THE CHEMISTRY OF LIFE THE NATURE OF MATTER

THE CHEMISTRY OF LIFE T H E N AT U R E O F M AT T E R AT O M S • What three subatomic particles make up atoms? • ATOM - the basic subunit of matter...
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THE CHEMISTRY OF LIFE

T H E N AT U R E O F M AT T E R

AT O M S • What three subatomic particles make up atoms? • ATOM - the basic subunit of matter • Incredibly small • 100 million atoms placed side by side would make

a row only about 1 centimeter long

• The subatomic particles that make up atoms are

PROTONS, NEUTRONS, and ELECTRONS.

PROTONS AND NEUTRONS

• Protons and neutrons have about the same mass • Protons are positively charged particles (+) • Neutrons have no charge (neutral) • NUCLEUS - center of the atom where protons and

neutrons are located

AT O M

• PROTONS = (+) • NEUTRONS = NEUTRAL • ELECTRONS = (-)

ELECTRONS • The ELECTRON is a negatively charged particle (-) with

only 1/1840 the mass of a proton

• In constant motion • Outside the nucleus • Attracted to the positively charged nucleus but remain

outside because of the energy of their motion

• Atoms have equal numbers of protons (+) and electrons (-),

so they are neutral (no charge)

ELEMENTS AND ISOTOPES • How are all of the isotopes of an element similar? • A chemical ELEMENT is a pure substance that

consists entirely of one type of atom

• More than 100 elements are known • Only about 24 are commonly found in living things • Represented by one or two-letter symbols • Example: C is the symbol for Carbon

ELEMENTS AND ISOTOPES

• H is for Hydrogen • N is for Nitrogen • Na is for Sodium • HG is for Mercury

ELEMENTS AND ISOTOPES

• The number of protons in the nucleus is called its

ATOMIC NUMBER

• Carbon’s atomic number is 6 • 6 protons and therefor 6 electrons

ISOTOPES • Atoms of elements can have different numbers of neutrons • Atoms of the same element that differ in the number of neutrons are known

as ISOTOPES

• The total number of protons and neutrons in the nucleus of an atom is called

its MASS NUMBER

• Isotopes are identified by their mass numbers

ISOTOPES • The weighted average of the masses of an element’s

isotopes is called its ATOMIC MASS

• “Weighted” means that the abundance of each

isotope in nature is considered when the average is calculated

• Because they all have the same number of

electrons, all isotopes of an element have the same chemical properties

ISOTOPES OF CARBON

RADIOACTIVE ISOTOPES • Some isotopes are radioactive, meaning their nuclei are unstable

and break down at a constant rate over time

• The radiation they give off is dangerous, but they do have some

important uses

• Geologists can determine the ages of rocks and fossils by

analyzing the isotopes found in them

• Radiation from certain isotopes can be used to detect and treat

cancer and kill bacteria in food that cause it to spoil

• Radioactive isotopes can also be used as labels or “tracers” to

follow the movements of substances within organisms

CHEMICAL COMPOUNDS • Most elements are combined with other elements in nature to

form compounds • A chemical compound is a substance formed by the chemical

combination of two or more elements in definite proportions • Written in shorthand known as chemical formula • Water = H2O, Salt = NaCl • The physical and chemical properties of a compound are

usually very different from those of the elements from which it is formed

CHEMICAL BONDS • The main types of chemical bonds are ionic bonds and covalent

bonds • Ionic bonds - formed when one or more electrons are transferred

from one atom to another • Atoms are electrically neutral because they have the same number

of protons and electrons • An atom that loses electrons becomes positively charged • An atom that gains electrons becomes negatively charged • These positively and negatively charged atoms are known as ions

I O N I C B O N D S I N TA B L E S A LT

A sodium atom easily loses its one valence electron and becomes a sodium ion (Na+). A chlorine atom easily gains one valence electron and becomes a chlorine ion (Cl-). The opposite charges have a strong attraction, forming an ionic bond.

C O VA L E N T B O N D S • Covalent bond - The moving electrons travel about the nuclei

of both atoms

• When the atoms share two electrons, it is a single covalent

bond

• Sometimes the atoms share four electrons and form a double

bond

• In a few cases, atoms can share six electrons and form a triple

bond

• The structure that results when atoms are joined together by

covalent bonds is called a molecule

C O V A L E N T B O N D S I N W AT E R

• Each hydrogen atom

share two electrons with the oxygen atom

VA N D E R WA A L S F O R C E S • Because of their structures, atoms of different elements

do not all have the same ability to attract electrons • Some atoms have a stronger attraction for electrons

than others • In covalent bonds, the sharing is not always equal • Even when the sharing is equal, the rapid movement of

electrons can create regions on a molecule that have a tiny positive or negative charge

VA N D E R WA A L S F O R C E S

• When molecules are close together, a slight attraction

can develop between the oppositely charged regions of nearby molecules

• Chemists call such intermolecular forces of attraction

van der Waals forces, after the scientist who discovered them