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The Minerals, Metals, & Materials Society Global Symposium on Recycling, Waste Treatment and Clean Technology REWAS 2008 October 12-15, 2008 Cancun,...
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The Minerals, Metals, & Materials Society

Global Symposium on Recycling, Waste Treatment and Clean Technology REWAS 2008

October 12-15, 2008 Cancun, Mexico

Volume 1 of 3

Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 www.proceedings.com ISBN: 978-1-60560-620-0

Some format issues inherent in the e-media version may also appear in this print version.

A Publication of The Minerals, Metals & Materials Society (TMS) 184 Thorn Hill Road Warrendale, Pennsylvania 15086-7528 (724) 776-9000 Visit the TMS Web site at http://www.tms.org Statements of fact and opinion are the responsibility of the authors alone and do not imply an opinion on the part of the officers, staff, or members of TMS. TMS assumes no responsibility for the statements and opinions advanced by the contributors to its publications or by the speakers at its programs. Registered names and trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by the law. No part of this book may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, microfilming, recording, or otherwise, without written permission from the publisher. Printed in the United States of America ISBN Number 978-0-87339-726-1 Authorization to photocopy for internal or personal use beyond the limits of Sections 107 and 108 of the U.S. Copyright Law is granted by TMS, provided that the base fee of $7.00 per copy is paid directly to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923 USA, www.copyright. com. Prior to photocopying items for educational classroom use, please contact the Copyright Clearance Center, Inc. For those organizations that have been granted a photocopy license by the Copyright Clearance Center, a separate system of payment has been arranged. This consent does not extend to copying items for general distribution or for advertising or promotional purposes or to republishing items whole or in part in any work in any format.

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TABLE OF CONTENTS Volume 1

AUTOMOTIVE AND AEROSPACE RECYCLING Physical Separation of Crushed Product of Waste Nickel-Metal Hydride Batteries from Hybrid Vehicles .......................................................................................................................... 1 M. Ito, M. Tsunekawa, K. Kahiwaya, N. Sumiya, H. Furuya, N. Hiroyoshi

Preheating and Surface Cleaning of Steel Scrap by ASR............................................................... 7 G. Ye, M. Larsson, S. Angstrom, E. Burstrom

Economic and Environmental Evaluation of Aerospace Aluminum End-of-Life Options Using a Chance-Constrained Optimization Model.......................................................... 13 G. Gaustad, E. Olivetti, E. Chen, R. Kirchain

CASE STUDIES IN THE DEVELOPMENT OF WASTE TREATMENT TECHNOLOGIES Pelletization of Slag from Steel Desulfurization ............................................................................ 20 S. Komar Kawatra

The Application of ViroMineŽ Technology to Intractable Mine Waste: Global Treatment Outcomes ........................................................................................................................ 31 L. Fergusson

Stabilization of EAF Slag for Use as Construction Material ......................................................... 43 Q. Yang, B. Haase, F. Engström, A. Wedholm

Uses of Flying Ashes to Eliminate Copper from Waste Cyanided Mine Waters ........................ 49 J. Ayala, J. Martínez, P. Coque, B. Fernández

Adsorption of Molybdenum in Nitric Acid Solution by Using Pb-Fe Based Adsorbents ........................................................................................................................................ 57 G. Dodbiba, T. Kikuchi, T. Fujita

Active Carbons and Their Reactivation in Non-ferrous and Noble Hydrometallurgy................ 63 V. Mukhin

Combined Process for Treatment and Recycling of Municipal Solid Waste with Complex Morphological Composition ............................................................................................ 67 L. Kuzev, R. Markov

Waste Processing - Latest Achievements...................................................................................... 73 P. Stehlik

Flexible Technologies of Processing the Textile Wastes into High Added Value Products............................................................................................................................................. 79 E. Carpus, E. Visileanu, R. Scarlat, S. Ionescu, A. Popa

Vitrification by Plasma Treatment, an Environmentally Sound Technology for APC Residues.................................................................................................................................... 85 L. Yurramendi, J. Múgica, J. Antoñanzas, J. Aragón, S. Caballero

Development of Waste-Free Technology in the Steel Industry.................................................... 91 D. Esezobor, S. Balogun, S. Adeosun

Physical, Mechanical and Durability Study of Dunes Sand Mortar in the Region of Laghouat ............................................................................................................................................ 98 A. Lakhdar, B. Benchaa, B. Akram Salah Eddine

Assessment of Ladle Slag as Binder Alternative for Cold Bonded Briquettes ........................ 109 D. Adolfsson, R. Robinson, J. Blagojevic, F. Su

Case Study: Quality Improvement of Recycled Aggregates from a Construction and Demolition Waste Recycling Pilot Plant................................................................................ 116 D. Algarvio, M. Cunha, M. Lima

Cost-Effectiveness of C&D Waste Recycling In Italy: A Case Study......................................... 125 V. Basilico, M. Quattrone, M. Bassan

Extraction of Gold, Silver and Copper from the Copper Electrorefining Anode Slime: Separation of the Metals..................................................................................................... 131 L. Sobral, G. Bard

CLEAN TECHNOLOGY AND REENGINEERING OF CURRENT PROCESSES OxyFuel Combustion for Low-Caloric Fuels ................................................................................ 139 W. Hoeltl, T. Pröll, H. Hofbauer, M. Potesser, J. Rohovec, B. Kronberger

The Alkaline Sulfide Hydrometallurgical Separation, Recovery and Fixation of Tin, Arsenic, Antimony, Mercury and Gold.......................................................................................... 146 C. Anderson, L. Twidwell

Study of Environmental Benefit Ground-Source Heat Pump System with LCA ...................... 156 F. Liu, J. Cai, W. Liu

Thermodynamic Analysis and Cascaded Utilization of Residual-Heat in Sinter Process ...... 161 J. Cai, C. Chen, Y. Kim

Sludge Characteristics of a UASB/CO2-Stripper System for the Treatment of High Strength Wastewater ...................................................................................................................... 168 A. Vlyssides, S. Mai, E. Barampouti

Desulfurization During Calcination of Anode-Grade Petroleum Coke ...................................... 174 X. Chen, J. Zhou, W. Li

Development of Ion-Selective Membranes of Polyaniline (PAni) and Sulfonated Polystyrene (SPS) and High Impact Polystyrene (HIPS) for Application in Electrodialysis to the Treatment of Industrial Effluent ............................................................... 177 M. Proença, B. Hansen, M. Rodrigues, C. Ferreira

A Thermodynamic Study of Arsenic Adsorption onto Iron Species Generated by Electrocoagulation.......................................................................................................................... 183 J. Parga, A. de los Santos, J. Valenzuela

The Advantage of CTAB(Cetyl-Three-Ethyl-Ammonium Bromide) Use on the Electroleaching of Copper Sulphides Flotation Concentrate..................................................... 191 V. Mori, M. Aguiar, L. Sobral

Bioleaching of Copper Sulphides Flotation Concentrate Using Consorptium of Mesophiles and Termophiles Microorganisms............................................................................ 197 R. Lima, L. Sobral, C. Souza, S. Leite, P. Silva

DESIGN AND ENGINEERING OF WASTE TREATMENT PLANTS Electric Pulse Disintegration: Russian Experience and Prospects........................................... 203 A. Usov, V. Tsukerman

Protection of Reinforced Concrete against Corrosion in Waste Treatment Plant (Case Study) .................................................................................................................................... 209 M. Yaneva, E. Kostakeva

Dual Plant to Produce SHG Zinc and Pure Zinc Sulphate from Zinc Oxide Secondaries by Using ZincexTM Technology ............................................................................. 215 C. Frias, M. Frades, A. Mejias, D. Martin, G. Diaz

DESIGN FOR RECYCLING, PRODUCT-SERVICE SYSTEMS, DEMATERIALIZATION Design and Engineering of the Plant for Man-Made Hydrocarbon-Containing Raw Materials Available in Countries of the Baltic Sea Region ......................................................... 222 A. Tarasov, V. Paretsky, E. Unn

Technology Based Design for Recycling and Eco-Design......................................................... 235 A. Van Schaik, M. Reuter

Design of Concepts for the Utilization of Residues and Wastes in Ajaokuta Steel Company.......................................................................................................................................... 244 D. Esezobor, S. Balogun, S. Adeosun

Splash Technology: Applying the Design-for-Recyclability Concept to Spent Potlining Management.................................................................................................................... 254 C. Young, J. Downey

Improvements in Ceramics for Boiler Protection in WTE Applications .................................... 261 C. Thibault, C. His, P. Stephan, S. Mulch

ECONOMIC EVALUATION OF WASTE TREATMENT STRATEGIES Innovation Technologies of Solid Minerals Processing in the Arctic Zone with Waste Minimization......................................................................................................................... 267 T. Vyacheslav, L. Ivanova

A Contribution to the Strategic Analysis of Alternatives for Waste Management in Valle de Aburrá Area, Medellín-Colombia..................................................................................... 278 E. Posada

Economic and Environmental Evaluation of Various Aluminum Scrap Upgrading Options Using Chance Constrained Optimization Modeling...................................................... 284 G. Gaustad, E. Olivetti, R. Kirchain

ENVIRONMENTAL ISSUES RELATED IN WASTE STORAGE AND RECYCLING Remediation of Soils Contaminated by Dioxins and Furans...................................................... 290 V. Hintikka

Reduction of Sulfur Dioxide Emissions........................................................................................ 297 V. Lobanov, N. Ageev, A. Pritchin

The Modification of Pyrite and Arsenopyrite Specific Surface and Porosity at Thermal Decomposition ................................................................................................................. 301 V. Luganov, E. Kilibayev, B. Mishra, T. Chepushtanova

Colloid Facilitated Heavy Metal Mobilization from Incinerator Ashes....................................... 309 R. Köster, T. Wagner, W. Ferstl, M. Delay, W. Höll

Slag Valorization: Relevance of Standard Protocols to Evaluate Environmental Impacts............................................................................................................................................. 317 P. Pareuil, F. Bordas, E. Joussein, H. Bril, J. Bollinger

Ageing Investigation of Steel Slags from EAF (Electric Arc Furnace) Processes................... 323 F. Engström, M. Larsson, C. Samuelsson, B. Björkman

Pollutant Characterization from a Municipal Waste Disposal Site (Navarro) in Cali, Colombia.......................................................................................................................................... 329 S. Regenspurg, C. Ludwig, N. Benitez, F. Mendez

Prediction of Trace Elemental Flows during The Reaction of Bottom Ashes with Chloride-Rich Cement Dusts ......................................................................................................... 334 S. Regenspurg, C. Ludwig, V. Silberstein

Production and Industrial Adaptation of Fast Single Firing Wall Tile Opaque Glass-Ceramic Glazes Containing Borax Solid Wastes.............................................................. 340 K. Pekkan, B. Karasu, A. Kucuk

Utilization of Borax Solid Wastes in Fast Firing Porcelain Tile Glass-Ceramic Glazes under Industrial Working Conditions............................................................................... 348 B. Karasu, G. Kaya, S. Yesilay, A. Cakir

Indonesian Palm Oil Bio-Wastes and Its Environmental Impacts ............................................. 357 K. Hayashi

GENERAL RECYCLING AND SOLID WASTE PROCESSING DC Electric Arc Rotary Furnace .................................................................................................... 364 B. Lucheva, T. Tzonev

Recovery of Metal Aluminum from Aluminum Dross in DC Electric Arc Rotary Furnace ............................................................................................................................................ 369 B. Lucheva, T. Tzonev

Elkem Spent Pot Lining Recycling Project................................................................................... 375 F. Olesen

The Recycling of Electrofilter Fines to Produce Aluminum Sulfate .......................................... 382 J. Ayala, J. Sancho, P. García, B. Fernández

Nickel Recovery from the Alloy Al2Ni and the Mixtures Al-Ni, Al2O3-Ni and Al2O3NiO Comparative Study by Direct Chlorination of the Species.................................................. 390 F. Alvarez, D. Pasquevich, A. Bohé

Alumina Surface Material from Aluminum Solid Waste and Its Catalytic Application....................................................................................................................................... 395 T. Abd El Hamid, S. Ali

Reuse of Fines and Environmental Issues in the Production of Ferroalloys SAIL™s Experience ........................................................................................................................ 399 A. Kumar Das

Hazardous Spent Potlining from Aluminum Smelters and Its Countermeasures in China .... 408 X. Chen, W. Li

Incorporation of Industrial Wastes Along with Natural Fiber for the Development of Innovative Building Materials.................................................................................................... 411 M. Saxena, P. Asokan, R. Bux

Comparative Characteristics of Paints Developed from Fly Ash, Copper Tailing and Blue Dust .................................................................................................................................. 423 M. Saxena, S. Tiwari

Demonstration Study on Impact of Fly Ash on Soil Fertility and Crop Yield ........................... 435 M. Saxena, P. Asokan, B. Pal Singh Yadav, S. Murali, H. Dangi

Recycled Polyethylene Composites Reinforced with Jute Fabric from Post ΠUsed Sackcloth ΠAn Environmentally Correct Building Material............................................ 446 S. Monteiro, A. Lima, L. Terrones

Practical Applications for Epoxy Composites Reinforced with Residual Coconut Fibers ..... 452 S. Monteiro, L. Costa, F. Lopes, H. Santafe

Cost-Benefit Evaluation of Ramie Waste Reinforced Composites as Substitute for Conventional Building Materials ................................................................................................... 458 S. Monteiro, F. Margem, L. Santos, F. Lopes

Impact Resistance of Polyester Composites Reinforced with Ramie Waste Fibers ............... 464 S. Monteiro, L. Santos, F. Margem, F. Lopes

Effect of Piassava Waste Fiber Surface Treatment on the Reinforcement Strength in Epoxy Composites...................................................................................................................... 470 S. Monteiro, D. Nascimento, L. Motta

Study of the Buriti Waste Fiber as a Possible Reinforcement of Polyester Composites...................................................................................................................................... 476 S. Monteiro, F. Lopes, L. Costa, L. Motta, L. Santos

Reclamation of Aluminum Matrix from Aluminum Composites Reinforced with Graphite Particles ........................................................................................................................... 482 P. Moldovan, G. Popescu, C Popescu, A. Buzaianu

Study on CaSO3.0.5H2O Typed Flue Gas Desulfurization Gypsum Used as Cement Retarder ........................................................................................................................................... 490 Z. Tao, H. Geng, Z. Yang, W. Huang, J. Yao, H. Guo

Nanocomposite Rubber Material with Industrial Waste.............................................................. 497 G. Martín-Cortés, F. Esper, C. Anjos, H. Wiebeck, W. Hennies, F. Valenzuela-Díaz

Influence of Risk Components Contained in Industrial Waste Materials Used in the Building Industry ...................................................................................................................... 505 M. Svoboda, J. Ledererova, P. Sulovsky, R. Cechmanek

Use of Co-Products from Oil Extraction of Sunflower for Manufacture of Composites ......... 511 A. Rodríguez, C. Mahlamnn, R. Schneider, N. Balbinot, D. Lopez

Recycling of Tire Rubber in Porous Asphalts Using the Dry Process: Mechanical Characterization and Performance Evaluation of Mixes............................................................. 516 M. Pasetto, N. Baldo

Comparative Performance Analysis of Bituminous Mixtures with EAF Steel Slags: A Laboratory Evaluation................................................................................................................. 522 M. Pasetto, N. Baldo

Laboratory Evaluation of Bituminous Mixtures with Bottom Ash from Municipal Solid Waste Incineration (MSWI) ................................................................................................... 528 M. Pasetto, N. Baldo

Recovery of Zinc from EAF Dust - Pilot Experiences at MEFOS ............................................... 534 G. Ye

Eureka Process for Recycling Electric Arc Furnace Dust (EAFD)............................................. 540 J. Lockwood

Treatment of BF and BOF Dusts by Oxidative Leaching ............................................................ 546 M. Soria-Aguilar, F. Carrillo-Pedroza, S. Preciado-Nuñez

Zinc Oxide from Recycling Processes as a Source for Electrolytic Galvanising .................... 554 J. Antrekowitsch

Volume 2 A Study on Recovery of Metallic Values from EAF Flue Dusts.................................................. 561 H. Morcali, B. Derin, A. Aydin, O. Yucel

ReLCD ΠRecycling and Re-Use of LCD Panels ......................................................................... 566 B. Kopacek

Recycling System of Waste Materials from Discarded Mobile Phone ...................................... 571 K. Takahashi, G. Dodbiba, T. Fujita

Development of an Automatic Weee Treatment Using Physical Separation Techniques to Limit Manual Sorting ............................................................................................. 577 S. Touzé, M. Save, C. Lucion, P. Hubaux

Silica Nanopowder from Waste Silicon Sludge and CFD Modeling of the Flame Spray Pyrolysis Process ................................................................................................................ 583 M. Olivas-Martinez, H. Sohn, H. Jang

E-Waste Generation in Chile: Analysis of the Generation of Computer Waste Using Material Flow Analysis ........................................................................................................ 591 B. Steubing, C. Ludwig, H. Böni

Studies on Bromination and Volatile Separation of Metallic Oxides by Gaseous Products from Thermal Decomposition of TBBPA ..................................................................... 598 M. Grabda, S. Oleszek-Kudlak, M. Rzyman, E. Shibata, T. Nakamura

Studies on Bromination Reaction of Heavy Metal Oxides by SbBr3 and TBBPA with Thermal Methods .................................................................................................................... 607 S. Oleszek-Kudlak, M. Grabda, M. Rzyman, E. Shibata, T. Nakamura

E-Waste Recycling in Latin America: Overview, Challenges and Potential ............................. 615 H. Boeni, U. Silva, D. Ott

A Material Recovery Facility in Cape Town, South Africa, as a Replicable Concept for Sustainable e-Waste Management and Recycling in Developing Countries ...................... 624 M. Schluep, S. Dittke, G. Newson, C. Kane, K. Hieronymi

Behaviors of Metals in Spent Lithium Primary Battery Recycling Process.............................. 635 K. Yoo, S. Shin, D. Yang, J. Kang, J. Sohn

Recovery of Metals from Electronic Scrap by Hydrometallurgical Route ................................ 641 N. Dhawan, M. Kumar, V. Kumar, M. Wadhwa

Mechanical and Pyrometallurgical Recycling of Electronic Wastes ......................................... 647 L. Zhang, X. Zuo, J. Kers, D. Goljandin, P. Peetsalu

Effect of the Composition on the Immobilization of Chromium in Slags.................................. 657 J. Romero-Serrano, E. García-Ramos, B. Zeifert, P.Sánchez, E. Palacios-Beas, J. López

Different Alternatives to Recycle the Industrial Wastes ............................................................. 665 N. Menad, S. Touzé, M. Save

Removal of Lead, Cadmium and Boron From Um-Gheig Pb-Zn Spent Ore Sample ................ 680 M. Mahdy, M. El Shahat, O. El-Hussaini, G. Abd El Wahab

Experimental Investigation of Metal Recovery and Treatment for Smelting Residue by "Dry-and-Wet" Process .............................................................................................. 684 A. Shibayama, A. Yamatodani, Y. Higuchi, S. Sunagawa, E. Ono

Prediction of Trace Elemental Flows during the Reaction of Bottom Ashes with Chloride-Rich Cement Dusts ......................................................................................................... 691 S. Regenspurg, V. Silberstein, C. Ludwig

A Method of Treating the Leaching Residue from Sered Nickel Plant Stockpile ..................... 697 J. Schmiedl, F. Sekula, F. Molnár, Z. Szentirmai

Recovery of Metal Values from Industrial Waste Water in Galvanization Process.................. 706 M. Rabah, F. Farghaly, M. Motaleb

Chemical and Thermal Treatment of Dredged Sediments (Sludges): Modification of Heavy Metal Mobilities ............................................................................................................... 713 J. Ramaroson, J. Dirion, A. Nzihou, P. Sharrock, G. Depelsenaire

Characterisation of Zinc Containing Residues from Metallurgical Processes......................... 719 J. Antrekowitsch

Refinement of the Secondary Lead Received from Accumulator Scrap................................... 728 P. Arkhipov, Y. Zaikov, V. Ashikhin, Y. Khalimulina

Processing of Um-Gheig Lead-Zinc Deposits, Eastern Desert, Egypt for Separating Pure Cadmium Sulfide ................................................................................................ 734 M. Mahdy, M. El Shahat, O. El-Hussaini, G. Abd El Wahab

Disposal of the Lead-Containing Wastes at IMN™s Division in Legnica.................................. 740 Z. Smieszek, R. Chamer, Z. Kurek, R. Prajsnar

Treatment of Some Liquid Waste Associated with Lead Battery Recycling ............................ 750 C. Lupi, A. Pescetelli

Advanced Solid-State Recycle of Magnesium Alloy Wastes by Repetitive Severe Plastic Working for High-Strengthened Wrought Materials ....................................................... 757 K. Kondoh, K. Kawabata, J. Umeda, K. Kaneko, M. Ueda

Recycling of Heat Resistant Magnesium Alloys .......................................................................... 763 N. Hort, K. Kainer, D. Fechner

Recycling of Magnesium Alloys Aeronautical Parts for Obtaining Sacrificial Anodes........... 771 A. Buzaianu, G. Popescu, C. Popescu, A. Olteanu, I. Rusu, P. Motoiu

Design for Recycling - A Key to Sustainable Magnesium Application ..................................... 779 C. Meskers, M. Reuter, U. Boin

Quality Control Issues in Magnesium Scrap Recycling.............................................................. 787 B. Thompson

Removal of Magnesium and Boron from Chloride Containing Spent Liquors......................... 792 M. Sonmez, M. Alkan, B. Derin, O. Yucel

Aluminum Recycling - An Integrated, Industry-Wide Approach ................................................ 798 S. Das, J. Kaufman, J. Green

Hydrometallurical Extraction of Zinc and Lead from Çinkur Leach Residue ........................... 806 Y. Topkaya, A. Rüsen

Characterization and Possible Treatment Routes of the Solid Waste Generated by the Caron Process of Nickel Production ...................................................................................... 820 M. Mourao, C. Takano, N. Alonso-Falleiros, C. Giraldo

The Immobilisation of As2O3-Rich Wastes from Ore Smelting Using Low Temperature Ceramics ................................................................................................................... 827 D. Brew, E. Vance

The Combined Technology of Cobalt-Manganous Slimes Processing..................................... 833 A. Sudnev, D. Panov, I. Kudryavtsev, B. Radionov, V. Skorohodv

Options for Recycling the Fine Ni-Containing Waste in Ukraine. .............................................. 840 V. Sokolov, B. Bondarenko, V. Yakubovsky, V. Noskov

Recovering Heavy Metals from Spent HDP Catalysts................................................................. 853 Z. Llanos

Processing of Zinnwaldite Wastes to Obtain Lithium and Rubidium Compounds.................. 860 J. Jandova, H. Vu

Recovery of Nickel from Diluted Solutions by the Combination of Ion Exchange and Successive Electrodeposition................................................................................................ 867 J. De Clercq, E. Vande Steene, K. Verbeken, M. Verhaege

Innovative and High Economic Burner Systems for Recycling Furnaces................................ 873 M. Potesser, B. Holleis, A. Hengelmolen, H. Antrekowitsch, D. Spoljaric

Stabilization and Storage of Thermal Residues by Accelerated Carbonation ......................... 879 L. Yurramendi, S. Caballero

The Role of Top Submerged Lance (TSL) Technology in Recycling and Closing the Material Loop ............................................................................................................................ 886 M. Reuter, R. Matusewicz

Recycling of Non-Ferrous Metals at Hydrométal, Belgium ........................................................ 897 P. Henry

Sustainable Metals Production and Recycling in Japan: The Present and Issues.................. 905 T. Okura

Effects of Al2O3 on Mineralogy of the Fayalite Slag .................................................................... 910 S. Mostaghel, C. Samuelsson

Synthesis of Mn-Zn-Fe Soft Ferrite from Mixed Batteries with Spent Zinc-Carbon Batteries and Spent Alkaline Batteries ......................................................................................... 916 S. Shin, J. Kang, D. Yang, T. Kim, J. Sohn

Recovery of Valuable Metals from Spent Lithium Ion Batteries by Solvent Extraction......................................................................................................................................... 922 J. Kang, S. Shin, J. Sohn, D. Yang, S. Kim

Synthesizing Mn-Zn Ferrite from Spent Zinc Carbon Batteries through Hydrometallurgical Processes ...................................................................................................... 928 T. Kim, S. Shin, J. Sohn, J. Kang, K. Rhee

Secondary Phosphorus for the European Fertilizer Industry Quality of Recovered Products and their Markets............................................................................................................ 934 L. Hermann

Nonmetallic Inclusions in Solar Cell Silicon: Focusing on Recycling of Scraps..................... 941 L. Zhang

Minor Element Control by Flue Dust Treatment in Copper Smelting ........................................ 957 R. Parra, I. Wilkomirsky, F. Parada, R. Parada

Metals Recovery from Spent Zn-MnO2 Batteries by Hydrometallurgy ...................................... 969 R. Guerra, F. Margarido, C. Nogueira, F. Pedrosa

Physical Processing Efficiency of Saline vs. Alkaline Spent Batteries .................................... 975 M. Cabral, C. Nogueira, F. Margido

Processing of Grinding Waste of Rhenium-Containing Alloys to Manufacture Commercial-Grade Metals.............................................................................................................. 981 A. Tarasov, V. Paretsky, A. Besser, E. Gedgagov

Extraction of Platinum Metals from Automobile Catalysts......................................................... 990 V. Lobanov, B. Radionov, A. Evdokimov, V. Skorohodov

Sorption Concentration of Platinum Group Metals from Nitrate Solutions .............................. 993 S. Babaeva, O. Makovskaya, A. Shabalin, V. Skorohodv

Use of the Modified Sorbents for Extraction of Precious Metals............................................... 998 V. Lobanov, B. Radionov, O. Makovskaya, V. Skorohodv

Treatment of Radioactive Waste Solution Containing Ni, Co and Cs Obtained From The Dissolution Of Purification Ionic Exchange Resins of a Nuclear Reactor Primary Cooling System and its Later Immobilization in a Ferritic Matrix ............................. 1002 E. Esparza, S. Galasso, M. Castro, C. Osuna, J. Duca

LIFE CYCLE ASSESSMENT, MODELING AND ANALYSIS OF RECYCLING BEHAVIOR Life Cycle Analysis of the Sunflower Production...................................................................... 1008 R. Schneider, M. Prediger, L. Dornelles, D. Lopez

Methods for Managing Uncertainty in Material Selection Decisions: Robustness of Early Stage Life Cycle Assessment........................................................................................ 1017 A. Allen, A. Larsson, S. Das, J. Gregory, R. Kirchain

MATERIALS AND ENERGY EFFICIENCY IN PROCESS ENGINEERING Cumulative Energy and Exergy Analysis of Shaft Furnace and Outocumpu Processes of Copper Production ................................................................................................ 1024 K. Zygmunt, B. Bozena, H. Adam, D. Janusz, E. Bocardo Jose

Process and Practice of Reducing the Cr Loss during EAF with De-P Hot Metal Charging Melting Stainless Steel ................................................................................................ 1030 F. Zhu

Energy Savings and Carbon Dioxide Emission Reduction by Use of Advanced Refractory Technology ................................................................................................................. 1036 B. Drew, M. Kirschen, A. Spanring

RECYCLING IN BUILDING AND CONSTRUCTION INDUSTRIES Recycling of Ornamental Rock Waste into Clayey Ceramics................................................... 1042 C. Vieira, S. Monteiro

Ceramic Tile Wastes as Alternative Raw Materials for the Production of Portland Cement Clinker.............................................................................................................................. 1048 F. Puertas, I. García-Díaz, A. Barba, F. Gazulla, M. Palacios, P. Gómez, S. MartínezRamírez

Valorization of Mineral Wastes for Ceramic Industries............................................................. 1061 J. Junkes, F. Pereira, V. Della, G. Cunto, D. Hotza

Usability of the Turkish Coal Bottom Ash and Natural Zeolite in Concrete Applications................................................................................................................................... 1069 H. Kurama, C. Karakurt, I. Topçu

Characterization and Incorporation of Paper Sludge Waste into Clay Bricks........................ 1075 R. Pinheiro, C. Vieira, S. Monteiro, R. Sanchez, D. Souza

The Recycling of Construction and Demolition Waste: The Quality Standards for the Reuse in Construction Field.................................................................................................. 1081 A. Bonoli, M. Garfì

Development of Recycled Aggregate Producing Process Waste Concrete Using a Autogenous Mill and Density Separation ................................................................................... 1088 K. Kim, D. Lee, H. Cho, J. Ahn

Rejected Sands from Smelting Metallurgical Process Used in Structural Ceramics ............ 1094 F. Valenzuela-Díaz, C. Carvalho, S. Cosin, G. Martín-Cortés

Upgrade of Mixed C&DW Recycled Aggregates Quality by Automatic Sorting ..................... 1103 S. Angulo, A. Mueller, T. Schnellert

Volume 3 REMEDIATION OF CONTAMINATED SOIL AND INDUSTRIAL SITES Purification of Oil-Contaminated Soil by Flotation.................................................................... 1115 G. Anastassakis, N. Georgiou

Remediation of Contaminated Soils and Industrial Sites ......................................................... 1121 E. Kostakeva, M. Yaneva

Production of Copper and Zinc Oxide in the Process of Brass Scrap Recycling.................. 1127 M. Cirkovic, V. Trujic, M. Bugarin

RESOURCE STATISTICS, MATERIAL FLOW ANALYSIS, INFORMATION SYSTEMS Substance Flow Analysis of Zinc in China................................................................................. 1133 G. Xueyi, S. Yu, W. Yong, T. Qianghua

Addressing Impurity Accumulation: A Simple Model of Limiting Recycled Fraction .......................................................................................................................................... 1143 E. Olivetti, G. Gaustad, F. Field, R. Kirchain

RESOURCES, MONITORING AND CHARACTERIZATION OF WASTE The Integrated Management of Textile Wastes - A Strategic Tendency for Developing a Sustainable Textile Industry in Romania ............................................................ 1150 E. Visileanu, E. Carpus

Considerations on Strategy, Policy and Management of Resources and Environment ....... 1156 S. Osmani

Management of Bio-Medical Waste in Captive Hospitals of Steel Authority of India Limited, A Public Sector Undertaking......................................................................................... 1170 K. Das Sarkar

Influence of Fine Particulate Material Pollutants on Human Health at University Campus .......................................................................................................................................... 1176 R. Santana, M. Pacheco, M. Tieccher, J. Urach

Monitoring Greenhouse Pollutants from Human Source ......................................................... 1181 C. Niedersberg, V. Dalenogore, M. Almeida, R. Santana

SEPARATION TECHNOLOGIES AND THEIR ENERGY EFFICIENCY Liberation of a Large Quantitiy of Waste Materials by the Explosion in Water: A Technique with a Relatively Low Energy Consumption ........................................................... 1185 T. Fujita, K. Murata, G. Dodbiba

Metal Recovery and Refining from MSW Incineration Bottom Ash......................................... 1191 Y. Yang, Y. Xiao, L. Balentina, D. Brouwer, J. Voncken, R. Boom

TRADE POLICIES AND INCENTIVE STRUCTURES IN RECYCLING A Methodology for Evaluating and Comparing Recycling Systems: A Case Study of Electronics Recycling Systems .............................................................................................. 1201 J. Gregory, S. Fredholm, R. Kirchain

Modeling the Economic and Environmental Performance of Recycling Systems ................ 1207 J. Dahmus, S. Fredholm, E. Olivetti, J. Gregory, R. Kirchain

Incentives for Recycling: Mitigating Risks to Downstream Firms........................................... 1214 E. Alonso, F. Field, R. Kirchain

TRAINING, EDUCATION AND SOCIAL COMPATIBILITY OF RECYCLING SYSTEMS Recycling, Waste Treatment, and Clean Technology: A Terminological Approach.............. 1222 G. Rata, C. Petroman, I. Petroman

Optimizing the Material Life Cycle on Campus: The University of Sonora Case Study........ 1228 L. Velazquez, N. Munguia, A. Zavala

Training for Women Self Help Groups on the Production of Live Foods for Ornamental Fish Culture through Recycling of Agricultural and Animal Wastes ................. 1234 R. Santhakumar, N. Sujathkumar, I. Vasudhaven

TREATMENT OF LIQUID AND GASEOUS EFFLUENTS Adsorption of Heavy Metals from Aqueous Solutions on Synthetic Zeolite .......................... 1239 M. Barakat

Mine Waters Decontamination Using Geochemical Barriers ................................................... 1253 F. Aurelian, M. Popescu

Copper Elimination in Cyanidation Effluents............................................................................. 1257 F. Nava-Alonso, O. Alonso-González, A. Uribe-Salas, R. Pérez-Garibay

Up to Date Technologies for off-Gas Cleaning .......................................................................... 1262 P. Stehlik, R. Dvorak, L. Bebar, T. Parizek

Studies on the Aeration Way of the Biological Pretreatment Process for Slightly Polluted Raw Water....................................................................................................................... 1268 J. Luo, H. Guan, G. Sun, X. Zhou

Removal of Zinc and Phosphaye from Zincic Phosphatizing Wastewater ............................. 1274 J. Luo, W. Su, J. Lu, Y. Lei, M. Chen

Adsorptions of Copper from Aqueous Solutions by Modified Orange Peel Biosorbent ...... 1282 G. Xueyi, F. Ningchuan, L. Sha, T. Qinghua

Ferrihydrite and Aluminum-Modified Ferrihydrite Enhanced High-Density Sludge Treatment for Removing Dissolved Metals from Acid Rock Drainage.................................... 1290 J. Downey, L. Twidwell

Hydrothermal Mineralization Treatment of Hazardous Oxoanions in Wastewater for Resource Recovery................................................................................................................. 1300 T. Itakura, H. Imaizumi, R. Sasai, H. Itoh

Electrochemical Purification of Cobalt Polluted Liquid Effluents ........................................... 1306 C. Lupi, P. Mauro, A. Dell'Era

Usage of Calcium Phosphate Sorbent for the Removal of Heavy Metals from Industrial Flue Gas - Investigation at Pilot Scale....................................................................... 1312 C. Verwilghen, A. Nzihou, D. Gauthier, P. Sharrock, G. Flamant, G. Depelsenaire

The Electrolytic Recovery of Silver from Photographic Fixing Baths..................................... 1320 C. Lupi, M. Pasquali

Cadmium (II) Adsorption onto Nanostructured Hybrid Material Derived from the Functionalization of Smectite Clay ............................................................................................. 1326 A. Guimarães, V. Ciminelli, W. Vasconcelos

URBAN DEVELOPMENT Modeling Approach for the Sustainable Development of Industrial Zones under Uncertain Information................................................................................................................... 1335 C. Piluso, Y. Huang

An Analysis of Urban Eco-Industrial System and Its Metabolism ........................................... 1341 W. Liu, J. Cai, F. Liu

Monitoring of Air Quality in the Bus Terminal of an University Campus................................ 1350 R. Ghisleni, L. Ratke, R. Santana

WASTE CONVERSION AND REUTILIZATION Fractal Phenomenon in BF Slag Leaching Process.................................................................. 1356 P. Wang, Y. Dong, H. Xie, L. Yu

Biogas Production from Cassava Waste.................................................................................... 1361 S. Ojolo, A. Kehinde

Production of Structural Products from Copper Mining Tailings ............................................ 1367 T. Claridge, T. Weyand, D. Nickels

Environmentally Benign Process of High-Purity Amorphous Silica Originated in Rice Husks of Agricultural Wastes ............................................................................................. 1378 J. Umeda, K. Kondoh, Y. Michiura

Reuse of Waste Paper Sludge as Supplementary Cementing Material................................... 1384 M. Frías, M. Sánchez de Rojas, O. Rodríguez, I. Vegas, R. García, R. Vigil

Generation, Recycling and Reutilization of Waste at Production and Operation of Catalyst for Chemical Industry in CIS......................................................................................... 1392 S. Alexander, V. Sokolov

High Temperature Techniques for Chemical Incorporation of Wastes Aimed to the Obtainment of Re-Products ......................................................................................................... 1400 I. Lancellotti, L. Barbieri, F. Andreola, L. Morselli, F. Passarini, I. Vassura

Pre-Washing and Vitrification of Fly Ash from a Municipal Solid Waste Incinerator ............ 1406 Y. Xiao, R. Harskamp, Y. Yang

Water Reuse for Irrigation - Can Developing Countries Afford a Tolerable Disease Burden of No More Than 10-6 Disability-Adjusted Life Years (DALY) Per Person Per Year (PPPY)? .......................................................................................................................... 1417 I. Hespanhol

The Use of Fired Roof Tile and Brick Wastes in Stoneware Bodies as Alternative Raw Materials ................................................................................................................................ 1425 M. Caki, B. Karasu, S. Yesilay, R. Imrak, C. Bayraktar

Amelioration of HCFA for Further Application in Oil Spill Clean Up ....................................... 1433 A. Moutsatsou, I. Kavallari, O. Karakasi

Characterization of MA-MOX Powders and Pellets ................................................................... 1439 A. Neuman, C. Davis, T. Nothwang, F. Hampel, S. Voit, M. Lopez, A. Martinez

Development of a Multi-Stage Process for Reutilization of Coal Pond Ash ........................... 1447 S. Lee, H. Cho, N. Um, G. Han, J. Ahn

Controlled Production Conditions and Characterization of Rice Husk Ash for the Synthesis of ZSM-5 Zeolite .......................................................................................................... 1454 K. Kordatos, A. Ntziouni, L. Iliadis, S. Gavela, K. Pistiolas, A. Kyritsi, V. KasselouriRigopoulou

A New Method to Recycle PET Bottles ....................................................................................... 1460 V. Veselý

The Role of Fly-Ash and Rice-Hull-Ash in Preventing the Degradation of Hybrid Al/SiCp Composites Prepared from Recycled Aluminum ........................................................ 1465 M. Pech-Canul, R. Escalera-Lozano, M. Pech-Canul, J. López-Cuevas, J. Rendón-Angeles, M. Herrera-Trejo, J. Méndez-Nonell

POSTER SESSION Effect of Attrition Scrubbing on the Recovery of Platinum Group Metals from Automotive Catalytic Converters ................................................................................................ 1475 W. Kim, T. Oki, S. Kim, J. Lee

Use of Agro Industrial Residues for Lipase Production ........................................................... 1481 V. Corbellini, M. Macagnan, R. Schneider, M. Vieira, T. Bjerk

Renewable Energy and Amorphous Silica Obtained from Rice Husk Combustion in a Fluidized Bed Reactor ........................................................................................................... 1488 J. Martínez, T. Pineda, J. Junkes, D. Hotza

Incorporation of Sanitary Ware Wastes in Structural Ceramics .............................................. 1498 S. Cosin, G. Martín-Cortés, J. DiRito, F. Valenzuela-Díaz

Metallographic Evaluation of a Breached Container................................................................. 1504 R. Pereyra, D. Schwartz, D. Lovato

Problems and Prospects of Ecological and Technological Development of Hydrocarbon Resources Processing in the Arctic.................................................................... 1515 T. Vyacheslav, L. Ivanova

A Comparative Study of Curaua Waste Fibers Reinforced Epoxy Matrix Composites as Building Material ................................................................................................ 1523 S. Monteiro, A. Ferreira, F. Lopes

Uses of Aggregates Produced from Marble and Granite Quarry Waste in Asphalt Pavements: A Form of Clean Technology.................................................................................. 1529 R. Ribeiro, J. Correia, A. Caranassios

Particle Size and Morphology of MA-MOX Precursor Powders ............................................... 1536 T. Nothwang, A. Neuman, C. Davis, S. Voit, M. Lopez, A. Martinez

Recovery of Precious Metals from Electronic Scraps .............................................................. 1542 I. Lancellotti, F. Andreola, L. Barbieri, R. Giovanardi, E. Soragni

Chlorination of Manganese Oxides............................................................................................. 1547 G. Fouga, G. De Micco, A. Bohé

A Liquidus Temperature Model of High Alumina Blast Furnace Slags................................... 1557 Y. Li, Y. Dong, L. Yu

Application Heat Pumps for Waste Energy Utilization in Sulfuric Acid Production .............. 1564 M. Cirkovic, M. Mitovski, D. Zivkovic, V. Trujic

Processing of Plastic Waste Mixture: Study of Mechanical and Morphologycal Properties ...................................................................................................................................... 1570 L. Montagna, R. Santana

Development of Green Rust/Ferrite Process for Treating Selenium Contaminated Groundwater.................................................................................................................................. 1575 H. Hayashi

Basic Aspects of Ecological and Economical Industrial Waste Material Usage.................... 1581 M. Svoboda, J. Ledererova, P. Sulovsky, M. Suchardova

Recovery of Hexavalent Chromium Using Electrochemical Reactors Provided with Ceramic Diaphragms ............................................................................................................ 1587 J. García-Antón, V. Pérez-Herranz, J. Luís Guiñón, H. Reyes

Exploitation of Crude Glycerol from Biodiesel Production for Alkyd Resin Production ..................................................................................................................................... 1593 R. Schneider, H. Hesse, E. Bavaresco, R. Klamt, L. Dornelles, W. Filho, L. Lara, D. Bottega

Solvent Extraction of Pt(IV) from Acidic Chloride Solutions Using Alamine 336 .................. 1600 J. Lee, R. Kumar, J. Kim, J. Sohn

A Comparative Study between Hybrid Natural/Biodegradation and Biodegradation Methods of Cyanide from Ore Waste Using Native Bacteria ........................ 1606 A. Leal-Cruz, M. Certucha-Barragán, M. Pech-Canul, S. Aguayo-Salinas, J. ValenzuelaGarcía

A Critical Analysis of the Biodiesel Program in Brazil.............................................................. 1611 S. Monteiro, L. Oliveira, L. Marques

Infrastructure for Biodiesel Production from Waste Materials in Campos dos Goytacazes, Brazil ........................................................................................................................ 1617 S. Monteiro, L. Oliveira, L. Marques, V. Marques, A. Stumbo

Biodiesel Produced from Urban Wastes ΠThe Experience of Rio de Janeiro, Brazil.......... 1623 S. Monteiro, L. Oliveira, L. Marques

A Park for Renewable Energy at the State University of the Northern Rio de Janeiro.......... 1629 S. Monteiro, V. Marques, M. Alves, F. Pinheiro, J. Alexandre, P. Silva, A. Stumbo

Biostimulators from the Waste of Tanning Industry ................................................................. 1635 K. Kolomaznik, V. Kasparkova, K. Kodrikova, M. Uhlirova

Biogas Digester with Built-in Solar Collector ............................................................................ 1641 K. Karimov, M. Abid

High Temperature Gasification Using Plasma Technology...................................................... 1646 J. Antoñanzas, J. Carlos Múgica, L. Yurramendi

Solar Pyro-Metallurgical Recycling of Carbon Dioxide - Water [Soda Reactants]................. 1651 N. Neelameggham, M. Deo

Expanded Polystyrene Wastes Recycling by Using Natural Solvents and Supercritical CO2 for Solvent Recovery ..................................................................................... 1657 T. Garcia, J. Rodriguez, A. Lucas, I. Gracia, G. Duque

Development of Pharmaceutical Products from the Wastes of Processed Marine Shellfish Resources of India........................................................................................................ 1664 S. Ramesh

Formulation and Preparation of Pet Foods from Low Value Fishes of India.......................... 1671 R. Santhanam

Nontraditional Reclamation Methods in North Bohemia Region............................................. 1677 V. Cablik, N. Mucha, K. Cechlova, P. Fecko

Author Index

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