RAU-PVC 1100-1999

Unplasticized polyvinyl chloride (PVC-U) AV0200 EN Material Data Sheet

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Construction Automotive Industry

Chemical structure RAU-PVC 1100–1999 (PVC-U) is made of polyvinyl chloride and additives such as stabilizers, lubricants, impact modifiers, pigments, etc., without the use of plasticizers. Characteristic properties Tough, rigid, inherently stable, excellent resistance to chemicals and ageing.

Permeability to gas (20 °C, thickness of test specimens 0.1 mm) Oxygen cm3 appr. 119 × m2 × 24 hrs. × 1 bar Nitrogen

Thermal properties (See Table 1) RAU-PVC 1100–1999 is thermoplastic. The physical values therefore vary with changes in temperature. The strength values given in Table 1 are based on +20 °C. At lower temperatures impact resistance decreases, elongation at break decreases, compressive strength and flexural strength increase. With higher temperatures, elongation at break increases, compressive strength and flexural strength decrease. Between +10 °C and +40 °C the changes in the mechanical values are small and can be disregarded for most applications. Between +40 °C and +60 °C mechanical stresses should be reduced. When mechanical stresses are present, the material should be subjected to temperatures above +60 °C for short periods only. The softening point of RAU-PVC 1100–1999 lies at approximately 72–83 °C. For applications with higher requirements in regard to impact and shock, especially at temperatures below 0 °C, we recommend impact resistant grades such as RAU-PVC 1406. Mechanical and electrical properties (See Table 1) Chemical resistance RAU-PVC 1100–1999 is resistant to most diluted and concentrated acids and lyes and also to aqueous salt solutions. It is also resistant to mineral oils, vegetable oils, paraffin oils, alcohols, benzine, aliphatic hydrocarbons and higher fatty acids. Unplasticized polyvinyl chloride swells or becomes soluble in esters, ketones, chloride hydrocarbons, aromatic hydrocarbons, carbon disulphide and other solvents and is therefore not resistant. Table 2 shows the resistance of RAU-PVC 1100–1999 to the most commonly met chemicals and solvents. Weathering and aging resistance Because of its chemical structure, RAU-PVC 1100–1999 possesses an excellent inherent resistance to ageing. For outdoor use, formulations with increased weather resistance are available (RAU-PVC 1406, RAU-PVC 1302). Combustibility Being a hydrocarbon with high chlorine content, RAU-PVC 1100– 1999 is difficult to ignite and self-extinguishing after removal of the flame.

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cm3 appr. 45 × m2 × 24 hrs. × 1 bar Carbon dioxide cm3 appr. 270 × m2 × 24 hrs. × 1 bar Physiological properties For medical applications or for use with foodstuffs, special non-toxic formulations are available that meet all known standards and recommendations of the health authorities. Coloring RAU-PVC 1100–1999 can be supplied in practically any desired shade. RAL colors are particularly recommended. Where metallic colors are required, however, the advice of our application engineering department should be sought, as metallic pigments can have an adverse effect on certain properties. Bonding RAU-PVC 1100–1999 can be bonded to itself and other materials quite simply using normal commercial adhesives for rigid PVC and a very good bond is achieved. The adhesives manufacturer’s instructions should be observed. Welding RAU-PVC 1100–1999 can be welded by means of simple thermal techniques (welding using a welding wedge, nitrogen current, high frequency). The quality of the weld is very high. Application Profiles, pipes, moldings, hollow parts and semi-finished products in RAU-PVC 1100–1999 are used for a wide range of applications in all branches of industry. Recyclability RAU-PVC 1100–1999 is suitable for recycling and re-use in the manufacture of new products, just as any other thermoplastic polymer is in principle. If materials are sorted properly according to color and type, e.g. off-cuts left over after sawing or punching, they can often be recycled and used in further production of the same article. Even well-worn components still retain their material properties to a large extent despite many years of usage, and depending on how clean the material is it can be employed in the manufacture of new products that have greater or lesser requirements in terms of quality.

Table 1: Mechanical, thermal and electrical properties Thermal properties Vicat softening temperature (method B50) Stationary thermal resistance

ISO 306

72–83 °C

ISO 8302

W 0.17 K × m

Coefficient of linear thermal expansion Specific heat (+20 °C)

ISO 11359-2 ISO 11357-4

80 × 10−6 K−1 1.00 kJ/kg K

Mechanical properties Tensile strength Elongation at break Flexural stress at break Flexural yield strength Charpy impact strength at +20 °C Charpy notched impact strength at +23 °C Ball indentation hardness Flexural modulus of elasticity

ISO 527 ISO 527 ISO 178 ISO 178 ISO 179-1, 1eU ISO 179-1, 1eA DIN ISO 2039-1 ISO 178-1

>45 N/mm2 >15 % approx. 100 N/mm² approx. 100 N/mm² no breakage >2 kJ/m2 >100 N/mm2 >2300 N/mm2

DIN IEC 60093 DIN IEC 60167 DIN 53483-1

Electrical properties Volume resistivity Leakage resistance Dielectric constant   50 Hz 850 Hz 1 MHz Dielectric dissipation factor 800 MHz Dielectric strength of insulating materials

DIN 53483-1 DIN EN 60243

approx. 1016 Ω cm approx. 1013 Ω Ohm × cm 3.2–3.7 3–3.5 approx. 3 0.012–0.015 >20 kV/mm

Water absorption Storage at 23 °C up to saturation

ISO 62

0.1 %

Table 2: Chemical Resistance of RAU-PVC 1100-1999 Reagent Acetaldehyde, conc. Acetaldehyde, aqueous Acetaldehyde + acetic acid Acetic acid, crude Acetic anhydride

Acetone Acetone, aqueous Acronal dispersions Acronal solutions Acrylic acid ethyl esther Adipic acid, aqueous Aktivin, aqueous Allyl alcohol Aluminium chloride, aqueous

Aluminium sulphate, aqueous

Alum, aqueous

Ammonia, liquid

Concentration % 100 40 90/10 95 100 100 100 100 100 traces commerc. commerc. 100 saturated saturated 1 96 96 diluted diluted saturated diluted diluted saturated diluted diluted saturated 100

Temp °C 20 40 20 40 20 40 60 20 60 20 20 20 20 20 60 20 20 60 40 60 60 40 60 60 40 60 60 20

* nr pr pr pr nr nr nr nr nr nr r nr nr r pr r pr nr r pr r r pr r r pr r pr

Reagent Ammonia, gaseous Ammonia water Ammonium chloride, aqueous

Ammonium fluoride, aqueous Ammonium nitrate, aqueous

Ammonium sulphate, aqueous

Ammonium sulphide, aqueous

Aniline, pure Aniline, aqueous Aniline chlorine hydrate, aqueous Animal glue Anthraquinone sulphonic acid, aqueous Antimony butter, aqueous

Concentration % 100 warm sat. warm sat. diluted diluted saturated up to 20 up to 20 diluted diluted saturated diluted diluted saturated diluted diluted saturated 100 100 saturated saturated saturated saturated ind. conc. ind. conc. susp. 90

Temp °C 60 40 60 40 60 60 20 60 40 60 60 40 60 60 40 60 60 20 60 20 60 20 60 20 60 30 20

* r r pr r pr r r pr r pr r r pr r r pr r nr nr nr nr pr nr r r r r 3

Reagent Arsenic acid, aqueous

Asfluid 1, liquid Asfluid 1, dry (film) Beef suet emulsion (sulphurised) Beer Beer sugar colouring Benzaldehyde, aqueous Benzene Benzine Benzine-benzene mixture Benzoic acid, aqueous

Benzoic acid soda, aqueous

Bisulphite lye, containing SO2 Bleaching lye, 12.5 % active chlorine Borax, aqueous

Boric acid, aqueous

Brandy Bromine, liquid Bromine vapours Butadiene Butanediol Butanediol, aqueous

Butane, gaseous Butanol

Butindiol Butyl acetate Butylene, liquid Butyl phenol Butyric acid, aqueous Calcium chloride, aqueous

Calcium nitrate, aqueous Carbon disulphide Carbonic acid, dry Carbonic acid, moist Carbonic acid, aqueous below 8 atm. Carbon tetrachloride, techn. Caustic potash lye, aqueous

Chloramine, aqueous Chloric acid, aqueous

Chlorine, gaseous, dry Chlorine, gaseous, moist

Chlorine water Chloroacetic acid (mono-) Chloroacetic acid (mono-), aqueous Chloromethyl Chlorosulphonic acid 4

Concentration % diluted diluted 80 80 – – commerc. commerc. commerc. 0.1 100 100 80/20 any any any up to 10 up to 10 36 warm saturated usual usual diluted diluted saturated diluted diluted saturated commerc. 100 low 100 up to 100 up to 10 up to 10 up to 10 50 up to 100 up to 100 up to 100 up to 100 100 100 100 20 conc. diluted diluted saturated 50 diluted 100 any any saturated 100 up to 40 up to 40 50/60 diluted 1 1 10 10 20 20 100 0.5 1 5 saturated 100 100 85 100 100

Temp °C 40 60 40 60 20 20 20 20 60 60 20 60 20 20 40 60 40 60 60 50 40 60 40 60 60 40 60 60 20 20 20 60 20 20 40 60 20 20 40 60 40 20 −20 20 20 20 40 60 60 40 40 60 40 60 20 20 40 60 60 20 40 60 40 60 40 60 20 20 20 20 20 40 60 20 20 20

* r pr r pr nr pr r r r nr nr r nr r r pr r pr pr r r pr r pr pr r pr pr r nr pr r pr r pr nr r r r pr pr nr r pr r nr r pr r r pr r r pr r nr r pr r r r pr r pr r pr pr r pr pr pr r pr r nr pr

Reagent Chromic acid, aqueous Chromic acid/sulphuric acid/water Chromium potassium sulphate, aqueous

Cider Citric acid, aqueous

Clophene Coconut fat alcohol Copper fluoride, aqueous Copper sulphate, aqueous

Cresol, aqueous Crotonic aldehyde Copper (I) - chloride, aqueous Cyclanon Cyclohexanol Cyclohexanone Densodrin W Dextrine, aqueous Diglycolic acid, aqueous Dimethylamine, aqueous Ethyl acetate, acetic ester Ethyl alcohol, aqueous Ethyl alcohol, denatured (with 2 % toluene) Ethyl alcohol (fermentation mash) Etyl alcohol + acetic acid (fermentation mixture) Ethyl ether Ethylene chloride Ethylene oxide, liquid Fatty acids Formaldehyde, aqueous

Formic acid Formic acid, aqueous Freon Fruit pulp Fruit tree creosote, aqueous Gas liquor Glacial acetic acid Glucose, aqueous Glycerine, aqueous Glycocoll, aqueous Glycol, aqueous Glycolic acid, aqueous Hexanetriol Hydrobromic acid, aqueous

Hydrochloric acid, aqueous

Hydrofluoric acid, aqueous

Hydrofluorosilicic acid, aqueous Hydrogen

Concentration % up to 50 up to 50 50/15/35 50/15/35 diluted diluted saturated commerc. up to 10 up to 10 saturated commerc. commerc. 100 100 2 diluted diluted saturated up to 90 100 saturated commerc. commerc. 100 100 commerc. saturated 18 30 saturated 100 100 100 any 96 96 ind. stand. ind. stand. ind. stand. 100 100 100 100 diluted diluted 40 100 100 up to 50 50 100 ind. conc. usual usual 100 100 saturated saturated any 10 commerc. 37 commerc. up to 10 up to 10 48 up to 30 up to 30 over 30 over 30 up to 40 40 60 70 up to 32 100

Temp °C 40 60 40 60 40 60 60 20 40 60 60 20 60 20 60 50 40 60 60 45 20 20 20 60 20 20 60 20 60 60 20 −30 20 60 20 60 20 40 60 20 20 20 −20 60 40 60 30 20 60 40 60 20 20 20 40 20 40 20 60 60 40 60 20 60 40 60 60 40 60 20 60 20 60 20 20 60 60

* r pr r pr r pr r r r pr r pr nr r r r r pr r pr nr r r r nr nr r r pr pr r pr nr nr r pr r r pr r r nr nr r r pr r pr nr r pr r r r pr pr nr r pr r r r r r r pr r r pr pr pr r pr pr pr r r

Reagent Hydrogen peroxide, aqueous Hydrogen phosphide Hydrogen sulphide, dry Hydrogen sulphide, aqueous Hydrosulphite, aqueous Hydroxylamine sulphate, aqueous Iron chloride (ferri), aqueous

Lactic acid, aqueous

Lead acetate, aqueous

Liqueurs Magnesium chloride, aqueous

Magnesium sulphate, aqueous

Maleic acid, aqueous

Malic acid, aqueous Manure salts, aqueous

Mersol D Methyl alcohol Methylamine, aqueous Methylene chloride Methyl sulphuric acid, aqueous

Milk Mixed acid 1 (sulph. acid/nitric acid/water)

Molasses Molasses, aromatics for Mowilith D Nekal, BX, aqueous Nickel sulphate, aqueous

Nicotine, aqueous Nicotine preparations, aqueous Nitric acid, aqueous

Nitrous fumes Oils, fats and greases Oleic acid Oleum Oleum fumes Oxalic acid, aqueous

Oxygen

Concentration % up to 30 up to 20 100 warm sat. warm sat. − up to 10 up to 10 up to 12 up to 10 up to 10 saturated up to 10 up to 10 90 warm sat. diluted diluted saturated commerc. diluted diluted saturated diluted diluted saturated saturated saturated 35 1 up to 10 up to 10 saturated ind. conc. 100 100 32 100 up to 50 up to 50 100 100 commerc. 48/49/3 48/49/3 50/50/0 50/50/0 10/20/70 10/87/3 50/31/19 ind. conc. ind. conc. ind. conc. commerc. diluted diluted diluted diluted saturated usual usual up to 30 30/50 98 98 conc. conc. commerc. commerc. 10 lower higher diluted diluted saturated any

Temp °C 20 50 20 40 60 40 40 60 35 40 60 60 40 60 60 50 40 60 60 20 40 60 60 40 60 60 40 60 40 20 40 60 60 40 40 60 20 20 20 40 40 60 20 20 40 20 40 50 20 30 20 60 60 20 40 60 40 60 60 20 20 50 50 20 60 20 60 60 60 20 20 20 40 60 60 60

* r r r r pr r r pr r r pr r r pr r r r pr r r r pr r r pr r r pr r r r pr r r r pr pr nr r pr r pr r r pr pr pr r pr r r pr r r r pr r pr r r r pr pr nr nr pr nr r r nr r pr r pr r r

Reagent Ozone Palm nut fatty acids Paraffin emulsions Perchloric acid, aqueous

Phenol, aqueous Phenylhydrazine Phenylhydrazine-hydrochloride, aqueous Phosgene, gaseous Phosgene, liquid Phosphoric acid, aqueous

Phosphorus pentoxide Phosphorus trichloride Photo developer Photo emulsions Photo fixing baths Picric acid, aqueous Pitching yeast Potassium bichromate, aqueous Potassium borate, aqueous Potassium bromate, aqueous Potassium bromide, aqueous

Potassium carbonate, aqueous Potassium chloride, aqueous

Potassium chromate, aqueous Potassium cyanide, aqueous

Potassium ferricyanide + potassium ferrocyanide, aqueous Potassium nitrate, aqueous

Potassium perchlorate, aqueous Potassium permanganate, aqueous

Potassium persulphate, aqueous

Propane, gaseous Propane, liquid Propargyl alcohol, aqueous Ramasite Roasting gases, dry Sea water Silicic acid, aqueous Soap solution, aqueous Silvernitrate, aqueous Soda, aqueous

Concentration % 100 10 100 commerc. commerc. up to 10 up to 10 saturated up to 90 1 100 100 saturated saturated 100 100 100 up to 30 up to 30 40 80 80 100 100 commerc. any commerc. 1 ind. conc. ind. conc. 40 1 1 up to 10 up to 10 diluted diluted saturated saturated diluted diluted saturated 40 up to 10 up to 10 saturated diluted diluted saturated diluted diluted saturated 1 1 up to 6 up to 6 up to 6 up to 18 diluted diluted saturated saturated 100 100 7 commerc. commerc. any – any conc. conc. up to 8 up to 8 diluted diluted saturated

Temp °C 20 30 60 20 40 40 60 60 45 20 20 60 20 60 20 60 20 40 60 60 20 60 20 20 40 40 40 20 40 60 20 40 60 40 60 40 60 60 40 40 60 60 20 40 60 60 40 60 60 40 60 60 40 60 20 40 60 40 40 60 40 60 20 20 60 20 40 60 60 60 20 60 40 60 40 60 60

* pr pr r r r r pr r pr r nr nr pr nr r pr nr r pr pr r pr r nr r r r r r pr r r pr r pr r pr r r r pr r r r pr r r pr r r pr r r pr r r r r r pr r pr r r r r r r pr r r pr r pr r r r 5

Reagent Soda lye, aqueous

Sodium bisulphite, aqueous

Sodium chlorate, aqueous

Sodium chloride, aqueous

Sodium chlorite, aqueous Sodium hypochlorite, aqueous Sperm oil alcohol Spinning bath acids, containing CS2

Spirits (brandy, whisky, etc.) Stannous chloride, aqueous Starch, aqueous Starch sirup Stearic acid Sulphur dioxide, aqueous below 8 atm. Sulphur dioxide, dry Sulphur dioxide, liquid

Sulphur dioxide, moist and aqueous

Sulphuric acid, aqueous

Sulphuric sodium, aqueous

Tallow Tanigan special A, aqueous Tanigan special B, aqueous Tanigan special D, aqueous

Concentration % up to 40 up to 40 50/60 diluted diluted saturated up to 10 up to 10 saturated diluted diluted saturated diluted diluted diluted commerc. 0.01 0.02 0.07 commerc. diluted diluted any any ind. conc. 100 saturated 100 any 100 100 100 any 50 any up to 40 70 70 80–90 96 96 100 diluted saturated up to 40 100 100 any any saturated saturated

Temp °C 40 60 60 40 60 60 40 60 60 40 60 60 20 60 20 20 52 52 52 20 40 60 40 60 40 60 20 −10 60 20 60 20 40 50 60 60 20 60 40 20 60 60 60 60 40 20 60 20 20 40 60

* r r r r pr r r pr r r r r pr nr r r r pr nr r r pr r r r r r pr r pr nr pr r r pr pr r pr pr pr pr pr pr r r r r r r pr nr

Reagent Tanigan F, aqueous Tanigan U, aqueous Tanning extracts, of cellulose Tanning extracts, vegetable Tartaric acid, aqueous

Tetraethyl lead Thionyl chloride Toluene Trichlorethylene Triethanolamine Trilone Trimethylol propane, aqueous

Urea, aqueous

Urine Vinegar (wine vinegar)

Vinyl acetate Waste gases, containing carbonic acid Waste gases, containing hydrogen fluoride Waste gases, containing hydrochloric acid Waste gases, containing nitrous gases Waste gases, containing oleum Waste gases, containing sulphuric acid, moist Waste gases, containing SO2 Water Wax alcohol Wine, red and white Xylene Zinc chloride, aqueous

Zinc sulphate, aqueous

Concentration % saturated saturated saturated usual usual up to 10 up to 10 saturated 100 100 100 100 100 commerc. up to 10 up to 10 commerc. commerc. up to 10 up to 10 33 normal normal commerc. commerc. commerc. up to 25 up to 25 25–60 80 100 any traces any traces higher lower higher any lower 50 100 100 100 commerc. 100 diluted diluted saturated diluted diluted saturated

* Resistance of polyvinyl chloride Abbreviations: r = resistant pr = partially resistant nr = not resistant – = not tested

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Temp °C 60 40 60 20 20 40 60 60 20 20 20 20 20 60 40 60 40 60 40 60 60 40 60 40 50 60 40 60 60 40 20 60 60 60 60 60 20 20 60 60 50 40 60 60 20 20 40 60 60 40 60 60

* r r pr r r r pr r r nr nr nr pr r r pr pr pr r pr r r pr r r pr r pr r pr nr r r r r nr r nr r r r r pr r r nr r pr r r pr r

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AV0200 EN

02.2013