Flash Professional Clean & Bleach Kitchen & Bathroom Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Date of issue: 26/08/2015
Revision date:
:
Version: 1.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
Product identifier
Product form
: Mixture
Trade name
: Flash Professional Clean & Bleach Kitchen & Bathroom
Product code
: PA00189306
Product group
: Trade product
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Main use category
: Professional use
Function or use category
: Washing and cleaning products (including solvent based products)
1.2.2.
Uses advised against
No additional information available 1.3.
Details of the supplier of the safety data sheet
Procter & Gamble UK Brooklands, Weybridge, Surrey, KT13 0XP, UK Tel: 01932 896000 Fax: 01932 896200 Professional:
[email protected] 1.4.
Emergency telephone number
Emergency number
: (UK) Emergency Tel: 0800 328 8304(IRL) Emergency Tel: 1800 509 497
SECTION 2: Hazards identification 2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Irrit. 2
H315
Eye Irrit. 2
H319
Aquatic Chronic 3 H412 Full text of H-statements: see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Xi; R36/37/38 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects No additional information available 2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP)
:
Signal word (CLP)
: Warning
Hazard statements (CLP)
: H315 - Causes skin irritation H319 - Causes serious eye irritation. H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP)
: P102 - Keep out of reach of children P101 - If medical advice is needed, have product container or label at hand P302+P352 - IF ON SKIN: Wash with plenty of water P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P501 - Dispose of contents/container to an appropriate local waste system P260 - Do not breathe spray
EUH-statements
: EUH206 - Warning! Do not use together with other products. May release dangerous gases (chlorine)
26/08/2015
EN (English)
1/8
Flash Professional Clean & Bleach Kitchen & Bathroom Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH)
2.3.
Other hazards
Other hazards not contributing to the classification
: No presence of PBT and vPvB ingredients.
SECTION 3: Composition/information on ingredients 3.1.
Substance
Not applicable 3.2.
Mixture
Name
Product identifier
%
Classification according to Directive 67/548/EEC
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Sodium nonyl sulphate
(CAS No) 1072-15-7 (EC no) 214-002-6
1-5
Xn; R22 Xi; R41 Xi; R38
Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 3, H412
Sodium Hypochlorite
(CAS No) 7681-52-9 (EC no) 231-668-3 (REACH-no) 01-2119488154-34
1-5
C; R34 R31 N; R50
Met. Corr. 1, H290 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic Acute 1, H400 (M=10) Aquatic Chronic 1, H410
Sodium Hydroxide
(CAS No) 1310-73-2 (EC no) 215-185-5 (EC index no) 011-002-00-6 (REACH-no) 01-2119457892-27
2000 mg/kg Sodium Hypochlorite (7681-52-9) LD50 dermal rabbit
20000 mg/kg OECD 402
Sodium nonyl sulphate (1072-15-7) LD50 oral rat LD50 dermal rat ATE CLP (oral) ATE CLP (dermal)
977 mg/kg 2001 mg/kg 977 mg/kg bodyweight 2001 mg/kg bodyweight
Skin corrosion/irritation
: Causes skin irritation.
Serious eye damage/irritation
: Causes serious eye irritation.
Respiratory or skin sensitisation
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
pH: 11.36 pH: 11.36
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: Not classified
Specific target organ toxicity (repeated exposure)
: Not classified
26/08/2015
EN (English)
5/8
Flash Professional Clean & Bleach Kitchen & Bathroom Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH)
Aspiration hazard
: Not classified
Potential Adverse human health effects and symptoms
: Acute Toxicity: based upon available data of the substances, classification criteria are not met. Carcinogenicity: based upon available data of the substances, classification criteria are not met. Corrosivity: based upon available data of the substances, classification criteria are not met. Irritation: moderately irritating to eyes. Irritation: moderately irritating to skin. Mutagenicity: based upon available data of the substances, classification criteria are not met. Repeated Dose Toxicity: based upon available data of the substances, classification criteria are not met. Sensitization: based upon available data of the substances, classification criteria are not met. Toxicity for Reproduction: based upon available data of the substances, classification criteria are not met.
Other information
: Likely routes of exposure: skin and eye. Information on Effects: refer to section 4.
SECTION 12: Ecological information 12.1.
Toxicity
Ecology - general
: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Sodium Hypochlorite (7681-52-9) LC50 fishes 1 LC50 other aquatic organisms 1 EC50 Daphnia 1 ErC50 (algae) NOEC (chronic) NOEC chronic fish NOEC chronic crustacea NOEC chronic algae
0.032 mg/l Coho salmon; 96 h 77.1 mg/l OECD 209; 3 h 0.035 mg/l OECD 202; Ceriodaphnia dubia; 48 h 0.0365 mg/l OECD 201; Pseudokirchneriella subcapitata; 72 h 41.1 mg/l OECD 209; 3 h 0.04 mg/l Menidia peninsulae; 28 d 0.007 mg/l 0.0054 mg/l OECD 201; Pseudokirchneriella subcapitata; 3 d
Sodium nonyl sulphate (1072-15-7) LC50 fishes 1 EC50 Daphnia 1 ErC50 (algae) LOEC (chronic) NOEC chronic fish NOEC chronic crustacea
13 mg/l 100 mg/l 8.64 mg/l 6.86 mg/l 1.357 mg/l 1.4 mg/l
Sodium Hydroxide (1310-73-2) EC50 Daphnia 1
40.4 mg/l Ceriodaphnia
12.2.
Persistence and degradability
Sodium nonyl sulphate (1072-15-7) Persistence and degradability Biodegradation 12.3.
The substance is biodegradable. Unlikely to persist. 90 %
Bioaccumulative potential
Sodium Hypochlorite (7681-52-9) Bioaccumulative potential
Not expected to bioaccumulate due to the low log Kow (log Kow < 4).
Sodium Hydroxide (1310-73-2) Bioaccumulative potential
Not measured.
12.4.
Mobility in soil
No additional information available 12.5.
Results of PBT and vPvB assessment
Flash Professional Clean & Bleach Kitchen & Bathroom Results of PBT assessment No presence of PBT and vPvB ingredients Component Sodium Hypochlorite (7681-52-9) Sodium Hydroxide (1310-73-2) 12.6.
Other adverse effects
Other information
26/08/2015
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII PBT: not relevant – no registration required vPvB: not relevant – no registration required
: No other effects known.
EN (English)
6/8
Flash Professional Clean & Bleach Kitchen & Bathroom Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH)
SECTION 13: Disposal considerations 13.1.
Waste treatment methods
13.1.1.
Regional legislation (waste)
: Disposal must be done according to official regulations.
13.1.2
Disposal recommendations
: The waste codes/waste designations below are in accordance with EWC. Waste must be delivered to an approved waste disposal company. The waste is to be kept separate from other types of waste until its disposal. Do not throw waste product into the sewer. Where possible recycling is preferred to disposal or incineration. . For handling waste, see measures described in section 7. Empty, uncleaned packaging need the same disposal considerations as filled packaging.
13.1.3
EURAL Waste code product
: 20 01 29* - detergents containing dangerous substances 15 01 10* - packaging containing residues of or contaminated by dangerous substances
SECTION 14: Transport information 14.1.
UN number
Not applicable 14.2.
UN proper shipping name
Not applicable 14.3. Transport hazard class(es) Not applicable 14.4.
Packing group
Not applicable 14.5.
Environmental hazards
Not applicable 14.6.
Special precautions for user
Not applicable 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
SECTION 15: Regulatory information Ingredient label
: