RESPIRATORY PROTECTION PROGRAM University of Wisconsin – Stout Reviewed July 21, 2010

PURPOSE The purpose of this respiratory protection program (RPP) is to insure that all UW-Stout employees, therein referred to as users, are protected from respiratory hazards which cannot be feasibly controlled by engineering controls. The objective of the RPP is to comply with OSHA 1910.134 by fully implementing the respiratory protection standard. The RPP applies to all users who are required to wear respiratory protection regardless of the type of equipment used. SCOPE This program applies to all employees who are required to wear respirators during normal work operations and during non-routine or emergency operations. This includes designated employees in the following departments:      

Safety and Risk Management (SRM) – For collection of bulk samples, waste handling and emergency response incidents. Physical Plant Employees – For collection of bulk samples, asbestos removal and work in other hazardous environments. Student Health Center – For potential exposure to tuberculosis and other infectious agents. Power Plant Workers – For cleaning of combustion vessels. Animal Care Workers – For potential exposure to allergens. Steam Fitters – For welding work in steam pits.

RESPONSIBILITIES The Director of Safety & Risk Management Services will serve as the program administrator for the RPP and is responsible for the application, oversight and annual review. The duties of the program administrator shall include:    

Assist in the coordination and scheduling personnel for training, medical evaluations, fit testing and conduct exposure monitoring. Select all respiratory protection equipment and supplies. Maintain records of exposure monitoring, user training and medical clearance records. Perform annual review of the RPP to evaluate its effectiveness.

Supervisors shall be responsible for identifying potential respirator users to the program administrator and shall ensure that all users comply with this RPP.

Individual users shall successfully complete training prior to being issued a respirator, shall maintain all respiratory equipment in proper repair, and shall notify their supervisor of any defects or needed repair of their issued respiratory protection equipment. RESPIRATOR SELECTION Respirator selection will be made by the program administrator after conducting an exposure assessment and will be documented on the Respiratory Protection Hazard Assessment, Selection and Assignment Form which will be maintained in Appendix A. Only NIOSH certified respiratory equipment will be selected and used at UW-Stout. The Respirator Selection Chart in Appendix B can be used by supervisors to help assess areas or tasks that may require the use of respirators and warrant additional attention and evaluation. Under 1910.1001(g)(2)(ii), employers must provide an employee with a tightfitting, PAPR instead of a negative pressure respirator when the employee chooses to use a PAPR and it provides adequate protection to the employee. Individual user selection will also be considered based on work activities face piece designs, maintenance, and overall costs. Users may request a respirator which provides greater protection than that specified by the program administrator. VOLUNTARY USE The voluntary use of filtering facepiece respirators (dust mask, N-95) by employees and students whose exposures are below the PEL’s for personal comfort is allowed. Since elastometric face piece respirators place stress on the users cardiovascular system, they shall not be worn in work environments where exposure assessment as determined that respiratory protection is not required. Information for voluntary use of respirators can be found in Appendix C. MEDICAL EVALUATION The program administrator will provide the physician with any information regarding the user's working environment, protective equipment, exposure data, pertinent regulatory information, and other requested information using the RPP Respiratory Use Requirements form which will be retained in Appendix D. Each prospective respirator user shall receive a medical evaluation using either the medical questionnaire in Appendix E or an initial medical evaluation by the Occupational Medicine Department in the Red Cedar Medical Center to determine the employee’s ability to safely use a respirator prior to fit testing and use of the respirator. The physician may request additional tests or evaluations at his or her discretion.

Additional medical evaluation is required for respirator use covered under the substance-specific standards as part of a comprehensive medical surveillance

program. The additional medical questionnaire and information for the physician requirements for workers who must use a respirator to reduce asbestos exposures can be found in Appendix F. All respirator users will obtain a completed RPP Respirator Medical Recommendation which will be retained in Appendix G prior to being fit tested for a respirator. FIT TESTING Fit testing shall be performed prior to issuance and annually thereafter and will be retained on the Respirator Fit Test Record in appendix H. Qualitative fit testing will be performed by the Occupational Medicine Department in the Red Cedar Medical Center. Any required personal protective equipment that may affect the fit of the respirator shall be worn during testing. The positive and negative User Fit Checks (detailed in Appendix I for reference) shall be performed each time a respirator is worn. RESPIRATOR USE Respirators selected by the program administrator shall be issued for use by the User’s supervisor. Each user shall meet the following criteria prior to being issued an authorized to use a respirator:   

Successful completion of respiratory protection training. Complete all medical evaluation requirements. Pass all fit test requirements.

Upon issuance, the user must complete the Respirator Inspection Record in Appendix J for each respirator received. Cartridge service life will be determined by one of the recognized methods in Appendix K and will be monitored by the user’s supervisor. All respirators shall be cleaned and disinfected upon issuance, in daily use, monthly or if exchange between individuals becomes necessary. Cleaning and disinfecting shall be conducted in accordance with the Respirator Cleaning Procedures in Appendix L or by following the manufacturers recommendations. Respirators shall be stored in a convenient, clean and sanitary location. Users shall report any damage or malfunction discovered during inspection or while in use to a supervisor or the program administrator. Respirators with tight fitting face-pieces will not be permitted to be worn when any condition interferes with the face-to-facepiece seal. In areas considered to be immediately dangerous to life or health (IDLH), only supplied air respirators or Self-Contained Breathing Apparatus (SCBA) will be used. In addition, a second individual suitably equipped with the necessary PPE and rescue equipment must maintain visual or voice communication and be trained and capable of providing assistance. This respiratory equipment will be inspected after each use and monthly by the user and only Grade D air will be used.

Respirator Use Determination Process 1

Supervisor Role Inform SRM about areas or tasks where respirators use may be required.

2

Conduct a hazard assessment to determine worker exposure and respirator requirements. Complete the Respiratory Use form and send to the Occupational Medicine Department in the Red Cedar Medical Center (RCMC). Inform the supervisor of the prospective users respiratory protection requirements and selects the appropriate respirator type.

3

4

5 6

Help user select respirator model. Directs supervisor to contact RCMC for an appointment for medical questionnaire, fit test and/or additional medical surveillance. Receives medical authorization for respirator use from RCMC. Conduct initial respiratory protection training. Document issuance of respirator.

7 8 9 10

11

Safety and Risk Management (SRM)

Send user to RCMC for annual fit test and additional medical surveillance. Conduct annual respiratory protection training.

TRAINING All training will be conducted in accordance with ANSI Z88.2 and OSHA 1910.134 and will include the proper fit testing, use, limitations and care of respirators in addition to a review of the RPP and OSHA 1910.134. A detailed training outline can be found in Appendix M. RPP EVALUATION The program administrator shall, on an annual basis, evaluate the RPP using the checklist in appendix N to assess its effectiveness and to insure the safety of UW-Stout employees. The results of periodic inspections of respirator use, consultations with wearers, measurements of hazard levels in work areas, and medical surveillance of wearers will also be reviewed in the assessment process. Any evidence of excessive exposure to workplace hazards will be immediately addressed to determine why inadequate protection was provided, and action shall be taken to remedy the problem. Based on the evaluation, the program administrator will make changes to insure the continued effectiveness of the RPP.

Respiratory Protection Program Appendix

Respiratory Protection Hazard Assessment and Assignment

Appendix A

Respirator Selection Chart

Appendix B

Voluntary Use of Respirators

Appendix C

RPP Respiratory Use Requirements

Appendix D

RPP Medical Questionnaire

Appendix E

OSHA Asbestos Exposure Medical Surveillance

Appendix F

RPP Respirator Medical Recommendation

Appendix G

Respirator Fit Testing Procedures & records

Appendix H

Respirator User Seal Check Procedure

Appendix I

Respirator Inspection Checklist

Appendix J

Respirator Service Life (Wood Math Model)

Appendix K

Respirator Cleaning Procedures

Appendix L

Respiratory Protection Program Training

Appendix M

Respiratory Protection Program Evaluation

Appendix N

List of Current Respirator Users

Appendix O

Respirator Program Review Dates

Appendix P

Appendix A

Respiratory Protection Hazard Assessment, Selection and Assignment Form User Name:_______________________Department: ________________________ Worksite: ___________________________________________________________ General Description of Job Task: ________________________________________ ___________________________________________________________________ Job Classification(s) ___________________________________________________ Level of physical exertion required to perform job: ___________________________ ___________________________________________________________________ Respiratory hazard(s) present: __________________________________________ ___________________________________________________________________ ___________________________________________________________________ OSHA PEL/STEL:___________________ ACGIH TLV: ___________________ Is monitoring data available? _______Yes ________No If yes, attach to this form. Contaminant concentrations present in the workplace: Contaminant(s): ____________________________________ Concentration: _____ Contaminant(s): ____________________________________ Concentration: _____ Contaminant(s): ____________________________________ Concentration: _____ Does data indicate levels that exceed applicable limits? ______Yes

______No

Does data indicate IDLH concentrations? ______Yes ______ No Note: Wherever hazardous exposure(s) cannot be identified or reasonably quantified, the atmosphere must be considered IDLH.

Does data indicate oxygen deficiency (less than 19.5%)? ______Yes ______No Is the respirator for routine use or emergency use? __________________________ Additional factors (i.e. temperature and humidity levels, etc.): __________________ ___________________________________________________________________ Communication requirements: ___________________________________________ ___________________________________________________________________ Are engineering/ administrative controls feasible? _______ Yes _______No If no, describe reasons: ________________________________________________ ___________________________________________________________________ Protection Factor required:________

Fit test protocol:____________________

Type of respirator selected: ______ air purifying _______ atmosphere supplying Style of respirator selected: ______ tight-fitting __________ loose-fitting N-95______ Half Face ______ Full Face______ PAPR______ SCBA_______ Make:____________________________ Model:_________________________

Cartridge/canister type to be used: _______________________________________ Cartridge/canister change-out schedule: ___________________________________ ___________________________________________________________________ Notes: _____________________________________________________________ ___________________________________________________________________ ___________________________________________________________________

Respirator Approval Number:___________________________________ Name of Evaluator ___________________________________Date:__________ Title: ___________________________________Work Phone: ______________

Appendix B

Respirator Selection Chart Title Heating Plant Operator Medical Staff (nurses)

Maintenance Mechanic Building and Grounds Superintendants Steamfitter

Steamfitter Steamfitter

Process or Job Boiler cleaning heating plant Medical Workers with infectious disease in Student Health Care Center Pool chemicals

Potential Respirator/Filter Type Supplied air respirator

Comments

N95 respirators

OSHA Class I, II or III asbestos work

Half face respirator with organic vapor cartridge Half face respirator with HEPA cartridge

Indoor welding and cutting

PAPR with welding cover lenses and HEPA cartridges

Welding Steam pit entry

N95, half face, full face Half face respirator with HEPA cartridge if tests show asbestos or fiberglass dust is likely

Full face respirator or PAPR also acceptable Eye protection against welding flash burns must be provided Follow confined space entry procedures

Appendix C

Voluntary Use of Respirators

Appendix D to Sec. 1910.134 (Mandatory) Information for Employees Using Respirators When Not Required Under the Standard

Respirators are an effective method of protection against designated hazards when properly selected and worn. Respirator use is encouraged, even when exposures are below the exposure limit, to provide an additional level of comfort and protection for workers. However, if a respirator is used improperly or not kept clean, the respirator itself can become a hazard to the worker. Sometimes, workers may wear respirators to avoid exposures to hazards, even if the amount of hazardous substance does not exceed the limits set by OSHA standards. If your employer provides respirators for your voluntary use, or if you provide your own respirator, you need to take certain precautions to be sure that the respirator itself does not present a hazard. You should do the following: 1. Read and heed all instructions provided by the manufacturer on use, maintenance, cleaning and care, and warnings regarding the respirators limitations. 2. Choose respirators certified for use to protect against the contaminant of concern. NIOSH, the National Institute for Occupational Safety and Health of the U.S. Department of Health and Human Services, certifies respirators. A label or statement of certification should appear on the respirator or respirator packaging. It will tell you what the respirator is designed for and how much it will protect you. 3. Do not wear your respirator into atmospheres containing contaminants for which your respirator is not designed to protect against. For example, a respirator designed to filter dust particles will not protect you against gases, vapors, or very small solid particles of fumes or smoke. 4. Keep track of your respirator so that you do not mistakenly use someone else's respirator.

[63 FR 1152, Jan. 8, 1998; 63 FR 20098, April 23, 1998]

Appendix D

RPP Respiratory Use requirements

Appendix E

RPP Medical Questionnaire

Appendix F

OSHA Asbestos Exposure Medical Surveillance Federal Register, 29 CFR 1910.1001 Appendix D. This mandatory appendix contains the medical questionnaires that must be administered to all employees who are exposed to asbestos, tremolite, anthophyllite, actinolite, or a combination of these minerals above the action level, and who will therefore be included in their employer's medical surveillance program. Part 1 of the appendix contains the Initial Medical Questionnaire, which must be obtained for all new hires who will be covered by the medical surveillance requirements. Part 2 includes the abbreviated Periodical Medical Questionnaire, which must be administered to all employees who are provided periodic medical examinations under the medical surveillance provisions of the standard.

INFORMATION PROVIDED TO THE PHYSICIAN

Federal Register, 1910.1001(1)(6) (6)

Information provided to the physician. The employer shall provide the following information to the examining physician:

(i)

A copy of this standard and Appendices D and E.

(ii)

A description of the affected employee's duties as they relate to the employee's exposure.

(iii)

The employee's representative exposure level or anticipated exposure level.

(iv)

A description of any personal protective and respiratory equipment used or to be used.

(v)

Information from previous medical examinations of the affected employee that is not otherwise available to the examining physician.

INFORMATION FOR THE PHYSICIAN The OSHA General Industry Standard require the following: FEDERAL REGISTER 29CFR 1910.1001(I)(2)(ii) – (ii)

Such examination shall include, as a minimum, a medical and work history: A complete physical examination of all systems with emphasis on the respiratory system, the cardiovascular system and digestive tract; completion of the respiratory disease standardized questionnaire in Appendix E, Part 1; a chest roentgenogram (posterior-anterior 14 x 17 inches); pulmonary function tests to include forced vital capacity (FVC) and forced expiratory volume at 1 second (FEV1.0); and any additional tests deemed appropriate by the examining physician. Interpretation and classification of chest roentgenograms shall be conducted in accordance with Appendix E.

(3)

Periodic examinations. (i) Periodic medical examinations shall be made available annually.

(ii)

The scope of the medical examination shall be in conformance with the protocol established in paragraph (1) (2) (ii), except that the frequency of chest roentgenograms shall be conducted in accordance with Table 2, and the abbreviated standardized questionnaire contained in Appendix D, Part 2, shall be administered to the employee. Table 2 - Frequency of Chest Roentgenograms

Age of Employee Years since first exposure

15 to 35

35+ to 45

45+

0 to 10

Every 5 years

Every 5 years

Every 5 years

10+

Every 5 years

Every 2 years

Every 1 year

Appendix D. - Medical Questionnaire is attached. Appendix E to ss1926.58 -Interpretation and Classification of Chest Roentgenograms --Mandatory (a)

Chest roentgenograms shall be interpreted and classified in accordance with a professionally accepted classification system and recorded on a Roentgenographic Interpretation Form. *Form CSD/NIOSH(M)2.8.

(b)

Roentgenograms shall be interpreted and classified only by a Breader, a board eligible/certified radiologist, or an experienced physician with known expertise in pneumoconioses.

(c)

All interpreters, whenever interpreting chest roentgenograms made under this section, shall have immediately available for reference a complete set of the ILO-U/C International Classification of Radiographs for Pneumoconioses, 1980.

MEDICAL SURVEILLANCE

Federal Register, 29CFR 1910.1001(m)(3) (3)

Medical surveillance. (i) The employer shall establish and maintain an accurate record for each employee subject to medical surveillance by paragraph (1)(1)(i) of this section, in accordance with 29 CFR 1910.20.

(ii)

The record shall include at least the following information:

(A)

The name and social security number of the employee;

(B)

Physician's written opinions;

(C)

Any employee medical complaints related to exposure to asbestos, tremolite, anthophyllite, or actinolite; and

(D)

A copy of the information provided to the physician as required by paragraph (1)(6) of this section.

(iii)

The employer shall ensure that this record is maintained for the duration of employment plus thirty (30 years, in accordance with 29 CFR 1910.20.

NOTE: Medical Examinations are required yearly.

Appendix G

RPP Respirato or Mediical Reccommen ndation

Appendix H

RESPIRATOR FIT TESTING

Name:

Date:

Name of Test conductor:

Respirator Selected: Manufacturer: Model: Respirator Approval Number: Cartridge approval Number:

A qualitative fit test was performed following all testing procedures found under Appendix C to 29CFR 1910.134 App A. The test subject has successfully completed the fit testing with the respirator listed above. The test subject has failed the fit testing with the respirator listed above.*

*NOTE: The test subject should try fit testing with another make, model or size respirator.

Test Subject Signature

Test Conductor Signature

Appendix I

User Seal Check Procedures

Negative Pressure Check The wearer can perform this test by themselves in the field. The wearer should use this test just before entering any toxic atmosphere. It consists merely of closing off the inlet of the canister, cartridge(s), or filters(s) by covering with the palm(s) or replacing the seal(s), or of squeezing the breathing tube so that it does not pass air; inhaling gently so that the face piece collapses slightly; and holding the breath for ten seconds. If the face piece remains slightly collapsed and no inward leakage is detected, the respirator is probably tight enough. This test, of course, can be used only on respirators with tight fitting face pieces.

Positive Pressure Check This test is like the negative pressure test, and has the same advantages and limitations. It is conducted by closing off the exhalation valve and exhaling gently into the face piece. The fit is considered satisfactory if slight positive pressure can be built up inside the face piece without any evidence of outward leakage. For some respirators, this method requires that the wearer remove the exhalation valve cover and then carefully replace it after the test, often a difficult task. Removing and replacing the exhalation valve cover often disturbs the respirator fit; more so than the negative pressure test. Therefore, this test should be used sparingly if it requires removing and replacing a valve cover. The test is easy for respirators whose valve cover has a single small port that can be closed by the palm or a finger. The wearer should perform this test just before entering any hazardous atmosphere.

Appendix J-1

Respirator Inspection Checklist

Respirator Issued to: Hazard:

Type:

Make:

Model:

Face piece

_________ Cracks, tears, or holes _________ Face mask distortion _________ Cracked or loose lenses/face shield

Head straps

_________ Breaks or tears _________ Broken buckles

Valves:

_________ Residue or dirt _________ Cracks or tears in valve material

Filters/Cartridges:

_________ Approval designation _________ Gaskets _________ Cracks or dents in housing _________ Proper cartridge for hazard

Air Supply Systems

_________ Breathing air quality/grade _________ Condition of supply hoses _________ Hose connections _________ Regulator settings and valves

Rubber/Elastomer Parts

_________ Pliability _________ Deterioration

Inspected by: Action Taken:

Date:

Appendix J-2

SCBA Inspection Checklist SCBA Identification Number: 1. Is the Face piece in good condition? Excessive dirt Cracks, tears, holes or distortions from storage Inflexibility Cracked or badly scratched lenses in full face pieces Incorrectly mounted full face piece lens or broken or missing mounting clips 2. Are headstraps or head harness in good condition? Breaks in the straps Loss of elasticity Broken or malfunctioning buckles and attachments Excessively worn serrations on the head harness which might permit slippage 3. Is the exhalation valve in good condition? Foreign material under the valve seat Cracks, tears or distortion in the valve material Improper insertion of the valve body in the face piece Cracks, breaks or chips in the valve body, particularly in the sealing surface Missing or defective valve cover Improper installation of the valve in the valve body 4. Is the breathing tube in good condition Damaged, worn or missing end connectors Missing or loose hose clamps Deterioration or the hose material 5. Is the high pressure air supply in good condition? Supply lines, hoses, attachments and end fittings worn Valves and air flow regulators inoperable Low pressure alarm inoperable Air cylinder less than full Gauges inoperable Air cylinder damaged Air cylinder hydrostatic test out of date 6. Is the cylinder harness in good condition? Straps or frame showing wear or damage Broken or malfunctioning buckles and attachments Air cylinder attachment devices inoperable

Inspected by:

Yes/No

Comments

Date:

Ap ppendix K

Respiratorr Service Life - The Wo ood Ma ath Model Table e The tablle below pro ovides brea akthrough times for 12 20 chemicals at variou us concentrations. OS SHA used the t following standard conditionss to derive these breakthrrough times s: Respirator cartridges: 2

emperature e: 72o Fahre enheit (22o C) Te

Sorbentt: Activated charcoal

Re elative hum midity: < 50% %

Sorbentt mass per cartridge: 26 2 g

Brreakthrough h: 10%

Flow ratte: 53.3 liters per minu ute If the conditions in your case are a significa antly differe ent from the ese, in particular relative humidity y’s greater than t 65%, you y will nee ed to make the approp priate corre ections to th he time give en by the ta able. Anoth her section of o this advissor provide es a discusssion of thesse factors. How to use this Ta able Look down the left column to find f the che emical and across the row to the column witth the identified conce entration, and there yo ou will find tthe service life time in minutes. Breakthro ough Timess (min) Indicates that t the serrvice life forr this contam minant is lim mited to a ssingle worksshift by the OSHA Standard. Name

CAS #

Conta minant Con ncentration (ppm) 50

100

2 200

500

1000 0

Aromatiics Benzene

71-43-2

Limited to o a maximu um concentra ation of 50 p ppm for negative p pressure A APR See th he Benzene e Standard 1910.1 1028(g)

Toluene e

108-88-3

1018

562

3 307

135

72

Ethylbenzene

100-41-4

1133

604

3 319

135

70

m-Xylen ne

108-38-3

1143

608

3 321

136

70

Cumene e

98-82-8

1122

586

3 304

126

64

Mesityle ene

108-67-8

1159

603

3 311

128

65

p-Cyme ene

99-87-6

1104

566

2 289

117

59

Alcohols s Methanol

67-56-1

This ca alculation iss not appliccable to thiss compo ound

Ethanol

64-17-5

123

105

85

60

43

Isopropanol

67-63-0

425

286

186

101

61

Allyl alcohol

107-18-6

789

495

303

152

87

Propanol

71-23-8

551

364

233

123

73

sec-Butanol

78-92-2

773

464

272

130

72

Butanol

71-36-3

1073

615

345

156

84

2-Pentanol

6032-29-7

1091

601

327

143

75

3-Methyl-1-butanol

123-41-3

1242

672

358

152

78

4-Methyl-2-pentanol

108-11-2

1076

578

307

130

67

Pentanol

71-41-0

1281

690

366

155

79

2-Ethyl-1-butanol

97-95-0

1246

657

342

142

72

Monochlorides Methyl chloride

74-87-3

Vinyl chloride

75-01-4

Not applicable, boiling point below ambient temperatures Not applicable, boiling point below ambient temperatures See the Vinyl Chloride Standard 1910.1017(g) Not applicable, boiling point below ambient temperatures

Ethyl chloride

75-00-3

2-Chloropropane

75-29-6

224

150

99

54

34

Allyl chloride

107-05-1

264

177

116

64

40

1-Chloropropane

540-54-5

492

301

181

90

52

2-Chloro-2-methylpropane

507-20-0

655

374

212

98

54

1-Chlorobutane

109-69-3

733

422

239

111

61

2-Chloro-2-methylbutane

594-36-5

705

398

222

101

55

1-Chloropentane

543-59-9

852

474

260

116

62

Chlorocyclopentane

930-28-9

Chlorobenzene

108-90-7

1327

709

376

160

83

1-Chlorohexane

544-10-5

993

530

281

119

62

o-Chlorotoluene

95-49-8

1297

682

356

148

76

1-Chloroheptane

629-06-1

930

492

258

109

56

3-(Chloromethyl) heptane

123-04-6

771

410

216

92

48

Dichlorides See the Methylene Chloride Standard 1910.1052(g)

Dichloromethane

75-09-2

trans-1,2-Dichloroethylene

156-60-5

296

198

129

71

44

1,1-Dichloroethane

75-35-4

234

157

103

57

35

cis-1,2-Dichloroethylene

156-59-2

356

236

152

82

50

1,2-Dichloroethane

107-06-2

482

310

194

101

60

1,2-Dichloropropane

78-87-5

776

452

259

121

67

cis-1,2-Dichloropropene

6923-20-2

trans-1,2-Dichloropropene

7069-38-7

1,4-Dichlorobutane

110-56-5

846

475

263

118

64

o-Dichlorobenzene

95-50-1

Trichlorides Chloroform

67-66-3

409

263

166

87

52

Methyl chloroform

71-55-6

618

366

214

102

57

Trichloroethylene

79-01-6

749

441

256

122

68

1,1,2-Trichloroethane

79-00-5

976

558

314

143

77

1,2,3-Trichloropropane

96-18-4

Tetrachlorides Carbon tetrachloride

56-23-5

677

398

231

109

61

Perchloroethylene

127-18-4

1106

609

331

145

77

1,1,2,2-Tetrachloroethane

79-34-5

Pentachlorides Pentachloroethane

76-01-7

Acetates Methyl acetate

79-20-9

182

131

92

55

36

Vinyl acetate

108-05-4

389

251

158

82

49

Ethyl acetate

141-78-6

483

299

182

91

53

Isopropyl acetate

108-21-4

668

386

219

102

56

Isopropenyl acetate

108-22-5

Propyl acetate

109-60-4

768

438

246

112

61

Allyl acetate

591-87-7

sec-Butyl acetate

105-46-4

Butyl acetate

123-86-4

935

508

273

118

62

Isopentyl acetate

123-92-2

1007

530

277

116

59

1,3-Dimethylbutyl acetate

540-88-5

Pentyl acetate

628-63-7

1023

537

280

117

59

Hexyl acetate

142-92-7

Ketones Acetone

67-64-1

118

92

69

44

30

2-Butanone

78-93-3

423

271

170

88

52

2-Pentanone

107-87-9

729

424

243

113

62

3-Pentanone

96-22-0

744

433

248

115

63

4-Methyl-2-pentanone

108-10-1

884

488

266

117

62

Mesityl oxide

141-79-7

1063

581

314

136

71

Cyclopentanone

120-92-3

1020

589

333

153

83

2,4-Pentanedione

123-54-6

1103

612

335

147

78

3-Heptanone

106-35-4

1061

561

294

123

63

2-Heptanone

110-43-0

791

432

234

102

54

Cyclohexanone

108-94-1

1257

683

366

157

81

963

496

254

103

52

5-Methyl-3-heptanone 3-Methylcyclohexanone

625-96-7

Diisobutyl ketone

108-83-8

4-Methylcyclohexanone

589-92-4

Alkanes Pentane

109-66-0

332

205

124

63

37

2,3-Dimethylbutane

79-29-8

533

307

175

82

45

Hexane

110-54-3

585

334

189

87

48

Methylcyclopentane

96-37-7

613

357

205

96

53

Cyclohexane

110-82-7

2,2,4-Trimethylpentane

540-84-1

747

401

214

92

48

Heptane

142-82-5

769

420

227

99

52

Methylcyclohexane

108-87-2

842

463

252

111

59

1,3,5-Cycloheptatriene

544-25-2

2,2,5-Trimethylhexane

3522-94-9

817

429

224

93

48

Cyclooctane

292-64-8

747

410

224

99

53

Nonane

111-84-2

907

470

242

100

51

Decane

124-18-5

902

461

234

95

48

5-Ethylidene-2-orbornene

Amines Methylamine

74-89-5

Not applicable, boiling point below ambient temperatures

Dimethylamine

124-40-3

Not applicable, boiling point below ambient temperatures

Ethylamine

75-04-7

Not applicable, boiling point below ambient temperatures

Isopropylamine

75-31-0

167

117

80

46

30

Propylamine

107-10-8

226

155

104

59

37

Diethylamine

109-89-7

498

299

177

86

49

Butylam mine

109-73-9

580

349

2 207

100

57

Triethyla amine

121-44-8

747

412

2 225

100

53

Dipropy ylamine

142-84-7

871

474

2 255

111

58

Diisopro opylamine

108-18-9

716

395

2 216

96

51

Cyclohe exylamine

108-91-8

1065

575

3 308

132

69

Dibutyla amine

111-92-2

980

507

2 261

107

54

Miscella aneous Methyl iodide i

74-88-4

Acrylonitrile

107-13-1

This ca alculation iss not appliccable to thiss compo ound 465

Lim mited to a m maximum co oncentration n of 100 pp pm

See th he Acrylonittrile Standa ard 1910.1 1045(h) Dibromo omethane

74-95-3

947

565

3 331

158

89

Pyridine e

110-86-1

1031

599

3 342

158

87

Epichlorohydrin

106-89-8

866

525

3 310

150

84

2-Metho oxyethanol

109-86-4

1,2-Dibrromoethane e

106-93-4

1252

699

3 384

170

90

1-Nitrop propane

108-03-2

933

548

3 315

147

80

2-Ethox xyethanol

110-80-5

1105

624

3 345

154

81

Acetic anhydride a

108-24-7

1095

623

3 348

156

83

2-Metho oxyethyl acetate

32718-56 6-2

1092

594

3 319

137

71

Bromob benzene

108-86-1

1448

761

3 397

165

84

2-Ethox xyethyl acettate

111-15-9

1143

600

3 312

129

65

Appendix L

Respirator Cleaning Procedures: Appendix B-2 to § 1910.134 These procedures are provided for employer use when cleaning respirators. They are general in nature, and the employer as an alternative may use the cleaning recommendations provided by the manufacturer of the respirators used by their employees, provided such procedures are as effective as those listed here in Appendix B- 2. Equivalent effectiveness simply means that the procedures used must accomplish the objectives set forth in Appendix B-2, i.e., must ensure that the respirator is properly cleaned and disinfected in a manner that prevents damage to the respirator and does not cause harm to the user. Procedures for Cleaning Respirators A. Remove filters, cartridges, or canisters. Disassemble facepieces by removing speaking diaphragms, demand and pressure- demand valve assemblies, hoses, or any components recommended by the manufacturer. Discard or repair any defective parts. B. Wash components in warm (43 deg. C [110 deg. F] maximum) water with a mild detergent or with a cleaner recommended by the manufacturer. A stiff bristle (not wire) brush may be used to facilitate the removal of dirt. C. Rinse components thoroughly in clean, warm (43 deg. C [110 deg. F] maximum), preferably running water. Drain. D. When the cleaner used does not contain a disinfecting agent, respirator components should be immersed for two minutes in one of the following: 1. Hypochlorite solution (50 ppm of chlorine) made by adding approximately one milliliter of laundry bleach to one liter of water at 43 deg. C (110 deg. F); or, 2. Aqueous solution of iodine (50 ppm iodine) made by adding approximately 0.8 milliliters of tincture of iodine (6-8 grams ammonium and/or potassium iodide/100 cc of 45% alcohol) to one liter of water at 43 deg. C (110 deg. F); or, 3. Other commercially available cleansers of equivalent disinfectant quality when used as directed, if their use is recommended or approved by the respirator manufacturer. E. Rinse components thoroughly in clean, warm (43 deg. C [110 deg. F] maximum), preferably running water. Drain. The importance of thorough rinsing cannot be overemphasized. Detergents or disinfectants that dry on facepieces may result in dermatitis. In addition, some disinfectants may cause deterioration of rubber or corrosion of metal parts if not completely removed. F. Components should be hand-dried with a clean lint-free cloth or air-dried. G. Reassemble facepiece, replacing filters, cartridges, and canisters where necessary. H. Test the respirator to ensure that all components work properly. [63 FR 1152, Jan. 8, 1998]

Appendix M

Respiratory Protection Program Training Supervisors shall receive annual training provided by the Safety & Risk Management Department which will include, but not be limited to the following:     

User training and instruction Basic respiratory protection policies. Selection and use of respirators to protect each user against every respiratory hazard to which the user may be exposed. The structure and operation of the entire respirator program. The legal requirements pertinent to respirator use in their respective situations.

The training objective is to ensure that each supervisor understands the responsibility in facilitating all aspects of this RPP including:     

Maintenance that each user may be expected to perform Issuance of respirators Control of their use Designated or assigned storage areas and the requirements of the area Communication of feedback to the program administrator regarding the effectiveness of the respiratory protection program.

User’s shall receive in-house training provided by the Safety & Risk Management Department, the supervisor, or out-of-house training approved by the program administrator. The extent and frequency of user training will depend upon the nature and extent of the hazard. As a minimum, each user will receive respiratory protection training prior to issuance and annually thereafter. User training shall include, but not be limited to:       

Instruction in the nature of the hazard, whether acute, chronic, or both, and an honest appraisal of what may happen if the respirator is not used. Explanation of why a more positive control is not immediately feasible. This shall include recognition that every reasonable effort is being made to reduce or eliminate the need for respirator. A discussion of why this is a proper type of respirator for the particular purpose. A discussion of the respirators capabilities and limitations. Instruction and training in actual use of the respirator. Classroom and field training to recognize and respond to emergency situations. The general requirements of 29 CFR 1910.134

Appendix N

Respiratory Protection Program Evaluation In general, the respirator program should be evaluated for each job, or at least annually, with program adjustments, as appropriate, made to reflect the evaluation results. Program function can be separated into administration and operation. A. PROGRAM ADMINISTRATION Yes

No

Yes

No

___

____

1. Is there a written policy which acknowledges employer responsibility For providing a safe and healthful workplace and assigns program responsibility, accountability, and authority? 2. Is program responsibility vested in one individual who is knowledgeable And who can coordinate all aspects of the program at the job site? 3. Can feasible engineering controls or work practices eliminate the need for respirators? 4. Are there written procedures/statements covering the various aspects of the respirator program, including:  Designation of an administrator  Respirator selection  Purchase of MSHA/NIOSH certified equipment  Medical aspects of respirator usage  Issuance of equipment  Fitting  Training  Maintenance, storage, and repair  Inspection  Use under special conditions  Work area surveillance B. PROGRAM OPERATION 1. Respiratory Protective Equipment Selection  Are work area conditions and worker exposures properly surveyed?  Are respirators selected on the basis of hazards to which the worker is exposed?  Are selections made by individuals knowledgeable of proper selection procedures? 2. Are only NIOSH certified respirators purchased and used? 3. Do they provide adequate protection for the specific hazard? 4. Has a medical evaluation of the prospective user been made to determine physical and psychological ability to wear the selected respiratory protective equipment?

Yes 5. Where practical, have respirators been issued to the users for their exclusive use, and are there records covering issuance? 6. Respiratory protective equipment fitting:  Are the users given the opportunity to try on several respirators to determine whether the respirator they will subsequently be wearing is the best fitting one?  Is the fit tested at appropriate intervals?  Are those users who require corrective lenses properly fitted?  Are wearing contact lenses prohibited when using respirators?  Is the face piece-to-face seal tested in a test atmosphere?  Are workers prohibited from wearing respirators in contaminated work areas when they have facial hair or other characteristics that may cause face seal leakage? 7. Respirator use in the work area:  Are respirators being worn correctly (i.e., head covering over respiratory straps?  Are workers keeping respirators on all the time while in the work area? 8. Maintenance of respiratory protective equipment:  Are respirators cleaned and disinfected after each use when different people use the same devise, or as frequently as necessary for devices issued to individual users?  Are proper methods of cleaning and disinfecting utilized? Storage  Are respirators stored in a manner so as to protect them from dust, sunlight, heat, excessive cold or moisture, or damaging chemicals?  Are respirators stored properly in a storage facility so as to prevent them from deforming  Is storage in lockers and tool boxes permitted only if the respirator is in a carrying case or carton? Inspection  Are respirators inspected before and after each use and cleaning?  Are qualified individuals/users instructed in inspection techniques?  Is respiratory protective equipment designated as "emergency use" inspected at least monthly (in addition to after each use)?  Are SCBA incorporating breathing gas containers inspected weekly for breathing gas pressure?  Is a record kept of the inspection of "emergency use" respiratory protective equipment?

No

Yes Repair  Are replacement parts used in repair those of the manufacturer of the respirator? Special Use Conditions  Is a procedure developed for respiratory protective equipment usage in atmospheres immediately dangerous to life or health?  Is a procedure developed for equipment usage for entry into confined spaces? Training  Are users trained in proper respirator use, cleaning, and inspection?  Are users trained in basis for selection of respirators?  Are users evaluated, using competency-based evaluation, before and after training? Conclusion    

Is this Respiratory Protection Program adequate? Are administrative controls adequate? Are engineering controls adequate? Are there changes which could be made to increase the effectiveness of this plan?  Will changes be made (please attach explanation).

PROGRAM ADMINISTRATOR

DATE:

No

Appendix O

List of Current Respirator Users

Name of User Jim Uhlir

Date Issued Respirator Type Resp Make Resp Model 12/14/2009

1/2 Face, Neg

North

7700 Large

Issued By Dean Sankey

Appendix P

Respirator Program Review Dates Date 7/21/2010

Changes Made to Program Added List of Current Respiator Users (App O) and Respirator Program Review Dates (App P)