WORKSHOP: Matter and Working with Significant Figures

Name_______________________ Chem 305 Partner_______________________ Section (Circle) M Tu W Th F Date_______________________ WORKSHOP: Matter and W...
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Name_______________________ Chem 305

Partner_______________________ Section (Circle) M Tu W Th F

Date_______________________

WORKSHOP: Matter and Working with Significant Figures Part 1: Classifying Matter: Circle the appropriate words to make the statements true. 1. A mixture (is/is not) a chemical combining of substances. 2. In a compound the (atoms/molecules) are (chemically/physically) combined so that the elements that make up the compound (retain/lose) their identities and (do/do not) take on a new set of properties. 3. The smallest identifiable unit of a compound is a(n) ______________ , which is made up of _______________which are chemically bonded. 4. (True or False): A mixture is always made up of a combination of elements. 5. In a mixture, the substances (lose/retain) their identities. 6. In a mixture the substances involved (can/cannot) be separated by a simple physical process. In a compound the elements involved (can/cannot) be separated by a simple physical process because the elements are (physically combined/chemically bonded). 7. (True or False): An element can be broken down into a simpler substance. 8. The smallest identifiable unit of an element is a(n) _______________ . 9. From the following list of substances, circle the ones that are elements: silver carbon dioxide air chromium water

hydrogen

carbon

nitrogen

oxygen

gold

sugar

salt

10. How would you separate sand and water in a mixture?

12. Explain how to separate the sugar and water in a solution of sugar and water. Work Check

2-1 Adapted from Lalibert, 7/17/08

Name_______________________

13. Classify the following as pure substances (pure) or as mixtures (mix): air: _____________

gasoline: ______________

orange juice: ________

tap water: _________

sugar: _____________

gold: _________________

mercury: ___________

oxygen: _______________

salt water: __________

14.Classify the following as heterogeneous (het) or as homogeneous (hom): sand & salt mix: ______

hydrogen: ___________

iron: _________________

salt water: _________

filtered air: _________

iron with rust: ______

wood: ____________

an apple: ____________

tossed salad: _________

15.Classify the following as an element, a compound, a homogeneous mixture, or a heterogeneous mixture: aluminum: _________________ raisin bread: __________________________ carbon dioxide: _____________ pure water: ________________________ sugar and water: ____________ sodium chloride: ____________________ an orange: _________________ water & instant coffee: ___________________ hydrogen: _________________ carbon particles & sugar: _______________ gasoline: __________________ neon: ________________________ Work Check

2-2 Adapted from Lalibert, 7/17/08

Name_______________________

Elements, Compounds, and Mixtures Classify each of the pictures below by placing the correct label in the blanks below: A= Element D= Mixture of compounds B= Compound E= Mixture of elements and compounds C= Mixture of elements Each circle represents an atom and each different color represents a different kind of atom. If two atoms are touching then they are bonded together.

1)

2)

3)

4)

5)

6)

7)

8)

9)

10)

11)

12)

13)

14)

15)

2-3

Work Check

Name_______________________

Part 2: Physical and Chemical Changes to Matter Place a check in the appropriate column: Change

Physical Chemical Change Change

Salt dissolves in water. Hydrochloric acid reacts with magnesium to produce hydrogen gas. A piece of copper is cut in half. A sugar cube is ground up. Water is heated and changed to steam. Iron rusts. Ethyl alcohol evaporates. Ice melts. Milk sours (goes bad). Sugar dissolves in water. Sodium and potassium react violently with water. An antacid relieves heartburn. Grass grows on a lawn. A tire is inflated with air. Oxygen and hydrogen combine to form water. Water is absorbed by a paper towel. Ethyl alcohol boils at 79°C. Paper burns. Work Check

2-4

Name_______________________

Part 3 Mixed Practice INSTRUCTIONS: Write het in the blank if the material is heterogeneous or hom if it is homogeneous. 1. face cream

5. dirt

2. filtered green tea

6. sausage pizza

3. gravel

7. laundry bleach

4. Lucky Charms®

8. store-bought milk

INSTRUCTIONS: Classify each of the following as an element [E], a compound [C], or a mixture [M]. 9. calcium

13. pancake syrup

10. nitrous oxide

14. carbon monoxide

11. seawater

15. silver

12. sugar

16. ice

INSTRUCTIONS: Classify each of the following properties of matter as physical [P] or chemical [C]. 17. Color

21. Reacts violently with chlorine

18. Density

22. Good conductor of heat

19. Burns easily (flammable)

23. Dissolves readily in water

20. Not affected by acids

24. Melts at 145 °C

INSTRUCTIONS: Classify each of the following changes in matter as physical [P] or chemical [C]. 25. Grinding chalk into powder

29. Burning gasoline

26. Dissolving salt in water

30. Hammering gold into foil

27. Dissolving zinc in acid

31. Melting ice

28. Stretching copper into wire

32. Making hydrogen from water Work Check

2-5

Name_______________________

Part 4: Significant Figures, Scientific Notation, & Rounding How can we determine how many significant numbers a measurement has? The following rules apply to determining the number of significant figures in a measured quantity: 1. All NONZERO digits ARE significant: 457 cm (three significant figures) 0.25 g (two significant figures). 2. IMBEDDED ZEROS (between nonzero digits) ARE significant 1005 kg (four significant figures) 1.03 cm (three significant figures). 3. LEADING ZEROS (to the left of the first nonzero digits in a number) ARE NOT significant; they merely indicate the position of the decimal point: 0.02 g (one significant figure) 0.0026 cm (two significant figures). 4. ENDING ZEROS that are to the right of the decimal point ARE significant 0.0200 g (three significant figures) 3.0 cm (two significant figures). 5. ENDING ZEROS that are not to the right of a decimal point MAY BE significant: 130 cm (two or three significant figures) 10,300 g (three, four, or five significant figures). The way to remove this ambiguity is described on the following page. Use of standard exponential notation avoids the potential ambiguity of whether the zeros at the end of a number are significant (rule 5). For example, a mass of 10,300 g can be written in exponential notation showing three, four, or five significant figures: 1.03 x 104 g 1.030 x 104 g 1.0300 x 104 g

(three significant figures) (four significant figures) (five significant figures)

In these numbers all the zeros to the right of the decimal point are significant (rules 2 and 4). 1. Determine the number of significant figures in each of the following measured values: a) 200,073

_____

b) 0.00084

_____

c) 5.001

_____

d) 0.0620

_____

e) 107.010

_____

f)

_____

g) 3.400 x 103

_____

h) 3.40 x 103 2-6

3400

_____

Name_______________________ Rounding

When we express a value to the correct number of significant figures, this often requires rounding. To round off decimals: ♦ Find the place value you want (the "rounding digit") and look at the digit just to the right of it. ♦ If that digit is less than 5, do not change the rounding digit but drop all digits to the right of it. ♦ If that digit is greater than or equal to five, add one to the rounding digit and drop all digits to the right of it.

To round off whole numbers: ♦ Find the place value you want (the "rounding digit") and look to the digit just to the right of it. ♦ If that digit is less than 5, do not change the "rounding digit" but change all digits to the right of the "rounding digit" to zero. ♦ If that digit is greater than or equal to 5, add one to the rounding digit and change all digits to the right of the rounding digit to zero. NOTE: It may be necessary to use scientific notation to correctly

2. Round the value 673.1482 to:

3. Round the value 50.0696 to:

5 sig figs _______________

4 sig figs _______________

3 sig figs _______________

3 sig figs

_______________

2 sig figs _______________

2 sig figs 1 sig fig

_______________ _______________

1 sig fig

_______________

4. Round the value 273.84 to:

5. Round the value 48372000 to:

4 sig figs _______________

4 sig figs _______________

3 sig figs _______________

3 sig figs _______________

2 sig figs _______________

2 sig figs _______________

1 sig fig

1 sig fig

_______________

_______________

Work Check

2-7

Name_______________________

Scientific Notation In scientific notation, all numbers are represented by number with one non-zero digit to the left of the decimal place multiplied by ten raised to the appropriate power. • •

Small number (less than 1) will have negative exponents of 10. Large numbers (greater than 1) will have positive exponents of 10.

WORKING WITH SIGNIFICANT FIGURES Addition and Subtraction When adding or subtracting, the number of digits to the right of the decimal point in the answer equals the measurement which has the least number of digits to the right of the decimal point. EXAMPLE: adding:

EXAMPLE: subtracting:

26.46 this has the least digits to the right of the decimal point (2) + 4.123 30.583 rounds off to* → 30.58 ↑ 2 digits to the right of the decimal point 26.46 - 4.123 22.337 rounds off to → 22.34

Perform the following additions or subtractions. Report your results to the proper number of significant figures.

a) 28 + 16 + 227 =

__________

b) 2.222 + 2.22 + 2.2 =

__________

c) 81.42-18.4 =

__________

d) 4732.3 + 55 + 0.54 =

__________

e) 999.0 + 1.7 – 43.7 =

__________

f) 564,321 – 264,321 =

__________

g) 0.04216 – 0.0004134 = __________

Work Check

2-8

Name_______________________

Multiplication and Division In multiplying or dividing, the number of significant figures in the answer (regardless of the position of the decimal point) equals that of the quantity which has the smaller number of significant figures. EXAMPLE: multiplying:

EXAMPLE: dividing:

2.61 x 1.2 this has the smaller number of significant figures (2) 3.132 rounds off to → 3.1 has 2 significant figures 2.61 / 1.2 = 2.175 rounds off to → 2.2

5. Carry out the following multiplications, expressing your answer to the correct number of significant figures.

a) 27.88 x 0.00695 =

__________

b) 3.10 x 5428 =

__________

c) 3.00 x 0.4000 =

__________

d) 0.693 x 7.3x102 =

__________

e)

4317 0.88

__________

f)

(2.7x108 )(0.00149) (0.1500)

__________

g)

(8.4)(0.03) (147)(.11)

__________

(57332)(3.5x10 4 ) h) (185)(2x1012 )

__________

Work Check

2-9

Name_______________________

Mixed Practice – you must show the s.f on intermediate calcs to get credit!!! 1) (183 x 0.017) + 850. =

2)

(12.7 − 8.3) = (18.5 − 2.2)

3) (3.0 x 2.2) + (4 x 85) =

4)

(0.127 − 0.038) = 0.0445

3.24x10 −5 5) = (187 + 27)

6)

(438 + 825) = 1.234x10 −6

 4.02x108   + 385 = 7)  5  1.4x10    4.02x108   + 385 = 8)  −3  1.4x10  

9)

(14.8 − 12.5) = 12.5

(0.01020)(4.3 x10 4 ) 10) = (16 − 12)

11)

(83.4 − 27.4) = 0.0432 Work Check

2-10