NUCLEAR PHYSICS AND RADIOACTIVITY

30

Responses to Questions 1.

Different isotopes of a given element have the same number of protons and electrons. Because they have the same number of electrons, they have almost identical chemical properties. Each isotope has a different number of neutrons from other isotopes of the same element. Accordingly, they have different atomic masses and mass numbers. Since the number of neutrons is different, they may have different nuclear properties, such as whether they are radioactive or not.

2.

Identify the element based on the atomic number. (a) (b) (c) (d) (e)

Uranium Nitrogen Hydrogen Strontium Fermium

(Z = 92) (Z = 7) (Z = 1) (Z = 38) (Z = 100)

3.

The number of protons is the same as the atomic number, and the number of neutrons is the mass number minus the number of protons. (a) Uranium: 92 protons, 140 neutrons (b) Nitrogen: 7 protons, 11 neutrons (c) Hydrogen: 1 proton, 0 neutrons (d) Strontium: 38 protons, 48 neutrons (e) Fermium: 100 protons, 152 neutrons

4.

With 87 nucleons and 50 neutrons, there must be 37 protons. This is the atomic number, so the element is rubidium. The nuclear symbol is

5.

87 37 Rb.

The atomic mass of an element as shown in the Periodic Table is the average atomic mass of all 35 37 naturally occurring isotopes. For example, chlorine occurs as roughly 75% 17 Cl and 25% 17 Cl, so its atomic mass is about 35.5 (= 0.75 × 35 + 0.25 × 37). Other smaller effects would include the fact that the masses of the nucleons are not exactly 1 atomic mass unit and that some small fraction of the mass energy of the total set of nucleons is in the form of binding energy.

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30-1

30-2

Chapter 30

6.

The alpha particle is a very stable nucleus. It has less energy when bound together than when split apart into separate nucleons.

7.

The strong force and the electromagnetic (EM) force are two of the four fundamental forces in nature. They are both involved in holding atoms together: the strong force binds quarks into nucleons and binds nucleons together in the nucleus; the EM force is responsible for binding negatively charged electrons to positively charged nuclei and for binding atoms into molecules. The strong force is the strongest fundamental force; the EM force is about 100 times weaker at distances on the order of 10−17 m. The strong force operates at short range and is negligible for distances greater than about the size of the nucleus. The EM force is a long-range force that decreases as the inverse square of the distance between the two interacting charged particles. The EM force operates only between charged particles. The strong force is always attractive; the EM force can be attractive or repulsive. Both of these forces have mediating field particles associated with them—the gluon for the strong force and the photon for the EM force.

8.

Quoting from Section 30–3, “… radioactivity was found in every case to be unaffected by the strongest physical and chemical treatments, including strong heating or cooling and the action of strong chemical reagents.” Chemical reactions are a result of electron interactions, not nuclear processes. The absence of effects caused by chemical reactions is evidence that the radioactivity is not due to electron interactions. Another piece of evidence is the fact that the α particle emitted in many radioactive decays is much heavier than an electron and has a different charge than the electron, so it can’t be an electron. Therefore, it must be from the nucleus. Finally, the energies of the electrons or photons emitted from radioactivity are much higher than those corresponding to electron orbital transitions. All of these observations support radioactivity being a nuclear process.

9.

The resulting nuclide for gamma decay is the same isotope in a lower energy state. 64 29 Cu*



64 29 Cu + γ

The resulting nuclide for β − decay is an isotope of zinc, 64 29 Cu



64 − 30 Zn + e

64 30 Zn.

+v

The resulting nuclide for β + decay is an isotope of nickel, 64 29 Cu



64 + 28 Ni + e

64 28 Ni.

+v

10.

238 92 U

11.

Alpha (α) particles are helium nuclei. Each α particle consists of 2 protons and 2 neutrons and therefore has a charge of +2e and an atomic mass value of 4 u. They are the most massive of the three.

decays by alpha emission into

234 90Th,

which has 144 neutrons.

Beta (β) particles are electrons ( β − ) or positrons ( β + ). Electrons have a charge of –e and positrons have a charge of +e. In terms of mass, beta particles are much lighter than protons or neutrons, by a factor of about 2000, so are lighter than alpha particles by a factor of about 8000. Their emission is always accompanied by either an antineutrino ( β − ) or a neutrino ( β + ). Gamma (γ) particle are photons. They have no mass and no charge.

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Nuclear Physics and Radioactivity

12.

(a)

45 20 Ca



45 − 21Sc + e

(b)

58 29 Cu



58 29 Cu + γ

(c)

46 24 Cr



46 + 23 V + e

(d)

234 94 Pu



230 92 U + α

(e)

239 93 Np



239 − 94 Pu + e

+v

30-3

Scandium-45 is the missing nucleus. Copper-58 is the missing nucleus.

+v

The positron and the neutrino are the missing particles. Uranium-230 is the missing nucleus. + v The electron and the antineutrino are the missing particles.

13.

The two extra electrons held by the newly formed thorium will be very loosely held, as the number of protons in the nucleus will have been reduced from 92 to 90, reducing the nuclear charge. It will be easy for these extra two electrons to escape from the thorium atom through a variety of mechanisms. They are in essence “free” electrons. They do not gain kinetic energy from the decay. They might get captured by the alpha nucleus, for example.

14.

When a nucleus undergoes either β − or β + decay, it becomes a different element, since it has converted either a neutron to a proton or a proton to a neutron. Thus its atomic number (Z) has changed. The energy levels of the electrons are dependent on Z, so all of those energy levels change to become the energy levels of the new element. Photons (with energies on the order of tens of eV) are likely to be emitted from the atom as electrons change energies to occupy the new levels.

15.

In alpha decay, assuming the energy of the parent nucleus is known, the unknowns after the decay are the energies of the daughter nucleus and the alpha. These two values can be determined by energy and momentum conservation. Since there are two unknowns and two conditions, the values are uniquely determined. In beta decay, there are three unknown postdecay energies since there are three particles present after the decay. The conditions of energy and momentum conservation are not sufficient to exactly determine the energy of each particle, so a range of values is possible.

16.

In electron capture, the nucleus will effectively have a proton change to a neutron. This isotope will then lie to the left and above the original isotope. Since the process would only occur if it made the nucleus more stable, it must lie BELOW the line of stability in Fig. 30–2.

17.

Neither hydrogen nor deuterium can emit an α particle. Hydrogen has only one nucleon (a proton) in its nucleus, and deuterium has only two nucleons (one proton and one neutron) in its nucleus. Neither one has the necessary four nucleons (two protons and two neutrons) to emit an α particle.

18.

Many artificially produced radioactive isotopes are rare in nature because they have decayed away over time. If the half-lives of these isotopes are relatively short in comparison with the age of Earth (which is typical for these isotopes), then there won’t be any significant amount of these isotopes left to be found in nature. Also, many of these isotopes have a very high energy of formation, which is generally not available under natural circumstances.

19.

After two months the sample will not have completely decayed. After one month, half of the sample will remain, and after two months, one-fourth of the sample will remain. Each month, half of the remaining atoms decay.

20.

For Z > 92, the short range of the attractive strong nuclear force means that no number of neutrons is able to overcome the long-range electrostatic repulsion of the large concentration of protons.

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30-4

21.

Chapter 30

There are a total of 4 protons and 3 neutrons in the reactant. The α particle has 2 protons and 2 neutrons, so 2 protons and 1 neutron are in the other product particle. It must be 32 He. 6 1 3 Li + 1 p



4 2α

+ 23 He

22.

The technique of 146 C would not be used to measure the age of stone walls and tablets. Carbon-14 dating is only useful for measuring the age of objects that were living at some earlier time.

23.

The decay series of Fig. 30–11 begins with a nucleus that has many more neutrons than protons and lies far above the line of stability in Fig. 30–2. The alpha decays remove both 2 protons and 2 neutrons, but smaller stable nuclei have a smaller percentage of neutrons. In β + decay, a proton is converted to a neutron, which would take the nuclei in this decay series even farther from the line of stability. Thus, β + decay is not energetically preferred.

24.

There are four alpha particles and four β − particles (electrons) emitted, no matter which decay path is 206 chosen. The nucleon number drops by 16 as 222 86 Rn decays into 82 Pb, indicating that four alpha decays occurred. The proton number only drops by four, from Z = 86 to Z = 82, but four alpha decays

would result in a decrease of eight protons. Four β − decays will convert four neutrons into protons, making the decrease in the number of protons only four, as required. (See Fig. 30–11.) 25.

(i)

Since the momentum before the decay was 0, the total momentum after the decay will also be 0. Since there are only two decay products, they must move in opposite directions with equal magnitude of momentum. Thus, (c) is the correct choice: both the same. (ii) Since the products have the same momentum, the one with the smallest mass will have the greater velocity. Thus (b) is the correct choice: the alpha particle. (iii) We assume that the products are moving slowly enough that classical mechanics can be used. In that case, KE = p 2 /2m. Since the particles have the same momentum, the one with the smallest mass will have the greater kinetic energy. Thus, (b) is the correct choice: the alpha particle.

Responses to MisConceptual Questions 1.

(a)

A common misconception is that the elements of the Periodic Table are distinguished by the number of electrons in the atom. This misconception arises because the number of electrons in a neutral atom is the same as the number of protons in its nucleus. Elements can be ionized by adding or removing electrons, but this does not change what type of element it is. When an element undergoes a nuclear reaction that changes the number of protons in the nucleus, the element does transform into a different element.

2.

(b)

The role of energy in binding nuclei together is often misunderstood. As protons and neutrons are added to the nucleus, they release some mass energy, which usually appears as radiation or kinetic energy. This lack of energy is what binds the nucleus together. To break the nucleus apart, the energy must be added back in. As a result, a nucleus will have less energy than the protons and neutrons that made up the nucleus.

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Nuclear Physics and Radioactivity

3.

(c)

30-5

Large nuclei are typically unstable, so increasing the number of nuclei does not necessarily make the nucleus more stable. Nuclei such as stable as

16 8 O.

14 8O

have more protons than neutrons, yet

14 8O

is not as

Therefore, having more protons than neutrons does not necessarily make a

nucleus more stable. Large unstable nuclei, such as

238 94 Pu,

have a much larger total binding

energy than small stable nuclei such as 42 He, so the total binding energy is not a measure of stability. However, stable nuclei typically have large binding energies per nucleon, which means that each nucleon is more tightly bound to the others. 4.

(e)

The Coulomb repulsive force does act inside the nucleus, pushing the protons apart. Another larger attractive force is thus necessary to keep the nucleus together. The force of gravity is far too small to hold the nucleus together. Neutrons are not negatively charged. It is the attractive strong nuclear force that overcomes the Coulomb force to hold the nucleus together.

5.

(b)

The exponential nature of radioactive decay is a concept that can be misunderstood. It is sometimes thought that the decay is linear, such that the time for a substance to decay completely is twice the time for half of the substance to decay. However, radioactive decay is not linear but exponential. That is, during each half-life, half of the remaining substance decays. If half the original decays in the first half-life, then half remains. During the second half-life, half of what is left decays, which would be one-quarter of the initial substance. In each subsequent half-life, half of the remaining substance decays, so it takes many half-lives for a substance to effectively decay away. The decay constant is inversely related to the half-life.

6.

(e)

The half-life is the time it takes for half of the substance to decay away. The half-life is a constant determined by the composition of the substance and not by the quantity of the initial substance. As the substance decays away, the number of nuclei is decreasing and the activity (number of decays per second) is decreasing, but the half-life remains constant.

7.

(d)

A common misconception is that it would take twice the half-life, or 20 years, for the substance to completely decay. This is incorrect because radioactive decay is an exponential process. That is, during each half-life, 1/2 of the remaining substance decays. After the first 10 years, 1/2 remains. After the second 10-year period, 1/4 remains. After each succeeding half-life another half of the remaining substance decays, leaving 1/8, then 1/16, then 1/32, and so forth. The decays stop when none of the substance remains, and this time cannot be exactly determined.

8.

(e)

During each half-life, 1/2 of the substance decays, leaving 1/2 remaining. After the first day, 1/2 remains. After the second day, 1/2 of 1/2, or 1/4, remains. After the third day, 1/2 of 1/4, or 1/8, remains. Since 1/8 remains, 7/8 of the substance has decayed.

9.

(c)

A common misconception is that after the second half-life none of the substance remains. However, during each half-life, 1/2 of the remaining substance decays. After one half-life, 1/2 remains. After two half-lives, 1/4 remains. After three half-lives, 1/8 remains.

10.

(a)

The decay constant is proportional to the probability of a particle decaying and is inversely proportional to the half-life. Therefore, the substance with the larger half-life (Tc) will have the smaller decay constant and smaller probability of decaying. The activity is proportional to the amount of the substance (number of atoms) and the decay constant, so the activity of Tc will be smaller than the activity of Sr.

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30-6

11.

Chapter 30

(d)

The element with the largest decay constant will have the shortest half-life. Converting each of the choices to decays per second yields the following: (a) 100/s, (b) 1.6 × 108 /s, (c) 2.5 × 1010 /s, (d) 8.6 × 1013 /s. Answer (d) has the largest decay rate, so it will have the smallest half-life.

12.

(d)

If U-238 only decayed by beta decay, the number of nucleons would not change. Pb-206 has 32 nucleons less than U-238, so all decays cannot be beta decays. In each alpha decay, the number of nucleons decreases by four and the number of protons decreases by two. U-238 has 92 protons and Pb-206 has 82 protons, so if only alpha decays occurred, then the number of nucleons would need to decrease by 20. But Pb-206 has 32 fewer nucleons than U-238. Therefore, the sequence is a combination of alpha and beta decays. Gamma decays are common, since some of the alpha and beta decays leave the nuclei in excited states where energy needs to be released.

13.

(d)

A common misconception is that carbon dating is useful for very long time periods. C-14 has a half-life about 6000 years. After about 10 half-lives only about 1/1000 of the substance remains. It is difficult to obtain accurate measurements for longer time periods. For example, after 600,000 years, or about 100 half-lives, only one part in 1030 remains.

14.

(b)

The half-life of radon remains constant and is not affected by temperature. Radon that existed several billion years ago will have completely decayed away. Small isotopes, such as carbon-14, can be created from cosmic rays, but radon is a heavy element. Lightning is not energetic enough to affect the nucleus of the atoms. Heavy elements such as plutonium and uranium can decay into radon and thus are the source of present-day radon gas.

15.

(d)

The gravitational force between nucleons is much weaker (about 50 orders of magnitude weaker) than the repulsive Coulomb force; therefore, gravity cannot hold the nucleus together. Neutrons are electrically neutral and therefore cannot overcome the Coulomb force. Covalent bonds exist between the electrons in molecules, not among the nucleons. The actual force that holds the nucleus together is the strong nuclear force, but this was not one of the options.

16.

(a)

The nature of mass and energy in nuclear physics is often misunderstood. When the neutron and proton are close together, they bind together by releasing mass energy that is equivalent to the binding energy. This energy comes from a reduction in their mass. Therefore, when the neutron and proton are far from each other, their net mass is greater than their net mass when they are bound together.

Solutions to Problems 1.

Convert the units from MeV/c 2 to atomic mass units. ⎛ ⎞ 1u m = (139 MeV/c 2 ) ⎜ = 0.149 u 2 ⎜ 931.5 Me V/c ⎟⎟ ⎝ ⎠

2.

The α particle is a helium nucleus and has A = 4. Use Eq. 30–1. r = (1.2 × 10−15 m) A 3 = (1.2 × 10−15 m)(4) 3 = 1.9 × 10−15 m = 1.9 fm 1

1

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Nuclear Physics and Radioactivity

3.

30-7

The radii of the two nuclei can be calculated with Eq. 30–1. Take the ratio of the two radii. 1/3

r238 (1.2 × 10−15 m)(238)1/3 ⎛ 238 ⎞ = =⎜ ⎟ r232 (1.2 × 10−15 m)(232)1/3 ⎝ 232 ⎠

So the radius of 4.

238 92 U

= 1.00855

is 0.855% larger than the radius of

232 92 U.

Use Eq. 30–1 for both parts of this problem. (a)

r = (1.2 × 10−15 m) A1/3 = (1.2 × 10−15 m)(112)1/3 = 5.8 × 10−15 m = 5.8 fm

(b)

r = (1.2 × 10−15 m) A1/3

3

5.



3 r ⎛ ⎞ ⎛ 3.7 × 10−15 m ⎞ A=⎜ ⎟ = 29.3 ≈ 29 ⎟ =⎜ ⎝ 1.2 × 10−15 m ⎠ ⎜⎝ 1.2 × 10−15 m ⎟⎠

To find the mass of an α particle, subtract the mass of the two electrons from the mass of a helium atom: mα = mHe − 2me

⎛ 931.5 MeV/c 2 = (4.002603 u) ⎜ ⎜ 1u ⎝

6.

⎞ 2 2 ⎟⎟ − 2(0.511 MeV/c ) = 3727 MeV/c ⎠

Each particle would exert a force on the other through the Coulomb electrostatic force (given by Eq. 16–1). The distance between the particles is twice the radius of one of the particles. 2

(8.988 ×109 N ⋅ m 2 /C 2 ) ⎡(2)(1.60 × 10−19 C) ⎤ ⎣ ⎦ = 63.41 N ≈ 63 N = F =k 2 2 (2rα ) ⎡ (2) 41/3 (1.2 × 10−15 m) ⎤ ⎣ ⎦ Qα Qα

( )

The acceleration is found from Newton’s second law. We use the mass of a “bare” alpha particle as calculated in Problem 5. F = ma → a =

7.

F = m

63.41 N = 9.5 × 1027 m/s 2 −27 ⎛ ⎞ 1.6605 × 10 kg 3727 MeV/c 2 ⎜ ⎜ 931.5 MeV/c 2 ⎟⎟ ⎝ ⎠

First, we calculate the density of nuclear matter. The mass of a nucleus with mass number A is approximately (A u) and its radius is r = (1.2 × 10−15 m) A1/3 . Calculate the density.

ρ=

m A(1.6605 × 10−27 kg/u) A(1.6605 × 10−27 kg/u) = = = 2.294 × 1017 kg/m3 4 π r3 4 π (1.2 × 10 −15 m)3 A V 3 3

We see that this is independent of A. The value has 2 significant figures. (a)

We set the density of the Earth equal to the density of nuclear matter.

ρ Earth = ρ nuclear = matter

REarth

M Earth 4 π R3 Earth 3 1/3

⎛ ⎜ M = ⎜ 4 Earth ⎜ 3 πρ nuclear matter ⎝

⎞ ⎟ ⎟ ⎟ ⎠

→ 1/3

⎛ ⎞ 5.98 × 1024 kg ⎟ =⎜ 17 3 4 ⎜ π (2.294 × 10 kg/m ) ⎟ ⎝3 ⎠

= 183.9 m ≈ 180 m

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30-8

Chapter 30

(b)

Set the density of Earth equal to the density of uranium, and solve for the radius of the uranium. Then compare that with the actual radius of uranium, using Eq. 30–1, with A = 238.

ρ=

M Earth 3 4πR Earth 3

=

mU 4πr 3 U 3 1/3

⎛ mU ⎞ rU = REarth ⎜ ⎟ ⎝ M Earth ⎠ 2.58 × 10−10 m (1.2 × 10−15 )(238)1/3

8.

M Earth



REarth

3

=

mU

1/3

⎡ (238 u)(1.6605 × 10−27 kg/u) ⎤ = (6.38 × 106 m) ⎢ ⎥ (5.98 × 1024 kg) ⎥⎦ ⎣⎢

= 2.58 × 10−10 m

= 3.5 × 104

Use Eq. 30–1 to find the value for A. We use uranium-238 since it is the most common isotope. runknown (1.2 × 10−15 m) A1/3 = = 0.5 → rU (1.2 × 10−15 m)(238)1/3

From Appendix B, a stable nucleus with A ≈ 30 is 9.



rU3

A = 238(0.5)3 = 29.75 ≈ 30

31 15 P .

Use conservation of energy. Assume that the centers of the two particles are located a distance from each other equal to the sum of their radii, and use that distance to calculate the initial electrical PE. Then we also assume, since the nucleus is much heavier than the alpha, that the alpha has all of the final KE when the particles are far apart from each other (so they have no PE). KE i

KEα

+ PE i = KE f + PE f

→ 0+

= (8.99 × 109 N ⋅ m 2 /C2 )

qα qFm = KEα + 0 → 4πε 0 (rα + rFm ) 1

(2)(100)(1.60 × 10−19 C) 2 (41/3 + 2571/3 )(1.2 × 10−15 m)(1.60 × 10−19 J/eV)

= 3.017 × 107 eV

≈ 3.0 × 107 eV = 30 MeV

10.

(a)

The hydrogen atom is made of a proton and an electron. Use values from Appendix B.

mp mH (b)

=

1.007276 u = 0.9994553 ≈ 99.95% 1.007825 u

Compare the volume of the nucleus to the volume of the atom. The nuclear radius is given by Eq. 30–1. For the atomic radius we use the Bohr radius, given in Eq. 27–13. 3

3

3 ⎡ (1.2 × 10−15 m) ⎤ Vnucleus 34 π rnucleus ⎛ rnucleus ⎞ −14 = = = ⎢ ⎥ = 1.2 × 10 ⎜ ⎟ −10 4 π r3 Vatom r × (0.53 10 m) ⎢ ⎥ ⎝ atom ⎠ ⎣ ⎦ atom 3

11.

Electron mass is negligible compared to nucleon mass, and one nucleon weighs about 1.0 atomic mass unit. Therefore, in a 1.0-kg object, we find the following: N=

(1.0 kg)(6.02 × 1026 u/kg) ≈ 6.0 × 1026 nucleons 1.0 u/nucleon

No, it does not matter what the element is, because the mass of one nucleon is essentially the same for all elements. © Copyright 2014 Pearson Education, Inc. All rights reserved. This material is protected under all copyright laws as they currently exist. No portion of this material may be reproduced, in any form or by any means, without permission in writing from the publisher.

Nuclear Physics and Radioactivity

12.

30-9

The initial kinetic energy of the alpha must be equal to the electrical potential energy when the alpha just touches the uranium. The distance between the two particles is the sum of their radii. KE i

KEα

+ PE i = KE f + PE f



KEα

= (8.99 × 109 N ⋅ m 2 /C2 )

+0 = 0+k

Qα QU (rα + rU )



(2)(92)(1.60 × 10−19 C) 2 1/3

(4

1/3

+ 232

)(1.2 ×10

−15

m)(1.60 × 10

−19

J/eV)

= 2.852 × 107 eV

≈ 29 MeV

13.

The text states that the average binding energy per nucleon between A ≈ 40 and A ≈ 80 is about 8.7 MeV. Multiply this by the number of nucleons in the nucleus. (63)(8.7 MeV) = 548.1 MeV ≈ 550 MeV

14.

From Fig. 30–1, we see that the average binding energy per nucleon at A = 238 is 7.5 MeV. Multiply this by the 238 nucleons.

(a)

(238)(7.5 MeV) = 1.8 × 103 MeV

From Fig. 30–1, we see that the average binding energy per nucleon at A = 84 is 8.7 MeV. Multiply this by the 84 nucleons.

(b)

(84)(8.7 MeV) = 730 MeV 15.

15 7N

consists of seven protons and eight neutrons. We find the binding energy from the masses of the components and the mass of the nucleus, from Appendix B.

( )

Binding energy = ⎡ 7m 11 H + 8m ⎣

( 01n ) − m ( 157 N )⎤⎦ c2

⎛ 931.5 MeV/c 2 ⎞ = [7(1.007825 u) + 8(1.008665 u) − (15.000109 u)]c 2 ⎜ ⎟⎟ ⎜ u ⎝ ⎠ = 115.49 MeV Binding energy per nucleon = (115.49 MeV)/15 = 7.699 MeV

16.

Deuterium consists of one proton, one neutron, and one electron. Ordinary hydrogen consists of one proton and one electron. We use the atomic masses from Appendix B, and the electron masses cancel.

( ) ( 01n ) − m ( 21H )⎤⎦ c2

Binding energy = ⎡ m 11 H + m ⎣

⎛ 931.5 MeV/c 2 = [(1.007825 u) + (1.008665 u) − (2.014102 u)]c 2 ⎜ ⎜ u ⎝

⎞ ⎟⎟ ⎠

= 2.224 MeV

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30-10

17.

Chapter 30

We find the binding energy of the last neutron from the masses of the isotopes. Binding energy = ⎡ m ⎣

( 2211 Na ) + m ( 01n ) − m ( 2311 Na )⎤⎦ c2

= [(21.994437 u) + (1.008665 u) − (22.989769 u)]c 2 (931.5 MeV/c 2 ) = 12.42 MeV

18.

(a)

7 3 Li

consists of three protons and three neutrons. We find the binding energy from the masses, using hydrogen atoms in place of protons so that we account for the mass of the electrons.

( )

Binding energy = ⎡3m 11 H + 4m ⎣

( n ) − m ( Li )⎤⎦ c 1 0

7 3

2

⎛ 931.5 MeV/c 2 ⎞ = [3(1.007825 u) + 4(1.008665 u) − (7.016003 u)]c 2 ⎜ ⎟⎟ ⎜ u ⎝ ⎠ = 39.25 MeV Binding energy 39.25 MeV = = 5.607 MeV/nucleon nucleon 7 nucleons

(b)

195 78 Pt

consists of 78 protons and 117 neutrons. We find the binding energy as in part (a).

( )

Binding energy = ⎡78m 11 H + 117 m ⎣

( n) − m( 1 0

195 78 Pt

)⎤⎦ c

2

⎛ 931.5 MeV/c 2 = [78(1.007825 u) + 117(1.008665 u) − (194.964792 u)]c 2 ⎜ ⎜ u ⎝

⎞ ⎟⎟ ⎠

= 1545.7 MeV ≈ 1546 MeV Binding energy 1545.7 MeV = = 7.927 MeV/nucleon nucleon 195 nucleons

19.

23 11 Na

consists of 11 protons and 12 neutrons. We find the binding energy from the masses.

( )

Binding energy = ⎡11m 11 H + 12m ⎣

( n) − m( 1 0

23 11 Na

)⎤⎦ c

2

⎛ 931.5 MeV/c 2 ⎞ = [11(1.007825 u) + 12(1.008665 u) − (22.989769 u)]c 2 ⎜ ⎟⎟ ⎜ u ⎝ ⎠ = 186.6 MeV Binding energy 186.6 MeV = = 8.113 MeV/nucleon nucleon 23

We do a similar calculation for

24 11 Na,

( )

consisting of 11 protons and 13 neutrons.

Binding energy = ⎡11m 11 H + 13m ⎣

( n) − m( 1 0

24 11 Na

)⎤⎦ c

2

⎛ 931.5 MeV/c 2 ⎞ = [11(1.007825 u) + 13(1.008665 u) − (23.990963 u)]c 2 ⎜ ⎟⎟ ⎜ u ⎝ ⎠ = 193.5 MeV Binding energy 193.5 MeV = = 8.063 MeV/nucleon nucleon 24 © Copyright 2014 Pearson Education, Inc. All rights reserved. This material is protected under all copyright laws as they currently exist. No portion of this material may be reproduced, in any form or by any means, without permission in writing from the publisher.

Nuclear Physics and Radioactivity

By this measure, the nucleons in 23 11 Na

20.

to be more stable than

23 11 Na

are more tightly bound than those in

24 11 Na.

30-11

Thus we expect

24 11 Na.

We find the required energy by calculating the difference in the masses. (a) Removal of a proton creates an isotope of carbon. To balance electrons, the proton is included as a hydrogen atom:

15 7N

→ 11H + 146 C.

Energy needed = ⎡ m ⎣

( 146 C ) + m ( 11 H ) − m ( 157 N )⎦⎤ c2

⎛ 931.5 MeV/c 2 = [(14.003242 u) + (1.007825 u) − (15.000109 u)] ⎜ ⎜ u ⎝ = 10.21 MeV

(b)

Removal of a neutron creates another isotope of nitrogen: Energy needed = ⎡ m ⎣

15 7N

( N ) + m ( n ) − m ( N )⎤⎦ c 14 7

1 0

15 7



⎞ ⎟⎟ ⎠

1 14 0 n + 7 N.

2

⎛ 931.5 MeV/c 2 = [(14.003074 u) + (1.008665 u) − (15.000109 u)] ⎜ ⎜ u ⎝ = 10.83 MeV

⎞ ⎟⎟ ⎠

The nucleons are held by the attractive strong nuclear force. It takes less energy to remove the proton because there is also the repulsive electric force from the other protons. 21.

(a)

We find the binding energy from the masses. Binding energy = ⎡ 2m ⎣

(

4 2 He

) − m ( Be )⎤⎦ c 8 4

2

⎛ 931.5 MeV/c 2 = [2(4.002603 u) − (8.005305 u)]c 2 ⎜ ⎜ u ⎝ = −0.092 MeV

⎞ ⎟⎟ ⎠

Because the binding energy is negative, the nucleus is unstable. It will be in a lower energy state as two alphas instead of a beryllium. (b)

We find the binding energy from the masses. Binding energy = ⎡3m ⎣

(

4 2 He

) − m ( C)⎤⎦ c 12 6

2

⎛ 931.5 MeV/c 2 = [3(4.002603 u) − (12.000000 u)]c 2 ⎜ ⎜ u ⎝

⎞ ⎟⎟ = +7.3 MeV ⎠

Because the binding energy is positive, the nucleus is stable. 22.

The wavelength is determined from the energy change between the states. ΔE = hf = h

c

λ

→ λ=

hc (6.63 × 10−34 J ⋅ s)(3.00 × 108 m/s) = = 2.6 × 10−12 m ΔE (0.48 MeV)(1.60 × 10−13 J/MeV)

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30-12

23.

Chapter 30

For the decay 116 C → 105 B + 11 p, we find the difference of the initial and the final masses. We use hydrogen so that the electrons are balanced. Δm = m

( C) − m ( B) − m ( H ) 11 6

10 5

1 1

= (11.011434 u) − (10.012937 u) − (1.007825 u) = −0.009328 u

Since the final masses are more than the original mass, energy would not be conserved. 24.

The decay is 13H →

3 0 2 He + −1 e + v .

When we add one electron to both sides to use atomic masses, we

see that the mass of the emitted β particle is included in the atomic mass of 23 He. The energy released is the difference in the masses. Energy released = ⎡ m ⎣

( H) − m ( 3 1

3 2 He

)⎤⎦ c

2

⎛ 931.5 MeV/c 2 ⎞ = [(3.016049 u) − (3.016029 u)]c 2 ⎜ ⎟⎟ = 0.019 MeV ⎜ u ⎝ ⎠

25.

The decay is 01 n → 11 p + −01e + v . The electron mass is accounted for if we use the atomic mass of 11 H as a product. If we ignore the recoil of the proton and the neutrino, and any possible mass of the neutrino, then we get the maximum kinetic energy. KE max

= ⎡m ⎣

⎛ 931.5 MeV/c 2 ⎞ − m 11 H ⎤ c 2 = [(1.008665 u) − (1.007825 u)]c 2 ⎜ ⎟⎟ ⎜ ⎦ u ⎝ ⎠

( ) ( ) 1 0n

= 0.782 MeV

26.

For each decay, we find the difference of the final masses and the initial mass. If the final mass is more than the initial mass, then the decay is not possible. (a)

Δm = m

(

232 92 U

) + m( n) − m( 1 0

232 92 U

) = 232.037156 u + 1.008665 u − 233.039636 u = 0.006185 u

Because an increase in mass is required, the decay is not possible. (b)

Δm = m

( 137 N ) + m ( 01n ) − m ( 137 N ) = 13.005739 u + 1.008665 u − 14.003074 u = 0.011330 u

Because an increase in mass is required, the decay is not possible. (c)

Δm = m

( K) + m( n) − m( 39 19

1 0

40 19 K

) = 38.963706 u + 1.008665 u − 39.963998 u = 0.008373 u

Because an increase in mass is required, the decay is not possible. 27.

24 11Na

(a)

From Appendix B,

(b)

The decay reaction is

is a β − emitter .

24 11 Na



24 − 12 Mg + β

+ v . We add 11 electrons to both sides in order to

use atomic masses. Then the mass of the beta is accounted for in the mass of the magnesium. The maximum kinetic energy of the β − corresponds to the neutrino having no kinetic energy (a limiting case). We also ignore the recoil of the magnesium. © Copyright 2014 Pearson Education, Inc. All rights reserved. This material is protected under all copyright laws as they currently exist. No portion of this material may be reproduced, in any form or by any means, without permission in writing from the publisher.

Nuclear Physics and Radioactivity

KE

β−

= ⎡m ⎣

(

24 11 Na

) − m(

24 12 Mg

)⎤⎦ c

30-13

2

⎛ 931.5 MeV/c 2 ⎞ = [(23.990963 u) − (23.985042 u)]c 2 ⎜ ⎟⎟ = 5.515 MeV ⎜ u ⎝ ⎠

28.

(a)

We find the final nucleus by balancing the mass and charge numbers. Z ( X ) = Z (U) − Z (He) = 92 − 2 = 90 A( X ) = A(U) − A(He) = 238 − 4 = 234 234 90 Th

Thus the final nucleus is (b)

.

If we ignore the recoil of the thorium, then the kinetic energy of the α particle is equal to the difference in the mass energies of the components of the reaction. The electrons are balanced.

( 23892 U ) − m ( 23490Th ) − m ( 24 He )⎤⎦ c2 KE 238 4 m ( 234 90Th ) = m ( 92 U ) − m ( 2 He ) − 2 c KE

= ⎡m ⎣



⎡ 4.20 MeV ⎛ 1u = ⎢ 238.050788 u − 4.002603 u − ⎜⎜ 2 c 931 5 . MeV/c 2 ⎝ ⎣⎢

⎞⎤ ⎟⎟ ⎥ ⎠ ⎦⎥

= 234.043676 u

This answer assumes that the 4.20-MeV value does not limit the significant figures of the answer. 29.

60 − − The reaction is 60 27 Co → 28 Ni + β + v . The kinetic energy of the β will be maximum if the (essentially) massless neutrino has no kinetic energy. We also ignore the recoil of the nickel. KE β

= ⎡m ⎣

(

60 27 Co

) − m(

60 28 Ni

)⎤⎦ c

2

⎛ 931.5 MeV/c 2 = [(59.933816 u) − (59.930786 u)]c 2 ⎜ ⎜ u ⎝

30.

We add three electron masses to each side of the reaction 74 Be +

⎞ ⎟⎟ = 2.822 MeV ⎠

0 −1 e

→ 37 Li + v. Then for the mass of

the product side, we may use the atomic mass of 37 Li. For the reactant side, including the three electron masses and the mass of the emitted electron, we may use the atomic mass of 74 Be. The energy released is the Q-value. Q = ⎡m ⎣

( Be ) − m ( Li )⎤⎦ c 7 4

7 3

2

⎛ 931.5 MeV/c 2 = [(7.016929 u) − (7.016003 u)]c 2 ⎜ ⎜ u ⎝

⎞ ⎟⎟ = 0.863 MeV ⎠

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30-14

31.

Chapter 30

For alpha decay we have Q = ⎡m ⎣

218 84 Po



214 4 82 Pb + 2 He.

We find the Q-value, which is the energy released.

( 21884 Po ) − m ( 21482 Pb ) − m ( 24 He )⎤⎦ c2

⎛ 931.5 MeV/c 2 ⎞ = [218.008973 u − 213.999806 u − 4.002603 u]c 2 ⎜ ⎟⎟ ⎜ u ⎝ ⎠ = 6.114 MeV 218 0 For beta decay we have 218 84 Po → 82 At + −1 e + v . We assume that the neutrino is massless, and find the Q-value. The original 84 electrons plus the extra electron created in the beta decay means that there are 85 total electrons on the right side of the reaction, so we can use the mass of the astatine atom and “automatically” include the mass of the beta decay electron.

Q = ⎡m ⎣

(

218 84 Po

) − m(

218 85 At

)⎤⎦ c

2

⎛ 931.5 MeV/c 2 = [218.008973 u − 218.008695 u]c 2 ⎜ ⎜ u ⎝

32.

(a)

⎞ ⎟⎟ = 0.259 MeV ⎠

We find the final nucleus by balancing the mass and charge numbers. Z ( X ) = Z (P) − Z (e) = 15 − (−1) = 16 A( X ) = A(P) − A(e) = 32 − 0 = 32

Thus the final nucleus is (b)

32 16 S .

If we ignore the recoil of the sulfur and the energy of the neutrino, then the maximum kinetic 32 − energy of the electron is the Q-value of the reaction. The reaction is 32 15 P → 16 S + β + v . We add 15 electrons to each side of the reaction, and then we may use atomic masses. The mass of the emitted beta is accounted for in the mass of the sulfur. KE

m

33.

= ⎡m ⎣

( P ) − m ( S)⎤⎦ c 32 15

32 16

( S) = m ( P ) − c 32 16

32 15

KE 2

2



⎡ ⎤ 1.71 MeV 1u = ⎢ (31.973908 u) − ⎥ = 31.97207 u c2 931.5 MeV/c 2 ⎦⎥ ⎣⎢

We find the energy from the wavelength. E=

hc

λ

=

(6.63 × 10−34 J ⋅ s)(3.00 × 108 m/s) (1.15 × 10−13 m)(1.602 × 10−13 J/MeV)

= 10.8 MeV

This has to be a γ ray from the nucleus rather than a photon from the atom. Electron transitions do not involve this much energy. Electron transitions involve energies on the order of a few eV. 34.

The emitted photon and the recoiling nucleus have the same magnitude of momentum. We find the recoil energy from the momentum. We assume that the energy is small enough that we can use classical relationships.

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Nuclear Physics and Radioactivity

pγ = KE K

35.

Eγ c =

= pK = 2mK KE K Eγ2

2mK c 2

=

30-15



(1.46 MeV) 2 = 2.86 × 10−5 MeV = 28.6 eV 2 ⎛ 931.5 MeV/c ⎞ 2 2(39.963998 u) ⎜ ⎟⎟ c ⎜ u ⎝ ⎠

The kinetic energy of the β + particle will be its maximum if the (almost massless) neutrino has no kinetic energy. We ignore the recoil of the boron. Note that if the mass of one electron is added to the mass of the boron, then we may use atomic masses. We also must include the mass of the β + . (See Problem 36 for details.)

( 115 B + −01e ) + 10β + + v 11 11 0 0 + 2 11 11 0 2 KE = ⎡ m ( 6 C ) − m ( 5 B ) − m ( −1 e ) − m ( 1 β ) ⎤ c = ⎡ m ( 6 C ) − m ( 5 B ) − 2m ( −1 e ) ⎤ c ⎣ ⎦ ⎣ ⎦

11 6C



⎛ 931.5 MeV/c 2 ⎞ = [(11.011434 u) − (11.009305 u) − 2(0.00054858 u)]c 2 ⎜ ⎟⎟ = 0.9612 MeV ⎜ u ⎝ ⎠

If the β + has no kinetic energy, then the maximum kinetic energy of the neutrino is also 0.9612 MeV . The minimum energy of each is 0, when the other has the maximum. 36.

For the positron emission process, ZA N → Z −A1 N′ + e + + v. We must add Z electrons to the nuclear mass of N to be able to use the atomic mass, so we must also add Z electrons to the reactant side. On the reactant side, we use Z − 1 electrons to be able to use the atomic mass of N′. Thus we have 1 “extra” electron mass and the β particle mass, which means that we must include 2 electron masses on the right-hand side. We find the Q-value given this constraint. Q = [ M P − ( M D + 2me )]c 2 = ( M P − M D − 2me )c 2

37.

We assume that the energies are low enough that we may use classical kinematics. In particular, we will use p = 2m KE . The decay is

238 92 U



234 4 90Th + 2 He.

If the uranium nucleus is at rest when it

decays, then the magnitude of the momentum of the two daughter particles must be the same. pα = pTh ;

KE Th

=

p 2 2m K m pTh 2 = α = α α = α 2mTh 2mTh 2mTh mTh

KEα

⎛ 4u ⎞ =⎜ ⎟ (4.20 MeV) = 0.0718 MeV ⎝ 234 u ⎠

The Q-value is the total kinetic energy produced.

Q = KEα + KE Th = 4.20 MeV + 0.0718 MeV = 4.27 MeV

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30-16

38.

Chapter 30

(a)

The decay constant can be found from the half-life, using Eq. 30–6.

λ= (b)

ln 2 ln 2 = = 1.5 × 10−10 yr −1 = 4.9 × 10−18 s −1 T1/2 4.5 × 109 yr

The half-life can be found from the decay constant, using Eq. 30–6. ln 2

T1/2 = 39.

λ

ln 2 3.2 × 10−5 s −1

= 21, 660 s = 6.0 h

We find the half-life from Eq. 30–5 and Eq. 30–6. 2

R = R0 e− λt = R0 e

40.

=

ln 2 t T1/ 2

→ T1/2 = −

ln 2 ln 2 (3.6 h) = 1.2 h t=− 140 R ln ln 1120 R0

We use Eq. 30–4 and Eq. 30–6 to find the fraction remaining. ln 2

N = N0 e

− λt



⎡ (ln 2)(2.5 yr)(12 mo/yr) ⎤ ⎥ 9 mo ⎦

−⎢ t − N = e −λt = e T1/ 2 = e ⎣ N0

= 0.0992 ≈ 0.1 ≈ 10%

Only 1 significant figure was kept since the Problem said “about” 9 months. 41.

The activity at a given time is given by Eq. 30–3b. We also use Eq. 30–6. The half-life is found in Appendix B. dN ln 2 ln 2 N= (6.5 ×1020 nuclei) = 2.5 ×109 decays/s = λN = 7 dt T1/2 (5730 yr)(3.16 × 10 s/yr)

42.

For every half-life, the sample is multiplied by one-half. N = N0

43.

( 12 ) = ( 12 ) n

5

= 0.03125 = 1/32 = 3.125%

We need the decay constant and the initial number of nuclei. The half-life is found in Appendix B. Use Eq. 30–6 to find the decay constant.

λ=

ln 2 ln 2 = = 9.99668 × 10−7 s −1 T1/2 (8.0252 days)(24 h/day)(3600 s/h)

⎡ (782 × 10−6 g) ⎤ 23 18 N0 = ⎢ ⎥ (6.02 × 10 atoms/mol) = 3.5962 × 10 nuclei (130.906 g/mol) ⎣⎢ ⎦⎥

(a)

We use Eq. 30–3b and Eq. 30–4 to evaluate the initial activity. Activity = λ N = λ N 0 e− λt = (9.99668 × 10−7 s −1 )(3.5962 × 1018 )e−0 = 3.5950 ×1012 decays/s ≈ 3.60 × 1012 decays/s

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Nuclear Physics and Radioactivity

(b)

30-17

We evaluate Eq. 30–5 at t = 1.5 h. R = R0 e

−λt

12

= (3.5950 ×10

⎛ 3600 s ⎞ − (9.99668 × 10−7 s −1 )(1.5 h)⎜ ⎟ ⎝ h ⎠ decays/s)e

≈ 3.58 × 1012 decays/s

(c)

We evaluate Eq. 30–5 at t = 3.0 months. We use a time of 1/4 year for the 3.0 months. R = R0 e− λt = (3.5950 ×1012 decays/s)e−(9.99668 × 10

−7

s −1 )(0.25yr)(3.156×107 s/yr)

= 1.3497 decays/s ≈ 1.34 × 109 decays/s

44.

We find the number of nuclei from the activity of the sample, using Eq. 30–3b and Eq. 30–6. The halflife is found in Appendix B. ΔN ln 2 N = λN = T1/2 Δt N=

45.



T1/2 ΔN (4.468 × 109 yr)(3.156 × 107 s/yr) = (420 decays/s) = 8.5 × 1019 nuclei ln 2 Δt ln 2

Each α emission decreases the mass number by 4 and the atomic number by 2. The mass number changes from 235 to 207, a change of 28. Thus there must be 7 α particles emitted. With the 7 α emissions, the atomic number would have changed from 92 to 78. Each β − emission increases the atomic number by 1, so to have a final atomic number of 82, there must be 4 β − particles emitted.

46.

We use the decay constant often, so we calculate it here: λ = (a)

We find the initial number of nuclei from an estimate of the atomic mass. N0 =

(b)

(8.7 × 10−6 g) (6.02 × 1023 atoms/mol) = 4.223 × 1016 ≈ 4.2 ×1016 nuclei (124 g/mol)

Evaluate Eq. 30–4 at t = 2.6 min . N = N 0 e− λt = (4.223 × 1016 )e −(0.022505 s

(c)

ln 2 ln 2 = = 0.022505 s −1. T1/2 30.8 s

−1

)(2.6 min)(60 s/ min)

= 1.262 × 1015 ≈ 1.3 ×1015 nuclei

The activity is found from using the absolute value of Eq. 30–3b.

λ N = (0.022505 s −1 )(1.262 × 1015 ) = 2.840 ×1013 decays/s ≈ 2.8 ×1013 decays/s (d)

We find the time from Eq. 30–4.

λ N = λ N 0 e − λt



⎡ ⎤ 1 decay/s ⎛ λN ⎞ ln ⎢ ln ⎜ ⎥ ⎟ −1 16 λ N0 ⎠ ⎢ (0.022505 s )(4.223 ×10 ) decays/s ⎦⎥ ⎝ ⎣ t=− =− = 1532 s ≈ 26 min λ 0.022505 s −1 © Copyright 2014 Pearson Education, Inc. All rights reserved. This material is protected under all copyright laws as they currently exist. No portion of this material may be reproduced, in any form or by any means, without permission in writing from the publisher.

30-18

47.

Chapter 30

Find the initial number of nuclei from the initial decay rate (activity) and then the mass from the number of nuclei. ln 2 N0 → initial decay rate = 2.0 × 105 decays/s = λ N 0 = T1/2 N0 =

T1/2 (1.248 × 109 yr)(3.156 × 107 s/yr) (2.4 × 105 s −1 ) = (2.4 ×105 s −1 ) = 1.364 × 1022 nuclei ln 2 ln 2

m = N0

48.

(atomic weight) g/mol 6.02 × 10

23

nuclei/mol

= (1.364 × 1022 nuclei)

(39.963998 g) (6.02 × 1023 )

= 0.91 g

The number of nuclei is found from the mass and the atomic weight. The activity is then found from the number of nuclei and the half-life. ⎡ (6.7 × 10−6 g) ⎤ 23 17 N=⎢ ⎥ (6.02 × 10 atoms/mol) = 1.261× 10 nuclei ⎢⎣ (31.9739 g/mol) ⎥⎦

λN = 49.

(a)

⎡ ⎤ ln 2 ln 2 17 10 N=⎢ ⎥ (1.261× 10 ) = 7.1× 10 decays/s 6 T1/2 ⎢⎣ (1.23 × 10 s) ⎦⎥

The decay constant is found from Eq. 30–6.

λ= (b)

ln 2 ln 2 = = 1.381× 10−13 s −1 ≈ 1.38 ×10−13 s −1 T1/2 (1.59 × 105 yr)(3.156 × 107 s/yr)

The activity is the decay constant times the number of nuclei. ⎛ 60 s ⎞ ⎟ ⎝ 1 min ⎠

λ N = (1.381× 10−13 s −1 )(4.50 × 1018 ) = 6.215 × 105 decays/s ⎜ = 3.73 ×107 decays/ min

50.

We use Eq. 30–5. R = 16 R0 = R0 e − λt T1/2 = 2

51.

ln 2 ln

( ) 1 6

t=−

→ ln 2 ln

( 16 )

1 6

= e − λt

→ ln

( 16 ) = −λt = 2 Tln 2 t



1/2

(9.4 min) = 3.6 min

Because the fraction of atoms that are 146 C is so small, we use the atomic weight of number of carbon atoms in the sample. The activity is found from Eq. 30–3b. ⎛ 1.3 N 14 C = ⎜ 12 6 ⎝ 10

λN =

12 6C

to find the

⎞ ⎛ 1.3 ⎞ ⎡ (345 g) ⎤ 23 13 ⎟ N 126 C = ⎜ 12 ⎟ ⎢ (12 g/mol) ⎥ (6.02 × 10 nuclei/mol) = 2.250 × 10 nuclei 10 ⎠ ⎝ ⎠⎣ ⎦

⎡ ⎤ ln 2 ln 2 13 N=⎢ ⎥ (2.250 × 10 ) = 86 decays/s 7 T1/2 ⎣⎢ (5730 yr)(3.156 × 10 s/yr) ⎦⎥

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Nuclear Physics and Radioactivity

52.

30-19

We first find the number of nuclei from the activity and then find the mass from the number of nuclei and the atomic weight. The half-life is found in Appendix B. ln 2 N = 4.20 × 102 decays/s → Activity = λ N = T1/2 N=

(4.468 × 109 yr)(3.156 × 107 s/yr)(4.20 × 102 decays/s) = 8.544 × 1019 nuclei ln 2

⎡ (8.544 × 1019 nuclei) ⎤ −2 m=⎢ ⎥ (238.05 g/mol) = 3.38 × 10 g = 33.8 mg 23 ⎣⎢ (6.02 × 10 atoms/mol) ⎦⎥

53.

We assume that the elapsed time is much smaller than the half-life, so we can approximate the decay rate as being constant. We also assume that the 87 37 Rb

rocks were formed. Thus every atom of NSr = −ΔN Rb = λ N Rb Δt

→ Δt =

87 38 Sr

is stable, and there was none present when the

that decayed is now an atom of

87 38 Sr.

NSr T1/2 4.75 × 1010 yr = (0.0260) = 1.78 ×109 yr N Rb ln 2 ln 2

This is ≈ 4% of the half-life, so our original assumption is valid. 54.

We are not including the neutrinos that will be emitted during beta decay. First sequence:

232 90Th



228 88 Ra

+ 42α ;

228 90Th



224 88 Ra

+ 42α ;

235 92 U

Second sequence:

227 89 Ac

55.

231 90Th



+ 42α ;

227 90Th



Because the fraction of atoms that are



224 88 Ra 231 90Th

+ β −;

14 6C

228 88 Ra



227 90Th



228 89 Ac



+ β −;

220 86 Rn

231 91 Pa



228 90Th

+ β −;

+ 24α

+ β −;

223 88 Ra

228 89 Ac

231 91 Pa



227 89 Ac

+ 24α ;

+ 42α

is so small, we use the atomic weight of

12 6C 14 6C

to find the

number of carbon atoms in 73 g. We then use the given ratio to find the number of atoms present when the club was made. Finally, we use the activity as given in Eq. 30–5 to find the age of the club. ⎡ (73 g) ⎤ 23 24 N 12 C = ⎢ ⎥ (6.02 × 10 atoms/mol) = 3.662 × 10 atoms 6 (12 g/mol) ⎣ ⎦ N 14 C = (1.3 ×10−12 )(3.662 × 1024 ) = 4.761× 1012 nuclei 6

(λ N C ) 14 6

t=−

=−

1

λ

today

ln

(

= λ N 14 C 6

(λ N C ) (λ N C ) 14 6

)e

today

14 6

0

− λt

0

=−



(

)

λ N 14 C 6 T1/2 today ln ln 2 ⎛ ln 2 ⎞ N 14 C ⎟ ⎜ ⎝ T1/2 6 ⎠0

5730 yr (7.0 decays/s) ln = 7921 yr ≈ 7900 yr ln 2 ⎡ ⎤ ln 2 12 (4.761× 10 nuclei) ⎥ ⎢ 7 ⎢⎣ (5730 yr)(3.156 × 10 s/yr) ⎥⎦ 0

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30-20

56.

Chapter 30

The decay rate is given by Eq. 30–3b,

α emission.

ΔN = −λ N . We assume equal numbers of nuclei decaying by Δt

⎛ ΔN ⎞ T1/2 ⎜ ⎟ (1.6 × 10−4 s) 214 ⎝ Δt ⎠218 −λ218 N 218 λ218 = = = = = 8.6 × 10−7 N Δ −λ214 N 214 λ214 T1/2 (3.1 min)(60 s/ min) ⎛ ⎞ ⎜ ⎟ 218 ⎝ Δt ⎠ 214

57.

The activity is given by Eq. 30–5. The original activity is λ N 0 , so the activity 31.0 hours later is 0.945λ N 0 . 0.945λ N 0 = λ N 0 e−λt T1/2 = −

58.

→ ln 0.945 = −λ t = −

⎛ 1d ⎞ ln 2 (31.0 h) = 379.84 h ⎜ ⎟ = 15.8 d ln 0.945 ⎝ 24 h ⎠

The activity is given by Eq. 30–5.

1

T R R 53 d ⎛ 25 decays/s ⎞ 2 = − 1/2 ln =− ⎜ ln ⎟ = 201.79 d ≈ 2.0 ×10 d R0 ln 2 R0 ln 2 ⎝ 350 decays/s ⎠

(a)

R = R0e−λt

(b)

We find the mass from the activity. Note that N A is used to represent Avogadro’s number, and A is the atomic weight.

→ t=−

λ

ln

R0 = λ N 0 = m=

59.

ln 2 t → T1/2

ln 2 m0 N A T1/2 A



R0T1/2 A (350 decays/s)(53 d)(86, 400 s/d)(7.017 g/mole) = = 2.7 × 10−14 g N A ln 2 (6.02 × 1023 nuclei/mole) ln 2

The number of radioactive nuclei decreases exponentially, and every radioactive nucleus that decays becomes a daughter nucleus. N = N 0 e−λt ; N D = N 0 − N = N 0 (1 − e−λt )

60.

The activity is given by Eq. 30–5, with R = 0.01050 R0 . R = R0 e−λt

→ λ=−

ln R /R0 ln 2 = t T1/2

→ T1/2 = −

From Appendix B we see that the isotope is 61.

t ln 2 (4.00 h) ln 2 =− = 0.6085 h = 36.5 min ln R /R0 ln 0.01050

211 82 Pb .

Because the carbon is being replenished in living trees, we assume that the amount of 146 C is constant until the wood is cut, and then it decays. Use Eq. 30–4 and Eq. 30–7 to find the age of the tool. N = N0e

−λt

= N0e



0.693t T1/ 2

= 0.045 N 0

→ t=−

T1/2 ln(0.045) (5730 yr) ln (0.045) =− = 2.6 × 104 yr 0.693 0.693

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Nuclear Physics and Radioactivity

62.

(a)

The mass number is found from the radius, using Eq. 30–1. 3

r = (1.2 × 10

(b)

30-21

−15

1/3

m) A

3

⎛ ⎞ ⎛ 5000 m ⎞ r = = 7.23 × 1055 ≈ 7 × 1055 A=⎜ ⎜ 1.2 × 10−15 m ⎟⎟ ⎜⎜ 1.2 × 10−15 m ⎟⎟ ⎝ ⎠ ⎝ ⎠



The mass of the neutron star is the mass number times the atomic mass unit conversion in kg. m = A(1.66 × 10−27 kg/u) = (7.23 × 1055 u)(1.66 × 10−27 kg/u) = 1.20 × 1029 kg ≈ 1× 1029 kg

Note that this is about 6% of the mass of the Sun. (c)

The acceleration of gravity on the surface of the neutron star is found from Eq. 5–5 applied to the neutron star. g=

63.

Gm r2

=

(6.67 × 10−11 N ⋅ m 2 /kg 2 )(1.20 × 1029 kg) (5000 m) 2

Because the tritium in water is being replenished, we assume that the amount is constant until the wine is made, and then it decays. We use Eq. 30–4.

N = N 0 e − λt

64.

= 3.20 × 1011 m/s 2 ≈ 3 × 1011 m/s 2

(a)

ln → λ=−

N N 0 ln 2 = t T1/2

→ t=−

T1/2 N (12.3 yr) ln 0.10 =− = 41 yr ln ln 2 N 0 ln 2

We assume a mass of 70 kg of water and find the number of protons, given that there are 10 protons in a water molecule. ⎡ (70 × 103 g water) ⎤ ⎛ ⎞ 23 molecules water ⎞⎛ 10 protons N protons = ⎢ ⎥ ⎜ 6.02 × 10 ⎟⎜ ⎟ (18 g water/mol water) mol water water molecule ⎠⎝ ⎠ ⎣⎢ ⎦⎥ ⎝

= 2.34 × 1028 protons

We assume that the time is much less than the half-life so that the rate of decay is constant. ⎛ ln 2 ⎞ ΔN = λN = ⎜ ⎟N Δt ⎝ T1/2 ⎠

Δt =



⎛ 1033 yr ⎞ ΔN ⎛ T1/2 ⎞ 1 proton 4 ⎜⎜ ⎟⎟ = 6.165 × 10 yr ≈ 60, 000 yr ⎜ ⎟= 28 N ⎝ ln 2 ⎠ 2.34 × 10 protons ⎝ ln 2 ⎠

This is about 880 times a normal life expectancy. (b)

Instead of waiting 61,650 consecutive years for one person to experience a proton decay, we could interpret that number as there being 880 people, each living 70 years, to make that 61,650 years (since 880 × 70 ≈ 61, 650). We would then expect one person out of every 880 to experience a proton decay during their lifetime. Divide 7 billion by 880 to find out how many people on Earth would experience proton decay during their lifetime. 7 × 109 = 7.95 × 106 ≈ 8 million people 880

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30-22

65.

Chapter 30

We assume that all of the kinetic energy of the alpha particle becomes electrostatic potential energy at the distance of closest approach. Note that the distance found is the distance from the center of the alpha to the center of the gold nucleus. KE i

+ PE i = KE f + PE f

r=k

Qα QAu KEα



KEα

+0 = 0+k

= (8.988 × 109 N ⋅ m 2 /C2 )

Qα QAu r



(2)(79)(1.60 × 10−19 C) 2 (7.7 MeV)(1.60 × 10

−13

J/MeV)

= 2.951× 10−14 m

≈ 3.0 × 10−14 m

We use Eq. 30–1 to compare to the size of the gold nucleus. rapproach

=

rAu

2.951× 10−14 m 1971/3 (1.2 × 10−15 m)

= 4.2

So the distance of approach is about 4.2 × the radius of the gold nucleus. 66.

Use Eq. 30–5 and Eq. 30–6. R = R0 e

− λt

= R0 e



t ln 2 T1/ 2

= 0.0200 R0



t ln (0.0200) =− = 5.64 ln 2 T1/2

It takes 5.64 half-lives for a sample to drop to 2.00% of its original activity. 67.

The number of 40 19 K nuclei can be calculated from the activity, using Eq. 30–3b and Eq. 30–5. The half-life is found in Appendix B. A subscript is used on the variable N to indicate the isotope.

R = λ N 40

→ N 40

The mass of

40 19 K

⎛ 3.156 × 107 ⎛ decays ⎞ 9 42 (1.248 10 yr) × ⎜⎜ ⎜ ⎟ s ⎠ 1 yr R RT1/2 ⎝ ⎝ = = = ln 2 ln 2 λ

s⎞ ⎟⎟ ⎠ = 2.387 × 1018 nuclei

in the milk is found from the atomic mass and the number of nuclei.

m40 = (2.387 × 1018 )(39.964 u)(1.66 × 10−27 kg/u) = 1.583 × 10−7 kg ≈ 0.16 mg

From Appendix B, in a natural sample of potassium, 0.0117% is number of

39 19 K

40 19 K

and 93.2581% is

nuclei and then use the atomic mass to find the mass of

N 40 = (0.0117%) N total ; N 39 = (93.2581%) N total

39 19 K

39 19 K.

Find the

in the milk.



⎡ (93.2581%) ⎤ ⎡ (93.2581%) ⎤ 18 22 N39 = ⎢ ⎥ N 40 = ⎢ (0.0117%) ⎥ (2.387 ×10 nuclei) = 1.903 × 10 nuclei (0.0117%) ⎣ ⎦ ⎣ ⎦

The mass of

39 19 K

is the number of nuclei times the atomic mass.

m39 = (1.903 × 1022 )(38.964 u)(1.66 × 10−27 kg/u) = 1.231× 10−3 kg ≈ 1.2 g

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Nuclear Physics and Radioactivity

68.

30-23

In the Periodic Table, Sr is in the same column as Ca. If Sr is ingested, then the body may treat it chemically as if it were Ca, which means it might be stored by the body in bones. Use Eq. 30–4 to find the time to reach a 1% level. ln

N = N 0 e − λt

→ λ=−

N N0 ln 2 T (29 yr) ln 0.01 N = → t = 2 1/2 ln =− = 192.67 yr ≈ 200 yr ln 2 N0 ln 2 t T1/2

Assume that both the Sr and its daughter undergo beta decay, since the Sr has too many neutrons. 90 38 Sr

69.



90 0 39 Y + −1 e + ν

;

90 39 Y



90 0 40 Zr + −1 e + ν

The number of nuclei is found from Eq. 30–5 and Eq. 30–3b. The mass is then found from the number of nuclei and the atomic weight. The half-life is given. R = λN =

ln 2 N T1/2

→ N=

T1/2 T R; m = N (atomic weight) = 1/2 R (atomic weight) ln 2 ln 2

⎛ 24 h ⎞⎛ 3600 s ⎞ (87.37 d) ⎜ ⎟⎜ ⎟ 1 d ⎠⎝ 1 h ⎠ ⎝ m= (4.28 × 104 decays/s)(34.969 u)(1.66 × 10−27 kg/u) ln 2 = 2.71× 10−14 kg = 2.71× 10−11 g

70.

(a)

We find the daughter nucleus by balancing the mass and charge numbers. Z ( X ) = Z (Os) − Z (e − ) = 76 − (−1) = 77 A( X ) = A(Os) − A(e − ) = 191 − 0 = 191

The daughter nucleus is

71.

191 77 Ir .

191 76 Os

β – (0.14 MeV) γ (0.042 MeV) γ (0.129 MeV)

191 77 Ir* 191 77 Ir*

(b)

See the diagram.

(c)

Because there is only one β energy, the β decay must be to the higher excited state.

(a)

The number of nuclei is found from the mass of the sample and the atomic mass. The activity is found from the half-life and the number of nuclei, using Eq. 30–3b and Eq. 30–5.

191 77 Ir

⎛ ⎞ 1.0 g 23 21 N =⎜ ⎟ (6.02 × 10 nuclei/mol) = 4.599 × 10 nuclei ⎝ 130.91 g/mol ⎠ ⎡ ⎤ 0.693 21 15 R = λN = ⎢ ⎥ (4.599 × 10 ) = 4.6 × 10 decays/s 4 × (8.02 d)(8.64 10 s/d) ⎣⎢ ⎦⎥

(b)

Follow the same procedure as in part (a). ⎛ ⎞ 1.0 g 23 21 N =⎜ ⎟ (6.02 × 10 nuclei/mol) = 2.529 × 10 nuclei 238.05 g/mol ⎝ ⎠ ⎡ ⎤ 0.693 21 4 R = λN = ⎢ ⎥ (2.529 × 10 ) = 1.2 × 10 decays/s 9 7 ⎣⎢ (4.47 × 10 yr)(3.16 × 10 s/yr) ⎦⎥

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30-24

72.

Chapter 30

From Fig. 30–1, the average binding energy per nucleon at A = 63 is ~8.6 MeV. Use the average atomic weight as the average number of nucleons for the two stable isotopes of copper to find the total binding energy for one copper atom. (63.5 nucleons)(8.6 MeV/nucleon) = 546.1 MeV ≈ 550 MeV

Convert the mass of the penny to a number of atoms and then use the above value to calculate the energy needed. Energy = (# atoms)(energy/atom) ⎡ (3.0 g) ⎤ 23 6 −19 =⎢ J/eV) ⎥ (6.02 × 10 atoms/mol)(546.1× 10 eV/atom)(1.60 × 10 (63.5 g/mol) ⎣ ⎦ = 2.5 × 1012 J

73.

(a)

Δ

( 42 He ) = m ( 42 He ) − A ( 42 He ) = 4.002603 u − 4 = 0.002603 u = (0.002603 u)(931.5 MeV/uc 2 ) = 2.425 MeV/c 2

(b)

Δ

( 126 C ) = m ( 126 C ) − A ( 126 C ) = 12.000000 u − 12 = 0

(c)

Δ

( 8638 Sr ) = m ( 8638 Sr ) − A ( 8638 Sr ) = 85.909261 u − 86 = −0.090739 u = (−0.090739 u)(931.5 MeV/uc 2 ) = −84.52 MeV/c 2

(d)

Δ

( 23592 U ) = m ( 23592 U ) − A ( 23592 U ) = 235.043930 u − 235 = 0.043930 u = (0.043930 u)(931.5 MeV/uc 2 ) = 40.92 MeV/c 2

(e)

From Appendix B, we see the following: Δ ≥ 0 for 0 ≤ Z ≤ 8 and Z ≥ 85; Δ < 0 for 9 ≤ Z ≤ 84

74.

Δ ≥ 0 for 0 ≤ A ≤ 15 and A ≥ 218; Δ < 0 for 16 ≤ A < 218

The reaction is 11 H + 01 n → 21 H. If we assume that the initial kinetic energies are small, then the energy of the gamma is the Q-value of the reaction.

( ) ( 01n ) − m ( 21H )⎤⎦ c2

Q = ⎡ m 11 H + m ⎣

= [(1.007825 u) + (1.008665 u) − (2.014102 u)]c 2 (931.5 MeV/uc 2 ) = 2.224 MeV

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Nuclear Physics and Radioactivity

75.

30-25

The mass of carbon 60,000 years ago was 1.0 kg. Find the number of carbon atoms at that time and then find the number of 146 C atoms at that time. Use that with the half-life to find the present activity, using Eq. 30–5 and Eq. 30–6. N=

(1.0 × 103 g)(6.02 × 1023 atoms/mol) = 5.017 × 1025 C atoms 12 g/mol

N14 = (5.017 × 1025 )(1.3 × 10−12 ) = 6.522 × 1013 nuclei of ln 2 ln 2 R = λN = N= N0e T1/2 T1/2

ln 2 t − T1/ 2

=

14 6C

= N0

ln 2

13

(5730 yr)(3.16 × 107 s/yr)

(6.522 × 10 )e



ln 2(60,000 yr) (5730 yr)

= 0.1759 decays/s ≈ 0.2 decays/s

76.

The energy to remove the neutron would be the difference in the masses of the 42 He and the combination of 32 He + n. It is also the opposite of the Q-value for the reaction. The number of electrons doesn’t change, so atomic masses can be used for the helium isotopes. ⎛ 931.5 MeV/c 2 −QHe = (mHe-3 + mn − mHe-4 )c 2 = (3.016029 u + 1.008665 u − 4.002603 u)c 2 ⎜ ⎜ u ⎝

⎞ ⎟⎟ ⎠

= 20.58 MeV

Repeat the calculation for the carbon isotopes. ⎛ 931.5 MeV/c 2 −QC = (mC-12 + mn − mC-13 )c 2 = (12.000000 u + 1.008665 u − 13.003355 u)c 2 ⎜ ⎜ u ⎝ = 4.946 MeV

⎞ ⎟⎟ ⎠

The helium value is 4.16 × greater than the carbon value. 77.

(a)

Take the mass of the Earth and divide it by the mass of a nucleon to find the number of nucleons. Then use Eq. 30–1 to find the radius. 1/3

⎡ 5.98 ×1024 kg ⎤ r = (1.2 × 10−15 m) A1/3 = (1.2 × 10−15 m) ⎢ ⎥ −27 kg ⎦⎥ ⎣⎢1.67 × 10

(b)

= 183.6 m ≈ 180 m

Follow the same process as above, but this time use the Sun’s mass. 1/3

r = (1.2 × 10

−15

1/3

m) A

= (1.2 × 10

−15

⎡ 1.99 × 1030 kg ⎤ m) ⎢ ⎥ −27 kg ⎥⎦ ⎢⎣1.67 × 10

= 12, 700 m ≈ 1.3 × 104 m

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30-26

78.

Chapter 30

(a)

14 −12 . 6 C is 1.3 × 10 weight of 126 C to find the

From Section 30–11, the usual fraction of

Because the fraction of atoms that

are 146 C is so small, use the atomic Use Eq. 30–4 to find the time.

number of carbon atoms in 72 g.

⎛ 72 g ⎞ 23 24 N12 = ⎜ ⎟ (6.02 × 10 atoms/mol) = 3.612 × 10 atoms ⎝ 12 g/mol ⎠ N14 = (3.612 × 1024 atoms)(1.3 ×10−12 ) = 4.6956 × 1012 atoms N = N 0 e−λt → t = −

(b)

1

λ

ln

T (5730 yr) 1 N N ln = − 1/2 ln =− = 2.4 × 105 yr ln 2 N 0 ln 2 N0 4.6956 × 1012

Do a similar calculation for an initial mass of 340 g. ⎛ 340 g ⎞ 23 −12 13 N14 = ⎜ ⎟ (6.02 × 10 atoms/mol)(1.3 × 10 ) = 2.217 × 10 atoms 12 g/mol ⎝ ⎠ T N N 1 (5730 yr) 1 N = N 0 e−λt → t = − ln = − 1/2 ln =− = 2.5 × 105 yr ln ln 2 N 0 ln 2 λ N0 2.217 × 1013

For times on the order of 105 yr, the sample amount has fairly little effect on the age determined. Thus, times of this magnitude are not accurately measured by carbon dating. 79.

(a) (b)

This reaction would turn the protons and electrons in atoms into neutrons. This would eliminate chemical reactions and thus eliminate life as we know it. We assume that there is no kinetic energy brought into the reaction and solve for the increase of mass necessary to make the reaction energetically possible. For calculating energies, we write the reaction as 11 H → 10 n + ν , and we assume that the neutrino has no mass or kinetic energy.

( ) ( )

Q = ⎡ m 11 H − m 10 n ⎤ c 2 = [(1.007825 u) − (1.008665 u)]c 2 (931.5 MeV/uc 2 ) ⎣ ⎦ = −0.782 MeV

This is the amount that the proton would have to increase in order to make this energetically possible. We find the percentage change. ⎡ (0.782 MeV/c 2 ) ⎤ ⎛ Δm ⎞ (100) = 0.083% ⎜ ⎟ (100) = ⎢ 2 ⎥ ⎝ m ⎠ ⎢⎣ (938.27 MeV/c ) ⎥⎦

80.

We assume that the particles are not relativistic, so that p = 2mKE . The radius is given in mυ . Set the radii of the two particles equal. Note that the charge of the alpha qB particle is twice that of the electron (in absolute value). We also use the “bare” alpha particle mass, subtracting the two electrons from the helium atomic mass.

Example 20–6 as r =

mα υα mβ υ β = 2eB eB

→ mα υα = 2mβ υ β



pα = 2 pβ

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Nuclear Physics and Radioactivity

KEα KE β

=

pα2 2mα 2



4 pβ2 =

2mβ

81.

30-27

2mα

=

2



4mβ mα

=

4(0.000549 u) = 5.48 × 10−4 4.002603 u − 2(0.000549 u)

2mβ

Natural samarium has an atomic mass of 150.36 grams per mole. We find the number of nuclei in the natural sample and then take 15% of that to find the number of of

147

147 62 Sm

nuclei. We first find the number

Sm nuclei from the mass and proportion information. (0.15)(1.00 g)(6.02 × 10 23 nuclei/mol) = 6.006 × 10 20 nuclei of 150.36 g/mol

N 147 Sm = (0.15) N natural = 62

147 62 Sm

The activity level is used to calculate the half-life. Activity = R = λ N = T1/2 =

82.

ln 2 N T1/2



ln 2 ln 2 (6.006 × 1020 ) = 3.469 × 1018 N= 120 decays/s R

⎛ 1 yr s⎜ ⎜ 3.156 × 107 ⎝

Since amounts are not specified, assume that “today” there is 0.720 g of 238 92 U.

100.000 − 0.720 = 99.280 g of

(a)

in our sample, and

Use Eq. 30–4.

Relate the amounts today to the amounts 1.0 ×109 years ago. N = N0e

−λt

→ N 0 = Ne

( N 0 ) 235 = ( N 235 )e ( N 0 ) 238 = ( N 238 )e

The percentage of (b)

235 92 U

⎞ 11 ⎟⎟ = 1.1× 10 yr s⎠

235 92 U

was

λt

t ln 2 T1/ 2 t ln 2 T1/ 2

= Ne

t ln 2 T1/ 2

= (0720 g)e

(1.0 × 109 yr) ln 2 (7.04 × 108 yr)

= 1.927 g

9

= (99.280 g)e

(1.0 × 10 ) ln 2 (4.468 × 109 )

= 115.94 g

1.927 × 100% = 1.63% . 1.927 + 115.94

Relate the amounts today to the amounts 100 × 106 years from now. N = N0e

−λt

→ ( N 235 ) = ( N 0 ) 235 e

( N 238 ) = ( N 0 )238 e

The percentage of



t T1/ 2

235 92 U

ln 2



t ln 2 T1/ 2

= (99.280 g)e

will be

= (0.720 g)e



(100 × 106 yr) ln 2 (7.04 × 108 yr)

(100 × 106 yr) − ln 2 (4.468 × 109 yr)

= 0.6525 g

= 97.752 g

0.6525 × 100% = 0.663% . 0.6525 + 97.752

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30-28

83.

Chapter 30

We determine the number of activity.

40 19 K

nuclei in the sample and then use the half-life to determine the

N 40 K = (0.000117) N naturally 19

occurring K

R = λN =

84.

= (0.000117)

(420 × 10−3 g)(6.02 × 1023 atoms/mol) = 7.566 × 1017 39.0983 g/mol

ln 2 ln 2 1 yr ⎛ ⎞ = 13.14 decays/s ≈ 13 decays/s N= (7.566 × 1017 ) ⎜ 9 7 ⎟ T1/2 1.265 × 10 yr ⎝ 3.156 × 10 s ⎠

The kinetic energy of the electron will be at its maximum if the (essentially) massless neutrino has no kinetic energy. We also ignore the recoil energy of the sodium. The maximum kinetic energy of the reaction is then the Q-value of the reaction. Note that the emitted electron mass is accounted for by using atomic masses. KE

= Q = ⎡m ⎣

(

23 10 Ne

) − m(

23 11 Na

)⎤⎦ c

2

= [(22.9947 u) − (22.9898 u)]c 2 (931.5 MeV/uc 2 )

= 4.6 MeV

If the neutrino were to have all of the kinetic energy, then the minimum kinetic energy of the electron is 0. The sum of the kinetic energy of the electron and the energy of the neutrino must be the Q-value, so the neutrino energies are 0 and 4.6 MeV, respectively. 85.

(a)

If the initial nucleus is at rest when it decays, then momentum conservation says that the magnitude of the momentum of the alpha particle will be equal to the magnitude of the momentum of the daughter particle. We use that to calculate the (nonrelativistic) kinetic energy of the daughter particle. The mass of each particle is essentially equal to its atomic mass number, in atomic mass units. Note that classically, p = 2mKE . pα = pD ;

KE D KEα

(b)

+ KE D

KE D

=

=

2m KE p2 m pD2 = α = α α = α 2mD 2mD 2mD mD 4 AD

KEα

⎡ 4 ⎢ KEα + A D ⎣

We specifically consider the decay of KE D KEα

+ KE D

=

1 1 + AD 1 4

=

KEα

226 88 Ra.

1 1+

⎤ ⎥ ⎦

1 (222) 4

=

⎡ AD ⎢ 4 ⎣

KEα KEα

KEα

⎤ + KEα ⎥ ⎦

=

=

Aα AD

KEα

=

4 AD

KEα

1 1 4

1 + AD

The daughter has AD = 222.

= 0.017699 ≈ 1.8%

Thus, the alpha particle carries away 1 − 0.0177 = 0.9823 = 98.2% . 86.

The mass number changes only with α decay, and it changes by − 4. If the mass number is 4n, then the new number is 4n − 4 = 4(n − 1) = 4n′. There is a similar result for each family, as shown here. 4n → 4n − 4 = 4(n − 1) = 4n′ 4n + 1 → 4n − 4 + 1 = 4(n − 1) + 1 = 4n′ + 1

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Nuclear Physics and Radioactivity

30-29

4n + 2 → 4n − 4 + 2 = 4(n − 1) + 2 = 4n′ + 2 4n + 3 → 4n − 4 + 3 = 4(n − 1) + 3 = 4n′ + 3

Thus, the daughter nuclides are always in the same family.

Solutions to Search and Learn Problems 1.

The nucleus of an atom consists of protons (which carry a positive electric charge) and neutrons (which are electrically neutral). The electric force between protons is repulsive and much larger than the force of gravity. If the electric and gravitational forces are the only two forces present in the nucleus, then the nucleus would be unstable, as the electric force would push the protons away from each other. Nuclei are stable; therefore, another force must be present in the nucleus to overcome the electric force. This force is the strong nuclear force.

2.

(a)

An einsteinium nucleus has 99 protons and a fermium nucleus has 100 protons. If the fermium undergoes either electron capture or β + decay, then a proton would in effect be converted into a neutron. The nucleus would now have 99 protons and be an einsteinium nucleus.

(b)

3.

If the einsteinium undergoes β − decay, then a neutron would be converted into a proton. The nucleus would now have 100 protons and be a fermium nucleus.

Take the momentum of the nucleon to be equal to the uncertainty in the momentum of the nucleon, as given by the uncertainty principle. The uncertainty in position is estimated as the radius of the nucleus. With that momentum, calculate the kinetic energy, using the classical formula. Iron has about 56 nucleons (depending on the isotope). ΔpΔx ≈ = → KE

=

p ≈ Δp ≈

= = = Δx r

=2 (1.055 × 10−34 J ⋅ s) 2 p2 = = 2m 2mr 2 2(1.67 × 10−27 kg) ⎡ (561/3 )(1.2 × 10−15 m) ⎤ 2 (1.60 × 10−13 J/MeV) ⎣ ⎦

= 0.988 MeV ≈ 1 MeV

4.

(a)

From Fig. 30–17, the initial force on the detected particle is down. Using the right-hand rule, the force on a positive particle would be upward. Thus the particle must be negative, and the decay is β − decay.

(b)

The magnetic force is producing circular motion. Set the expression for the magnetic force equal to the expression for centripetal force and solve for the velocity. qυ B =

5.

mυ 2 r

→ υ=

qBr (1.60 × 10−19 C)(0.012 T)(4.7 × 10−3 m) = = 9.9 × 106 m/s −31 m 9.11× 10 kg

In β decay, an electron is ejected from the nucleus of the atom, and a neutron is converted into a proton. The atomic number of the nucleus increases by one, and the element now has different chemical properties. In internal conversion, an orbital electron is ejected from the atom. This does not change either the atomic number of the nucleus or its chemical properties.

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30-30

Chapter 30

Also, in β decay, both a neutrino and an electron will be emitted from the nucleus. Because there are three decay products (the neutrino, the β particle, and the nucleus), the momentum of the β particle can have a range of values. In internal conversion, since there are only two decay products (the electron and the nucleus), the electron will have a unique momentum and, therefore, a unique energy. 6.

If the Earth had been bombarded with additional radiation several thousand years ago, then there would have been a larger abundance of carbon-14 in the atmosphere at that time. Organisms that died in that time period would have had a greater percentage of carbon-14 in them than organisms that die today. Since we assumed the amount of starting carbon-14 was the same, we would have previously underestimated the age of the organisms. With the new discovery, we would re-evaluate the organisms as older than previously calculated.

7.

(a)

The decay constant is calculated from the half-life using Eq. 30–6.

λ= (b)

ln 2 ln 2 = = 3.83 × 10−12 s −1 T1/2 (5730 yr)(3.156 × 107 s/yr)

In a living organism, the abundance of 146 C atoms is 1.3 × 10−12 per carbon atom. Multiply this abundance by Avogadro’s number and divide by the molar mass of carbon to find the number of carbon-14 atoms per gram of carbon. ⎛ N = ⎜ 1.3 × 10−12 ⎜ ⎝

14 6C 12 6C

atoms ⎞ N A ⎛ = ⎜ 1.3 × 10−12 ⎟ atoms ⎟⎠ M ⎜⎝

= 6.516 atoms 146 C/g

(c)

12 6C

14 6C 12 6C

atoms ⎞ (6.02 × 1023 atoms 126 C/mol) ⎟ atoms ⎟⎠ 12.0107 g 126 C/mol

≈ 6.5 × 1010 atoms 146 C/ g

12 6C

The activity in natural carbon for a living organism is the product of the decay constant and the number of

14 6C

atoms per gram of

12 6 C.

Use Eq. 30–5 and Eq. 30–3b.

R = λ N = (3.83 × 10−12 s −1 )(6.5 × 1010 atoms 146 C/g 126 C) = 0.249 decays/s/g 126 C ≈ 0.25 decays/s/g 126C

(d)

Take the above result as the initial decay rate (while Otzi was alive) and use Eq. 30–5 to find the time elapsed since he died. R = R0 e− λt t=−



⎛ R ⎞ 1 1 yr ⎛ 0.121 ⎞ 11 ⎛ ln ⎜ ⎟ = − ln 1.884 10 s⎜ = × ⎜ ⎟ 7 −12 −1 ⎜ 0.249 λ ⎝ R0 ⎠ ⎝ ⎠ 3.83 ×10 s ⎝ 3.156 × 10 1

⎞ ⎟ s ⎟⎠

= 5970 yr ≈ 6000 yr

Otzi lived approximately 6000 years ago. 8.

Use Eq. 30–5 and 30–3b to relate the activity to the half-life, along with the atomic weight. ΔN ln 2 = R = λN = N Δt T1/2 T1/2 =



⎛ 6.02 × 10 23 nuclei ⎞ ⎛ ln 2 ln 2 1 yr N= (1.5 × 107 g) ⎜ ⎟⎟ ⎜⎜ 7 ⎜ R 1 decay/s 152 g ⎝ ⎠ ⎝ 3.156 × 10

⎞ 21 ⎟⎟ = 1.3 × 10 yr s⎠

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