LIST OF PARTICIPANTS
DIRECTOR: DR. R.G. WOOLLEY, Cavendish Laboratory, University of Cambridge, Madingley Road, CAMBRIDGE CB3 ORE, United Kingdom. ORGANIZING COMMITTEE: PROFESSOR R.S. BERRY, Department of Chemistry, University of Chicago, 5735 South Ellis Avenue, CHICAGO, Illinois 60637, U.S.A. PROFESSOR J.-M. COMBES, Departement de Mathematiques, Centre Universitaire de Toulon, Chateau Saint-Michel, 83130 LA GARDE, France. DR. B.T. SUTCLIFFE, Department of Chemistry, University of York, Heslington, YORK YOI 5DD, United Kingdom. LECTURERS: PROFESSOR P.G. BURKE, F.R.S., Daresbury Laboratory, Science Research Council, Daresbury, WARRINGTON WA4 4AD, United Kingdom. DR. E.B. DAVIES, Mathematical Institute, University of Oxford, 24-29 St. Giles, OXFORD OXI 3LB, United Kingdom. PROFESSOR DR. W. DEMTRODER, Fachbereich Physik, Universitat Klaiserslautern, D-675 KAISERSLAUTERN, Pfaffenbergstrasse 95, Postfach 3049, West Germany. PROFESSOR R.A. HARRIS, Department of Chemistry, University of California, BERKELEY, California 94720, U.S.A. DR. L. LATHOUWERS, Faculteit der Wetenschappen, Rijksuniversitair Centrum Antwerpen, Middelheimlaan I, 2020 ANTWERP, Belgium. PROFESSOR D.H. LEVY, The James Franck Institute, University of Chicago, 5640 Ellis Avenue, CHICAGO, Illinois 60637, U.S.A. PROFESSOR H. PRIMAS, Laboratory of Physical Chemistry, Swiss Federal Institute of Technology, Universitatstrasse 16, CH-8092 ZURICH, Switzerland. PROFESSO.R S.A. RICE, The James Franck Institute, University of Chicago, 5640 Ellis Avenue, CHICAGO, Illinois 60637, U.S.A. PROFESSOR R. SEILER, Freie Universitat Berlin, Institut fUr Theoretische Physik (WE4), Arnimallee 3, 1000 BERLIN 33, West Germany. PROFESSOR P. VAN LEUVEN, Dienst Theoretische en Wiskundige Natuurkunde, Rijksuniversitair Centrum Antwerpen, Groenenborgerlaan 171, 2020 ANTWERP, Belgium. 549
550
PARTICIPANTS
STUDENTS: Francois G. AMAR, Department of Chemistry, University of Chicago, 5735 South Ellis Avenue, CHICAGO, Illinois 60637, U.S.A. Sheldon ARONOWITZ, National Aeronautics and Space Administration, Ames Research Center, 239-9 MOFFETT FIELD, California 94035, U.S.A. Michael BERMAN, Institute of Chemistry, University of Tel-Aviv, Ramat-Aviv, TEL AVIV, Isra~l. Vincenzo CARRAVETTA, Laboratorio di Chimica Quantistica, Via Risorgimento 35, 56100 PISA, Italy. Renzo CIMlRAGLIA, Istituto di Chimica Fisica, Via Risorgimento 35, 56100 PISA, Italy. Charles W. CLARK, Department of Physics, University of Chicago, 1108 East 58 Street, CHICAGO, Illinois 60637, U.S.A. Monique COMBESCURE, L.P.T.H.E. - Batiment 211, Universite de Paris-Sud, 91405 ORSAY CEDEX, France. Peter D. DACRE, Department of Chemistry, University of Sheffield, SHEFFIELD S3 7HF, United Kingdom. Jens Peder DAHL, Chemistry Department B, Chemical Physics, Technical University of Denmark, DTH 301, DK-2800 LYNGBY, Denmark. Esper DALGAARD, Department of Chemistry, University of Aarhus, DK-8000 AARHUS, Denmark. Ian D. DAWBARN, Mathematical Institute, University of Oxford, 24-29 St. Giles, OXFORD OXI 3LB, United Kingdom. David A. DOLSON, Department of Chemistry, Indiana University, BLOOMINGTON, Indiana 47405, U.S.A. Maarten C.A. DONKERSLOOT, Laboratorium voor Organische Chemie, Eindhoven University of Technology, P.O. Box 513, EINDHOVEN, The Netherlands. Pierre DUCLOS, Departement de Mathematiques, Centre Universitaire de Toulon, Chateau Saint-Michel, 83130 LA GARDE, France. John O. EAVES, Joint Institute for Laboratory Astro-physics, University of Colorado, BOULDER, Colorado 80309, U.S.A. Gregory EZRA, Physical Chemistry Laboratory, University of Oxford, South Parks Road, OXFORD OXI 3QZ, United Kingdom. Knut FAEGRI, Jr., Department of Chemistry, University of Oslo, P.O. Box 1033, Blindern, OSLO 3, Norway. Stavros FARANTOS, School of Molecular Sciences, University of Sussex, Falmer, BRIGHTON BNI 9QJ, United Kingdom. Werner GANS, Laboratory of Physical Chemistry, Swiss Federal Institute of Technology, Universitatstrasse 16, CH 8092 ZURICH, Switzerland. Jean-Pierre GAZEAU, Laboratoire de chimi physique, II rue Pierre et Marie CUrie, 75005 PARIS, France. Genevieve GRENET, Institut de Physique Nucleaire, Universite Claude Bernard Lyon I, 43 bd du II Novembre 1918, 69621 VILLEURBANNE, France. Karl GUSTAFSON, Department of Mathematics, University of Colorado, BOULDER, Colorado 80309, U.S.A. Peter HABITZ, Institut fUr Physikalische Chemie und Elektrochemie, (Theoretische Chemie) , 75 KARLSRUHE, Kaiserstrasse 12, West Germany.
PARTICIPANTS
551
Klaus D. HANSEL, Projektgruppe fUr Laserforschung der Max-Planck Gesellschaft, D-8046 GARCHING, West Germany. Richard HEENAN, Department of Chemistry, University of Reading, Whiteknights, READING RG6 2AD, United Kingdom. Richard M. HEDGES, Jr, Joint Institute for Laboratory Astro-physics, University of Colorado, BOULDER, Colorado, 80309, U.S.A. Thomas HOFFMAN-OSTENHOF, Institut fUr Theoretische Chemie und Strahlenchemie der Universitat Wien, Wihringerstrasse 17, A-I090 VIENNA, Austria. Brian J. HOWARD, Physical Chemistry Laboratory, University of Oxford, South Parks Road, OXFORD OXI 3QZ, United Kingdom. lone IGA, Departamento de Quimica, Universidade Federal de Sao Carlos, Caixa Postal 676, 13560 sAo CARLOS-SP, Brazil. Claude JAUFFRET, U.E.R. Physique Fondamentale, Universit~ des Sciences et Techniques, 59655 VILLENEUVE D'ASCQ CEDEX, France. Juha M. JAVANAlNEN, Research Institute for Theoretical Physics, University of Helsinki, Siltavuorenpenger 20C, 00170 HELSINKI 17, Finland. Maurice KIBLER, Institut de Physique Nucleaire, 43 bd du II Novembre 1918, 69621 VILLEURBANNE, France. Patrick R.R. LANGRIDGE-SMITH, Physical Chemical Laboratory, University of Oxford, South Parks Road, OXFORD OXI 3QZ, United Kingdom. Mu-Tao LEE, Departamento de Quimica, Universidade Federal de Sao Carlos, Caixa Postal 676, 13560 SAO CARLOS-SP, Brazil. Elliott H. LIEB, Departments of Mathematics and Physics, Princeton University, P.O. Box 708, PRINCETON, New Jersey 08544, U.S.A. David E. LOGAN, University Chemical Laboratory, University of Cambridge, Lensfield Road, CAMBRIDGE CB2 lEW, United Kingdom. Giancarlo MARCONI, Laboratorio Frae CNR, Via Castagnoli I, BOLOGNA 40126, Italy. Noemio MACIA MARQUES, Laboratorio de Fisica da Universidade de Lisboa, Faculdade de Ciencias, Rua da Escola Politecnica, 58, 1294 LISBOA CODEX, Portugal. Elaine Ann MOORE, Faculty of Science, The Open University, Walton Hall, MILTON KEYNES MK7 6AA, United Kingdom. John MORGAN, Department of Physics, Princeton University, PRINCETON, New Jersey 08544, U.S.A. Andre NAUTS, Universite Catholique de Louvain, Laboratoire de Chimie Quantique, B~timent Lavoisier - Place Louis Pasteur I, 1348 LOUVAIN-LA-NEUVE, Belgium. T. Tung NGUYEN DANG, Department of Chemistry, McMaster University, HAMILTON, Ontario L8S 4MI, Canada. Jose C. NOGUEIRA, Departamento de Quimica, Universidade Federal de Sao Carlos, Caixa Postal 676, 13560 SAO CARLOS-SP, Brazil. Donald W. NOID, Chemistry Division, Oak Ridge National Laboratory, P.O. Box X, OAK RIDGE, Tennessee 37830, U.S.A. Juan J. NOVOA, Department of Physical Chemistry, Faculty of Chemistry, University of Barcelona, BARCELONA, Spain.
552
PARTICIPANTS
H. Onder PAMUK, Department of Chemistry, Middle East Technical University, ANKARA, Turkey. Rex PENDLEY, Department of Chemistry, Indiana University, BLOOMINGTON, Indiana 47405, U.S.A. Carlo PETRONGOLO, Laboratorio di Chimica Quantistica, Via Risorgimento 35, 56100 PISA, Italy. Peter PFEIFER, Laboratory of Physical Chemistry, Swiss Federal Institute of Technology, Universit~tstrasse 16, CH-8092 ZURICH, Switzerland. Roger PRAT, Laboratoire de Photophysique Moleculaire, Batiment 213, Universite de Paris Sud, 91405 ORSAY CEDEX, France. Guido RAGGIO, Laboratory of Physical Chemistry, Swiss Federal Institute of Technology, Universit~tstrasse 16, CH-8092 ZURICH, Switzerland. Patricia L. RADLOFF, The James Franck Institute, University of Chicago, 5640 Ellis Avenue, CHICAGO, Illinois 60637, U.S.A. Paul B. REHMUS, Department of Chemistry, University of Chicago, 5735 South Ellis Avenue, CHICAGO, Illinois 60637, U.S.A. Joerg REUSS, Faculteit Wiskunde & Natuurwetenshappen, University of Nymegen, Tournooiveld, NYMEGEN, The Netherlands. William C. ROWLAND, Department of Chemistry, Louisiana State University, BATON ROUGE, Louisiana 70803, U.S.A. Francese SAGUES MESTRE, Department of Physical Chemistry, Faculty of Chemistry, University of Barcelona, BARCELONA, Spain. Eduardo SANHUEZA, Quantum Chemistry Group, University of Uppsala, Box 518, S-751 20 UPPSALA I, Sweden. Lutgard SCREIRE, Seminarie voor Theoretische Vaste Stof - en Lage Energie Kernfysica, Rijksunitersiteit Gent, Krigslaan 271/59, B-9000 GENT, Belgium. Stephen J. SMITH, Department of Chemistry, University of York, Heslington, YORK YOI 5DD, United Kingdom. Peter R. TAYLOR, Mathematical Institute, University of Oxford, 24-29 St. Giles, OXFORD OXI 3LB, United Kingdom. Ad VAN DER AVOIRD, Institute of Theoretical Chemistry, University of Nijmegen, Toernooiveld, NIJMEGEN, The Netherlands. Ewine F •. VAN DISHOECK, Gorlaeus-Laboratories, Department of Physical Chemistry, State University Leiden, P.O. Box 75, LEIDEN, The Netherlands. Marc C. VAN REMERT, Gorlaeus-Laboratories, Department of Physical Chemistry, State University Leiden, P.O. Box 75, LEIDEN, The Netherlands. Antonio J.C. VARANDAS, Departamento de Quimica, Universidade de Coimbra, 3000 CO IMBRA , Portugal. Paul E.S. WORMER, Institute of Theoretical Chemistry, University of Nijmegen, Toernooiveld, NIJMEGEN, The Netherlands.
INDEX
Absolute wavelength measurement, 420-421 Absorption coefficient, 390-391 Acceleration cooling, 405 Action-angle variables, 263-271, 274-276, 302, 314-316, 340, 342, 344 Adiabatic Hamiltonian, 469, 475 Adiabatic nuclei approximation, 513, 522, see fixed nuclei approximation Ammonia inversion, 369 Anti-Henon-Hei1es system, 337 Arnold diffusion, 303 Arnold web, 303 Atom-atom scattering, 234-237 Banach space, 69, 70, 76, 90, 96 Barbanis Hamiltonian, 291, 306 Bennet-hole, 407 8-decay, 360-361 Birkhoff normal form, 299-301, 316 Bloch equations, 243, 247 Bohr-Sornrnerfe1d-Wi1son quantization, 305, 311, 312, 316, 319 Boolean algebra, 42-50, 52-56, 65,68,71,73,74,83, 85-88, 100 Boolean atlas, 85-86 Boolean frame of reference, 42-44, 50-55, 65, 70, 74, 83-85 Boolean lattice, 48, 73-76, 78, 84, 89 Boolean logic, 44, 68, 84, 85, 87 553
Boomerang model, 518, 521-522 Borel algebra, 51-55, 66-67 Botel sets, 54-55, 58-60, 65, 67-69, 72, 77, 82 Born approximation, 527-531, 542 Born-Oppenheimer method, 106, 145-148, 154, 155, 157, 159, 164, 180, 197,219, 222, 240, 250, 369, 435, 458-482, 516, 520, 523 Brumer-Toda-Duff criterion, 320, 331-338, 352 C*-a1gebra, 71, 76, 90, 95, 96 Canonical coordinates, 436 Channel functions, 486-487 Chirality in atoms, 364, 366 Chira1 molecules, 368 Chirikov criterion, 338-348, 352 Circular dichroism, 364-366, 372, 375 Clamped nuclei approximation, 460 Classified limit, 475 Clusters, 184-190 Cluster decomposition, 436, 439, 447, 453, 455-456 Compact operator, 445, 447 Continuum multiple scattering method, 539-541 Corio1is coup1ina, 12, 156-157 Corio1is force, 9 Correlation, 182 Correlation functions, 485, 487-488, 498 Coupled nonlinear oscillators, 259-303
554 Detection sensitivity, 388-389 Detector noise, 388 Dilation analytic potentials, 460 Dirichlet-Neumann bracketing, 478-481 Dissociative attachment, 484, 513-526 Doppler-free techniques, 400 Doppler limit, 387 Dunham series, 233 Eckart conditions, 11-13 Eckart frame, 1, 3, 11, 30, 33, 34 Eckart Hamiltonian, 1-9, 31-35, 162 Einstein-Podolsky-Rosen Correlations, 41, 43, 101-102 Einstein quantization condition, 311-312, 321 Electron~olecule collisions, 483-547 Electron-molecular ion collision, 503 Electron scattering by polar molecules, 527-539 Electronic curve, 452, 455-456, 458, 467, see Potent ial energy curve Electronic Hamiltonian, 450 Energy gap model, 131, 138 Euler angles, 5, 9-14, 16-19, 34, 203, 210, 223-225 F-G matrix technique, 13 Fixed nuclei approximation, 483-504, 507, 513, 516, 530 Fixed point, 274-280, 283, 285 Frame transformation theory, 483, 506, 514-517, 524, 530 Galitei group, 102-103 Gaussian overlap approximation, 208, 231-232 Generator coordinate method, 197 -237
INDEX
Geometric cooling, 121, 403 Gibbs State, 240, 243, 251 Glauber approximation, 530-531 Greene Orbital Instability Criterion, 350-352 Hamilton-Jacobi representation, 262, 302 Helleman-Bountis periodic orbital construction, 350-352 Hel1mann-Frynman theorem, 462, 467, 468 Henon-Heiles »amiltonian, 280-286, 293, 296, 299-301, 303-305, 309, 316, 319-324, 327, 350, 351 eigenfunctions of, 309-311 Hilbert space, 30, 69, 72, 77, 80, 82, 90-95, 106, 199, 200, 239, 242, 244, 305, 324-326, 439-442, 451, 466 Hill-Wheeler equation, 200-210, 212, 214-215, 217 HVZ theorem, 448, 450, 452, 454, 455 Hybrid theory, 515-517 Integrals of the motion, 259, 262 isolating, 260, 262, 272, 282, 288, 302, 303 non-isolating, 260, 262, 302 Intermodulated fluorescence technique, 410, 421 and 12 spectrum, 411-412 Intra cavity absorption, 396-398, 412 Intramolecular dynamics, 257-356 Intramolecular energy transfer, 257-356 Inversion, 357-358, see Parity operation Ionization collision-induced, 399 field-, 399 Penning, 399 Spectroscopy, 398-399
INDEX
K-matrix, 493, 503, 517, 526 K-system, 63-66, 83 KAM theory, 61, 62, 263-266, 275-279, 282-286, 302-306, 312-321, 328-331, 350 Kato-Rellich theorem, 442, 444, 446 Kernel Hamiltonian, 200, 201, 205, 208, 211-217, 227, 230 overlap, 200, 201, 205, 208, 211-217, 227, 230 Kohn-variational principle, 485, 511 Kolmogorov-Sinai entropy, 64 L2 -methods, 504-513, 522 -A-doubling, 232 Lamb-dip, 408, 409, 412, 416, 417 Large amplitude motions, 151, 152 Laser, 122, 128, 155, 329, 377-433 colour=centre, 379-381, 383 dye-, 381-385 ring-, 386 semi-conductor, 379-381 spectroscopy, see Spectroscopy spin-flip Raman, 379 Lifetime measurements, 378, 426 Linstedt-Poincar~ method, 288-289 Liouville equation, 349 Lippmann-Schwinger equation, 510 M-matrix, 503 Mach number, 117-126 Mapping area preserving, 273-275, 280, 283 twist, 275-279 Master equation, 245 Measuring apparatus, 328 Method of averaging, 289 Method of multiple time scales, 289 Molecular dimers, 153
555 Molecular energies asymptotic expansion, 475-482, see Dunham series Molecular force field, 258 Molecular spectroscopy, see Spectroscopy Molecular structure, 1, 105, 143, 198, 240, 250, 459 Molecular symmetry group, 148, 153, 158, 162, 169-171, 214 N-body Rinematics, 435-439 N-body Schrooinger operator theory, 435-475 Non-adiabatic effects, 197, 198, 210, 213-215, 221, 232, 428 Non-linear dynamics, 239-255 Non-linear optical mixing techniques, 386 Non-linear Schrodinger equation, 248-252 Nonrigid molecules, 143-190 Norm resolvent continuity, 464, 465, 476 Nuclear magnetic resonance, 150-151 Optical activity, 364, 365, 369-374 Optical-optical double resonance, 422-426 Optical parametric oscillator, 379 Optical pumping, 390 Parity conservation of, 357, 359 operation, 357, 358, 360, 363, 365, 366, 369 violating neutral currents, 361-364, 369, 372, 375 violating potential, 361-364, 374, 375 violations, 357-376 Pendulum motions, 340-343, 353 Permutation group, 145, 157, 159, 170, 172, 174-176
556 Perturbation theory, 288-301, 324 regular, 442 singular, 475 Phase-sensitive detection, 391 Photoacoustic spectroscopy, see Spectroscopy Photochemistry, 115, 126, 127 Photoionization, 398, 503, see Ionization Poincare-Birkhoff theorem, 276, 279, 284 Poincare surface of section, 268, 27 0, 272, 273, 276, 283, 299, 301, 322-329, 340, 351 Potential correlation, 488, 492, 498, 502 direct, 487, 489, 491, 498, 516, 540 energy curve, 525, 537 exchange, 487, 490, 492, 497, 498, 502, 516, 531 polarization, 490, 494-497, 502, 517, 531, 540 Pseudorotation, 144, 150 Pseudostates, 490, 491 Quantum defect theory, 503 Quantum dynamical semigroups, 240-248 Quantum efficiency, 393 Quantum logic, 40, 84, 85, 90, 98 Quantum optics, 243 Quasi-periodic motions, 258, 283, 284, 290, 291, 298, 302-304, 309, 312, 319-321, 330, 331, 348, 350, 352 R-matrix method, 484, 491, 502-509, 514, 517, 519, 522-526, 538 Racemization, 371 Raman-effect, 379 Ram sauer-Town send mln~um 497 Resolvent set, 446, 461, 464 Resonance structure, 345-349
INDEX Resonance theory, 517-522, 526 Resonance zone, 338-340 Rigidity, 143, 157, 161 Rotational excitation crosssection, 501, 514 Runge-Lenz vector, 183 Semiclassical quantization, 310-320, 330, see Bohr-Sommerfeld-Wilson quantization, see Einstein quantization condition Sobolev inequalities, 443 Sobolev norm, 442 Sobolev space, 442, 469, 472 Spectral measure, 73 Spectral properties of Schrodinger Hamiltonians, 446-458 Spectraphone, 394-396 Spectroscopy excitation, 392-394 fluorescence, 390 ionization, 398-399 laser and molecular beams, 400-402 in fast ion beams, 405 molecular, 124 high resolution, 155, 166, 377-433 photoacoustic, 392, 394-396 polarization, 378, 413-422 saturation, 406-413 sub-Doppler laser, 400-426 Spectrum clamped nuclei Hamiltonian, 453 continuous, 446 discrete, 446, 450 essential, 446-450 irregular, 312, 323, 324, 329 regular, 312, 323, 324, 329 Weyl, 446 Stochastic motion, 61, 63, 64, 258, 280, 283, 285, 290, 291, 298, 302-309, 312, 316, 319-321, 325, 330-335, 348-352 Stochastic process, 68
557
INDEX
Sub-Doppler spectral resolution, 378, 388, 406, 409, 424 Supersonic expansion, 116, 120, 124 Supersonic jet, 116, 122, 127, 132 Supersonic molecular beams, 115, 122,124, see Spectroscopy Symmetric double-well potential, 369, 370, 373 Symmetry breaking, 252 T-matrix method, 484, 506, 510-513 Time-reversal invariance, 350, 368 Tin Woodman, 357, 361 Toda Hamiltonian, 286, 287 Trace class linear operators, 239, 241 Translation operator, 449, 456, 457, 465., 468 Tunable coherent light sources, 378-387 Van der Waals bonds, 115, 131, 133, 139 Van der Waals forces, 115 Van der Waals molecule, 115, 125-132, 137, 139, 153, 154 Vibrational excitation, 484, 513-526, 535-536
Vibronic coupling, 215 Virial theorem, 464 Virtual state, 537-539 W*-algebra, 71, 73-78, 81-84, 90-97 W*-system, 40, 77, 78, 81-84, 90-97 Wave function, 144, 145, 182, 198, 199, 210, 212, 234, 251 adiabatic, 459, 468-475 asymptotic Generator coordinate, 236 atomic, 456-457 Wave function (continued) correlated, 182 electronic, 463 asymptotic behaviour, 456-457 of Henon-Heiles Hamiltonian, 309-311 intrinsic, 210, 225 molecular, 214, 223, 224, 228 nodal patterns, 306-309 Wavemeter, 389 Weak coupling lim·it theorem, 245-248 Weinberg-Salam theory, 361, 362, 368 Wigner function, 319-323, 330 Wizard of Oz, 357
