Revision Date 12-JAN-12 - rev. 02:01070 Revision 02 replaces 01:01070 Supersedes date 10-DEC-05

SAFETY DATA SHEET Knockout Kitchen and Bathroom Cleaner SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name

Knockout Kitchen and Bathroom Cleaner

1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against

Cleaning agent. for unblocking waste pipes. Any use other than those identified.

1.3. Details of the supplier of the safety data sheet Supplier

Barrettine Barrettine Works St Ivel Way Warmley Bristol BS30 8TY 0117 960 0060 0117 935 2437 [email protected]

1.4. Emergency telephone number 0870 190 6777

SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical and Chemical Not classified. Hazards Human health Skin Corr. 1A - H314 Environment Not classified. Classification (1999/45/EEC) C;R35. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Human health Corrosive. Prolonged contact causes serious eye and tissue damage. Environment Substantial amounts of the product may lead to a local change in acidity in small water systems which may have adverse effects on aquatic organisms.

2.2. Label elements Contains

SODIUM HYDROXIDE Label In Accordance With (EC) No. 1272/2008

Signal Word

Danger 1/ 7

Knockout Kitchen and Bathroom Cleaner Hazard Statements Precautionary Statements

H314

Causes severe skin burns and eye damage.

P101

If medical advice is needed, have product container or label at hand. Store locked up. Keep out of reach of children. Wear protective gloves, eye and face protection. If SWALLOWED: Do NOT induce vomiting. Get immediate medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing until no signs of contamination remain, Get medical advice/attention. Dispose of contents/container in accordance with national regulations.

P102+405 P280 P301+P331+P315 P305+351+338+313

P501 Supplementary Precautionary Statements P260 P303+361+353 P403+233

Do not breathe vapour/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep container tightly closed.

2.3. Other hazards SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures SODIUM HYDROXIDE CAS-No.: 1310-73-2

10-30% EC No.: 215-185-5

Classification (EC 1272/2008) Skin Corr. 1A - H314

Classification (67/548/EEC) C;R35

SODIUM HYPOCHLORITE SOLUTION, ... % Cl ACTIVE CAS-No.: 7681-52-9

14 @ 1%

Aqueous solution.

9.2. Other information Volatile Organic Compound (VOC)

0 % (EC/1999/13)

SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity The solution is strongly alkaline and reacts with strong acids with heat generation.

10.2. Chemical stability Stable under normal conditions of storage and use. See section 7.

10.3. Possibility of hazardous reactions Hazardous Polymerisation Will not polymerise.

10.4. Conditions to avoid Avoid contact with acids.

10.5. Incompatible materials Materials To Avoid Acids Oxidising agents. Aluminium.

10.6. Hazardous decomposition products None under normal conditions. Dangerous Reactions Avoid unintended contact with strong acids.

SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects

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Knockout Kitchen and Bathroom Cleaner Toxic Dose 1 - LD 50 40 mg/kg (oral rat) Toxicological information Health effects of this preparation have not been determined. Data given refer to the major component. Aspiration hazard: Inhalation May cause damage to mucous membranes in nose, throat, lungs and bronchial system. Ingestion Causes severe burns. May cause chemical burns in mouth and throat. Skin contact Causes severe burns. Eye contact Strongly corrosive. Causes severe burns and serious eye damage. Immediate first aid is imperative. May cause irreversible eye damage. Route of entry Skin absorption. Ingestion.

SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.

12.1. Toxicity Acute Fish Toxicity Discharge of large quantities may kill fish and other aquatic life due to excessive changes in water pH. Discharge of large amounts causes changes in pH which may affect effluent and sewage treatment processes. Acute Toxicity - Fish LC50 96 hours 145 mg/l Freshwater fish Data refers to the major component. Acute Toxicity - Aquatic Invertebrates EC50 76 mg/l Daphnia magna

12.2. Persistence and degradability Degradability The product solely consists of inorganic compounds which are not biodegradable.

12.3. Bioaccumulative potential Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

12.4. Mobility in soil Mobility: Stays dissolved in water. May be leached from the soil.

12.5. Results of PBT and vPvB assessment 12.6. Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS General information Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.

13.1. Waste treatment methods Product is intended as a household drain cleaner. Small quantities may be disposed of by emptying into the drain whilst carefully flushing away with running water. Larger quantities should be diposed of in accordance with local authority requirements. 5/ 7

Knockout Kitchen and Bathroom Cleaner SECTION 14: TRANSPORT INFORMATION 14.1. UN number UN No. (ADR/RID/ADN)

1824

UN No. (IMDG)

1824

UN No. (ICAO)

1824

14.2. UN proper shipping name Proper Shipping Name

SODIUM HYDROXIDE SOLUTION

14.3. Transport hazard class(es) ADR/RID/ADN Class

8

ADR/RID/ADN Class

Class 8: Corrosive substances.

ADR Label No.

8

IMDG Class

8

ICAO Class/Division

8

Transport Labels

CORROSIVE

8 14.4. Packing group ADR/RID/ADN Packing group

II

IMDG Packing group

II

ICAO Packing group

II

14.5. Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No.

14.6. Special precautions for user EMS

F-A, S-B

Emergency Action Code

2R

Hazard No. (ADR)

80

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 SI No 716. (CHIP4). Control of Substances Hazardous to Health Regulations (as amended). (COSHH) Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2007. (CDG 2009) Approved Code Of Practice The Control of Substances Hazardous to Health Regulations 2002 (as amended). Approved code of practice and guidance. Fifth Edition 2005. HSE Books, or download at: http://www.hse.gov.uk/pubns/priced/l5.pdf Approved classification and labelling guide L131 (Sixth Edition - 2009) Guidance Notes CHIP for everyone HSG(108). 6/ 7

Knockout Kitchen and Bathroom Cleaner Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. ADR (L’Accord européen relative au transport international des marchandises dangereuses par route.)

15.2. Chemical Safety Assessment No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION Revision Comments Comprehensive revision. GHS information added. Revision Date Revision Supersedes date Risk Phrases In Full R34 R35 R31 R50 Hazard Statements In Full H314 EUH031 H400

12-JAN-12 - rev. 02:01070 02 replaces 01:01070 10-DEC-05 Causes burns. Causes severe burns. Contact with acids liberates toxic gas. Very toxic to aquatic organisms. Causes severe skin burns and eye damage. Contact with acids liberates toxic gas. Very toxic to aquatic life.

Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 7/ 7