2016 C O P PE R C L A D L AMI N AT E S
HITACHI COPPER CLAD LAMINATES
In the world of electronics, especially information systems
and equipment, advancements are occurring
on a daily basis and many new technologies
are rebuting one after the other.
The solution you need is here Hitachi Chemical Co., Ltd. is engaged
in producing materials from printed wiring boards
to substrates and in processing materials
using "combined technology," a combination of
our existing reliable technologies developed over years
and of leading-edge technologies.
The balanced, reliable, advanced solutions of Hitachi Chemical
and related peripheral technologies are designed
to support the electronics of the future.
CONTENTS ■Recommended Base Materials by Application ……… P 4 ■Characteristics …………………………………………………… P 6 ■Glass Epoxy Multilayer Materials ………………………… P 9 MCL-E-770G ………………………………………………………… P10 MCL-E-705G ………………………………………………………… P12 MCL-E-700G ………………………………………………………… P14 MCL-E-679FG ……………………………………………………… P16 MCL-E-679F Type (R)……………………………………………… P18 MCL-E-78G…………………………………………………………… P20 TD-002 ………………………………………………………………… P22 MCL-E-75G…………………………………………………………… P24 MCL-E-67……………………………………………………………… P26 ……………………………………… P28 MCL-BE-67G Type (H) (R) , ■Materials for ICT Infrastructure ……………………………… P31 MCL-E-679 Type (W)……………………………………………… P32 MCL-E-679F Type (J)……………………………………………… P34 MCL-LW-900G/910G …………………………………………… P36 …………………………………………… P38 MCL-HE-679G Type (S) ■Polyimide Multilayer Material ……………………………… P41 MCL-I-671 …………………………………………………………… P42 ■Glass Epoxy Double Sided Materials ……………………… P45 MCL-E-67 …………………………………………………………… P46 MCL-E-670 …………………………………………………………… P48 ■Materials for Fine Patterning ………………………………… P51 ……………………… P52 SAPP(Semi-Additive Process Primer) PF-E,PF-EL …………………………………………………………… P54 AirFoil ………………………………………………………………… P56 ■Epoxy Adhesive Film …………………………………………… P57 AS-2600 ……………………………………………………………… P58 ■Precautionary Statement ……………………………………… P59 Precautions for Use ………………………………………………… P60 Precautions in Process …………………………………………… P61 Precautions in Designing ………………………………………… P62 Standard Press Condition for Multilayer Board Lamination ……………………………… P63 Precautions for Use of Completed PWB ……………………… P77
■Standards …………………………………………………………… P79 UL Standard ………………………………………………………… P80 BS Standard・CSA Standard ……………………………………… P81 ■KOBELITE Materials for Printed Circuit Boards ……… P83 ■CEM-3 ………………………………………………………………… P84 ………………………… P84 E-668T Type (K) (Tracking resistance) ■High heat-resistance material ……………………………… P86 CEL-475SD (Low thermal-expansion material)……………… P86 ■KOBELITE LAMINATE ………………………………………… P88 …………………………………………………… P90 KEL-GEF Type (R) KEL-571 (Only non-woven aramid structure)………………… P92 KEL-973(Composite structure of non-woven aramid and polyester) P92 ■Authorization under UL ratings …………………………… P94 ■Manufacturing Specifications ……………………………… P96 Safety precautions,Precautions ………………………………… P96
Recommended Base Materials by Application MultiLayer Materials
Product E-770G
E-705G
E-700G
E-679FG
E-679F Type(R)
E-78G
TD-002
E-75G
E-67
BE-67G Type(H),(R)
High Tg, High Elasticity, Low Thermal Expansion
High Tg, High Elasticity, Low Thermal Expansion
High Tg, High Elasticity, Low Thermal Expansion
High Tg, High Elasticity, Low Thermal Expansion
High Tg, High Elasticity, Low Thermal Expansion
Low Dielectric Constant, High Elasticity
Low Elastic Modulus
High Tg, High Heat Resistance
Good Dimensional Reliability, and Dielectric Property
High Heat Resistance
Halogen Free
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Lead Free Application (288℃)
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Consumer products
Environmentally Friendly
Feature
Infrastructure Products Electronics Devices Products Automotive Products
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Digital Consumer Products
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Game Instrument
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Router・Server
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Base Station
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Personal Computer
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Mobile Phone
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Antenna Package For Semiconductor (BGA・CSP・MCM)
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Memory Modules
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Semiconductor Testing Devices
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High-frequency Parts
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Electronic Control Unit
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Automotive Electronics
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UL ANSI
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FR-4.1
FR-4.0
FR-4.1
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FR-4.1
FR-4.0
FR-4.1
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Materials For ICT Infrastructure E-679 Type(W)
High Tg, High insulating Reliability
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Polyimide Multilayer Materials
Glass Epoxy Double Side Materials
E-679F Type(J)
LW-900G HE-679G LW-910G Type(S)
High Tg, High Elasticity
High Tg High Heat High Heat Dimensional Resistance, Resistance, High Tg, Stability, High CTI Low Low Low (More than High Heat Dielectric Dielectric Resistance Warpage 600V) Constant, Constant Low Dissipation Factor
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I-671
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E-67
E-670
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CEM-3
High heat resistance Materials
SAPP
PF-E/ PF-EL
AirFoil
E-668T Type(K)
CEL475SD
Semiadditive Process Compatible
Semiadditive Process Compatible
Semiadditive Process Compatible
High CTI CEM-3
Surface mounting Reliability
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Materials for Fine Patterning
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FR-4.0
FR-4.0
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FR-4.1
GPY
FR-4.0
FR-4.0
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CEM-3
FR-4.0
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5
General Characteristics Multilayer Materials
Condition
Item
Unit
MCL-E-770G Halogen Free
UL ANSI TMA
Tg
DMA X
℃
(30∼120℃)
Y
(<Tg)
CTE
*1
ppm/℃
MCL-E-705G Halogen Free
MCL-E-700G Halogen Free
MCL-E-679FG Halogen Free
MCL-E-679F Type(R)
MCL-E-78G
Halogen Free
MCL-E-75G
TD-002
Halogen Free
MCL-BE-67G Type(H) (R) ,
MCL-E-67
Halogen Free
−
−
−
FR-4.1
FR-4.0
FR-4.1
−
FR-4.1
FR-4.0
FR-4.1
260∼280
250∼270
250∼270
165∼175
160∼170
160∼170
155∼170
155∼170
120∼130
140∼150
320∼340
295∼305
295∼305
200∼220
190∼200
200∼220
−
195∼215
150∼160
180∼220
4∼6
5∼7
7∼9
13∼15
12∼14
13∼15
6∼9
12∼15
13∼16
15∼19
4∼6
5∼7
7∼9
13∼15
12∼14
15∼17
6∼9
14∼17
14∼17
17∼21
8∼13
10∼15
15∼25
23∼33
20∼30
35∼45
80∼130
30∼40
50∼70
40∼55
70∼90
70∼90
90∼120
140∼170
130∼160
180∼230
200∼300
180∼240
200∼300
170∼250
>300
>300
>300
>300
>300
>300
>300
>300
>120
>300
0.6∼0.8
0.9∼1.1
1.0∼1.2
0.9∼1.1
1.1∼1.2
1.0∼1.2
0.8∼0.9
1.2∼1.4
1.4∼1.6
1.2∼1.4
0.8∼1.0
−
−
1.1∼1.2
1.2∼1.3
1.1∼1.3
0.9∼1.1
1.5∼1.8
1.7∼2.1
1.3∼1.5
Z (>Tg)
Solder Heat Resistance(260℃)
A
Sec.
18μm
Copper Peel Strength
A
kN/m
35μm
Surface Roughness
A
μm
2∼3
2∼3
2∼3
2∼3
2∼3
−
5∼13
−
5∼13
5∼13
Flexural Modulus (Lengthwise)
A
GPa
30∼32
32∼34
32∼34
23∼28
27∼33
25∼29
5∼8
25∼29
23∼25
23∼26
4.4∼4.6
4.5∼4.7
4.8∼5.0
5.2∼5.4
4.8∼5.0
4.2∼4.4
−
5.0∼5.2
4.7∼4.8
4.8∼5.0
4.1∼4.3
4.2∼4.4
4.6∼4.8
4.6∼4.8
4.5∼4.7
3.4∼3.6
3.6∼3.8
4.4∼4.6
4.1∼4.2
4.3∼4.5
0.0030∼0.0050
0.0060∼0.0080
0.0080∼0.0100
0.0080∼0.0100
0.0080∼0.0100
0.0070∼0.0090
−
0.0090∼0.0110
0.0130∼0.0170
0.0060∼0.0070
0.0040∼0.0060
0.0070∼0.0090
0.0090∼0.0110
0.0160∼0.0180
0.0130∼0.0150
0.0090∼0.0110
0.011∼0.013
0.0140∼0.0160
0.0180∼0.0200
0.0090∼0.0110
1MHz
Dielectric Constant
C-96/20/65
−
*2
1GHz
1MHz
Dissipation Factor
C-96/20/65
−
*2
1GHz
Volume Resistivity
15
16
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
13
15
1×10 ∼1×10
Ω・cm
1×10 ∼1×10
Ω
1×10 ∼1×10
15
16
1×10 ∼1×10
15
16
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
13
15
1×10 ∼1×10
15
16
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
13
15
1×10 ∼1×10
15
16
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
13
15
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
14
16
1×10 ∼1×10
13
15
1×10 ∼1×10
13
15
15
16
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
1×10 ∼1×10
13
15
1×10 ∼1×10
0.08∼0.12
0.12∼0.14
0.04∼0.08
15
16
1×10 ∼1×10
15
16
1×10 ∼1×10
14
15
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
14
16
1×10 ∼1×10
1×10 ∼1×10
14
15
1×10 ∼1×10
13
15
0.1∼0.3
0.1∼0.3
15
16
14
15
14
16
14
15
C-96/20/65
Surface Resistance
Insulation Resistance
C-96/20/65
A
RH,DC100V
Thermal Conductivity
6
E-24/50 +D24/23
85℃/85%
CAF
Ω
C-96/20/65 +D-2/100
Water Absorption Flammability (UL-94)
1×10 ∼1×10
1×10 ∼1×10
%
*4
0.2∼0.4
*3
0.4∼0.6
*3
*3
0.4∼0.6
0.4∼0.6
*3
0.3∼0.5
−
−
−
V−0
V−0
V−0
V−0
V−0
V−0
V−0
V−0
Hrs.
>2000
>2000
>2000
>2000
>2000
>1000
>2000
>1000
>1000
>1000
0.60∼0.70
0.60∼0.70
0.75∼0.85
0.75∼0.85
0.40∼0.50
0.40∼0.50
0.30∼0.40
0.60∼0.70
0.30∼0.40
0.60∼0.70
Xe-flash W/m・K
*1) Heating Rate: 10℃/min. *2) Measured by Triplate-line Resonator *3) 0.1mm *4) 0.2mm
Polyimide Multilayer Materials
Materials For ICT Infrastructure
MCL-E-679 Type(W)
MCL-E-679F Type(J)
MCL-LW900G/910G
MCL-HE-679G Type(S)
Halogen Free
Halogen Free
MCL-I-671
Glass Epoxy Double Sided Materials
MCL-E-67
MCL-E-670
FR-4.0
FR-4.0
−
FR-4.1
GPY
FR-4.0
FR-4.0
173∼183
165∼175
190∼210
180∼190
200∼213
120∼130
135∼145
205∼215
195∼205
240∼280
260∼280
230∼245
−
−
12∼15
12∼15
12∼15
12∼15
12∼15
13∼16
13∼16
14∼17
14∼17
12∼15
14∼17
12∼16
14∼17
14∼17
50∼60
35∼45
35∼45
30∼40
50∼80
50∼70
23∼35
200∼300
180∼240
240∼290
190∼230
200∼300
200∼300
150∼250
>300
>300
>300
>300
>300
>120
>120
1.2∼1.4
1.1∼1.4
1.3∼1.5
1.4∼1.6
1.2∼1.4
1.5∼1.7
1.7∼2.1
1.4∼1.7
1.5∼1.7
1.4∼1.6
0.5∼0.7
0.5∼0.7
(HVLP)
(RTF)
0.5∼0.8
0.6∼0.8
(HVLP)
(RTF)
5∼13
5∼10
−
5∼13
5∼13
−
−
24∼26
25∼31
16∼21
23∼26
24∼26
−
−
4.7∼4.8
4.6∼4.8
3.30∼3.80
4.10∼4.30
4.2∼4.4
4.7∼4.8
5.2∼5.4
4.2∼4.3
4.2∼4.4
3.20∼3.70
3.70∼3.90
4.1∼4.3
−
−
0.0130∼0.0150
0.0110∼0.0130
0.0005∼0.0010
0.0040∼0.0060
0.0110∼0.0130
0.0130∼0.0170
0.0100∼0.0150
0.0210∼0.0220
0.0170∼0.0190
0.0020∼0.0035
0.0060∼0.0080
0.0130∼0.0150
−
−
15
16
1×10 ∼1×10
15
16
1×10 ∼1×10
14
16
1×10 ∼1×10
14
16
1×10 ∼1×10
13
15
1×10 ∼1×10
13
15
1×10 ∼1×10
13
15
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
14
16
1×10 ∼1×10
14
16
1×10 ∼1×10
14
16
1×10 ∼1×10
1×10 ∼1×10
13
15
1×10 ∼1×10
13
15
1×10 ∼1×10
13
15
1×10 ∼1×10
13
14
0.15∼0.20
0.12∼0.17
0.2∼0.4
V−0
V−0
>2000
0.30∼0.40
1×10 ∼1×10
1×10 ∼1×10
1×10 ∼1×10
15
16
1×10 ∼1×10
15
16
1×10 ∼1×10
13
15
1×10 ∼1×10
14
16
1×10 ∼1×10
1×10 ∼1×10
13
15
0.1∼0.3
V−0
>2000
0.70∼0.75
15
16
13
15
1×10 ∼1×10
13
15
14
16
1×10 ∼1×10
14
16
1×10 ∼1×10
13
15
1×10 ∼1×10
13
15
0.10∼0.20
0.06∼0.08
0.1∼0.14
V−0
V−0
V−0
V−0
>2000
>1000
>1000
>1000
>1000
0.40∼0.50
0.40∼0.50
0.25∼0.35
0.30∼0.40
−
Above properties are typical figures as a laminate. The figures as PCB may change depending on its material construction.
7
General Characteristics High heatresistance material
CEM-3
Item
Condition Unit JIS UL ANSI TMA
Tg
DMA X Y
(30∼80℃)
(<Tg)
CTE
℃
ppm/℃
E-668T Type(K)
CEL-475SD
CGE3F CEM-3
GE4F FR-4.0
130∼140
170∼190
−
200∼210
18∼22
9∼11
19∼23
11∼13
*1
*1
40∼50
50∼70
280∼300
270∼370
>120
>600
1.2∼1.6
1.1∼1.3
1.8∼2.2
1.5∼1.7
Z (>Tg)
Solder Heat Resistance(260℃)
Copper Peel Strength
A
Sec.
18μm A
*2
kN/m
35μm
Surface Roughness
A
μm
−
−
Flexural Modulus (Lengthwise)
A
GPa
−
19∼21
4.4∼4.8
4.2∼4.6
C-96/20/65
− −
3.9∼4.3
0.024∼0.030
0.020∼0.024
−
0.023∼0.027
1MHz
Dielectric Constant 1GHz
1MHz
Dissipation Factor
C-96/20/65
*4
−
1GHz
*4
Volume Resistivity
C-96/20/65 Ω・cm
5×10 ∼5×10
Surface Resistance
C-96/20/65
5×10 ∼5×10
Insulation Resistance
Ω
C-96/20/65
15
16
1×10 ∼1×10
14
15
1×10 ∼1×10
14
15
5×10 ∼5×10
13
14
1×10 ∼1×10
1×10 ∼1×10
14
15
13
14
14
15
14
15
Ω C-96/20/65 +D-2/100
1×10 ∼1×10
E-24/50 +D24/23
%
0.04∼0.08 (1.6mm)
0.05∼0.07 (1.6mm)
Thermal Conductivity
A
W/m・K
0.6∼0.8
−
Flammability (UL-94)
A
−
V−0
V−0
85℃/85% RH,DC100V
Hrs.
>1000
Water Absorption
CAF
*5
*1) 30∼80℃. *2) 200∼250℃. *3) Measured by Impedance Analyzer *4) Measured by Network Analyzer *5) Condition:85℃/85%RH,DC30V
8
*5
>1000
Glass Epoxy Multilayer Materials Halogen Free, High Tg, High Elastic Modulus, Ultra Low CTE Multilayer Material
Halogen Free, Low Dielectric Constant, High Tg and High Heat Resistance Multilayer Material
P10
P20
Halogen Free, High Tg, High Elastic Modulus and Low CTE Multilayer Material
Reduction of Solder Crack/ Low Elastic Modulus Material
P12
P22
Halogen Free, High Tg, High Elastic Modulus and Low CTE Multilayer Material
Halogen Free, High Tg and High Heat Resistance Multilayer Material
P14
P24
Halogen Free, High Elastic Modulus and Low CTE Multilayer Material
FR-4 Multilayer Material
MCL-E-679FG
MCL-E-67
P16
P26
High Elastic Modulus and Low CTE Multilayer Material
Halogen Free FR-4 Multilayer Material
MCL-E-679F Type(R)
MCL-BE-67G Type(H),(R)
P18
P28
MCL-E-770G
MCL-E-705G
MCL-E-700G
MCL-E-78G
TD-002
MCL-E-75G
9
Halogen Free, High Tg, High Elastic Modulus, Ultra Low CTE Multilayer Material
MCL-E-770G
GEA-770G〈Prepreg〉
High Tg Glass Epoxy Multilayer Materials ■Features
●MCL-E-770G has ultra low CTE property in x,y direction and reduce warpage of package substrate significantly. ●MCL-E-770G(LH) has ultra low CTE value(less than 2.0ppm/℃). ●GEA-770G is suited for EPS(Embedded Passive Substrate) construction package. ●Well-suited for Build-up construction.
■Standard Specifications Part Number
Type
Copper Foil Thickness
ー
3μm 5μm 12μm (STD,LP,PF)
MCL-E-770G
●Semiconductor packages. (FC-CSP,PoP,SiP) ●Core material for HDI. ●Core material for Thinner Module.
Code Name
Actual Thickness and Tolerance
M0.06 0.1 HD0.15 M0.22 0.2 0.41 LHU0.04 LHM0.06 LH0.1 LHD0.15 LH0.2 LHY0.25
3,5,12μm (LP,PF) 3μm 5μm 12μm 18μm (STD,LP,PF)
(LH)
■Applications
0.060±0.020mm 0.110±0.020mm 0.155±0.020mm 0.205±0.030mm 0.210±0.040mm 0.415±0.040mm 0.040±0.013mm 0.060±0.020mm 0.105±0.020mm 0.155±0.020mm 0.210±0.030mm 0.255±0.030mm
Note1)In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note2) The thickness means that of dielectric layer.
■Characteristics ●Thin Laminate
(t0.2mm) Condition
Item
TMA
Tg
DMA X
CTE
Y
*1
Z
ppm/℃
min.
Decomposition Temperature
TGA
℃
Heat Resistance for HDI Process(Semi Additive)
260℃Reflow
12μm
kN/m
Surface Roughness (Ra)
A
μm
Flexural Modulus (Lengthwise)
A
GPa
Dielectric Constant Dissipation Factor
18μm
1MHz 1GHz*2 1MHz 1GHz*2
C-96/20/65 C-96/20/65
− −
Volume Resistivity
C-96/20/65+C-96/40/90
Ω・cm
Surface Resistance
C-96/20/65+C-96/40/90
Ω
Insulation Resistance
1.5∼2.0 8∼13
C-96/20/65 C-96/20/65+D-2/100
Water Absorption
E-24/50+D-24/23
CAF
85℃/85%RH, DC100V
*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator. t0.4mm thickness core is used depending on test item.
>300 >60 >60
430∼450 >20
cycles
A
Copper Peel Strength
1.5∼2.0
4.0∼6.0 70∼90
TMA
T288 (Without copper)
320∼340
(>Tg) sec.
T260 (Without copper)
MCL-E-770G Type (LH) 260∼280
4.0∼6.0
(30∼120℃) (<Tg)
Actual Value
MCL-E-770G
℃
A
Solder Heat Resistance (260℃)
10
Unit
Ω
0.5∼0.7 0.6∼0.8 2∼3 30∼32
34∼36
4.4∼4.6
4.2∼4.4
4.1∼4.3
3.9∼4.1
0.003∼0.005
0.003∼0.005
0.004∼0.006
0.004∼0.006
1×10
15
∼1×1016
1×1013∼1×1015 1×1014∼1×1016 1×1013∼1×1015
%
0.2∼0.4
Hrs.
>2000
●Prepreg Glass Cloth Designation
Type
GEA-770G
0.025 0.025 0.03 0.03 0.04 0.025 0.025 0.03 0.03 0.035 0.035 0.04 0.045
ー
(L)
Style 1017N72 1017N76 1027N72 1027N76 1037N72 L1017N72 L1017N76 L1027N72 L1027N76 L1024N68 L1024N73 L1037N72 L1030N71
1017 1017 1027 1027 1037 1017 1017 1027 1027 1024 1024 1037 1030
Properties Resin Content Volatile Content Gelation Time Dielectric Thickness (%) (%) (sec.) after Lamination*1(mm) 0.025 72±2 0.030 76±2 0.040 72±2 270±30 0.048 76±2 0.048 72±2 0.025 72±2 ≦2.0 0.030 76±2 0.040 72±2 0.048 76±2 270±30 0.041 68±2 0.050 73±2 0.048 72±2 0.058 71±2
Yarn Count (warp×fill) 95×95 95×95 75×75 75×75 69×72 95×95 95×95 75×75 75×75 69×72 53×53 69×72 90×90
Test Method (IPC-TM-650)
2.3.16
2.3.19
2.3.18
−
※1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●Warpage of FC-CSP
Underfill
●Narrow pitch CAF restraing
TEG Chip Chip *Package size : 14×14mm *Chip size : 7.3×7.3mm *Chip thickness : 150μm *Underfill thickness : 60μm (CEL-C-3730-4) *Solder Resist : 20μm(FZ-2700GA) Core Thickness 200μm+1024(S-HD)PPG MCL-E-705G (LH) +GEA705G (L) MCL-E-770G (LH) +GEA705G (L) substrate MCL-E-770G (LH) +GEA770G (L)
Condition : 130℃ 85%RH-DC5.5V Construction : t0.2mm (Core : #2116×2ply) Drill Diameter:Φ0.10mm Pre-condition : 30℃ 60%RH 168hr+260℃ reflow 3times measure condition:
+
-
150 Convex
RoomTemp (afterreflow)
50
0
-50
-100
Reflow Temp
Concave
E705G (LH) E770G (LH) E770G (LH) +GEA705G (L) +GEA705G (L) +GEA770G (L) 25℃
265℃
25℃
Inslation Resistance (Ω)
Warpage (μm)
100
Room Temp(Start)
1.00E+11
Wall to wall distance 90μm
1.00E+10 1.00E+09 1.00E+08 1.00E+07 1.00E+06 1.00E+05 0
50
100
150
200
250
300
350
Treatment Time (hr)
E770G(t0.2):E-glass
11
Halogen Free, High Tg, High Elastic Modulus and Low CTE Multilayer Material
MCL-E-705G GEA-705G〈Prepreg〉 High Tg Glass Epoxy Multilayer Materials ■Features
●MCL-E-705G has very low CTE property in x,y direction and would reduce warpage of package substrate significantly. ●MCL-E-705G(L) has ultra low CTE value(lower than 5ppm/℃). ●MCL-E-705G(LH) has ultra low CTE value(3ppm/℃). ●Well-suited for Build-up construction.
■Standard Specifications
Type
Part Number
Copper Foil Thickness 3μm 5μm 12μm (LP,PF) 3μm 5μm 12μm 18μm (STD,LP,PF)
(−) (L)
3μm 5μm 12μm 18μm 35μm 70μm (STD,LP,PF)
MCL-E-705G
3μm 5μm 12μm (STD,LP,PF)
(LH)
■Applications
●Semiconductor packages. (FC-BGA,FC-CSP,POP,SiP) ●Core material for HDI. ●Core material for Thinner Module. Code Name U0.03 *Note 3 U0.04 T0.06 *Note 3 M0.06 0.1 M0.11 M0.15 M0.22 0.2 0.31 0.41 0.51 0.61 0.71 0.81 M0.06 0.1 D0.15 0.2 0.26
Actual Thickness and Tolerance 0.03±0.013mm 0.04±0.013mm 0.06±0.013mm 0.06±0.02mm 0.11±0.02mm 0.10±0.02mm 0.15±0.02mm 0.21±0.03mm 0.21±0.03mm 0.31±0.03mm 0.41±0.04mm 0.52±0.05mm 0.62±0.06mm 0.72±0.07mm 0.82±0.08mm 0.06±0.02mm 0.11±0.02mm 0.15±0.02mm 0.21±0.03mm 0.26±0.03mm
Note 1)In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2)The thickness means that of dielectric layer. Note 3)Please contact us for U0.03 and T0.06. Note 4)Initial letter“U” stands for 1ply and“T” for 2ply.
■Characteristics ●Thin Laminate
(t0.1mm) Condition
Item TMA
Tg
DMA X
CTE
Y
*1
Z Solder Heat Resistance (260℃) T260 (Without copper) T288 (Without copper) Decomposition Temperature
(<Tg)
Copper Peel Strength
ppm/℃
A
min.
TGA
℃
μm GPa
Dissipation Factor
1GHz*2
2.5∼3.5
3∼4
2.5∼3.5
10∼15
>60
C-96/20/65
−
C-96/20/65
−
430∼450
2.3.40
>20
−
0.8∼1.0
34∼36
37∼39
2.4.4
4.5∼4.7
4.3∼4.5
4.3∼4.5
2.5.5.1
4.2∼4.4
4.0∼4.2
4.0∼4.2
2.5.5.5
0.006∼0.008
0.006∼0.008
0.006∼0.008
2.5.5.1
0.007∼0.009
0.007∼0.009
2.5.5.5
0.007∼0.009
15
16
13
15
1×10
Surface Resistance
C-96/20/65+C-96/40/90
Ω
1×10
C-96/20/65+D-2/100
Water Absorption
E-24/50+D-24/23
CAF
85℃85%RH,DC100V
*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator. 0.4mm thickness core is used depending on test item.
% Hrs.
2.2.17
2∼3 32∼34
Ω・cm
Ω
2.4.8
0.9∼1.1
C-96/20/65+C-96/40/90 C-96/20/65
2.4.24.1
>60
Volume Resistivity
Insulation Resistance
2.4.24
−
>300
kN/m
A
1MHz
3∼4
5∼7
cycles
A
1GHz*2
−
70∼90
Flexural Modulus (Lengthwise) 1MHz
2.4.24
295∼305
sec.
TMA
A
250∼270 5∼7
(>Tg)
Surface Roughness (Ra)
Dielectric Constant
12
18μm
Test Method (IPC-TM-650) MCL-E-705G MCL-E-705G Type(L)MCL-E-705G Type(LH)
℃
(30∼120℃)
Heat Resistance for HDI Process(Semi Additive) 260℃Reflow 12μm
Unit
Actual Value
∼1×10 ∼1×10
14
16
13
15
1×10 1×10
∼1×10
∼1×10
0.4∼0.6 >2000
2.5.17 − − 2.6.2.1 −
●Prepreg Designation
Type 0.025 (1017N73) 0.03 (1027N73) ー 0.04 (1037N73) 0.06 (1078N65) 0.1 (2116N58) 0.025(L1017N73) 0.03 (L1027N73) 0.035(L1024N70) 0.035(L1024N75) (L) 0.04 (L1037N73) 0.045(L1030N69) 0.045(L1030N73) 0.06 (L1078N65) 0.1 (L2116N58)
GEA-705G
Glass Cloth Yarn Count Style (warp×fill) 1017 95×95 1027 75×75 1037 69×72 1078 53×53 2116 60×58 1017 95×95 1027 75×75 1024 90×90 1024 90×90 1037 69×72 1030 90×90 1030 90×90 1078 53×53 2116 60×58
Properties Resin Content Volatile Content Gelation Time Dielectric Thickness (%) (%) (sec.) after Lamination*1(mm)
Test Method (IPC-TM-650)
0.025 0.040 0.048 0.071 0.126 0.025 0.040 0.042 0.050 0.048 0.050 0.060 0.071 0.126
160±30
73±2 73±2 73±2 65±2 58±2 73±2 73±2 70±2 75±2 73±2 69±2 73±2 65±2 58±2
≦2.0
2.3.16.1
2.3.19
180±30 200±30 160±30
180±30
200±30 2.3.18
−
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●Warpage of FC-BGA
●Warpage Evaluation Results
TEG Chip *Chip size:20mm×20mm *Chip thickness:0.725mm *Bump diameter:80μm *Bump pitch:200μm TEG Substrate *Sub size:35mm×35mm *Core thickness:0.4mm *Build up thickness:30μm×2stack *SR thickness:20μm
TEG Substrate spec *Size:14mm×14mm *Total thickness:250μm *SR thickness:20μm (SR-7200G:Hitachi Chemical) *Prepreg thickness:40μm *Core thickness:110μm
200
150 Convex
100 50 0 -50 -100
0 -50 -100
High Tg MCL-E-700G Halogen Free (R) FR-4
-200
MCL-E-705G
MCL-E-700G (R) 25℃
265℃
260℃
Inslation resistance(Ω)
1E+14 1E+13 1E+12 1E+11 1E+10 200
400
600
Treatment Time (h)
MCL-E-705G
MCL-E-705G (L)
Hole wall distance 90μm
1E+15
0
Concave
25℃
●Narrow pitch CAF restraing Hole wall distance 110μm
Inslation Resistance (Ω)
50
-150 Concave
-150
1E+9
Convex
100
Warpage (μm)
Warpage (μm)
150
800
1000
1E+15 1E+14 1E+13 1E+12 1E+11 1E+10 1E+9
0
200
400
600
800
1000
Treatment time(h) Condition:130℃85%RH DC5.5V structure:t0.2 (#1078×3ply) Drill Diameter:100μm Pre-condition:30℃60%RH168hr+260℃Reflow (3cycle)
13
Halogen Free, High Tg, High Elastic Modulus and Low CTE Multilayer Material
MCL-E-700G
GEA-700G〈Prepreg〉
High Tg Glass Epoxy Multilayer Materials ■Features
■Applications
●Well-suited for Build-up construction.
●Core material for HDI.
●MCL-E-700G has very low CTE in x,y direction and would reduce warpage of package substrate significantly.
●Semiconductor packages. (FC-BGA,FC-CSP,POP,SiP) ●Core material for Thinner Module.
●Good drill processability : lower process cost.
■Standard Specifications Part Number
Copper Foil Thickness
Type (R)
Code Name U 0.03 *Note 3 U 0.04 T 0.04 *Note 3 U 0.05 T 0.06 M 0.06 0.1 M 0.11 M 0.15 M 0.22 0.2 0.31 0.41 0.51 0.61 0.71 0.81
2μm 3μm 5μm 12μm (LP,PF) 2μm 3μm 5μm 12μm 18μm (STD,LP,PF)
(R) MCL-E-700G (RL)
2μm 3μm 5μm 12μm 18μm 35μm 70μm (STD,LP,PF)
Actual Thickness and Tolerance 0.03±0.013mm 0.04±0.013mm 0.04±0.013mm 0.05±0.013mm 0.06±0.013mm 0.06±0.02mm 0.11±0.02mm 0.10±0.02mm 0.15±0.02mm 0.20±0.03mm 0.20±0.03mm 0.30±0.03mm 0.40±0.04mm 0.50±0.05mm 0.60±0.06mm 0.70±0.07mm 0.80±0.08mm
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) The thickness means that of dielectric layer. Note 3) Please contact us for U0.03 and T0.04. Note 4) Initial letter "U" stands for 1ply and "T" for 2ply. (1) Thickness of STD:12μm, 18μm, 35μm, 70μm. (2) Thickness of LP:2μm, 3μm, 5μm, 12μm, 18μm. (3) Thickness of PF:2μm, 3μm, 5μm, 12μm.
■Characteristics ●Thin Laminate
(t0.1mm) Condition
Item TMA
Tg
DMA X
CTE
Y
*1
Z Solder Heat Resistance (260℃) T-260 (Without Copper)
(<Tg) A
Heat Resistance for HDI Process(Semi Additive) 260℃ reflow Copper Peel Strength
18μm
A
ppm/℃
Volume Resistivity Surface Resistance Insulation Resistance
1GHz*2
C-96/20/65 C-96/35/90+C-96/40/90 C-96/20/65 C-96/20/65+D-2/100
Water Absorption
E-24/50+D-24/23
Flammability (UL-94)
A
CAF
85℃/85%RH, DC100V
*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator 0.4mm thickness core is used depending on test item.
>300
−
>60
2.4.24.1
>60
℃
430∼450
2.3.40
>20
−
0.9∼1.1
kN/m μm
C-96/20/65
2.4.24
cycle
GPa
Dissipation Factor
5∼7 15∼25
min.
A
1MHz
7∼9 90∼120
A
1GHz*2
− 5∼7
sec.
Flexural Modulus (Lengthwise) 1MHz
2.4.24
295∼305 7∼9
Surface Roughness (Ra)
Dielectric Constant
14
12μm
250∼270
(>Tg)
TGA
Decomposition Temperature
Test Method (IPC-TM-650) MCL-E-700G Type (R)MCL-E-700G Type (RL)
℃
(30∼120℃)
TMA
T-288 (Without Copper)
Unit
Actual Value
− − Ω・cm Ω Ω
2.4.8
1.0∼1.2 2∼3
2.2.17
32∼34
34∼36
2.4.4
4.8∼5.0
4.6∼4.8
2.5.5.1
4.6∼4.8
4.2∼4.4
2.5.5.5
0.008∼0.010
0.008∼0.010
2.5.5.1
0.009∼0.011
0.010∼0.012
2.5.5.5
15
1×10
∼1×1016
1×1013∼1×1015 14
1×10
16
∼1×10
2.5.17 −
1×1013∼1×1015
−
0.4∼0.6
2.6.2.1
−
V−0
2.3.10
hrs.
>2000
−
%
●Prepreg Glass Cloth Yarn Count Style (warp×fill)
Designation
Type
GEA-700G
0.025 (1017N74) 0.03 (1027N74) (ー) 0.04 (1037N74) 0.06 (1078N66) 0.1 (2116N59) 0.03 (L1027N74) (L) 0.04 (L1037N74) 0.06 (L1078N66)
Properties Resin Content Volatile Content Gelation Time Dielectric Thickness (%) (%) (sec.) after Lamination*1(mm) 74±2 74±2 74±2 66±2 59±2 74±2 74±2 66±2
≦2.0
2.3.16.1
2.3.19
95×95 75×75 69×72 53×53 60×58 75×75 69×72 53×53
1017 1027 1037 1078 2116 1027 1037 1078
Test Method (IPC-TM-650)
130±30
0.025 0.040 0.048 0.072 0.127 0.040 0.048 0.072
2.3.18
−
160±30 130±30 125±30 160±30
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●Amount of deflection by hole area
●Elastic Modulus 0.4
Actual package aperture ratio
16 14
(R) MCL-E-700G Type
0.3
High Tg Halogen Free FR-4
0.2
1E+9
12 Flexure(mm)
1E+10 tan δ
Elastic Modulus(Pa)
1E+11
0.1
10 8
High Tg Halogen Free FR-4
6
MCL-E-700G Type (R)
4 2
1E+8
0
100
150 200 ( ℃) Temperature
250
0 300
0
●FC-BGA Warpage
1E+13 1E+12 1E+11 1E+10
1E+15 -50
-100
Convex MCL-E-700G Type (R)
MCL-E-700G Type (RL)
Insulation Resistance (Ω)
Warpage (μm)
0
265℃
40
1E+14
1E+9
Concave
25℃
20 30 Hole area ratio (%)
1E+15 Insulation Resistance (Ω)
50
High Tg Halogen Free FR-4
10
●Narrow Pitch reliability Wall to wall distance : 110μm
TEG Chip *Chip size : 20mmx20mm *Chip thickness : 0.725mm *Bump diameter : 80μm *Bump pitch : 200μm *TEG Substrate *Sub size : 35mmx35mm *Core thikness : 0.7mm *Build up thickness : 30μmx2 stack *SR thickness : 20μm
-150
0
0
200
400 600 Treatment Time(h)
800
1000
Wall to wall distance : 90μm
1E+14 1E+13 1E+12 1E+11 1E+10 1E+9
0
200
400 600 800 Treatment Time(h)
1000
Condition:130℃85%RH 5.5V Construction : t0.2 (#1078x3ply) Drill hole : 100μm Pre-condition : 30℃60%RH168hr+260℃ reflow 3 times
15
Halogen Free, High Elastic Modulus and Low CTE Multilayer Material
MCL-E-679FG
MCL-E-679FGB〈Black Type〉 GEA-679FG〈Prepreg〉
High Tg Glass Epoxy Multilayer Material(FR-4) ■Features
■Applications
●Halogen free material for environmental concerns. ●CTE (Z-direction) is about 50% lower than that of our standard FR-4. ●Elastic modulus is about 20% higher than that of our standard FR-4. Even thin laminate has less warpage and deflection.
●Semiconductor packages. (FC-BGA, BGA, CSP) ●Core material for HDI.
●Superior heat resistance for soldering.(Suitable for the lead free process) ●Surface roughness is about 1/4 of our standard FR-4, and making fine pattern possible.
■Standard Specifications Part Number
Type
Copperfoil Thickness 2μm 3μm 5μm 12μm (LP、 PF)
(S) MCL-E-679FG MCL-E-679FGB
Code Name U0.03 U0.04 U0.05 T0.04 T0.05 T0.06 T0.07 M0.06 0.1 0.15 0.2 0.3 0.41 0.61 0.81
Actual Thickness and Tolerance 0.030±0.013mm 0.040±0.013mm 0.050±0.013mm 0.040±0.013mm 0.050±0.013mm 0.060±0.013mm 0.070±0.013mm 0.07±0.02mm 0.11±0.02mm 0.16±0.03mm 0.21±0.04mm 0.32±0.05mm 0.40±0.05mm 0.60±0.06mm 0.80±0.08mm
2,3,5,12,18μm (STD,LP,PF) 2μm 3μm 5μm (R) 12μm (S) 18μm 35μm 70μm (STD,LP,PF) Note 1)STD;Standard copper foil,LP;Low profile copper foil,PF;Hitachi profile free copper foil Note 2)In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 3)The thickness means that of dielectric layer. Note 4)Initial letter "U" stands for 1ply and "T" for 2ply. (1) Thickness of STD:12μm, 18μm, 35μm, 70μm. (2) Thickness of LP:2μm, 3μm, 5μm, 12μm, 18μm. (3) Thickness of PF:2μm, 3μm, 5μm, 12μm.
■Characteristics ●Thin Laminate
(t0.1mm)
Item
Condition
Tg CTE *1
X Y Z
Solder Heat Resistance (260℃) T-260 (Without Copper) T-288 (Without Copper) Decomposition Temperature Heat Resistance for HDI Process(Semi Additive) 18μm Copper Peel Strength 35μm Surface Roughness (Ra) Flexural Modulus (Lengthwise) 1MHz Dielectric Constant 1GHz*2 1MHz Dissipation Factor 1GHz*2 Volume Resistivity Surface Resistance
TMA DMA (30∼120℃) (<Tg) (>Tg) A TMA
16
℃ ppm/℃ sec. min.
TGA 260℃ Reflow
℃ cycles
A
kN/m μm GPa
A A C-96/20/65
−
C-96/20/65
−
C-96/35/90
Ω・cm Ω
C-96/20/65 C-96/20/65+D-2/100 E-24/50+D-24/23 Water Absorption A Flammability (UL-94) 85℃/85%RH, DC100V CAF *1)Heating Rate:10℃/min. *2)Measured by Triplate-Line Resonator 0.8mm thickness core is used depending on test item. Insulation Resistance
Unit
Ω % − hrs.
Test Method MCL-E-679FG Type (R) MCL-E-679FG Type (S) (IPC-TM-650) 165∼175 2.4.24 175∼185 200∼220 ー 210∼230 13∼15 12∼14 13∼15 12∼14 2.4.24 23∼33 20∼30 140∼170 130∼160 ー >300 >60 2.4.24.1 >60 340∼360 2.3.40 >10 ー 1.1∼1.2 0.9∼1.1 2.4.8 1.2∼1.3 1.1∼1.2 2∼3 2.2.17 24∼29 2.4.4 23∼28 5.0∼5.2 2.5.5.1 5.2∼5.4 4.6∼4.8 2.5.5.5 0.008∼0.010 2.5.5.1 0.016∼0.018 2.5.5.5 15 16 1×10 ∼1×10 2.5.17 13 15 1×10 ∼1×10 1×1014∼1×1016 ー 1×1013∼1×1015 ー 0.4∼0.6 0.3∼0.5 2.6.2.1 V−0 2.3.10 >2000 ー Actual Value
●Prepreg Part Number
Style
Type
0.03 0.04 (R) 0.06 0.1 0.025 0.025 GEA-679FG 0.03 0.03 (S) 0.03 0.04 0.06 0.1
GBPE GRZPE GRROE GRSKE GSANE GSAOE GSAPE GSBPE GSBSE GSZPE GSROE GSSKE
Glass Cloth Yarn Content (warp×fill)
1027 1037 1078 2116 1017 1017 1017 1027 1027 1037 1078 2116
Properties Resin Content Volation Content Gelation Time Dielectric Thickness(mm) (%) (%) (Sec.) *1()After pattern filling >1.5 175±30 0.040 73±2 165±30 0.048 73±2 >1.0 0.079 68±2 155±30 0.0127 58±2 0.024 72±2 0.027 75±2 >1.5 0.031 78±2 175±30 0.040 73±2 0.050 78±2 0.048 73±2 >1.0 0.079 68±2 165±30 0.127 58±2
75×75 69×72 53×53 60×58 95×95 95×95 95×95 75×75 75×75 69×72 53×53 60×58
Test Method (IPC-TM-650)
2.3.16.1
2.3.19
2.3.18
−
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●HAST Properties
●Stiffness Property
1014
12 Weight (1g)
10
1013
90μm 110μm
Flexure (mm)
Insulation Resistance (Ω)
70μm
1012 Sample;MCL-E-679FG (ST0.06) / GEA-679FG (GSBPE) Pre-condition;Reflow260℃×3pass Condition;85℃85%RH,DC50V Drill Diameter;0.1mm
1011
8
Flexure
Span
6 4 2
1010
1 9
10
0
200
400
600
800
0
1000
U0.04
T0.04
U0.05
T0.06
T0.07
Span Span Span Span Span Span Span
: : : : : : :
10mm 15mm 20mm 25mm 30mm 35mm 40mm
Thickness
Treating time (Hr)
●Prepreg thickness after pattern filling (Inner layer copper 15μm)
60
GSBSE
prepreg thickness (μm)
50
GSBPE
40
GSAPE
30
GSANE 20 10 Prepreg Thickness
0
0
10
20
30
40
50
60
70
80
90
100
Copper remain ratio (%)
17
High Elastic Modulus and Low CTE Multilayer Material
MCL-E-679F Type(R)GEA-679F(R)〈Prepreg〉 High Tg Glass Epoxy Multilayer Material(FR-4) ■Features
●The coefficient of thermal expansion is about 20% (in the Xand Y-directions) and about 50% (in the Z-direction) lower than that of our standard FR-4. ●Elastic modulus is about 30% higher than that of our standard FR-4. Even thin laminate has less warpage and deflection. ●Superior heat resistance at PCT.
■Applications ●Semiconductor packages.(FC-BGA, BGA, CSP) ●Core material for HDI. (MCL-E-679F type (R) is recommended for FC-BGA with insulation film.)
●The surface roughness is about 1/4 that of our standard FR-4, making fine pattern possible.
■Standard Specifications Part Number
Type
Copper Foil Thickness 3,5,12,18,35μm
MCL-E-679F
3μm 5μm 12μm 18μm 35μm 70μm (STD,LP,PF)
(R)
Code Name
Actual Thickness and Tolerance
M0.06
0.07±0.02mm
0.1
0.11±0.02mm
0.15
0.16±0.03mm
0.2
0.21±0.04mm
0.3
0.32±0.04mm
0.4
0.41±0.05mm
0.6
0.61±0.06mm
0.8
0.80 (0.70) ±0.09mm
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) The thickness means that of dielectric layer. Figure in bracket ( )means thickness of dielectric layer of MCL using 70μm copper foil. (1) Thickness of STD:12μm, 18μm, 35μm, 70μm. (2) Thickness of LP:3μm, 5μm, 12μm, 18μm. (3) Thickness of PF:3μm, 5μm, 12μm.
■Characteristics ●Thin Laminate
(t0.1mm) Condition
Item TMA
Tg
DMA X
CTE
Y
*1
Z Solder Heat Resistance (260℃) T-260 (Without Copper)
(<Tg) A
Heat Resistance for HDI Process(Semi Additive) 260℃ Reflow Copper Peel Strength
Test Method (IPC-TM-650)
160∼170
2.4.24
190∼200
ー
ppm/℃
12∼14
2.4.24
20∼30 130∼160
sec. min. ℃ cycles
ー
>300 >60
2.4.24.1
>30
2.3.40
340∼360 >10
ー
1.1∼1.2
2.4.8
A
kN/m
Surface Roughness (Ra)
A
μm
2∼3
Flexural Modulus (Lengthwise)
A
GPa
27∼33
2.4.4
4.8∼5.0
2.5.5.1
4.5∼4.7
2.5.5.5
0.008∼0.010
2.5.5.1
0.013∼0.015
2.5.5.5
Dielectric Constant Dissipation Factor Volume Resistivity Surface Resistance Insulation Resistance
18
MCL-E-679F Type (R)
12∼14
(>Tg)
Decomposition Temperature (5% Weight Loss) TGA 18μm
℃
(30∼120℃)
TMA
T-288 (Without Copper)
Unit
Actual Value
35μm
1MHz 1GHz*2 1MHz 1GHz*2
C-96/20/65 C-96/20/65 C-96/35/90 C-96/20/65 C-96/20/65+D-2/100
− − Ω・cm Ω Ω
1.2∼1.3
15
2.2.17
16
1×10 ∼1×10
1×1013∼1×1015 1×1014∼1×1016
2.5.17 ー
1×1013∼1×1015
ー
Water Absorption
E-24/50+D-24/23
%
0.3∼0.5
2.6.2.1
Flammability (UL-94)
A
−
V−0
2.3.10
CAF
85℃/85%RH, DC100V
hrs.
>2000
ー
*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator 0.8mm thickness core is used depending on test item.
●Prepreg Part Number
GEA-679F
(R)
Type
Style
0.04 (FRZPE) (FRUOE) 0.06 (FRROE) 0.1 (FRSKE) 0.15 (FREGE)
1037 1080 1078 2116 1504
Glass Cloth Yarn Count (warp×fill) 69×72 60×48 53×53 60×58 60×50
Test Method (IPC-TM-650)
Properties Resin Content Volatile Content Gelation Time Dielectric Thickness (%) (%) (sec.) after Lamination *1(mm) 115±25 0.049 73±2 0.081 68±2 <1.0 0.081 68±2 110±25 0.130 58±2 <0.75 0.154 51±2 2.3.16.1
2.3.19
2.3.18
−
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●Flexural Modulus
●Barcol Hardness
35
80
MCL-E-679F Type(R)
70
25
Barcol Hardness
︵ GPa ︶ Flexural Modulus
30
20
Standard FR-4
15 10
0
50 40 30
Standard FR-4
20
MCL-E-679 Type(W)
5
MCL-E-679F Type(R)
60
MCL-E-679 Type(W)
10
0
50
100
150
0
200
0
50
100
Temperature ( ℃)
150
200
250
Temperature ( ℃)
●Flexure Characteristics
●Water Absorption under 85℃ 85%RH
(t0.4mm)
1.0
20 18 16
︵ ︶ Water Absorption %
14
︵ mm ︶ Flexure
0.8
MCL-E-679 Type(W) Standard FR-4
12 10 8 6
MCL-E-679F Type(R)
4
MCL-E-679 Type (W)
0.6
0.4
MCL-E-679F Type (R)
0.2
2 0 0.1
0.15
0.2
0.25
0.3
0.35
0.4
Laminate Thickness (mm)
0.45
0
0
50
100
150
200
Processing Time (hrs.)
〈Test Method〉 Substrate
Weight (20g)
Flexure
Span (100mm) Substrate Size 220mm (Length) ×10mm (Width)
19
Halogen Free, Low Dielectric Constant, High Tg and High Heat Resistance Multilayer Material
MCL-E-78G
GEA-78G <Prepreg>
Low Dielectric Constant Epoxy Multilayer Materials (FR-4) ■Features
■Applications
●MCL-E-78G is halogen-free material and has very low dielectric constanat property. (Dk 3.5 (@1GHz, Resin cont. = 70%)
●Smartphone.
●MCL-E-78G has high Tg and elastic modulus is higher than standard FR-4 at high temperature.
●Tablet PC.
●Heat resistance is superior. (Suitable for the lead free process)
■Standard Specifications Part Number
Type
Copper Foil Thickness
−
12μm 18μm 35μm 70μm
MCL-E-78G
Code Name 0.04 0.05 0.06 0.07 0.08 0.09 0.1 0.15
Actual Thickness and Tolerance 0.04±0.02mm 0.05±0.02mm 0.06±0.02mm 0.07±0.02mm 0.08±0.02mm 0.09±0.02mm 0.10±0.02mm 0.15±0.03mm
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one.
■Characteristics ●Thin Laminate
(t0.8mm) Condition
Item
TMA
Tg
DMA X
CTE
Y
*1
Z
Solder Heat Resistance (260℃) T-260 (Without Copper) T-288 (Without Copper) Decomposition Temperature(5% Weight Loss) Copper Peel Strength
18μm 35μm
Flexural Modulus (Lengthwise) Dielectric Constant (RC70%) Dissipation Factor (RC70%)
1GHz 10GHz*2 1GHz 10GHz*2
℃
160∼170 200∼220 13∼15
(30∼120℃) (<Tg)
Actual Value
ppm/℃
15∼17 35∼45 180∼230
(>Tg) A
sec.
>300
TMA
min.
>60
TGA
℃
380∼400
A
kN/m
A
GPa
C-96/20/65
−
C-96/20/65
−
1.0∼1.2 1.1∼1.3 25∼29 3.4∼3.6 3.3∼3.5 0.009∼0.011 0.012∼0.014
Volume Resistivity
C-96/20/65+C-96/40/90
Ω・cm
14 16 1×10 ∼1×10
Surface Resistance
C-96/20/65+C-96/40/90
Ω
1×1013∼1×1015
Insulation Resistance
C-96/20/65 C-96/20/65+D-2/100
Ω
1×1014∼1×1016 1×1013∼1×1015
Water Absorption
E-24/50+D-24/23
%
0.1∼0.3
Flammability (UL-94)
A
−
V-0
hrs.
>1000
CAF *1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator
20
Unit
85℃/85%RH, DC100V
●Prepreg Part Number 0.03 0.04 0.04 0.04 0.04 0.05 0.05 0.06 0.06
GEA-78G
Glass Cloth Yarn Count Style (warp×fill)
Type 1027N72 106N70 106N72 1037N70 1037N74 1067N69 1067N72 1080N62 1078N62
Properties Resin Content Volatile Content Gelation Time Dielectric Thickness (%) (%) (sec.) after Lamination*1(mm)
75×75 56×56 56×56 69×72 69×72 70×70 70×70 60×48 53×53
1027 106 106 1037 1037 1067 1067 1080 1078
Test Method (IPC-TM-650)
72±2 70±2 72±2 70±2 74±2 69±2 72±2 62±2 62±2
≦3.0
280±40
0.044 0.049 0.052 0.049 0.057 0.060 0.068 0.073 0.073
2.3.16.1
2.3.19
2.3.18
−
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●Correlation between Dielectric Constant and Frequency
●Correlation between Dissipation Factor and Frequency
4.5
0.030 0.025
MCL-E-75G
4.0
MCL-E-75G
3.5
Df
Dk
0.020 0.015
MCL-E-78G MCL-E-78G
0.010 3.0 0.005 0.000
2.5 0
1
2
3
4
5
0
1
Frequency (GHz)
3
4
5
Frequency (GHz)
●Elastic Modulus
●CAF (85℃85%RH, DC100V) Wall to Wall Distance : 0.3mm(t0.8mm)
1.0E+16
1.5
1.0
tan δ
MCL-E-78G
1.0
MCL-E-75G
0.5
Insulation Resistance (Ω)
10.0
︵ GPa ︶ Elastic Modulus
2
1.0E+14 1.0E+12
Pre Treatment: 260℃ Reflow 3 times
1.0E+10 1.0E+08 1.0E+06
0.1 50
100
150
200
Temperature ( ℃)
250
0.0 300
1.0E+04 0
200
400
600
800
1000
Treating Time (hrs)
Note) Measured by Triplate-line Resonator.
21 00
Reduction of Solder Crack/Low Elastic Modulus Material
] TD−002[ Prepreg
Low Elastic Modulus Thermosetting Resin Multilayer Material ■Features
■Applications
●Applied to PWBs surface of standard material, absorb soldering stress and inhibit solder crack. ●Elastic modulus is 1/ 4 of that of standard FR-4. ●Reduction of solder crack are enabled without using the high functional material, combing TD-002 with standard material.
●Electronic equipment for automobiles. ●Engine room set board. ●PCB's on component packagings.
■Standard Specifications[Prepreg] Glass Cloth Part Number
Type 0.06 0.08 0.10 0.20
TD−002 〔Prepreg〕
(1037N77) (1078N68) (3313N58) (1501N54)
Style
Yarn Count (warp×fill)
1037 1078 3313 1501
69×72 53×53 60×62 46×45
Properties Resin Content Volatile Content Dielectric Thickness (%) (%) after Lamination*1(mm) 77±2 68±2 58±2 54±2
0.073 0.099 0.118 0.213
≦2.0
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
■Characteristics ●Thin Laminate
(3313N58, t0.4mm) Condition
Item TMA
Tg
X Y
CTE *1
Z Solder Heat Resistance (260℃) T260 (Without copper) T288 (Without copper) Decomposition Temperature(5% Weight Loss) 18μm
Actual Value
Test Method(IPC TM-650)
℃
155-170
2.4.24
6∼9
(30∼120℃) (<Tg)
ppm/℃
(>Tg) A
6∼9
2.4.24
80∼130 200∼300
sec.
TMA
min.
TGA
℃
>300
ー
>50
2.4.24.1
>5
2.4.24.1
345∼360
2.3.40
0.8∼0.9
A
kN/m
Flexural Modulus (Lengthwise)
A
GPa
5∼8
2.4.4
Elastic Modulus (Lengthwise) Tensile
A
GPa
7∼10
ー 2.5.5.5
Copper Peel Strength
35μm
2.4.8
0.9∼1.1
*2
1GHz
C-96/20/65
ー
3.6∼3.8
Dissipation Factor *2
1GHz
C-96/20/65
ー
0.011∼0.013
Dielectric Constant
15
2.5.5.5
16
Volume Resistivity
C-96/20/65+C-96/40/90
Ω・cm
Surface Resistance
C-96/20/65+C-96/40/90
Ω
1×1014∼1×1015
Insulation Resistance
C-96/20/65+D-2/100
Ω
1×1014∼1×1015
ー
Water Absorption
E-24/50+D-24/23
%
0.1∼0.3
2.6.2.1
Flammability (UL-94)
A
ー
Vー0
2.3.10
hrs.
>2000
ー
CAF
85℃/85%RH, DC100V
*1)Heating Rate : 10℃/min. *2)Measured by cavity resonator. 0.1mm thickness core is used depending on test item.
22
Unit
1×10 ∼1×10
2.5.17
●Connection reliability of Pb-free solder〔Thermal condition:-40℃ (30min.)⇔125℃ (30min.)〕 100%
Thickness:t1.6 (4Layer) Specimen structure:Core t1.4mm, B/Ut0.1mm Solder:Pb-free solder
1000Cycles 2000Cycles 3000Cycles
80%
︵ ︶ Crack ratio %
Solder crack of FR-4+TD-002 (Cross section, after 3000cyc.) Crack ratio 6%
60%
2125R
Crack ratio 10%
3226R
40%
20%
0% 2125R
Elastic Modulus (Pa)
1.0E+10
3226R FR-4+TD-002
6332R
2125R
3226R FR-4
6332R
●Elastic modulus Resin only
1.0E+09
Conventional FR-4
TD-002 1.0E+08
1.0E+07
1.0E+06
0
50
100
150
200
250
300
Temperature ( ℃)
●CAF〔85℃85%RH,DC100V〕
●Mechanical drilling processing〔After 3000hits〕
1.0E+14
50
Thickness:t1.6(4Layer) Specimen structure:Core t1.4mm, B/Ut0.1mm
Thickness:t1.6 (4Layer) Specimen structure:Core t1.2mm, B/Ut0.2mm 40
1.0E+12
MCL-E-75G
︵ Roughness
μ
→
1.0E+11 1.0E+10
Ave. Max
︶ m
→
Insulation Resistance (Ω)
1.0E+13
TD-002+MCL-E-75G
30
20
1.0E+09 10 1.0E+08 1.0E+07
0 0
500
1000
1500
2000
Processing time (hrs.)
Prepreg
a
b
c
MCL-E-75G
TD-002+ MCL-E-75G
CEL-323
TD-002+ CEL-323
Core
Laminate thickness(a) :t1.6mm 18D Distance between TH(b) :0.3mm Drill diameter(c) :Φ0.4mm Land diameter:Φ0.6mm Hole pitch:0.7mm Number of holes:320(160×2) Plating thickness:15μm Pretreatment condition:40℃90%RH144hr+ 250℃Max Reflow×2
TD-002+MCL-E-75G
TD-002+CEL-323
《Condition of mechanical drilling》 ・Stack-up:3 panels ・E/B:Al t0.15mm ・Revolution:120krpm ・Feeding Speed:2.4m/min. ・Drill bit:φ0.3mm 23 00
Halogen Free, High Tg and High Heat Resistance Multilayer Material
MCL-E-75G GEA-75G
High Tg Glass Epoxy Multilayer Material(FR-4) ■Features
■Applications
●Environmentally friendly material. It has achieved the UL 94V-0 level of flammability without using any compound which includes halogen, antimony or red phosphorus. ●Heat resistance is superior to that of our standard FR-4, and suitable for the lead free process. ●The coefficient of thermal expansion in Z-direction is about 40% lower than that of our standard FR-4.Excellent through-hole reliability. ●CAF restraining property is superior to that of our standard FR-4.
●Electronics for automobiles. ●Personal computer, high density electronic equipment. ●Electronic branch exchanges, mobile phones, etc. ●Main frame computers.
■Standard Specifications Part Number
MCL-E-75G
Type
Copper Foil Thickness
−
12μm 18μm 35μm 70μm
Code Name 0.06 0.1 0.15 V0.2 0.3 V0.4 0.5 V0.6 0.8 1.0 1.2 1.6
Actual Thickness and Tolerance 0.06±0.03mm 0.10±0.03mm 0.15±0.04mm 0.20±0.04mm 0.30±0.05mm 0.40±0.06mm 0.50±0.07mm 0.60±0.08mm 0.80 (0.70) ±0.09mm 1.00 (0.90) ±0.10mm 1.20 (1.10) ±0.11mm 1.60 (1.50) ±0.19mm
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) The thickness is means that of dielectric layer.Figure in bracket( )means thickness of dieletric layer of MCL using 70μm copper foil.
■Characteristics ●Thin Laminate
(t0.8mm)
Item
Condition TMA
Tg
DMA
CTE *1
X
(30∼120℃)
Y
(30∼120℃)
Z
(<Tg) A
T260
TMA
T288
TMA
Decomposition Temperature(5% Weight Loss) TGA
18μm 35μm
Flexural Modulus (Lengthwise) 1MHz Dielectric Constant *2 1GHz Dissipation Factor
1MHz 1GHz*2
A C-96/20/65 C-96/20/65
Actual Value 155∼170
2.4.24
195∼215
ー
12∼15 ppm/℃
14∼17
2.4.24
30∼40 180∼240
sec. min. ℃ kN/m GPa − −
>300
ー
>60
2.4.24.1
>60
2.4.24.1
380∼390
2.3.40
1.2∼1.4
2.4.8
1.5∼1.8 25∼29
2.4.4
5.0∼5.2
2.5.5.1
4.4∼4.6
2.5.5.5
0.009∼0.011
2.5.5.1
0.014∼0.016
2.5.5.5
Volume Resistivity
C-96/20/65+C-96/40/90
Ω・cm
1×1015∼1×1016
Surface Resistance
C-96/20/65+C-96/40/90
Ω
1×1013∼1×1015
Insulation Resistance
C-96/20/65 C-96/20/65+D-2/100
Water Absorption
E-24/50+D-24/23
Flammability (UL-94)
A
CAF
85℃/85%RH, DC100V
*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator
24
℃
(>Tg)
Solder Heat Resistance (260℃)
Copper Peel Strength
Unit
Test Method (IPC-TM-650)
Ω
14
16
1×10 ∼1×10
2.5.17 ー
1×1013∼1×1015
ー
%
0.08∼0.12
2.6.2.1
−
V−0
2.3.10
hrs.
>1000
ー
●Prepreg Part Number 0.06 0.06 0.10 0.15 0.20
GEA-75G
Type
Glass Cloth Yarn Count Style (Warp×Fill)
(1080N65) (1078N65) (2116N56) (1501N52) (7628N51)
1080 1078 2116 1501 7628
Properties Resin Content Volatile Content Gelation Time Dielectric Thickness (%) (%) (sec.) after Lamination*1(mm)
60×48 53×53 60×58 46×45 44×31
Test Method (IPC-TM-650)
65±2 65±2 56±2 52±2 51±2 2.3.16
<1.0
145±30 145±30 145±30 135±30 135±30
0.077 0.077 0.128 0.182 0.219
2.3.19
2.3.18
−
●CAF(85℃85%RH, DC32V) t1.6 6layers PWB Pretreatment condition 260℃ Reflow X 3+260℃ Solder float 20s
1.0E+11 1.0E+10 1.0E+09 1.0E+08 1.0E+07
patternA Wall to wall Distance0.4mm patternB Wall to wall Distance0.5mm patternC Wall to wall Distance0.6mm
1.0E+06 0 0
200
400
600
800
1000
●Through-hole reliability ー55℃30min⇔150℃30min (t1.6) 20
Standard FR-4 15
High Tg FR-4 10
5
E-75G
0
ー5
0
500
1000
1500
2000
Treating time (hrs.)
Number of cycles
●Correlation between Dielectric Constant and Resin Content
●Correlation between Dissipation Factor and Resin Content
5.0
0.022
4.8
0.021
4.6
0.020
4.4
0.019
Df
DK
Insulation Resistance (Ω)
1.0E+12
Change ratio of conductive resistance (%)
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner-layer pattern.
4.2
0.018
4.0
0.017
1GHz 2GHz 5GHz
3.8 3.6 40
45
50
55
1GHz 2GHz 5GHz
0.016
60
65
Resin Content (%)
70
75
0.015 40
45
50
55
60
65
70
75
Resin Content (%)
Note) IPC TM-650 2.5.5.5
25
FR-4 Multilayer Material
MCL-E-67 GEA-67N〈Prepreg〉[
]
UV Block Type MCL-E-67 Type(W)
Glass Epoxy Multilayer Material(FR-4) ■Features
■Applications
●Superior CAF restraining property.
●Personal computers and high-density electronic equipment. ●Small and midsize computers and their peripheral devices. ●Electronic branch exchanges, portable terminal devices, etc.
●Superior electrical and mechanical characteristics. ●Laminating time can be reduced depending on prepreg types and conditions.
■Standard Specifications Part Number
Copper Foil Thickness
Type
̶ 12μm 18μm 35μm 70μm
MCL-E-67
Actual Thickness and Tolerance 0.06±0.03mm 0.10±0.03mm 0.15±0.04mm 0.20±0.05mm 0.30±0.05mm 0.40±0.08mm 0.50±0.08mm 0.60±0.09mm 0.80 (0.70) ±0.10mm 1.00 (0.90) ±0.12mm 1.20 (1.10) ±0.12mm
Code Name 0.06 0.1 0.15 V0.2 0.3 V0.4 0.5 V0.6 0.8 1.0 1.2
(W)
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) The thickness means that of dielectric layer. Figure in bracket( )means thickness of dielectric layer of MCL using 70μm copper foil.
■Characteristics ●Thin Laminate
(t0.8mm) Condition
Item TMA
Tg
DMA X
(<Tg)
Z
A
T-260 (Without Copper) T-288 (Without Copper) Decomposition Temperature (5% Weight Loss) 18μm 35μm
Flexural Modulus (Lengthwise) Dielectric Constant Dissipation Factor
1MHz 1GHz*2 1MHz 1GHz
Volume Resistivity Surface Resistance Insulation Resistance
*2
TGA
℃
A
kN/m
A
GPa
C-96/35/90 C-96/20/65 C-96/20/65+D-2/100
2.4.24
150∼160
ー
14∼17
2.4.24
50∼70 200∼300
sec. min.
C-96/20/65
Test Method (IPC-TM-650)
120∼130
− −
ー
>120 >10
2.4.24.1
ー
2.3.40
300∼320 1.4∼1.6
2.4.8
1.7∼2.1 23∼25
2.4.4
4.7∼4.8
2.5.5.1
4.1∼4.2
2.5.5.5
0.0130∼0.0170
2.5.5.1
0.0180∼0.0200
2.5.5.5
15
16
13
15
14
16
Ω・cm
1×10 ∼1×10
Ω
1×10 ∼1×10
Ω
1×10 ∼1×10 13
2.5.17.1 ー
1×10 ∼1×1015
ー
Water Absorption
E-24/50+D-24/23
%
0.12∼0.14
2.6.2.1
Flammability (UL-94)
A
−
Vー0
2.3.10
CAF
85℃/85%RH, DC100V
hrs.
>1000
ー
*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator
26
ppm/℃
TMA
C-96/20/65
Actual Value
13∼16
(>Tg)
Solder Heat Resistance (260℃)
Copper Peel Strength
℃
(30∼120℃)
Y
CTE *1
Unit
●Prepreg Part Number Type Natural UV Color Block (KLN)(WKLN) 0.06 − (LPN) (WAGN) (VAGN) 0.1 (VAJN) − GEA-67N (VEFP) − 0.15 (VEGJ)(WEGJ) (WHDN) (VHDN) 0.2 (VHGQ) −
Glass Cloth Properties Yarn Count Resin Content Volatile Gelation Time Resin Flow Dielectric Thickness Style (warp×fill) (%) content(%) (sec.) (%) after Lamination*1(mm) 1080
60×48
2116
60×58
1504
60×50
7629
44×34
Test Method(IPC-TM-650)
62±2 68±2 52±2 55±2 48±2 51±2 45±2 52±2
<0.5
2.3.16
2.3.19
105±25
42±5 48±5 31±5 37±5 27±5 32±5 27±5 35±8
0.076 0.093 0.126 0.136 0.158 0.171 0.208 0.249
2.3.18
2.3.17
−
125±25 105±25 120±25
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●CAF Property
●Dielectric Constant vs Resin Content of Laminate(1MHz) 5.0 4.8
1012
4.6
Dk
︵ ︶ Insulation Resistance Ω
1013
4.2
1011
4.0 3.8 40.0
1010
109
0
200
400
600
800
: : : :
85℃85%RH DC 100V Comb Pattern(L/S=100/100μm) Measured at room temperature after taken out from a thermo-hydrostat chamber.
3.8
)
0.2 0.05
2
4
Frequency(GHz)
6
●Correlation between Dissipation Factor and Frequency 0.030
φ50mm Electrode Time to Short Circuits Obtained the value of destruction voltage by increasing the voltage constantly per 500V /sec.
Laminate Thickness
0.020
Estimation
)
0.015 0.010 0.005
20
10
0
0.025
Laminate Thickness
(
4.1 3.9
100×100
Cu Foil
4.2 4.0
Df
︵ kV ︶ Withstand Voltage
65.0
4.3
Without Cu (●▲) With Cu (○△) φ50mm Etched on both sides (Cu on both Sides)
40
0
60.0
4.4
●Result of Withstand Voltage Test
About 4kV in Time of Short Circuits
55.0
4.5
Dk
Environmental Condition Applied Voltage Evaluation Pattern Measurement
30
50.0
●Correlation between Dielectric Constant and Frequency
1000
Evaluation Condition of CAF
50
45.0
Resin Content(%)
Time(hrs.)
(
4.4
0.000
Step by Step Maintaining 50% of the destruction voltage obtained in short circuits for 1min. then obtaining the max. value after rising the voltage for 1min. The voltage is increasing by 1.0kV.
( 0.4 0.5
)
1.0
Laminate Thickness (mm)
0
2
4
Frequency(GHz)
6
1.6 Note) Measured Triplate-line Resonator.
27
Halogen Free FR-4 Multilayer Material
MCL-BE-67G Type(H)( , R)GEA-67BE Type(H)(, R)〈Prepreg〉 High Heat Resistance Glass Epoxy Multilayer Material(FR-4) ■Features ●Environmentally friendly material. It has achieved the UL 94V-0 level of flammability without using any compound which includes halogen, antimony or red phosphorous. ●Heat resistance is superior to that of our standard FR-4, and suitable for the lead free process. ●Tg(>180℃:DMA) is higher than that of our standard FR-4 and the elastic modulus is high at high
temperature, making it suitable as HDI core material. ●Dk and Df are very stable regardless of the difference in frequency or temperature.
■Applications ●Personal computers and mobile phones. ●Digital audio and video equipment. ●Electronics for automobiles.
■Standard Specifications Part Number
Type
Copper Foil Thickness
(H)
Code Name 0.05 0.06 0.1 V0.2 0.3 V0.4 0.5 V0.6 0.8 1.0 1.2
12μm 18μm 35μm 70μm
MCL-BE-67G
(R)
Actual Thickness and Tolerance 0.05±0.02mm 0.08±0.02mm 0.10±0.03mm 0.20±0.04mm 0.30±0.04mm 0.40±0.05mm 0.50±0.05mm 0.60±0.06mm 0.77±0.06mm 0.96±0.09mm 1.16±0.11mm
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) The thickness means that of dielectric layer.
■Characteristics ●Thin Laminate
(t0.8mm)
Item
Condition TMA
Tg
DMA X
CTE
Y
*1
Z
Solder Heat Resistance (260℃) Solder Heat Resistance (288℃)
Unit ℃
(30∼100℃) (<Tg)
ppm/℃
(>Tg) A
sec
TMA
min.
T-260 (Without Copper) T-260 (With Copper) T-288 (Without Copper) TGA
Decomposition Temperature Copper Peel Strength
18μm 35μm
Flexural Modulus (Lengthwise) Dielectric Constant Dissipation Factor
A 150℃
1MHz
C-96/20/65
1GHz*2
C-96/20/65
1MHz
C-96/20/65
1GHz*2
C-96/20/65
Volume Resistivity Surface Resistance
28
A
C-96/35/90
℃ kN/m GPa − −
Test Method MCL-BE-67G Type(H)MCL-BE-67G Type(R) (IPC-TM-650) 140∼150
140∼150
2.4.24
180∼220
180∼220
ー
15∼19
15∼19
17∼21
17∼21
40∼55
40∼55
170∼250
170∼250
>300
>300
>120
>180
2.4.24
ー 2.4.24.1
>60
>60
>10∼20
>60
ー
>60
>60
2.4.24.1
340∼350
340∼350
2.3.40
1.2∼1.4
1.2∼1.4
1.3∼1.5
1.3∼1.5
23∼26
23∼26
16∼19
16∼19
4.8∼5.0
4.8∼5.0
2.5.5.1
4.3∼4.5
4.3∼4.5
2.5.5.5
0.0060∼0.0070
0.0060∼0.0070
2.5.5.1
0.0090∼0.0110
0.0090∼0.0110
2.5.5.5
2.4.8 2.4.4
Ω・cm
1×1015∼1×1016 1×1015∼1×1016
Ω
1×1014∼1×1015 1×1014∼1×1015
Insulation Resistance
C-96/20/65+D-2/100
Ω
Water Absorption
E-24/50+D-24/23
%
Flammability (UL-94)
A
CAF
85℃/85%RH, DC100V
*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator
Actual Value
14
15
1×10 ∼1×10 0.04∼0.08
14
15
1×10 ∼1×10
2.5.17.1 ー
0.04∼0.08
2.6.2.1
−
V−0
V−0
2.3.10
hrs.
>1000
>1000
ー
●Prepreg Type
Part Number
(H)
Glass Cloth Yarn Count Style (warp×fill)
(R)
0.05 (HZRJ)(RZRJ) (HLMJ)(RLMJ) (HLPJ)(RLPJ) 0.06 (HLQJ)(RLQJ) (RRMJ) (HRMJ) (HAHJ)(RAHJ) 0.1 (HAKJ)(RAKJ) (RFFQ) (HFFQ) 0.15 (HFHJ)(RFHJ) 0.2 (HHFQ) (RHFQ)
GEA-67BE
1037
69×72
1080
60×48
1078
53×53
2116
60×58
1501
46×45
7629
44×34
Test Method (IPC-TM-650)
Properties Resin Content Volatile Content Gelation Time (%) (%) (sec.) 75±2 63±2 67±2 71±2 62±2 53±2 57±2 49±2 53±2 49±2
100±20 120±20 95±20
0.060 0.076 0.087 0.101 0.074 0.123 0.137 0.179 0.195 0.223
*2
−
120±20
<2
2.3.16.1
Dielectric Thickness after Lamination*1(mm)
2.3.19
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern. *2) Original method of Hitachi Chemical(170℃)
No-flow type GEA-67BE Type(N) Glass Cloth Yarn Count Style (warp×fill)
Type 0.05 0.06 0.1
(NOQY) (NLOY) (NAHY)
56×56 60×48 60×58
106 1080 216
Resin Content Volatile Content (%) (%) 72±2 <2 65±2 <2 53±2 <2
Test Method (IPC-TM-650)
2.3.16.1
2.3.29
Properties Resin Flow (%) 5±4 5±4 5±4
Dielectric Thickness after Lamination*1(mm) 0.052 0.080 0.122
2.3.17
−
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner-layer pattern.
●Correlation between Dielectric Constant and Frequency
●Correlation between Dissipation Factor and Frequency
5.0
0.030 0.025
MCL-BE-67G Type(H) (R) ,
4.5
Standard FR-4
4.0
Df
Dk
0.020
Standard FR-4
0.015 0.010
MCL-BE-67G Type(H) (R) ,
3.5 0.005 3.0
0
1
2
3
4
0.000
5
0
1
2
Frequency (GHz)
3
4
5
Frequency (GHz)
●Correlation between Dielectric Constant and Temperature(1GHz)
●Correlation between Dissipation Factor and Temperature(1GHz)
5.0 0.030 4.5
0.025
MCL-BE-67G Type(H) (R) ,
Standard FR-4
4.0
Standard FR-4
Df
Dk
0.020 0.015 0.010
3.5
MCL-BE-67G Type(H) (R) ,
0.005 3.0 -40
-20
0
20
40
60
Temperature ( ℃) Note) Measured by Triplate-line Resonator.
80
100
0.000 -40
-20
0
20
40
60
80
100
Temperature ( ℃)
29
Materials For ICT Infrastructure High Tg Multilayer Material
MCL-E-679 Type(W) P32 High Tg and High Heat Resistance Multilayer Material
MCL-E-679F Type(J) P34
Halogen Free, High Tg, Low Transmission Loss Multilayer Material
MCL-LW-900G/910G P36
Halogen Free, Low Dielectric Constant and High Heat Resistance Multilayer Material
MCL-HE-679G Type(S) P38
31
High Tg Multilayer Material
MCL-E-679 Type(W)GEA-679N〈Prepreg〉 High Tg Glass Epoxy Multilayer Material(FR-4) ■Features
■Applications
●High Tg (>205℃: DMA) and excellent throughhole reliability.
●Semiconductor packages .(BGA, CSP and MCM)
●Superior CAF restraining property.
●Telephone switchboards.
●The thermal decomposition temperature is high and reliability at high temperature is superior. (Thermal decomposition temperature: >340℃) ●Water absorption is low and insulation degradation is small.
●Main frame computers. ●Mobile phones. ●Semiconductor testing devices and burn-in boards. ●Electronics for automobiles.
■Standard Specifications Part Number
MCL-E-679
Type
Copper Foil Thickness 12,18,35μm
Code Name 0.06 0.1 0.15 0.2 0.3 0.4 0.6 0.8 1.0 1.2
12μm 18μm 35μm 70μm (STD,LP)
(W)
Actual Thickness and Tolerance 0.07±0.02mm 0.10±0.03mm 0.15±0.03mm 0.20±0.04mm 0.30±0.05mm 0.40±0.07mm 0.60±0.07mm 0.80 (0.70) ±0.09mm 1.00 (0.90) ±0.10mm 1.20 (1.10) ±0.12mm
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) The thickness means that of dielectric layer. Figure in bracket( )means thickness of dielectric layer of MCL using 70μm copper foil. (1) Thickness of STD:12μm, 18μm, 35μm, 70μm. (2) Thickness of LP:12μm, 18μm.
■Characteristics ●Thin Laminate
(t0.8mm) Condition
Item TMA
Tg
DMA X Y
CTE *1
Z Solder Heat Resistance (260℃) T-260 (Without Copper) T-288 (Without Copper)
Copper Peel Strength
35μm
Surface Roughness (Ra) Flexural Modulus (Lengthwise) Dielectric Constant Dissipation Factor Volume Resistivity Surface Resistance Insulation Resistance
32
1MHz 1GHz*2 1MHz 1GHz*2
℃
(<Tg)
ppm/℃
A
sec.
TMA
min. ℃
A
kN/m
A
μm
A
GPa
C-96/20/65 C-96/35/90 C-96/20/65 C-96/20/65+D-2/100
Water Absorption
E-24/50+D-24/23
Flammability (UL-94)
A
CAF
85℃/85%RH, DC100V
*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator 0.8mm thickness core is used depending on test item.
Test Method (IPC-TM-650)
173∼183
2.4.24
205∼215
−
14∼17 50∼60
2.4.24
200∼300
(>Tg)
C-96/20/65
Actual Value
12∼15
(30∼120℃)
Decomposition Temperature(5% Weight Loss) TGA 18μm
Unit
− −
>300 >60 >30 340∼360 1.2∼1.4 1.5∼1.7 5∼13
2.4.24.1 2.3.40 2.4.8 2.2.17
24∼26
2.4.4
4.7∼4.8
2.5.5.1
4.2∼4.3
2.5.5.5
0.013∼0.015
2.5.5.1
0.021∼0.022
2.5.5.5
Ω・cm
15 16 1×10 ∼1×10
Ω
1×1013∼1×1015
Ω
−
1×1014∼1×1016
2.5.17 −
1×1013∼1×1015
−
0.15∼0.20
2.6.2.1
−
V−0
2.3.10
hrs.
>2000
−
%
●Prepreg Part Number
Glass Cloth Properties Yarn Count Resin Content Volatile Content Gelation Time Style (warp×fill) (%) (%) (sec.)
Type 0.03 (WOPE) (WULE) 0.06 (WUME) (WSGE) 0.1 (WCJE) 0.15 (WQEE)
GEA-679N
106
56×56
1080
60×48
2116 2117 1501
60×58 66×55 46×45
Dielectric Thickness after Lamination*1(mm)
<1.0
68±2 62±2 65±2 52±2 56±2 48±2
Test Method (IPC-TM-650)
Resin Flow (%)
35±5 − 33±5
0.050 0.078 0.086 0.126 0.146 0.174
2.3.17
−
− 120±25
<0.75
2.3.16
2.3.19
2.3.18
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●Barcol Hardness
●Thermal Shock Test(MIL-STD-202 Method107E) 100
70 60
Barcol Hardness
︵ ︶ Defect Rate %
80
60
40
Standard FR-4 20
0
1000
2000
50 40
Standard FR-4
30 20
0
3000
0
50
100
Number of cycles
150
200
250
Temperature ( ℃)
●Water Absorption 2.0
GPY
10
MCL-E-679 Type(W) GPY 0
MCL-E-679 Type (W)
●CAF(85℃ 85%RH, DC50V)
(t0.8mm)
PCT Condition: 121℃ 0.22Mpa
14
10
Wall to Wall Distance:0.3mm
(t0.5mm)
1.5
Standard FR-4
1.0
MCL-E-679 Type (W) 0.5
︵ ︶ Ω Insulation Resistance
︵ ︶ Water Absorption %
12
GPY
10
10
10
8
10
6
10
4
10
2
10 0.0
0
50
100
150
200
Processing time (hrs.)
250
0
500
1000
1500
2000
Processing Time (hrs.)
33
High Tg and High Heat Resistance Multilayer Material
MCL-E-679F Type(J)GEA-679F Type(J)〈Prepreg〉 High Tg Glass Epoxy Multilayer Material(FR-4) ■Features
●Superior solder heat resistance.(Suitable for the lead free process) ●The coefficient of thermal expansion in Z-direction is about 30% lower than that of our standard FR-4. Excellent through-hole reliability.
■Applications
●Main frame computers. ●Electronics for Automobiles.
●Superior filling ability of the high aspect ratio IVH in highcount layer PWB.
■Standard Specifications Part Number
Type
MCL-E-679F
Copper Foil Thickness 12,18,35μm
Code Name 0.07 0.1 0.13 0.15 0.2 0.3 0.4 0.6 0.8 1.0 1.2
12μm 18μm 35μm 70μm (STD,LP)
(J)
Actual Thickness and Tolerance 0.07±0.02mm 0.10±0.03mm 0.13±0.03mm 0.15±0.03mm 0.20±0.04mm 0.31±0.05mm 0.39±0.07mm 0.58±0.07mm 0.77±0.09mm 0.96±0.10mm 1.15±0.12mm
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) The thickness means that of dielectric layer. (1) Thickness of STD:12μm, 18μm, 35μm, 70μm. (2) Thickness of LP:12μm, 18μm.
■Characteristics ●Thin Laminate
(t0.8mm) Condition
Item TMA
Tg
DMA X
CTE
(<Tg)
Z
A
T-260 (Without Copper)
TMA
T-288 (Without Copper)
Decomposition Temperature(5% Weight Loss) TGA 18μm 35μm
Surface Roughness (Ra) Flexural Modulus (Lengthwise) Dielectric Constant Dissipation Factor Volume Resistivity Surface Resistance Insulation Resistance
34
1MHz 1GHz*2 1MHz 1GHz
*2
ppm/℃
min. ℃ kN/m
A
μm
A
GPa
C-96/20/65
−
C-96/20/65
−
C-96/20/65 C-96/20/65+D-2/100
Water Absorption
E-24/50+D-24/23
Flammability (UL-94)
A
CAF
85℃/85%RH, DC100V
*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator 0.8mm thickness core is used depending on test item.
Test Method (IPC-TM-650)
165∼175
2.4.24
195∼205
ー
14∼17
2.4.24
35∼45 180∼240
sec.
A
C-96/35/90
Actual Value
12∼15
(>Tg)
Solder Heat Resistance (260℃)
Copper Peel Strength
℃
(30∼120℃)
Y
*1
Unit
ー
>300 >60
2.4.24.1
>30 340∼360
2.3.40
1.1∼1.4
2.4.8
1.4∼1.6
2.2.17
5∼10 25∼31
2.4.4
4.6∼4.8
2.5.5.1
4.2∼4.4
2.5.5.5
0.011∼0.013
2.5.5.1
0.017∼0.019
2.5.5.5
15
16
13
15
Ω・cm
1×10 ∼1×10
Ω
1×10 ∼1×10
Ω
1×1014∼1×1016 13
15
1×10 ∼1×10
2.5.17 ー ー
0.12∼0.17
2.6.2.1
−
V−0
2.3.10
hrs.
>2000
ー
%
●Prepreg Glass Cloth Properties Yarn Count Resin Content Volatile Content Gelation Time Resin Flow Dielectric Thickness Style (warp×fill) (%) (%) (sec.) after Lamination *1(mm) (%) <1.0 56×56 106 0.056 73.5±2 − <0.75 0.078 65±2 30±5 60×48 1080 <1.0 0.087 68±2 − 120±25 60×62 3313 0.110 59±2 39±5 0.126 55±2 33±5 60×58 2116 <0.75 0.145 60±2 40±5 44×34 7629 0.197 45±2 −
Type
Part Number
0.03 (JORE) (JUME) 0.06 (JUNE) 0.08 (JGKE) (JSJE) 0.1 (JSKE) 0.2 (JPDE)
GEA-679F
Test Method (IPC-TM-650)
2.3.16.1
2.3.19
2.3.18
2.3.17
−
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●Thermal Shock Test (MIL-STD-202 Method107E)
●Thermal Expansion(Z-direction) 40
Test Method: TMA 10℃/min.
(t0.8mm)
100
80
︵ ︶ Defect Rate %
︵ m Expansion μ︶
30
Standard FR-4
20
High Tg FR-4 10
60
40
Standard FR-4
20
MCL-E-679F Type(J) High Tg FR-4
MCL-E-679F Type (J)
0 0
50
100
150
200
0
250
0
1000
2000
3000
Temperature (℃)
Number of Cycles
●Correlation Between Dielectric Constant and Frequency
●Correlation between Dissipation Factor and Frequency
0.030
5.0
0.025
High Tg FR-4
4.5 0.020 4.0
MCL-E-679F Type (J)
High Tg FR-4
Df
Dk
MCL-E-679F Type (J) 0.015 0.010 3.5 0.005 3.0
0
1.0
2.0
3.0
4.0
Frequency (GHz)
5.0
0.000
0
1.0
2.0
3.0
4.0
5.0
Frequency (GHz)
Note) Measured by Triplate-line Resonator.
35
Halogen Free, High Tg, Low Transmission Loss Multilayer Material
MCL−LW−900G/910G GWA−900G/910G<Prepreg> Low Dielectric constant Glass Thermosetting Resin Multilayer Material ■Features
■Applications
●MCL-LW-910G achieved low dielectric constant (3.3 at 10GHz) and low dissipation factor (0.0028 at 10GHz) using low Dk glass and HVLP copper.
●High-speed computer, server
●MCL-LW-910G enables the high-speed transmission/communication of 25Gbps by the low transmission loss.
●High-speed Router ●High Frequency Devices, Antenna
●MCL-LW-910G has excellent heat resistance, connection reliability, excellent anti-CAF property.
■Standard Specifications Part Number
Type
MCL-LW-900G (E glass cloth)
Copper Foil Thickness
Actual Thickness and Tolerance
M0.05
0.05±0.02mm
M0.06
0.06±0.02mm
M0.08
0.08±0.02mm
0.1
0.10±0.02mm
M0.11
0.10±0.02mm
0.13
0.13±0.03mm
M0.15
0.15±0.03mm
0.2
0.20±0.03mm
0.26
0.25±0.04mm
18μm 35μm 70μm (RTF)
̶
MCL-LW-910G (Low Dk glass cloth)
Code Name
12μm 18μm 35μm (HVLP)
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) Please inguire about the line-up except the above.
■Characteristics ●Thin Laminate
(t0.8mm) Condition
Item TMA
Tg
DMA X
CTE
Y
*1
Z
Solder Heat Resistance (260℃) T-260 (Without Copper) T-288 (Without Copper) Decomposition Temperature(5% Weight Loss) Copper Peel Strength
18μm RTF 18μm HVLP
Flexural Modulus (Lengthwise) Dielectric Constant Dissipation Factor
1GHz*2 10GHz*2 1GHz*2 10GHz*2
Volume Resistivity
*
℃
240∼280 12∼15 12∼15
ppm/℃
35∼45
(>Tg)
240∼290
A
sec.
TMA
min.
TGA
℃
A
kN/m
A
GPa
C-96/20/65 C-96/20/65
C-96/20/65 C-96/20/65+D-2/100
MCL-LW-910G
190∼210
− − Ω・cm Ω
>300 >60 >60 370∼390 0.6∼0.8 0.5∼0.7 16∼21 3.50∼3.70
3.20∼3.40
3.40∼3.60
3.20∼3.40
0.0025∼0.0035
0.0020∼0.0030
0.0040∼0.0050
0.0025∼0.0035
14
16
13
15
1×10 1×10
∼1×10 ∼1×10
14
Ω
1×10
∼1×1016
1×1013∼1×1015
Water Absorption
E-24/50+D-24/23
%
Flammability (UL-94)
A
−
V−0
CAF
85℃/85%RH, DC100V
hrs.
≧2000
1) Heating Rate: 10℃/min.
36
(<Tg)
C-96/20/65+C-96/40/90
Insulation Resistance
MCL-LW-900G
(30∼120℃)
C-96/20/65+C-96/40/90
Surface Resistance
Unit
Actual Value
*
2) Measured by Triplate-line Resonator.
0.2∼0.4
●Prepreg
Properties Volatile Content Dielectric Thickness (%) after Lamination *1(mm)
Glass Cloth Designation
Type 0.05 0.06 0.08 0.1 0.05 0.06 0.08 0.1
GWA-900G
GWA-910G
1037N72 1078N65 3313N57 2116N55 1037N74 1078N67 2013N59 2116N57
Style
Yarn Count (warp×fill)
Resin Content (%)
1037 1078 3313 2116 1037 1078 2013 2116
69×72 53×53 60×62 60×58 69×72 53×53 69×76 60×58
72 65 57 55 74 67 59 57
≦2.0
0.050 0.078 0.106 0.125 0.050 0.078 0.106 0.125
2.3.16
2.3.19
−
Test Method (IPC-TM-650)
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern. Please inguire about the line-up except the above. Note)
●Dielectric characterization results
0.0090
4.0 3.8
0.0080
LW-900G
FX-2
0.0070
3.6
FX-2
3.4
0.0060
Df
Dk
LW-900G (RT) 3.2
LW-910G
0.0050
PTFE CCL
0.0040
3.0
0.0030
2.8
PTFE CCL
LW-910G (HVLP)
0.0020
2.6
0.0010
2.4 0
2
4
6
8
10
12
14
Frequency (GHz)
16
18
20
0
2
4
6
8
10
12
14
Frequency (GHz)
16
18
20
《Measurement Conditions》 ・Method:Strip-Line Resonator (JPCA-TM001) ・Temperature & Humidity:25℃/60%RH ・Laminate Thickness:1.6mm (Signal-Ground : 800μm) Copper foil:18μm (LW : RT,HVLP) ・Signal Conductor Line Width:1mm (Zo:ca.50Ω)
●Transmission Loss 0
0
2
4
6
8
10
●The result of CAF Test
Frequency (GHz) 12
14
16
18
20
ー5 ー15 ー20
1.0E+12
ー25 ー30 ー35 ー40 ー45 ー50
LW-910G (HVLP) LW-900G (HVLP) LW-910G (RT) LW-900G (RT) FX-2 (VLP)
ー55
《Measurement conditions》 ・Evaluation PWB:Strip-line ・Temperature & Humidity:25℃/60%RH ・Characteristic impedance:Approx. 50Ω ・Inner layer surface treatment:Black-reduction ・Proofreading method : TRL w ●Trace width(w) :0.120mm P/P b t ●Dielectric thickness(b) :0.25mm Core ●Trace thickness(t) :18μm
Insulation Resistance (Ω)
S21 (dB/m)
ー10
《Board spec.》 ・Board thickness : 2.0mm ・T/H pitch : 0.8mm,Wall-Wall distance : 0.4,0.5mm, 2,000holes 《Test condition》 CAF Board ・Precondition : 255℃ reflow×8times ・CAF testing : 85℃/85%RH,DC100V ・Measurement of insulation resistance in chamber
1.0E+10
1.0E+08
TH-TH distance : 0.5mm
1.0E+06
TH-TH distance : 0.4mm
1.0E+04 0
200
400
600
Treating Time (hrs.)
800
1000
37
Halogen Free, Low Dielectric Constant and High Heat Resistance Multilayer Material
MCL-HE-679G Type(S)GHA-679G Type(S)〈Prepreg〉
Low Dielectric Constant Thermosetting Resin Multilayer Material(FR-4) ■Features
■Applications
●Dissipation factor is lower than MCL-HE-679G. So it enables further lower transmission loss.
●Network applications. ●High-frequency parts. (filters,VCOs,etc.)
●High Tg and superior heat resistance for soldering. (Suitable for the lead free process) ●The coefficient of thermal expansion in Z-direction is about 30% lower than that of our standard FR-4. ●Environmentally friendly material. It achieved the UL 94V-O level of flammability without using any compound which includes halogen, antimony or red phosphorous.
■Standard Specifications Part Number
MCL-HE-679G
Type
Copper Foil Thickness
(S)
12μm 18μm 35μm 70μm
Code Name 0.06 0.08 0.1 0.15 0.2 0.4 0.6 0.8 1.0 1.2
Actual Thickness and Tolerance 0.06±0.02mm 0.08±0.02mm 0.10±0.02mm 0.15±0.03mm 0.20±0.03mm 0.40±0.04mm 0.60±0.06mm 0.80±0.08mm 1.00±0.08mm 1.20±0.10mm
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) The thickness means that of dielectric layer.
■Characteristics ●Thin Laminate
(t0.8mm) Condition
Item TMA
Tg
DMA X
CTE
Y
*1
Z Solder Heat Resistance (260℃) T-260 (Without Copper)
(<Tg)
Copper Peel Strength (RTF)
35μm
Flexural Modulus (Lengthwise)
Test Method (IPC-TM-650)
180∼190
2.4.24
260∼280
ー
℃
12∼15 14∼17
ppm/℃
A
190∼230 sec.
>300
min.
kN/m
A
GPa
1GHz*2
C-96/20/65
Dissipation Factor
1GHz*2
C-96/20/65
0.5∼0.7
1GHz*3 Volume Resistivity Surface Resistance Insulation Resistance
*
C-96/35/90 C-96/20/65 C-96/20/65+D-2/100
Water Absorption
E-24/50+D-24/23
Flammability (UL-94)
A
CAF
85℃/85%RH, DC100V
Ω・cm Ω Ω
23∼26
2.4.4
4.10∼4.30
2.5.5.1
3.70∼3.90
2.5.5.5
3.90∼4.10
2.5.5.9
0.0040∼0.0060
2.5.5.1
0.0060∼0.0080
2.5.5.5
0.0050∼0.0070
2.5.5.9
14 16 1×10 ∼1×10 13
15
2.5.17
14
16
ー
1×10 ∼1×10 1×10 ∼1×10
1×1013∼1×1014
ー
0.1∼0.3
2.6.2.1
−
V−0
2.3.10
hrs.
>1000
ー
%
1) Heating Rate: 10℃/min. *2) Measured by Triplate-line Resonator. *3) Measured by Material Analyzer.
38
2.4.8
0.6∼0.8
−
−
2.3.40
370∼390
1GHz*3 1MHz
2.4.24.1
>60
℃
A
ー
>60
1MHz Dielectric Constant
2.4.24
30∼40
(>Tg)
Decomposition Temperature(5% Weight Loss) TGA 18μm
Actual Value
(30∼120℃)
TMA
T-288 (Without Copper)
Unit
●Prepreg Glass Cloth Yarn Count Style (Warp×Fill)
Type
Part Number
0.04(S1037N72) 0.06(S1080N64) 0.06(S1080N69) 0.06(S1078N64) 0.08(S3313N56) 0.08(S3313N62) 0.1 (S2116N54) 0.1 (S2116N60) 0.15(S1501N49)
GHA-679G
1037 1080 1080 1078 3313 3313 2116 2116 1501
69×72 60×48 60×48 53×53 60×62 60×62 60×58 60×58 46×45
Test Method (IPC-TM-650)
Properties Resin Content Volatile Content Gelation Time Dielectric Thickness (%) (%) (sec.) after Lamination*1(mm) 72±2 64±2 69±2 64±2 56±2 62±2 54±2 60±2 49±2
<3.0
150±40
0.053 0.080 0.095 0.078 0.105 0.126 0.128 0.152 0.178
2.3.16
2.3.19
2.3.18
−
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●Correlation between Dielectric Constant and Frequency
●Correlation between Dissipation Factor and Frequency
0.030
5.0
0.025
Standard FR-4 MCL-HE-679G
4.0
Standard FR-4
0.020
Df
Dk
4.5
MCL-HE-679G (S)
0.015
MCL-HE-679G
0.010
3.5
MCL-HE-679G (S)
0.005 3.0
0
1
2
3
Frequency (GHz)
4
0.000
5
●CAF(85℃85%RH,DC100V) Wall to Wall Distance:0.3mm
3
4
5
-20
MCL-HE-679G (S)
1012 1010
Pre Treatment: 260℃ Reflow 3 times
108
dB/m
Insulation Resistance (Ω)
2
Frequency (GHz)
0
1014
-40
MCL-HE-679G -60 -80
106 1014
1
●Transmission Loss
(t0.8mm)
1016
0
0
200
400
600
800
1000
Treating Time (hrs.)
1200
-100
0
5
10
15
Frequency (GHz)
20
Note) Measured by Triplate-line Resonator.
39
Polyimide Multilayer Material Polyimide Multilayer Material
MCL-I-671 P42
41
Polyimide Multilayer Material
MCL-I-671
GIA-671N〈Prepreg〉
Glass Modified Polyimide Multilayer Material(GPY) ■Features
■Applications
●High Tg (>230℃ : DMA) material for high throughhole reliability.
●Main frame computers and super computers.
●Same lamination condition as FR-4 is applicable. (175℃, 90 min.) ●MDA, a general polyimide resin curing agent, is not used. (Non-MDA Resin System)
●Semiconductor testing equipment, and burn-in boards. ●Flex-rigid PWBs. (no-flow prepreg)
●Resin flow control technology enables from high to low flow.
■Standard Specifications Part Number
MCL-I-671
Type
Copper Foil Thickness
Code Name 0.06 0.1 0.2 0.3 0.41 0.79
12μm 18μm 35μm 70μm
̶
Actual Thickness and Tolerance 0.06±0.02mm 0.10±0.02mm 0.20±0.04mm 0.30±0.04mm 0.41±0.05mm 0.79±0.10mm
Note 1)In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2)The thickness means that of dielectric layer.
■Characteristics ●Thin Laminate
(t0.8mm) Condition
Item TMA
Tg
DMA X
CTE
Y
*1
Z Solder Heat Resistance (260℃) T-260 (Without Copper)
(30∼120℃)
A
20℃ 180℃
Flexural Modulus(Lengthwise) Dielectric Constant Dissipation Factor
1MHz 1GHz*2 1MHz 1GHz*2
Volume Resistivity Surface Resistance Insulation Resistance
*
2.4.24
230∼245
ー
12∼16
2.4.24
200∼300 sec. min. ℃
A
GPa
C-96/20/65
−
C-96/20/65
−
C-96/20/65+D-2/100
200∼213
50∼80
kN/m
C-96/20/65
Test Method (IPC-TM-650)
Ω・cm Ω Ω
ー
>300 >60
2.4.24.1
>15
2.3.40
330∼350 1.3∼1.5
2.4.8
1.0∼1.2 24∼26
2.4.4
4.2∼4.4
2.5.5.1
4.1∼4.3
2.5.5.5
0.0110∼0.0130
2.5.5.1
0.0130∼0.0150
2.5.5.5
15
16
1×10 ∼1×10
1×1013∼1×1015 1×1014∼1×1016 13
15
1×10 ∼1×10
2.5.17 ー ー
Water Absorption
E-24/50+D-24/23
%
0.10∼0.20
2.6.2.1
Flammability (UL-94)
A
−
Vー0
2.3.10
CAF
85℃/85%RH, DC100V
hrs.
>1000
ー
1)Heating Rate: 10℃/min. * 2)Measured by Triplate-line Resonator.
42
ppm/℃
A
C-96/35/90
Actual Value
12∼15
(>Tg)
Decomposition Temperature(5% Weight Loss) TGA Copper Peel Strength (18μm)
℃
(<Tg)
TMA
T-288 (Without Copper)
Unit
●Prepreg Part Number
Type
GIA-671N
0.03 0.05 (T) 0.1 0.03 (N) 0.05 0.05 (F)
Glass Cloth Properties Application Yarn Count Resin Content Volatile Content Resin Flow Dielectric Thickness Style (Warp×Fill) (%) (%) (%) after Lamination*1(mm) 50±5 106 0.059 72±3 56×56 MLB 43±5 1080 0.087 65±3 60×48 2116 0.134 54±3 60×58 29±5 <2.0 106 0.047 68±3 56×56 4±3 Flex-rigid PWBs 1080 0.072 59±3 60×48 54±5 Metal core PWBs 1080 0.111 74±3 60×48
Test Method (IPC-TM-650)
2.3.16
2.3.19
2.3.17
−
−
*1) The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.
●Correlation between Dielectric Constant and Frequency (t0.8mm)
●Correlation between Dissipation Factor and Frequency (t0.8mm)
5.0
0.030 0.025
4.5
Df
Dk
4.0
Standard FR-4
0.020
Standard FR-4 MCL-I-671
0.015
MCL-I-671
0.010 3.5 0.005 3.0
0
1
2
3
4
0.000
5
0
1
2
Frequency (GHz)
3
4
5
Frequency (GHz)
Note) Measured by Triplate-line Resonator.
●Water Absorption
70
1.0
Barcol Hardness
60
MCL-I-671
50 40 30
FR-4
20
Water Absorption (%)
●Barcol Hardness
PCT Condition: 121℃ 0.22MPa
(t0.8mm)
MCL-I-671
Standard FR-4
0.5
10 0 0
50
100
150
200
0.0 250
0
2
Temperature (℃)
●Thermal Shock Test MIL-STD-202 Method 107E
8
700
Flexural Strength (MPa)
80
Defect Rate (%)
6
●Flexural Strength
100
Standard FR-4
60
40
20
0
4
Treating Time (hrs.)
600 500
210℃
400 300
225℃
200
255℃
100
MCL-I-671 0
1000
2000
No. of Cycles
3000
4000
0 1
10
100
1000
Treating Time (hrs.)
10000
43
Glass Epoxy Double Sided Materials Copper Clad Laminate for Double Sided PWBs(FR-4)
MCL-E-67 P46
High CTI Copper Clad Laminate for Double Sided PWBs(FR-4)
MCL-E-670 P48
45
Copper Clad Laminate for Double Sided PWBs
MCL-E-67 [
]
UV Block Type MCL-E-67 Type(WK)
Glass Epoxy Copper Clad Laminate(FR-4) ■Features
■Applications
●Superior electrical characteristics, surface smoothness and dimensional stability.
●Office automation equipment, communication tools and measuring instruments.
●Superior drilling ability.
●Game machines.
●Superior heat resistance, moisture resistance and through-hole reliability.
●Electronics for automobiles.
■Standard Specifications Part Number
Copper Foil Thickness
Type
Code Name
Actual Thickness and Tolerance
0.3
0.30±0.08mm
0.4
0.40±0.13mm
18μm
0.5
0.50±0.13mm
35μm
0.6
0.60±0.15mm
70μm
0.8
0.80 (0.70) ±0.17mm
(105μm)
1.0
1.00 (0.90) ±0.18mm
1.2
1.20 (1.10) ±0.19mm
1.6
1.60 (1.50) ±0.19mm
̶
MCL-E-67
(WK)
Note 1) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note 2) The thickness means that of dielectric layer. Figure in bracket ( ) means thickness of dielectric layer of MCL using 70μm copper foil. Note 3) Prior confirmation is recommended for 105μm copper foil availability.
■Characteristics
(t1.6mm) Condition
Item TMA
Tg X CTE
Y
*1
Z
Test Method (IPC-TM-650)
℃
120∼130
2.4.24
13∼16
(30∼120℃) (<Tg)
ppm/℃
(>Tg)
14∼17 50∼70
2.4.24
200∼300
A
sec.
>120
ー
Heat Resistance
A
−
E-1/200 No Problem
ー
A
kN/m
1.4∼1.6
2.4.8
A
N/mm2
Flexural Strength
18μm Length Width
500∼600 400∼500
Dielectric Constant (1MHz)
C-96/20/65
−
4.7∼4.8
Dissipation Factor (1MHz)
C-96/20/65
−
0.0130∼0.0170
Ω・cm
15 16 1×10 ∼1×10
Ω
1×1013∼1×1015
Volume Resistivity Surface Resistance Insulation Resistance
46
Actual Value
Solder Heat Resistance (260℃)
Copper Peel Strength
*
Unit
C-96/35/90 C-96/20/65 C-96/20/65+D-2/100
Ω
1×1014∼1×1016 1×1013∼1×1015
2.4.4
2.5.5.1
2.5.17.1
ー
Water Absorption
E-24/50+D-24/23
%
0.06∼0.08
2.6.2.1
Flammability(UL-94)
A
−
V−0
2.3.10
CAF
85℃/85%RH, DC100V
hrs.
>1000
ー
1)Heating Rate: 10℃/min.
●Dimensional Stability
●Heat Resistance Property
(t1.6mm)
0.01 Length
●IR Reflow Temperature Profile (Laminate Surface Temperature)
Width
-0.01
250
-0.02
℃
-0.03 As Received Etch Out Dried at (All Laminate)140℃ 20min. (Vertical)
Dried at 170℃ 30min. (Horizontal)
Process Sample Size:330mm (Length) ×250mm (Width) Tooling Hole:1.0φ310×230mm
200 150 100 50
︵ ︶ UV Transmission
%
14
10
12
10
11
10
10
10
%
7
0
400
800
1200
1600
2000
Treating Time(hrs.)
●Elastic Modulus(Tensile) 30
1.0 0.5 0 0.1
0.2
0.4
0.6
Thickness(mm)
0.8
1.0
20 15 10 5 0 0.1
0.2
0.4
0.6
Thickness(mm)
0.8
1.0
(t1.6mm)
0.40
Length 20
25 Wavelength: 420nm
0.50
Poisson's Ratio
︵ GPa ︶ Elastic Modulus
1.5
●Poisson's Ratio
(t1.6mm)
25
Width
15 10
0.30 Length
0.20
Width
0.10
5 0
240
●UV Blocking Property(Type(WK))
8
10
200
2.0
10 10
150
2.5 Wavelength: 350nm
9
︵ ︶ UV Transmission
︵ Ω ︶ Insulation Resistance
13
100
●UV Blocking Property(Type(WK))
Distance between Through-hole Walls (t1.6mm)
10
50
Processing Time(sec.)
●CAF Properties(Environmental Condition: 85℃85%, Applied Voltage:100V) 15
0
0
10
MAX257∼265℃
300
︵ ︶ Temperature
︵ ︶ Dimensional Change %
0.02
0
[Unit: sec.]
Reflow Heat ANSI Solder Heat Resistance(Float) Thickness Copper Resistance Grade 260℃ 288℃ 300℃ 260℃/30sec 35μm 1.6mm Double Sided FR-4 180 OK 180 OK 180 OK OK
0.00 30
50
100
150
200
Laminate Surface Temperature(℃)
30
50
100
150
200
Laminate Surface Temperature(℃)
47
High CTI Copper Clad Laminate for Double Sided PWBs
MCL-E-670
Glass Epoxy Copper Clad Laminate(FR-4) ■Features
■Applications
●High CTI.(600V)
●Communication tools, measuring instruments and office automation equipment.
●Superior moisture resistance.
●Consumer electronics and game machines.
●Superior long-term thermal reliability. ●Low CTE and superior through-hole reliability.
●Power supply PWB. ●Electronics for automobiles.
■Standard Specifications Part Number
Type
MCL-E-670
Copper Foil Thickness
̶
Code Name
Actual Thickness and Tolerance
0.6
0.60±0.15mm
18μm
0.8
0.80±0.17mm
35μm
1.0
1.00 (0.90) ±0.18mm
70μm
1.2
1.20 (1.10) ±0.19mm
1.6
1.60 (1.50) ±0.19mm
Note)The thickness means that of dielectric layer. Figure in bracket( )means thickness of dielectric layer of MCL using 70μm copper foil.
■Characteristics
(t1.6mm)
Item
Condition TMA
Tg X CTE
*1
Y Z
Solder Heat Resistance (260℃) Heat Resistance Copper Peel Strength
Flexural Strength
18μm Length Width
Dielectric Constant (1MHz)
Dissipation Factor (1MHz) Volume Resistivity Surface Resistance Insulation Resistance
*
Actual Value
℃
135∼145 13∼16
(30∼120℃) (<Tg)
ppm/℃
(>Tg)
14∼17
150∼250 >120
D-1/100
−
No Problem after 20 Sec.
A
−
E-1/200 No Problem
A S4 A C-96/20/65 D-24/23 C-96/20/65 D-24/23 C-96/35/90 C-96/20/65 C-96/20/65+D-2/100
2.4.24
23∼35
sec.
A
Test Method (IPC-TM-650)
kN/m
N/mm2
−
−
1.2∼1.4 1.2∼1.4 500∼600 400∼500
ー 2.4.8
2.4.4
5.2∼5.4 5.3∼5.5 0.0100∼0.0150
2.5.5.1
0.0110∼0.0160
Ω・cm
15 16 1×10 ∼1×10
Ω
1×1013∼1×1015
Ω
ー
1×1014∼1×1016 1×1013∼1×1015
2.5.17.1
ー
Water Absorption
E-24/50+D-24/23
%
0.1∼0.14
2.6.2.1
Flammability (UL-94)
A
−
Vー0
2.3.10
CAF
85℃/85%RH, DC100V
hrs.
>1000
ー
1)Heating Rate: 10℃/min.
48
Unit
●CTI Property(t1.6mm All Etch Out)
●Water Absorption
80
0.80
︵ ︶ Water Absorption %
Number of Drops
(t1.6mm)
1.00 PCT Condition : 121℃ 0.22MPa
100 Test Method: IEC Method
60
40
20
0
0.60
0.40
0.20
0.00 0
200
400
600
0
2
Voltage(V)
4
6
8
Treating Time(hrs.)
●Long-term Heat Aging Property (Heat Aging Temp. 180℃)
●Peel Strength after Heat Aging (Heat Aging Temp. 177℃)
(t1.6mm)
800
(t1.6mm, Copper Foil Thickness 18μm)
2.0
600
︵ kN/m ︶ Peel Strength
︵ N/mm ︶2 Flexural Strength
700
500 400 300 200
1.5
1.0
0.5
100 0
0.0
10
100
1000
10000
0
50
200
●Through-hole Reliability
●Thermal Expansion(Z-direction)
(t1.6mm)
Test Method: TMA 10℃/min.
150
250
Treating Time (hrs.)
Treating Time (hrs.)
30
100
(t1.6mm)
2
︵ Ω ︶ Series Resistance
25
︵ μ︶ Expansion m
20 15 10 5
1.5
1
0.5
0 0
-5 20
50
100
150
Temperature (℃)
200
0
20
40
60
80
100 110
Number of Cycle Condition(1 Cycle) 260℃ Oil Dip 10 sec. ↓ 20℃ Water Dip 10 sec. ↓ Drain 10 sec.
49
Materials for Fine Patterning Film for Fine Patterning(Semi-Additive Process Compatible)
SAPP(Semi-Additive Process Primer) P52 Copper Foil for Fine Patterning
PF-E,PF-EL P54
Film for Fine Patterning(Semi-Additive Process Compatible)
AirFoil(Under development) P56
Materials for Fine Patterning 5/5
Fine Patterning materials
AirFoil
10/10
SAPP
15/15
20/20 PF-EL
25/25
30/30
35/35
40/40
PF-E
51
Film for Fine Patterning(Semi-Additive Process Compatible)
SAPP(Semi-Additive Process Primer) ■Features
■Applications
●Semi-additive process primer with fine patterning especially.
●Semiconductor packages. (FC-BGA,FC-CSP,SIP)
●Fine patterning(<L/S=10/10μm)with low surface roughness(Ra:0.2∼0.3μm)
●Modules
●Excellent anti migration resin system. ●High flexural modulus substrates with using prepregs. ●Applicable for conventional prepreg press process.
■Standard Specifications Resin Thickness(μm)
Ra(μm)
Carrier Copper Thickness(μm)
5±1
0.2∼0.3
10μm
■Characteristics I t ems Surface Roughness after desmearing (Ra) Tg Solder Heat Resistance (260℃) Plating Copper Peel Strength
25μm
Conditions
Units
Actual Values
A
μm
0.2∼0.3
TMA
℃
160∼170
A
sec.
>600
A
kN/m
0.6∼0.8
●Ultra smooth surface after desmearing ●Fine patterning with semi-additive process
Ra:15μm
L/S=6μm/6μm
L/S=10μm/10μm
10μm ●Electrical reliability(CAF Restraining)
Sample structure
1.E+12
GEA-679FG (R) :#1037×1ply Line thickness:5μm SAPP
1.E+11
︵ ︶ Resistance
Ω
MCL-E-679FG (R)
1.E+10
L/S=10μm/10μm
1.E+09
Test condition:130℃85%RH,DC5.5V L/S=10μm/10μm
1.E+08 1.E+07 1.E+06
100μm 0
50
100
150
Time(h)
52
200
250
Copper Foil for Fine Patterning
PF-E,PF-EL
Profile-Free Copper Foil is Suitable for Very Fine Line Patterning with the Surface Roughness of Adhesive Side as About 1.0-2.0μm. ■Features
■Applications
●PF-EL is a copper foil that is appropriate for very fine line patterning with semi-additive process (SAP)using rough shapes of primer made with the copper profile.
●Semiconductor package substrates
●PF-EL is high peel strength for plating copper.
●High density multi-layer PWB ●PWB for high-frequency application
●PF-E is a copper foil that is appropriate for very fine line patterning with subtractive process and Modified Semi-Additive Process (MSAP) . ●High flexural modulus substrates with using prepregs. ●Possible to reduce transnission loss about 8dB/m compared to standard copper foil. (at 5GHz)
Item PF-EL-12
Copper thickness (μm) Roughness (μm) Roughening treatment 12 3
PF-EL-2
2
PF-E-12
12
Ra: 0.15∼0.25 Rz: 1.0∼2.0
3
Ra: 0.15∼0.25 Rz: 1.0∼2.0
PF-E-3
Low profile copper foil
Ra: 0.3∼0.4 Rz: 1.5∼2.5
PF-EL-3
Composition
Special surface treatment Profileless copper foil
Special surface treatment
20μm
54
SAP*1 MSAP*2
Ra: 0.3∼0.4 Rz: 1.5∼2.5
●Very fine circuit patternability
Design L/S=8/8μm by SAP(PF-EL)
Process
100μm
Design L/S=15/15μm by MSAP(PF-E)
SAP*1 Subtractive Process MSAP*2
●Plating copper peel strength(PF-EL) Plating copper peel strength (kN/m)
Copper peel strength (kN/m)
●Copper peel strength(PF-E) 1.2
Rz:7∼9μm
1.0 0.8
Rz:1∼2μm
Rz:3∼5μm
0.6 0.4
Rz:1∼2μm
0.2 0.0
Standard copper-foil
Low profile Profile-free copper foil copper foil (Untreated)
PF-E
※MCL-E-700G (R) 、Copper thickness 12μm
1.2 1.0
Rz:1.5∼2.5μm
0.8 0.6 0.4
Rz:1.5∼2.5μm
0.2 0.0
Ultra Low profile copper foil
PF-EL
※MCL-E-700G (R) 、Plating copper thickness 20μm
●Insulation reliability 1.0E+14
Sample structure
AS-Z3 MCL-679GT Precondition (a) TCT:-40degC(15min) to 60degC (15min) , 5cycles (b) Baking: 125 degC, 24hr (c) 60 degC, 60%RH, 120hr (d) Reflow: 260degC (max) , 3cycles
Resistance(Ω)
1.0E+12
PF-EL
1.0E+10
Test condition:130degC, 85%, 3.3V L/S=15/15μm
1.0E+08 1.0E+06 1.0E+04
0
50
100
150
200
250
300
350
Time (h)
●Transmission loss Board specifications : Size : 510mm x 510mm Layer count : 8 PWB structure : strip line Line length : 500mm Line width : 0.06-0.184mm Insulation thickness : 0.16-0.27mm Line terminal : plated thorough hole
Transmission loss(dB/m)
0 ー10
PF-E
ー20
Low profile copper foil
ー30
Standard copper foil
ー40
prepreg
ー50 ー60
Measurement line
0
1
2
3
4
5
MCL
6
Frequency(GHz) ※MCL-E-679FG
55
Film for Fine Patterning(Semi-additive process compatible)
AirFoil ■Features
■Applications
●Suitable for fine line patterning by semi-additive process. such as L/S=