Total Organic Carbon Analyzers Model 1010 Wet Oxidation TOC Analyzer Model 1020A Combustion TOC Analyzer Solids TOC Analyzer
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Advanced Technology: The Tradition Continues
OI Analytical has been a leader in designing and manufacturing TOC analyzers since 1970. OI Analyticals first TOC analyzer was the outgrowth of a technology transfer from the School of Oceanography at Texas A&M University. OI Analytical, working with Texas A&M, developed the TOC methodology that would ultimately serve as a substitute for BOD and COD analysis. In the early 1970s, OI Analytical pioneered the Ampule TOC Method and introduced the Model 524, used in conjunction with OI Analyticals first combustion TOC product. In the early 1980s, OI Analytical developed the automated 100°C/persulfate method, which led to the introduction of the Model 700 TOC Analyzer in 1984.
Model 524 TOC Analyzer
With the introduction of the Model 1010 in 1995, the Solids TOC Analyzer in 1997, and the Model 1020A in 2000, OI Analytical continues its tradition of providing reliable, high quality products to meet the growing needs and demands of our customers. Our research and development efforts are dedicated to developing and enhancing products to achieve high performance, increase productivity, maximize ease-of-operation, and expand the range of instrument applications for our customers. The Model 1010 and 1020A provide the improved reliability, versatility, and unmatched analytical performance required to serve an expanding range of markets, applications, and customers.
Model 700 TOC Analyzer
Model 1010 TOC Analyzer
High Temperature Persulfate Oxidation Method
Accurate and Reproducible Results As Low As 2 ppbC Automated and Precise Sample Introduction Compact and Versatile Configurations User-Friendly and Flexible Calibration
The Model 1010, small in size yet big on performance, uses approved 100°C/ persulfate oxidation methodology to analyze samples containing 2 ppb to 10,000 ppm carbon as TOC, TC, or TIC. This heated persulfate method has been proven to be the most reliable technique for analyzing acidic, ionic, refractory, or other difficult matrices. In the vast majority of applications, the Model 1010 achieves recoveries better than UV persulfate oxidation without the high expense required for routine lamp replacements. The Model 1010 performs both TIC and TOC analysis on a single aliquot of sample. Since TOC is measured directly, rather than by difference, the analytical results are more accurate and reproducible. With the capability to consistently analyze samples at very low ppb levels, the Model 1010s sensitivity and versatility make it an ideal choice for pharmaceutical, semiconductor, ultrapure water, and drinking water applications. Significant features include single- or multipoint calibration, operator-programmable sequencing, and optional Windows®-based control and data acquisition software.
Accurate and Reproducible Results As Low As 2 ppbC ·
Outstanding precision and accuracy from 2 ppbC (on-line) to 10,000 ppmC.
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CO2-specific NDIR detector eliminates potential ionic interferences.
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NDIR detector features wide linear range exceeding 125 µgC.
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Robust high temperature persulfate oxidation maximizes recovery and low-level performance. Measures TOC directly not by calculating TOC from TC_TIC.
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Automated and Precise Sample Introduction ·
Precision sample loops ensure accurate, reproducible, and reliable sample injections.
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Sequence programming with optional autosampler enables continuous unattended operation.
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Automated analysis from 2 ppbC to 125 ppmC.
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Automated, pump-less sampling configuration for on-line process applications.
Compact and Versatile Configurations ·
Small footprint minimizes benchspace requirements.
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Virtually no additional space required for vertical-docking autosampler.
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Control via mini-keyboard and monitor or optional Windows-based software.
User-Friendly and Flexible Calibration ·
Single-point or multipoint calibration (up to 5 points) defined by operator.
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Wide linear range minimizes need for multiple calibration curves.
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Enables operator to run check standards against each calibration point.
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Calibration using TOC, TIC, and TC.
Model 1020A TOC Analyzer Catalytic Combustion Method
Accurate and Reproducible Results Over Wide Range Approved and Versatile Combustion Methodology (200° 950°C) Automated and Precise Sample Introduction Broad and Reliable Particulate-Handling Capability
The Model 1020A combines USEPA and ASTM-approved combustion methods with todays advanced catalyst technology to create an instrument specifically designed to analyze the most challenging real-world sample matrices. Its wide linear range enables the Model 1020A to accurately and reliably analyze carbon levels as TOC, TC, or TIC from 25 µg/mL to 10,000 µg/mL. As a result, aqueous samples can be analyzed without special sample preparations, making the Model 1020A the ideal choice for wastewater, industrial effluents, seawater, brine, and drinking water. Its ease-of-operation, reliability, space-saving design, wide linear range, and outstanding accuracy make the Model 1020A unmatched in the industry. Unlike other TOC analyzers, the Model 1020A can accurately analyze samples over three orders of magnitude with a single calibration curve. Magnetic stirring, large I.D. sample pathways, and enhanced sample transfer techniques ensure that the Model 1020A consistently and reliably meets the particulate-handling requirements of Standard Method 5310A and ISO 824S. The selectivity of the NDIR detector and high oxidation efficiency of the combustion methodology make the Model 1020A the analyzer of choice for higher concentration TOC analysis.
Accurate and Reproducible Results Over Wide Range ·
Reliably analyzes TC/TIC/TOC from 25 ppbC to 10,000 ppbC in 36 minutes.
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NDIR response is linearized over entire dynamic range (up to 250 µgC).
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Provides NPOC analysis via preacidification (option) and prepurging.
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Optional POC analysis from 0.5500 ppm in 56 minutes.
Approved and Versatile Combustion Methodology (200° 950°C) ·
Best analytical method for maximizing recoveries.
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Facilitates the analysis of dirty, salty, or particulate-laden sample matrices.
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Variable temperature settings from 200°C to 950°C (680°C to 900°C optimal).
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Platinum catalyst not required for high temperature (900°C or greater) operation.
Automated and Precise Sample Introduction ·
Precision sample loops ensure accurate, reproducible, and reliable sample injections.
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Sequence programming with optional autosampler enables continuous unattended operation.
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Automated analysis from 25 ppbC to 10,000 ppmC.
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Preacidification option shortens analysis time by removing TIC prior to analysis.
Broad and Reliable Particulate-Handling Capability ·
Reliably handles samples with particulates up to 400 microns.
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Large I.D. sample pathways and enhanced sample transfer techniques.
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Optional autosampler includes magnetic stirring as standard feature.
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Exceptional ability to accurately and reliably analyze high salt matrices.
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Enables operator to run check standards against each calibration point.
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Calibration using TOC, TIC, and TC.
Solids TOC Analyzer
Catalytic Combustion Solids Analyzer
Operates as a Stand-Alone Analyzer - Does not Require an Existing TOC Approved and Versatile Combustion Methodology (200° 950°C) Easily Interfaces to an OI Analytical Model 1010 or 1020A TOC, or a PC Provides TC/TOC/TIC Analysis Capability for Solids, Sludges, and Slurries
The OI Analytical Solids TOC Analyzer operates as a stand-alone analyzer or as an option for either the Model 1010 or Model 1020A TOC Analyzer. It is a semi-automated system for analyzing solids, sludges, and slurries for TC, TOC, and TIC. It uses the same USEPA-approved combustion technology as the Model 1020A and is designed for analyzing samples containing 50 µg to 30 mg of carbon. An optional Windows-based software program is available to provide computer control and data acquisition for the instrument.
Automated sample injection with no manual addition of catalyst required. Temperature ramping enables analysis of TOC in a single run. Analytical results are directly printed as ppmC and mgC for TC, TOC, and TIC. Retains analytical parameters in memory, including the calibration constants, without external power. Vertical design minimizes benchspace requirements. Single-point or multipoint calibration (up to 5 points) defined by operator. Wide linear range minimizes need for multiple calibration curves.
WinTOC
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Software
WinTOC is a Windows®-based software that enables the operator to control and monitor a Model 1010, Model 1020A, or Solids TOC Analyzer from a PC. This sophisticated yet easy to use software enables the
Status Screen
operator to set analysis parameters, define analytical sequences, and perform standard/sample analyses in a user-friendly Windows environment. WinTOC enables stored methods and sequences to be recalled quickly and easily. Its comprehensive reporting capability and postprocessing analytical tools enhance and simplify daily operation.
Integrated remote control of up to four TOC Analyzers from a single PC. Seamless data acquisition and storage capability. Unlimited storage of methods, sequences, and calibration information.
Methods Screen
Informative screen/panel displays of run conditions, methods, and sequences. Comprehensive reporting capability. Detailed on-line help system. Powerful post-processing/analysis tools, including peak reintegration. Fully compatible with Windows Versions 3.1 to 2000.
Sequence Screen
Provides electronic recordkeeping functionality required to comply with FDA regulation 21 CFR, Part 11.
Model 1051 Autosampler Vial Autosampler with Sample Stirring
Vertically Docks with Model 1010 and 1020A TOC Analyzers to Minimize Benchspace Requirements Enables Programmable Rinses Through the TOC Analyzers to Eliminate Carryover Easily and Reliably Transfers Clean or Particulated Water Samples (up to 400 microns) Includes Variable-speed Magnetic Stirring Capability as Standard Feature The OI Analytical Model 1051 Autosampler is designed to automate either the Model 1010 or Model 1020A TOC Analyzers for the analysis of clean or particulated water samples. Three vial configurations are available, including a 12-sample vial tray (Model 1010 TOC only), 53-sample tray, and a high volume 88-sample tray. Sample trays can be easily removed for storage in a cooler to maintain integrity until analysis. The Model 1051 also includes a sample-stirring feature that automatically stirs the samples to ensure homogenization of insoluble or particulated matrices. The autosampler is easily configured and controlled through either TOC Analyzer and may be programmed to perform a broad range of sampling functions. The Model 1051 Autosampler offers the broadest capabilities available to perform the most accurate and rapid analysis possible.
Spiral-design carousel optimizes sampling accuracy.
Removable, lightweight sample vial trays make sample loading, unloading, and storage easy.
Choice of 12-position (100 mL), 53-position (40 mL), or 88-position (14 mL) trays.
Optional preacidification and presparging of samples reduces sample analysis time.
Supports both open-vial and closed-vial (septum piercing) sample modes.
POC Module
Option for Model 1020A
The POC Module is an option for the Model 1020A that enables analysis of POC from 0.5 ppm to 500 ppm in 5 6 minutes and requires no additional benchspace. POC (purgeable organic carbon) is determined by concentrating and trapping purgeable organics, then desorbing them to the combustion furnace. The furnace converts the organics to CO2, which is then detected by the NDIR detector.
Model 102OA docked with Model 1051 and POC Module
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Our commitment to your satisfaction begins when you consider buying an OI Analytical instrument. We strive to develop and maintain a one-on-one relationship to carry you successfully through the purchase experience and throughout your future with OI Analytical’s instruments. This highly regarded relationship is cultivated through customer focused programs.
Service Contracts
OI Analytical has made a long-term commitment to outstanding customer serAT • YOUR • SERVICE vice with a continuously growing network of support services designed to provide high quality service to our customers. OI Analytical offers a wide range of extended warranties and service contracts designed to fit your needs. Call and ask for details at 1-800-653-1711. OI Analytical offers several finance programs for your convenience. Renting and leasing programs as well as our rent-to-own program are available to help you get the equipment you need.
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Customer Communications A domestic toll-free technical support hotline is available for instrument support as well as specialized applications. On-site specific applications training and hands-on seminars are available. OI Analytical is proud to provide the highest quality instruments available, backed by a commitment to quality, service, and support. Call 1-800-653-1711.
151 Graham Road, PO Box 9010 College Station, Texas 77842-9010 FAX (979) 690-0440 • (979) 690-1711 (800) 653-1711 USA/Canada http://www.oico.com E-mail:
[email protected] Publication#16261200
A World of Solutions
Model 1010 TOC Analyzer Total Organic Carbon Analyzer USEPA, ASTM, Standard Method, and USP approved heated persulfate technology Measures total carbon (TC), total inorganic carbon (TIC), and total organic carbon (TOC) Same-sample TIC/TOC measurement Small, compact size Ultralow-level sensitivity Single- or multipoint calibration Sequence programming for unattended operation Programmable rinse capability for maximum accuracy and precision Nondispersive infrared (CO2 specific) detector For laboratory or at-line applications Choice of interface options for data handling and analyzer control: ® keyboard and monitor, or Windows -based software (WinTOC) WinTOC software provides electronic recordkeeping, auditing, and electronic signature requirements to comply with FDA Regulation 21 CFR, Part 11 Principal Applications
The Model 1010 Total Organic Carbon (TOC) Analyzer is an automated system for • Standard Method 5310C analyzing aqueous samples for total inorganic carbon (TIC) and TOC. The Model 1010 performs both TIC and TOC analysis on one aliquot of sample. This allows TOC to be • USEPA 415.1 measured directly rather than through subtraction (TC–IC), as is the case with most TOC • USEPA 9060 analyzers. • ASTM D4839 • ASTM D4779 • USP 643 • Cleaning validation • Boiler feedwater • Cooling water • Seawater • Drinking water • Ultrapure water • Groundwater
The Model 1010 uses approved 100°C persulfate oxidation methodology for analyzing samples containing 2 ppb to 10,000 ppm of organic carbon. This heated persulfate methodology has been proven to be the most reliable technique for acidic, ionic, refractory, and other difficult matrices. In addition, 100°C persulfate oxidation provides recoveries better than or equal to UV-promoted oxidation without the cost and maintenance of UV lamp replacement. Operating Principles Same-sample determination of TIC and TOC is performed by wet oxidation. TIC is determined by acidifying the sample to convert inorganic carbon to carbon dioxide. The carbon dioxide, which is purged from the sample with nitrogen, is detected by a nondispersive infrared (NDIR) detector and reported as ppm TIC. Sodium persulfate is then added to the sample, which is heated to digest the organic carbon to carbon dioxide. Once purged from the sample matrix, the carbon dioxide is detected by the NDIR detector and reported as ppm TOC.
A World of Solutions
OICO
Specifications Dimensions • With keyboard and monitor: 24.75" H x 13.5" W x 19" D (62.9 cm H x 34.3 cm W x 48.3 cm D) • With WinTOC: 17" H x 13.5" W x 19" D (43.2 cm H x 34.3 cm W x 48.3 cm D) • With autosampler option: 34" H x 18.75" W x 23.5" D (86.4 cm H x 47.6 cm W x 59.7 cm D)
Weight • 46 lbs (20 kg) • Autosampler option: 22 lbs (10 kg)
Alarm Relay Contacts • 10 A/240 VAC • 8 A/24 VDC
Performance Specifications Method
• TOC: 100°C persulfate (Na2S2O8) oxidation (TOC measured directly after removal of TIC) • TIC: acidification (H3PO4) and sparging • TC: simultaneous acidification (H3PO4) and 100°C persulfate (Na2S2O8) oxidation
Analysis Modes • TC, TIC, TOC, and TIC/TOC
Sample Introduction • • • •
Syringe (manual) Fixed volume loop sampling At-line Vial autosampler
Particle Size
Requirements
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