SAFETY DATA SHEET

Revision Date 10-Feb-2016

Version 3

1. IDENTIFICATION Product identifier Product Name

ANAEROBIC GASKET MAKER 50 ML

Other means of identification Product Code Synonyms

51813 None

Recommended use of the chemical and restrictions on use Sealant Recommended Use No information available Uses advised against Details of the supplier of the safety data sheet Manufacturer Address Distributor ITW Permatex ITW Permatex Canada 6875 Parkland Blvd. 35 Brownridge Road, Unit 1 Solon, OH 44139 USA Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 1-87-Permatex Company Phone Number (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address

[email protected]

2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) NOTE: This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commission regulations which take precedence over OSHA Hazard Communication labeling. The actual container label will not include the label elements below. The labeling below applies to industrial/professional products. Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Specific target organ toxicity (repeated exposure)

Category 2 Category 2 Category 1 Category 2

Label elements Emergency Overview Warning Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction May cause damage to organs through prolonged or repeated exposure

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51813 - ANAEROBIC GASKET MAKER 50 ML Revision Date 10-Feb-2016 _____________________________________________________________________________________________

Appearance Red

Physical state Gel

Odor Mild

Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Contaminated work clothing should not be allowed out of the workplace Do not breathe dust/fume/gas/mist/vapors/spray Precautionary Statements - Response Get medical advice/attention if you feel unwell Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Very toxic to aquatic life with long lasting effects Unknown acute toxicity

59.557 % of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret POLYURETHANE METHACRYLATE RESIN _ 30 - 60 * (MIXTURE) 2-HYDROXYETHYL METHACRYLATE 868-77-9 1-5 * DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 1-5 * *The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES Description of first aid measures General advice

Get medical advice/attention if you feel unwell.

Eye contact

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical

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51813 - ANAEROBIC GASKET MAKER 50 ML Revision Date 10-Feb-2016 _____________________________________________________________________________________________ advice/attention. Skin contact

IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Inhalation

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician.

Ingestion

IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician.

Self-protection of the first aider

Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.

Most important symptoms and effects, both acute and delayed Symptoms

See section 2 for more information.

Indication of any immediate medical attention and special treatment needed Note to physicians

Treat symptomatically.

5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge

None. None.

Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions

Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required.

Environmental precautions Environmental precautions

Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information.

Methods and material for containment and cleaning up Methods for containment

Prevent further leakage or spillage if safe to do so.

Methods for cleaning up

Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal.

Prevention of secondary hazards

Clean contaminated objects and areas thoroughly observing environmental regulations.

7. HANDLING AND STORAGE _____________________________________________________________________________________________ Page 3 / 8

51813 - ANAEROBIC GASKET MAKER 50 ML Revision Date 10-Feb-2016 _____________________________________________________________________________________________ Precautions for safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required.

Advice on safe handling

Conditions for safe storage, including any incompatibilities Storage Conditions

Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible materials

Strong oxidizing agents, Amines

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters . Exposure Guidelines NIOSH IDLH Immediately Dangerous to Life or Health Other Information

Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).

Appropriate engineering controls Engineering Controls

Showers Eyewash stations Ventilation systems

Individual protection measures, such as personal protective equipment Eye/face protection

Wear safety glasses with side shields (or goggles).

Skin and body protection

Wearpr ot ect i v enat ur alr ubber ,ni t r i l er ubber ,Neopr ene™ orPVCgl ov es.

Respiratory protection

Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate.

General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Appearance Odor Odor threshold

Gel Red Mild No information available

Property pH Melting point / freezing point Boiling point / boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limit in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density

Values No information available No information available > 149 °C / >300 °F > 93 °C / > 200 °F No information available No information available No information available No information available 1

Remar ks •Met hod

Tag Closed Cup

Air = 1

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51813 - ANAEROBIC GASKET MAKER 50 ML Revision Date 10-Feb-2016 _____________________________________________________________________________________________ Relative density Water solubility Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Oxidizing properties

1.08-1.18 No information available No information available No information available No information available No information available No information available No information available No information available No information available

Other Information Softening point Molecular weight VOC Content (%) Density Bulk density

No information available No information available 3000 mg/kg ( Rabbit )

Inhalation LC50 -

= 382 mg/kg ( Rat )

= 0.126 mL/kg ( Rabbit )

= 220 ppm ( Rat ) 4 h

Information on toxicological effects Symptoms

No information available.

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51813 - ANAEROBIC GASKET MAKER 50 ML Revision Date 10-Feb-2016 _____________________________________________________________________________________________ Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Germ cell mutagenicity Carcinogenicity

No information available. No information available. The table below indicates whether each agency has listed any ingredient as a carcinogen.

IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen

The following values are calculated based on chapter 3.1 of the GHS document . 4755 mg/kg ATEmix (oral) 9775 mg/kg ATEmix (dermal) ATEmix (inhalation-dust/mist) 7 mg/l

12. ECOLOGICAL INFORMATION Ecotoxicity 59.764 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name 2-HYDROXYETHYL METHACRYLATE 868-77-9

Algae/aquatic plants -

DIMETHYLBENZYL HYDROPEROXIDE 80-15-9

-

Fish Crustacea 213 - 242: 96 h Pimephales promelas mg/L LC50 flow-through 227: 96 h Pimephales promelas mg/L LC50 3.9: 96 h Oncorhynchus mykiss 7: 24 h Daphnia magna mg/L EC50 mg/L LC50 static

Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name 2-HYDROXYETHYL METHACRYLATE 868-77-9

Partition coefficient 0.47

Other adverse effects No information available

13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated packaging

Do not reuse container.

US EPA Waste Number

Not applicable

Chemical Name DIMETHYLBENZYL HYDROPEROXIDE 80-15-9

RCRA -

RCRA - Basis for Listing -

RCRA - D Series Wastes -

RCRA - U Series Wastes U096

This product contains one or more substances that are listed with the State of California as a hazardous waste.

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51813 - ANAEROBIC GASKET MAKER 50 ML Revision Date 10-Feb-2016 _____________________________________________________________________________________________ Chemical Name DIMETHYLBENZYL HYDROPEROXIDE 80-15-9

California Hazardous Waste Status Toxic Ignitable

14. TRANSPORT INFORMATION DOT Proper shipping name:

Not regulated

IATA Proper shipping name:

Not regulated

IMDG Proper shipping name:

Not regulated

15. REGULATORY INFORMATION International Inventories TSCA DSL/NDSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS

Complies Complies Not Listed. Complies Complies Complies Complies Complies

Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name DIMETHYLBENZYL HYDROPEROXIDE - 80-15-9

SARA 313 - Threshold Values % 1.0

SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard

Yes No No No No

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name DIMETHYLBENZYL

Hazardous Substances RQs 10 lb

CERCLA/SARA RQ -

Reportable Quantity (RQ) RQ 10 lb final RQ

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51813 - ANAEROBIC GASKET MAKER 50 ML Revision Date 10-Feb-2016 _____________________________________________________________________________________________ RQ 4.54 kg final RQ

HYDROPEROXIDE 80-15-9

US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations

Chemical Name DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 ACRYLIC ACID 79-10-7 1,4-NAPHTHOQUINONE 130-15-4

New Jersey X

Massachusetts X

Pennsylvania X

X

X

X

X

X

X

U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class D2B - Toxic materials

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA HMIS

Health hazards 2 Health hazards 2

Flammability 1 Flammability 1

Instability 0 Physical hazards 0

Personal protection B

NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System)

Revision Date

10-Feb-2016

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet

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