UNDERTAKING Product Name:

Virkon-S Page 1 of 9 Revision Date: 19/05/2016 Print Date: 13/06/16 SAFETY DATA SHEET According to Regulation (EC) 1907/2006 and 453/2010 This SDS ad...
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Virkon-S Page 1 of 9 Revision Date: 19/05/2016 Print Date: 13/06/16

SAFETY DATA SHEET According to Regulation (EC) 1907/2006 and 453/2010 This SDS adheres to the standards and regulatory requirements of Great Britain and may not meet the regulatory requirements in other countries.

VIRKONTM S 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name: VirkonTM S

Ref:

130000014173

Supplier:

Hugh Crane Cleaning Equipment Ltd South Walsham Road, Acle Norwich, NR13 3ES 01493 750072 Fax 01493 751854

Telephone:

Relevant Identified Uses of the Substance or Mixture and Uses Advised Against Use of the Substance/Mixture: Disinfectant. 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Skin Irritation, Category 2: H315 Serious Eye Damage, Category 1: H318 Chronic Aquatic Toxicity, Category 3: H412

Causes skin irritation. Causes serious eye damage. Harmful to aquatic life with long lasting effects.

Label Elements

Hazard Statements:

Special Labelling of Certain Substances and Mixtures:

Danger H315 Causes skin irritation. H318 Causes serious eye damage. H412 Harmful to aquatic life with long lasting effects Contains: Dipotassium peroxodisulphate, Dipentene / EUH208: May produce an allergic reaction. P102 Keep out of reach of children P280 Wear protective gloves / protective clothing / eye protection / face protection. P273 Avoid release to the environment. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE/doctor. P501 Dispose of container to a waste disposal plant in accordance with local, regional and national legislations.

Other hazards:

No data available

2. COMPOSITION/INFORMATION ON INGREDIENTS Substances: Not applicable. Mixtures: SUBSTANCE

CAS No

EC No

Registration No

Pentapotassium bis (peroxymonosulphate) bis (Sulphate)

70693-62-8

274-778-7

01-2119485567-22

Sodium C10-13 – alkylbenzenesulfonate

68411-30-3

270-115-0

Malic Acid

6915-15-7

230-022-8

Sulphamidic Acid

5329-14-6

226-218-8

Sodium toluenesulfonate

12068-03-0

235-088-1

01-2119906954-31

Classification (EC 1272/2008) (CLP) Acute Tox 4 H302 Skin Corr 1B H314 Eye Dam 1 H318 Aquatic Chronic 3 H412 Acute Tox 4 H302 Skin Irrit 2 H315 Eye dam 1 318 Aquatic Chronic 3 H412 Eye Irrit 2 H319 STOT SE H335 Acute Tox 4 H302 Skin Irrit 2 H315 Skin Irrit 2 H319 Skin Irrit 2 H315 Aquatic Chronic 3 H412 Skin Irrit 2 H315 Eye Irrit 2 H319

Concentration (% w/w) >=40 - =10 - =7 - =4 - =1 - 5mg/l 11.4 mg/l

Dipotassium Peroxodisulphate

LC50 / 4h Rat

10.7 mg/l

Method OECD Test guideline 403 The toxicological data has been taken from products of similar composition. Respiratory tract irritation. Dust

Virkon-S Page 5 of 9 Revision Date: 19/05/2016 Print Date: 13/06/16

Acute Dermal Toxicity LD50 / Rat:

2200 mg/kg (Data on the product itself)

Ingredient Pentapotassium bis (peroxymonosulphate) bis (Sulphate) Sodium C10-13-alkylbenzenesulfonate Malic Acid

Value LD50 / Rat 2,000 mg/kg LD50 / Rat 2,000 mg/kg LD50 / Rabbit 20,000 mg/kg

Sulphamidic Acid Sodium Toluenesulphonate Dipotassium Peroxodisulphate Dipentene

LD50 / Rat LD50 / Rabbit LD50 / Rabbit LD50 / Rat

Skin Irritation Result: Method:

2,000 mg/kg >2,000 mg/kg 10,000 mg/kg 5,000 mg/kg

Method Directive 67/548/EEC, Annex V, B.3 OECD Test guideline 402. The toxicological data has been taken from products of similar composition. OECD Test guideline 402.

Irritating to skin OECD Test Guideline 404 (Data on the product itself)

Ingredient

Species

Classification

Result

Method

Pentapotassium bis (peroxymonosulphate) bis (Sulphate)

Rabbit

Corrosive

Causes Burns

OECD Test guideline 404

Sodium C10-13-alkylbenzenesulfonate Malic Acid Sulphamidic Acid Sodium Toluenesulphonate Dipotassium Peroxodisulphate Dipentene

Rabbit Rabbit Rabbit Rabbit Rabbit Animals (unspecified species)

Irritating to Skin Irritating to Skin Irritating to Skin Irritating to Skin Irritating to Skin Skin Irritation

Severe Skin Irritation OECD Test guideline 404 Skin Irritation Severe Skin Irritation Severe Skin Irritation Skin Irritation OECD Test guideline 404 Information given is based on data obtained from similar substances

Species Rabbit

Classification Causes severe burns Risk of serious damage to eyes. Irritating to Eyes Irritating to Eyes.

Result Corrosive

Method

Irreversible effects on the eye. Severe eye irritation. Eye Irritation.

OECD Test guideline 405

Eye Irritation Ingredient Pentapotassium bis (peroxymonosulphate) bis (Sulphate) Sodium C10-13-alkylbenzenesulfonate

Rabbit

Malic Acid Sulphamidic Acid

Rabbit Rabbit

Sodium Toluenesulphonate Dipentene

Rabbit Rabbit

Sensitisation Guinea Pig Buehler Test Result: Result:

Irritating to Skin

US EPA Test Guideline OPPTS 870.2400

Mild eye irritation. Eye irritation.

Does not cause sensitisation (data on the product itself) Does not cause respiratory sensitisation.

Ingredient Pentapotassium bis (peroxymonosulphate) bis (Sulphate)

Species Guinea Pig

Classification Does not cause skin sensitisation

Result Does not cause skin sensitisation

Pentapotassium bis (peroxymonosulphate) bis (Sulphate) Sodium C10-13-alkylbenzenesulfonate

Human Guinea Pig

Sodium Toluenesulphonate

Guinea Pig

Dipotassium Peroxodisulphate

Human

Dipotassium Peroxodisulphate

Mouse local lymph node test Guinea Pig

Does not cause respiratory sensitisation Does not cause skin sensitisation. Does not cause skin sensitisation May cause sensitisation by inhalation May cause sensitisation by skin contact

Does not cause respiratory sensitisation Does not cause skin sensitisation. Does not cause skin sensitisation May cause sensitisation by inhalation May cause sensitisation by skin contact

Causes sensitisation

There are reports of human skin sensitisation

Dipentene

Method

OECD Test guideline 406 OECD Test guideline 406

OECD Test guideline 429

Repeated Dose Toxicity Ingredient Sodium C10-13alkylbenzenesulfonate Malic Acid Sulphamidic Acid Sodium Toluenesulphonate

Route/Species Ingestion Rat Exposure Time 28 days Oral – Feed Rat Oral Rat

NOAEL/LOAEL NOAEL: 125 mg/kg LOAEL: 250 mg/kg

Oral Rat Exposure Time 91 days

NOAEL: 114 mg/kg

Method

OECD Test Guideline 408 OECD Test Guideline 408

Result No toxicologically significant effects were found.

No toxicologically significant effects were found. No toxicologically significant effects were found. No toxicologically significant effects were found. Information given is based on data obtained from similar substances.

Virkon-S Page 6 of 9 Revision Date: 19/05/2016 Print Date: 13/06/16 Ingredient Sodium Toluenesulphonate Dipotassium Peroxodisulphate Dipentene

Route/Species Dermal Mouse Exposure Time 91 days Oral Rat

NOAEL/LOAEL NOAEL: 440 mg/kg

Method OECD Test Guideline 411

NOAEL: 131.5 mg/kg

OECD Test Guideline 407

Multiple Species

Result No toxicologically significant effects were found. Information given is based on data obtained from similar substances. No toxicologically significant effects were found. Organ weight changes, Altered blood chemistry.

Mutagenicity Assessment Ingredient

Remarks

Pentapotassium bis (peroxymonosulphate) bis (Sulphate)

Animal testing did not show any mutagenic effects. Did not cause genetic damage in cultured bacterial cells. Tests on mammalian cell cultures showed mutagenic effects. Evidence suggests this substance does not cause genetic damage in animals. Animal testing did not show any mutagenic effects. Did not cause genetic damage in cultured bacterial cells. Genetic damage in cultured mammalian cells was observed in some laboratory tests but not in others. Animal testing did not show any mutagenic effects. Evidence suggests this substance does not cause genetic damage in animals. Animal testing did not show any mutagenic effects. Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Animal testing did not show any mutagenic effects. Animal testing did not show any mutagenic effects. Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Information given is based on data obtained from similar substances. Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Animal testing did not show any mutagenic effects.

Sodium C10-13 – alkylbenzenesulfonate

Malic Acid Sulphamidic Acid Sodium Toluenesulphonate Dipotassium Peroxodisulphate

Dipentene

Carcinogenicity Assessment Ingredient Malic Acid Sodium Toluenesulphonate Dipotassium Peroxodisulphate Dipentene

Toxicity to Reproduction Assessment No toxicity to reproduction Ingredient Sodium C10-13 – alkylbenzenesulfonate Malic Acid Sodium Toluenesulphonate Dipotassium Peroxodisulphate Dipentene

Remarks Not classifiable as a human carcinogen. Due to its physical properties, there is no potential for adverse effects. Not classifiable as a human carcinogen. Animal testing did not show any carcinogenic effects. Information given is based on data obtained from similar substances. Not classifiable as a human carcinogen. Animal testing did not show any carcinogenic effects. Information given is based on data obtained from similar substances.. Not classifiable as a human carcinogen.

Remarks No toxicity to reproduction. Animal testing showed no reproductive toxicity. Information given is based on data obtained from similar substances. No toxicity to reproduction. Due to its physical properties, there is no potential for adverse effects. No data available. No toxicity to reproduction. Animal testing showed no reproductive toxicity. Information given is based on data obtained from similar substances. No toxicity to reproduction. Animal testing showed effects on reproduction at levels equal to or above those causing parental toxicity.

Assessment Teratogenicity Ingredient

Remarks

Pentapotassium bis (peroxymonosulphate) bis (Sulphate) Sodium C10-13 – alkylbenzenesulfonate

Animal testing showed no developmental toxicity. Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity. Animal testing showed no developmental toxicity. Animal testing showed no developmental toxicity. Information given is based on data obtained from similar substances. Animal testing showed no developmental toxicity. Information given is based on data obtained from similar substances. Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity.

Malic Acid Sodium Toluenesulphonate Dipotassium Peroxodisulphate Dipentene

12. ECOLOGICAL INFORMATION 12.1 TOXICITY Toxicity to Fish LC50 / 96h / Salmo Salar (Atlantic Salmon): 24.6 mg/l. (data on the product itself) Ingredient Toxicity Pentapotassium bis LC50 / 96h . Cyprinodon Variegatus (sheepshead Minnow): 1.09 mg/l (peroxymonosulphate) bis (Sulphate) Sodium C10-13LC50 / 96h Lepomis macrochirus (Bluegill sunfish): 1.67 mg/l alkylbenzenesulfonate

Method Directive 647/548/EEC, Annex V, C.1. See user defined free text.

Virkon-S Page 7 of 9 Revision Date: 19/05/2016 Print Date: 13/06/16 Ingredient Sulphamidic Acid

Toxicity LC50 / 96h Pimephales promelas (fathead minnow): 70.3 mg/l

Sodium Toluenesulphonate Dipotassium Peroxodisulphate

LC50 / 96h Oncorhynchus mykiss (rainbow trout): >490 mg/l

Dipentene

LC50 / 96h Pimephales promelas (fathead minnow): 0.702 mg/l

LC50 / 96h Oncorhynchus mykiss (rainbow trout): 76.3 mg/l

Method OECD Test Guideline 203 Information given is based on data obtained from similar substances. Information given is based on data obtained from similar substances. US EPA Test Guideline OPP 72-1. Information given is based on data obtained from similar substances. Information given is based on data obtained from similar substances

Toxicity to Aquatic Plants EC50 / 72h/ Algae : 20 mg/l (data on the product itself) NOEC/Algae : 6.25 mg/l (data on the product itself). EC50 / 72h / Dunaliella tertiolecta: 5.54 mg/l Ingredient Pentapotassium bis (peroxymonosulphate) bis (Sulphate) Sodium C10-13alkylbenzenesulfonate Sulphamidic Acid

Toxicity ErC50 / 96h / Selenastrum capricornutum (green algae): NOEC / 72h / Selenastrum capricornutum (green algae): ErC50 / 72h / Desmodesmus subspicatus (green algae): NOEC / 15 d / Algae: 3.1 mg/l ErC50 / 72h / Desmodesmus subspicatus (green algae): NOEC / 72h / Desmodesmus subspicatus (green algae): EC50 / 96h / Desmodesmus subspicatus (green algae):

>1mg/l 0.5mg/l 127.9 mg/l 48 mg/l 18 mg/l 236 mg/l

Sodium Toluenesulphonate

NOEC / 96h / Desmodesmus subspicatus (green algae): 75 mg/l

Dipotassium Peroxodisulphate

NOEC / 72h / Pseudokirchneriella Subcapitata (green algae): 39.2 mg/l

Method OECD Test Guideline 201

OECD Test Guideline 201 OECD Test Guideline 201 Information given is based on data obtained from similar substances Information given is based on data obtained from similar substances OECD Test Guideline 201 Information given is based on data obtained from similar substances

Toxicity To Aquatic Invertebrates EC50 / 48h / Daphnia Magna (water flea): 6.5 mg/l (data on the product itself). Ingredient Toxicity Pentapotassium bis EC50 / 48h / Daphnia magna (water flea): 3.5 mg/l (peroxymonosulphate) bis (Sulphate) Sodium C10-13EC50 / 48h / Daphnia magna (water flea): 2.9 mg/l alkylbenzenesulfonate Malic Acid EC50 / 48h / Daphnia magna (water flea): 240 mg/l Sulphamidic Acid EC50 / 48h / Daphnia magna (water flea): 71.6 mg/l Sodium Toluenesulphonate EC50 / 48h / Daphnia magna (water flea): >318 mg/l Dipotassium Peroxodisulphate

EC50 / 48h / Daphnia magna (water flea): 120 mg/l

Dipentene

EC50 / 48h / Daphnia magna (water flea): 0.421 mg/l

Method OECD Test Guideline 202 OECD Test Guideline 202

OECD Test Guideline 202 Information given is based on data obtained from similar substances US EPA Test Guideline OPP 72-2 Information given is based on data obtained from similar substances Information given is based on data obtained from similar substances

Toxicity To Other Organisms LD50 / Rat: 4,123 mg/kg Chronic Toxicity to Fish Ingredient Pentapotassium bis (peroxymonosulphate) bis (Sulphate) Sodium C10-13alkylbenzenesulfonate

Toxicity NOEC / 37d / Cyprinodon Variegatus (sheepshead minnow): 0.222 mg/l

Method

NOEC / 28d / Lepomis macrochirus (Bluegill sunfish): 1 mg/l

OECD Test Guideline 204

Chronic Toxicity To Aquatic Invertebrates Ingredient Pentapotassium bis (peroxymonosulphate) bis (Sulphate) Sodium C10-13alkylbenzenesulfonate

Toxicity NOEC / 28d / Americamysis bahia (mysid shrimp): 0.267 mg/l

Method

NOEC / 21d / Daphnia Magna (water flea): 1.18 mg/l

OECD Test Guideline 211

12.2.PERSISTENCE AND BIODEGRADABILITY Biodegradability: Expected to be biodegradable. Ingredient Pentapotassium bis (peroxymonosulphate) bis (Sulphate) Sodium C10-13-alkylbenzenesulfonate Malic Acid

Method

Biodegradability Biodegradable

OECD Test Guideline 301

Rapidly Biodegradable Readily Biodegradable

Virkon-S Page 8 of 9 Revision Date: 19/05/2016 Print Date: 13/06/16 Ingredient Sulphamidic Acid Sodium Toluenesulphonate

Method Not applicable / 28d Biodegradation : 0-2% OECD Test Guideline 301C

Dipotassium Peroxodisulphate Dipentene

Biodegradability Biodegradable Not readily biodegradable. Readily Biodegradable Not readily biodegradable.

Bioaccumulative Potential Ingredient Malic Acid Sodium Toluenesulphonate Dipentene

Mobility In Soil:

Method OECD Test Guideline 305

Bioaccumulation Accumulation in aquatic organisms is unlikely Bioconcentration Factor (BCF):

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