Material Safety Data Sheet
Issuing date 01-Jan-2013
Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Revision Date
Product name
PREVOX
Product code
F00394
Product Type
Extremely flammable aerosol
Recommended Use
Rust preventative
Kano Laboratories 1000 East Thompson Lane Nashville, TN 37211 Chemical Emergency Phone Number
DANGER!
Potential Health Effects Principle Routes of Exposure Acute toxicity Eyes Skin Inhalation Ingestion
Odor Solvent This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) Eye contact. Skin contact. Inhalation.
Irritating to eyes. Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. May cause frostbite. Irritating to respiratory system. Avoid breathing vapors or mists. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Not an expected route of exposure. Potential for aspiration if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Chronic Effects
No information available.
Aggravated Medical Conditions
Central nervous system. Preexisting eye disorders. Skin disorders. Respiratory disorders. Peripheral Nervous System (PNS).
Interactions with Other Chemicals
Use of alcoholic beverages may enhance toxic effects
Emergency Overview
Physical state Aerosol OSHA Regulatory Status
2. HAZARDS IDENTIFICATION
Extremely flammable aerosol Contents under pressure Irritating to respiratory system Irritating to skin Irritating to eyes Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal
Chemtrec 800-424-9300
Page 1 / 6
See Section 12 for additional Ecological Information
Environmental hazard
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). CAS # COMMERCIAL HEXANES, MAY BE SUBSTITUTED FOR CAS #110-54-3. Chemical Name HEXANE PROPANE/ISOBUTANE/N-BUTANE PETROLATUM NAPHTHENIC OIL, SEVERELY HYDROTREATED
CAS-No 110-54-3 68476-86-8 8009-03-8 64742-52-5
64742-49-0,
Weight % 40-70 10-30 5-10 1-5
4. FIRST AID MEASURES
General advice
Show this material safety data sheet to the doctor in attendance.
Eye contact
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Skin contact
Wash off immediately with soap and plenty of water. Wash contaminated clothing before reuse. If skin irritation persists, call a physician.
Inhalation
Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Ingestion
Do NOT induce vomiting. Call physician immediately.
Notes to physician
No information available.
5. FIRE-FIGHTING MEASURES
Flammable Properties
Extremely flammable aerosol.
Flash point Method
>= -156 °F / >= -104.4 °C Closed cup: Based on propellant.
Suitable Extinguishing Media
Foam. Dry chemical. Alcohol-resistant foam. Carbon dioxide (CO2).
Hazardous Combustion Products
Carbon oxides.
Explosion Data Sensitivity to Static Discharge
No information available.
Specific hazards arising from the chemical
Containers can build up pressure if exposed to heat (fire). Keep containers and surrounding areas cool with water spray.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA HMIS
Health Hazard 2
Flammability 4
Health Hazard 2*
Flammability 4
Stability 0
Physical Hazard 2
* Chronic Health Hazard: Repeated or prolonged exposure may cause central nervous system damage
6. ACCIDENTAL RELEASE MEASURES
Page 2 / 6
Physical and chemical hazards Personal protection X
Personal precautions
Ensure adequate ventilation. For personal protection see section 8.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal.
7. HANDLING AND STORAGE
Advice on safe handling
Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can.
Technical measures/Storage conditions
Keep out of the reach of children. Incompatible with oxidizing agents.
Aerosol Level
3
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines Chemical Name HEXANE 110-54-3
Engineering Measures
Ensure adequate ventilation.
Personal Protective Equipment Eye/Face Protection Skin and body protection
Hygiene measures
Safety glasses with side-shields. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Do not eat, drink or smoke when using this product. General industrial hygiene practice. Avoid contact with skin, eyes and clothing. Wash hands and face before breaks and immediately after handling the product. Avoid breathing vapors, mist or gas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state Odor
Aerosol Solvent
Property pH Boiling point/boiling range Flash Point Flammability Limits in Air upper flammability limit lower flammability limit
NIOSH IDLH IDLH: 1100 ppm TWA: 50 ppm TWA: 180 mg/m3
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
Respiratory protection
OSHA PEL TWA: 500 ppm TWA: 1800 mg/m3 (vacated) TWA: 50 ppm (vacated) TWA: 180 mg/m3
Other Exposure Guidelines
ACGIH TLV TWA: 50 ppm S*
Appearance Color
No information available No information available
M Rheom •tdskasr
Values Not applicable
>= -104.4 °C / >= -156 °F
Page 3 / 6
No information available Closed cup: Based on propellant. No data available
Vapor pressure Vapor density Specific Gravity Water solubility Viscosity, kinematic VOC Content(%)
Not Determined Heavier than air No information available No information available No information available
88.7
10. STABILITY AND REACTIVITY
Stability
Stable under recommended storage conditions.
Incompatible products
Strong oxidizing agents.
Conditions to Avoid
Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products Carbon oxides. Fumes. Hazardous Reactions
No information available.
Hazardous Polymerization
Hazardous polymerization does not occur.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Causes skin, eye and respiratory tract irritation. May be harmful if swallowed.
Product Information
Chemical Name HEXANE PETROLATUM NAPHTHENIC OIL, SEVERELY HYDROTREATED
LD50 Oral 25 g/kg ( Rat )
LD50 Dermal 3000 mg/kg ( Rabbit ) 3600 mg/kg ( Rabbit )
5000 mg/kg ( Rat )
5000 mg/kg ( Rabbit )
LC50 Inhalation 48000 ppm ( Rat ) 4 h
5 mg/L ( Rat ) 4 h
Chronic toxicity Carcinogenicity
There are no known carcinogenic chemicals in this product.
Target Organ Effects
Central nervous system. Eyes. Peripheral Nervous System (PNS). Respiratory system. Skin.
12. ECOLOGICAL INFORMATION
Ecotoxicity The environmental impact of this product has not been fully investigated.
13. DISPOSAL CONSIDERATIONS Waste Disposal Methods
This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261).
Contaminated packaging
Do not re-use empty containers.
14. TRANSPORT INFORMATION
Page 4 / 6
DOT Ground
Consumer Commodity ORM-‐D or Limited Quantity
DOT/49CFR Air
Aerosol, Flammable, Limited Quantity, UN1950, 2.1
IATA
Aerosol, Flammable, Limited Quantity, UN1950, 2.1
IMDG
Aerosol, Flammable, UN1950, 2.1
15. REGULATORY INFORMATION International Inventories TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Chemical Name HEXANE PROPANE/ISOBUTANE/NBUTANE PETROLATUM NAPHTHENIC OIL, SEVERELY HYDROTREATED
TSCA Complies Complies Complies Complies Complies Complies Complies TSCA Present Present
DSL X X
NDSL EINECS ELINCS Not listed 203-777-6 Not listed Not listed 270-705-8 Not listed
ENCS Present Not listed
IECSC X X
KECL KE-18626 KE-28192
PICCS X X
AICS X X
Present Present
X X
Not listed 232-373-2 Not listed Not listed 265-155-0 Not listed
Present Present
X X
KE-28170 KE-12543
X X
X X
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name HEXANE
SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard
SARA 313 - Threshold Values % 1.0
Yes Yes Yes no no
Page 5 / 6
U.S. State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals:
U.S. State Right-to-Know Regulations
Chemical Name HEXANE
Massachusetts X
New Jersey X
Pennsylvania X
Rhode Island
International Regulations Chemical Name HEXANE
Illinois X
Carcinogen Status
Exposure Limits Mexico: TWA 50 ppm Mexico: TWA 176 mg/m3
Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
16. OTHER INFORMATION
Prepared By Revision Note
Regulatory Affairs No information available.
Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of Material Safety Data Sheet
Page 6 / 6