RID Medicated Lotion Repellent Plus Antiseptic RID (RID (Australia))

Chemwatch Hazard Alert Code: 1

Chemwatch: 36-6826 Version No: 3.1.1.1 Material Safety Data Sheet according to NOHSC and ADG requirements

Issue Date: 07/02/2014 Print Date: 10/02/2014 Initial Date: Not Available S.Local.AUS.EN.RISK

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name Chemical Name Synonyms

RID Medicated Lotion Repellent Plus Antiseptic Not Applicable 201050 50ml Roll On APN 9311037120502, 201125 125ml Squeeze Bottle APN 93206495, 201375 375ml Squeeze Bottle APN 93110375355131

Proper shipping name

Not Applicable

Chemical formula

Not Applicable

Other means of identification CAS number

Not Available Not Applicable

Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses

Use according to manufacturer's directions. , Medicated before and after bite lotion and personal insecticide applied to the skin.

Details of the supplier of the safety data sheet Registered company name Address Telephone Fax

RID (RID (Australia)) 79 Denham Street Townsville 4810 QLD Australia +61 7 4772 1411 +61 7 4721 3892

Website

Not Available

Email

Not Available

Association / Organisation

Not Available

Emergency telephone number

Emergency telephone numbers

+61 7 4772 1411

Other emergency telephone numbers

+61 7 4772 1411

SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.

Label elements Relevant risk statements are found in section 2 Poisons Schedule Risk Phrases [1]

R62?

May possibly affect fertility*.

*LIMITED EVIDENCE Legend:

Indication(s) of danger

1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Not Applicable

SAFETY ADVICE S56

Dispose of this material and its container at hazardous or special waste collection point.

Other hazards

Continued...

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RID Medicated Lotion Repellent Plus Antiseptic

Print Date: 10/02/2014

Not Applicable

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures

Mixtures CAS No

%[weight]

Name

134-62-3

16

N,N-diethyl-m-toluamide

Not Available

0.1-10

ingredients determined not to be hazardous [Mfr]

7732-18-5

NotSpec.

water

SECTION 4 FIRST AID MEASURES Description of first aid measures

Eye Contact

Skin Contact

If this product comes in contact with eyes: Wash out immediately with water. If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. Intended for application to skin. Remove with soap and water if irritation occurs. Seek medical advice if irritation persists.

Inhalation

If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.

Ingestion

Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area.

Special hazards arising from the substrate or mixture Fire Incompatibility

None known.

Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area.

Fire Fighting

Fire/Explosion Hazard

Non combustible. Not considered a significant fire risk, however containers may burn. May emit poisonous fumes.

SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite.

Minor Spills

Major Spills

Moderate hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE Precautions for safe handling

Safe handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. Continued...

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RID Medicated Lotion Repellent Plus Antiseptic

Print Date: 10/02/2014

Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers.

Other information

Conditions for safe storage, including any incompatibilities Polyethylene or polypropylene container. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

Suitable container Storage incompatibility

+

+

X 0 +

+

Avoid reaction with oxidising agents

+

+

+

— Must not be stored together — May be stored together with specific preventions — May be stored together

PACKAGE MATERIAL INCOMPATIBILITIES

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Not Available EMERGENCY LIMITS Ingredient

TEEL-0

TEEL-1

TEEL-2

TEEL-3

water

500(ppm)

500(ppm)

500(ppm)

500(ppm)

Ingredient

Original IDLH

Revised IDLH

RID Medicated Lotion Repellent Plus Antiseptic

Not Available

Not Available

Exposure controls

Appropriate engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk.

Personal protection

Eye and face protection

Skin protection

Safety glasses with side shields Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. See Hand protection below

Hand protection

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when making a final choice.

Body protection

See Other protection below

Other protection

Overalls. P.V.C. apron. Barrier cream.

Thermal hazards

Recommended material(s)

Respiratory protection

GLOVE SELECTION INDEX Glove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the RID Medicated Lotion Repellent Plus Antiseptic Material

CPI

Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the "Exposure Standard" (or ES), respiratory protection is required. Degree of protection varies with both face-piece and Class of filter; Continued...

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Print Date: 10/02/2014

BUTYL

A

the nature of protection varies with Type of filter.

NEOPRENE

A

VITON

A

Required Minimum Protection Factor

Half-Face Respirator

Full-Face Respirator

Powered Air Respirator

up to 10 x ES

A-AUS P2

-

A-PAPR-AUS / Class 1 P2

up to 50 x ES

-

A-AUS / Class 1 P2

* CPI - Chemwatch Performance Index A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion C: Poor to Dangerous Choice for other than short term immersion

up to 100 x ES -

A-2 P2

A-PAPR-2 P2 ^

^ - Full-face A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC) SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance

Physical state Odour

White fragrant non-greasy liquid; miscible with water (200 g/l)

Liquid

Relative density (Water = 1)

0.98

Not Available

Partition coefficient n-octanol / water

Not Available

Odour threshold

Not Available

Auto-ignition temperature (°C)

Not Available

pH (as supplied)

6.4-6.7

Decomposition temperature

Not Available

Viscosity (cSt)

Not Available

Melting point / freezing point (°C) Initial boiling point and boiling range (°C) Flash point (°C)

Not Available 85-100 Not Applicable

Molecular weight (g/mol)

Not Applicable

Taste

Not Available

Evaporation rate

Not Available

Explosive properties

Not Available

Flammability

Not Available

Oxidising properties

Not Available

Upper Explosive Limit (%)

Not Applicable

Surface Tension (dyn/cm or mN/m)

Lower Explosive Limit (%)

Not Applicable

Volatile Component (%vol)

Vapour pressure (kPa)

Not Applicable

Gas group

Not Available

pH as a solution(1%)

Not Available

Solubility in water (g/L)

Miscible

Vapour density (Air = 1)

Not Available

Not Available 80-90

VOC g/L

SECTION 10 STABILITY AND REACTIVITY Reactivity Chemical stability

See section 7 Presence of incompatible materials. Product is considered stable. Hazardous polymerisation will not occur.

Possibility of hazardous reactions

See section 7

Conditions to avoid

See section 7

Incompatible materials

See section 7

Hazardous decomposition products

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects

Inhaled

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. Not normally a hazard due to non-volatile nature of product

Ingestion

The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence.

Skin Contact

The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Dermal application of Deet in man produces no primary skin irritation or skin sensitisation whereas in rabbits erythema and desquamation are described along with percutaneous intoxication. Central nervous system disorders (excitation, stiffness of movement and loss of coordination) Continued...

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were observed in rats following administration of the substance. Eye

Chronic

RID Medicated Lotion Repellent Plus Antiseptic

The liquid may produce eye discomfort causing transient smarting, blinking Exposure to the material may cause concerns for human fertility, on the basis that similar materials provide some evidence of impaired fertility in the absence of toxic effects, or evidence of impaired fertility occurring at around the same dose levels as other toxic effects, but which are not a secondary non-specific consequence of other toxic effects. . Principal routes of exposure are usually by inhalation of mists or vapours from heated material and skin contact/absorption. A 5 year old girl sprayed with Deet nightly for 3 months, developed headaches and slurred speech, progressing to athetosis (ceaseless slow, writhing motions especially of the hands), shaking, screaming and convulsion.

TOXICITY

IRRITATION

Not Available

Not Available

TOXICITY

IRRITATION

Dermal (rabbit) LD50: 3180 mg/kg

Eye (rabbit) : 10 mg - moderate

Dermal (rat) LD50: 5000 mg/kg

Eye (rabbit): 100 mg

Inhalation (rat) LC50: 5950 mg/m3

Skin (rabbit): 500 mg - moderate

N,N-diethyl-m-toluamide Oral (rat) LD50: 1950 mg/kg Not Available

Not Available

TOXICITY

IRRITATION

Not Available

Not Available

water

* Value obtained from manufacturer's msds unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances

N,N-DIETHYL-M-TOLUAMIDE

RID Medicated Lotion Repellent Plus Antiseptic, WATER

For N,N-diethyl-m-toluamide (Deet) Acute toxicity: Different preparations of Deet with different proportions of the m-isomer produced different oral LD50s. Rats killed by dosages in the LD50 range showed lacrimation, chromodacryorrhea, depression, prostration, tremors, and asphyxial convulsions. Reproductive effector in rats

No significant acute toxicological data identified in literature search.

Acute Toxicity

Not Applicable

Carcinogenicity

Not Applicable Reproductive Toxicity Category 2

Skin Irritation/Corrosion

Not Applicable

Reproductivity

Serious Eye Damage/Irritation

Not Applicable

STOT - Single Exposure

Not Applicable

Respiratory or Skin sensitisation

Not Applicable

STOT - Repeated Exposure

Not Applicable

Mutagenicity

Not Applicable

Aspiration Hazard

Not Applicable

CMR STATUS

SECTION 12 ECOLOGICAL INFORMATION Toxicity

For N,N-diethyl-m-toluamide (Deet): log Kow : 1.3-3.31 Octanol-Water Partition Coefficient (log Kow): 2.02 Henry's constant: 2.1 x 10-8 atm·m3/mol Persistence and degradability Ingredient

Persistence: Water/Soil

Persistence: Air

Not Available

Not Available

Not Available

Bioaccumulative potential Ingredient

Bioaccumulation

Not Available

Not Available

Mobility in soil Ingredient

Mobility

Not Available

Not Available

SECTION 13 DISPOSAL CONSIDERATIONS Waste treatment methods Continued...

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Product / Packaging disposal

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Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. A Hierarchy of Controls seems to be common - the user should investigate:

SECTION 14 TRANSPORT INFORMATION Labels Required Marine Pollutant HAZCHEM

NO Not Applicable

Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

SECTION 15 REGULATORY INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture

N,N-diethyl-m-toluamide(134-62-3) is found on the following regulatory lists

water(7732-18-5) is found on the following regulatory lists

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","Sigma-AldrichTransport Information","Australia National Pollutant Inventory","Australia Australian Pesticides and Veterinary Medicines Authority (APVM) Record of approved active constituents","Australia Hazardous Substances Information System - Consolidated Lists" "OSPAR National List of Candidates for Substitution – Norway","OECD List of High Production Volume (HPV) Chemicals","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport Information","Australia High Volume Industrial Chemical List (HVICL)"

SECTION 16 OTHER INFORMATION Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

end of SDS