sol.
T°C 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60 20 60
LLDPE S S
S S
S S S S S S S S S S S S S S S S S S S S S S L NS S S S S S S S S S S S S S S
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