SIGMA-ALDRICH

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Version 5.2 Revision Date 18.05.2013 Print Date 05.06.2014 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1

1.2

Product identifiers Product name

:

Sodium fluoride

Product Number Brand Index-No. REACH No.

: : : :

CAS-No.

:

S6776 Sigma 009-004-00-7 A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. 7681-49-4

Relevant identified uses of the substance or mixture and uses advised against Identified uses

1.3

1.4

:

Laboratory chemicals, Manufacture of substances

Details of the supplier of the safety data sheet Company

:

Sigma-Aldrich Chemie GmbH Riedstrasse 2 D-89555 STEINHEIM

Telephone Fax E-mail address

: : :

+49 89-6513-1444 +49 7329-97-2319 [email protected]

Emergency telephone number Emergency Phone #

:

+49 7329-97-2323

SECTION 2: Hazards identification 2.1

Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 3), H301 Eye irritation (Category 2), H319 Skin irritation (Category 2), H315 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC T Toxic R25 Xi Irritant R36/38 R32 For the full text of the R-phrases mentioned in this Section, see Section 16.

2.2

Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word

Danger

Hazard statement(s) H301

Toxic if swallowed.

Sigma - S6776

Page 1 of 9

H315 H319

Causes skin irritation. Causes serious eye irritation.

Precautionary statement(s) P301 + P310

IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P305 + P351 + P338

Supplemental Hazard information (EU) EUH032 Contact with acids liberates very toxic gas. 2.3

Other hazards - none

SECTION 3: Composition/information on ingredients 3.1

Substances Formula Molecular Weight CAS-No. EC-No. Index-No.

: : : : :

FNa 41,99 g/mol 7681-49-4 231-667-8 009-004-00-7

Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Sodium fluoride CAS-No. EC-No. Index-No.

7681-49-4 231-667-8 009-004-00-7

Acute Tox. 3; Skin Irrit. 2; Eye Irrit. 2; H301, H315, H319, EUH032

Hazardous ingredients according to Directive 1999/45/EC Component Classification Sodium fluoride CAS-No. EC-No. Index-No.

7681-49-4 231-667-8 009-004-00-7

T, R25 - R32 - R36/38

Concentration