Material Safety Data Sheet

 

   

Issuing date 01-Jan-2013

   

   

Version 1

1. PRODUCT AND COMPANY IDENTIFICATION

   

Revision Date

Product name

PREVOX

Product code

F00394

Product Type

Extremely flammable aerosol

Recommended Use

Rust preventative

 

 

 

Kano Laboratories 1000 East Thompson Lane Nashville, TN 37211 Chemical Emergency Phone Number

 

 

DANGER!

 

  Potential Health Effects Principle Routes of Exposure Acute toxicity Eyes Skin Inhalation Ingestion

   

Odor Solvent This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) Eye contact. Skin contact. Inhalation.

Irritating to eyes. Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. May cause frostbite. Irritating to respiratory system. Avoid breathing vapors or mists. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Not an expected route of exposure. Potential for aspiration if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Chronic Effects

No information available.

Aggravated Medical Conditions

Central nervous system. Preexisting eye disorders. Skin disorders. Respiratory disorders. Peripheral Nervous System (PNS).

Interactions with Other Chemicals

Use of alcoholic beverages may enhance toxic effects

 

 

Emergency Overview

Physical state Aerosol OSHA Regulatory Status

 

2. HAZARDS IDENTIFICATION

Extremely flammable aerosol Contents under pressure Irritating to respiratory system Irritating to skin Irritating to eyes Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal

   

Chemtrec 800-424-9300

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See Section 12 for additional Ecological Information

Environmental hazard

3. COMPOSITION/INFORMATION ON INGREDIENTS

 

 

This product is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). CAS # COMMERCIAL HEXANES, MAY BE SUBSTITUTED FOR CAS #110-54-3. Chemical Name HEXANE PROPANE/ISOBUTANE/N-BUTANE PETROLATUM NAPHTHENIC OIL, SEVERELY HYDROTREATED

CAS-No 110-54-3 68476-86-8 8009-03-8 64742-52-5

64742-49-0,

Weight % 40-70 10-30 5-10 1-5

 

4. FIRST AID MEASURES

   

General advice

Show this material safety data sheet to the doctor in attendance.

Eye contact

Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.

Skin contact

Wash off immediately with soap and plenty of water. Wash contaminated clothing before reuse. If skin irritation persists, call a physician.

Inhalation

Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.

Ingestion

Do NOT induce vomiting. Call physician immediately.

Notes to physician

No information available.

       

 

5. FIRE-FIGHTING MEASURES

             

 

   

 

Flammable Properties

Extremely flammable aerosol.

Flash point Method

>= -156 °F / >= -104.4 °C Closed cup: Based on propellant.

Suitable Extinguishing Media

Foam. Dry chemical. Alcohol-resistant foam. Carbon dioxide (CO2).

Hazardous Combustion Products

Carbon oxides.

Explosion Data Sensitivity to Static Discharge

No information available.

Specific hazards arising from the chemical

Containers can build up pressure if exposed to heat (fire). Keep containers and surrounding areas cool with water spray.

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

NFPA HMIS

Health Hazard 2

Flammability 4

Health Hazard 2*

Flammability 4

 

 

Stability 0

 

Physical Hazard 2

* Chronic Health Hazard: Repeated or prolonged exposure may cause central nervous system damage

6. ACCIDENTAL RELEASE MEASURES  

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Physical and chemical hazards Personal protection X

   

       

Personal precautions

Ensure adequate ventilation. For personal protection see section 8.

Environmental precautions

Do not flush into surface water or sanitary sewer system.

Methods for Containment

Prevent further leakage or spillage if safe to do so.

Methods for cleaning up

Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal.

 

7. HANDLING AND STORAGE

  Advice on safe handling

Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can.

Technical measures/Storage conditions

Keep out of the reach of children. Incompatible with oxidizing agents.

Aerosol Level

3

   

 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

 

 

Exposure Guidelines Chemical Name HEXANE 110-54-3

Engineering Measures

Ensure adequate ventilation.

Personal Protective Equipment Eye/Face Protection Skin and body protection

  Hygiene measures

Safety glasses with side-shields. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Do not eat, drink or smoke when using this product. General industrial hygiene practice. Avoid contact with skin, eyes and clothing. Wash hands and face before breaks and immediately after handling the product. Avoid breathing vapors, mist or gas.

 

9. PHYSICAL AND CHEMICAL PROPERTIES

  Physical state Odor

Aerosol Solvent

Property pH Boiling point/boiling range Flash Point Flammability Limits in Air upper flammability limit lower flammability limit

 

NIOSH IDLH IDLH: 1100 ppm TWA: 50 ppm TWA: 180 mg/m3

Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).

Respiratory protection

 

OSHA PEL TWA: 500 ppm TWA: 1800 mg/m3 (vacated) TWA: 50 ppm (vacated) TWA: 180 mg/m3

Other Exposure Guidelines

 

 

ACGIH TLV TWA: 50 ppm S*

Appearance Color

No information available No information available

M Rheom •tdskasr

Values Not applicable

 

>= -104.4 °C / >= -156 °F

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No information available Closed cup: Based on propellant. No data available

   

 

Vapor pressure Vapor density Specific Gravity Water solubility Viscosity, kinematic VOC Content(%)

Not Determined Heavier than air No information available No information available No information available

         

88.7

 

  10. STABILITY AND REACTIVITY

           

 

Stability

Stable under recommended storage conditions.

Incompatible products

Strong oxidizing agents.

Conditions to Avoid

Strong oxidizing agents. Strong bases.

Hazardous Decomposition Products Carbon oxides. Fumes. Hazardous Reactions

No information available.

Hazardous Polymerization

Hazardous polymerization does not occur.

11. TOXICOLOGICAL INFORMATION

     

Acute toxicity Causes skin, eye and respiratory tract irritation. May be harmful if swallowed.

Product Information

  Chemical Name HEXANE PETROLATUM NAPHTHENIC OIL, SEVERELY HYDROTREATED

   

LD50 Oral 25 g/kg ( Rat )

LD50 Dermal 3000 mg/kg ( Rabbit ) 3600 mg/kg ( Rabbit )

5000 mg/kg ( Rat )

5000 mg/kg ( Rabbit )

 

LC50 Inhalation 48000 ppm ( Rat ) 4 h

  5 mg/L ( Rat ) 4 h

Chronic toxicity Carcinogenicity

There are no known carcinogenic chemicals in this product.

Target Organ Effects

Central nervous system. Eyes. Peripheral Nervous System (PNS). Respiratory system. Skin.

   

12. ECOLOGICAL INFORMATION

 

 

 

Ecotoxicity The environmental impact of this product has not been fully investigated.

13. DISPOSAL CONSIDERATIONS Waste Disposal Methods

This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261).

Contaminated packaging

Do not re-use empty containers.

 

 

14. TRANSPORT INFORMATION

 

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DOT  Ground  

 

Consumer  Commodity  ORM-­‐D        or        Limited  Quantity  

DOT/49CFR  Air    

Aerosol,  Flammable,  Limited  Quantity,  UN1950,  2.1  

IATA  

 

 

Aerosol,  Flammable,  Limited  Quantity,  UN1950,  2.1  

IMDG    

 

Aerosol,  Flammable,  UN1950,  2.1  

 

     

   

 

15. REGULATORY INFORMATION International Inventories TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Chemical Name HEXANE PROPANE/ISOBUTANE/NBUTANE PETROLATUM NAPHTHENIC OIL, SEVERELY HYDROTREATED

TSCA Complies Complies Complies Complies Complies Complies Complies TSCA Present Present

DSL X X

NDSL EINECS ELINCS Not listed 203-777-6 Not listed Not listed 270-705-8 Not listed

ENCS Present Not listed

IECSC X X

KECL KE-18626 KE-28192

PICCS X X

AICS X X

Present Present

X X

Not listed 232-373-2 Not listed Not listed 265-155-0 Not listed

Present Present

X X

KE-28170 KE-12543

X X

X X

 

   

 

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name HEXANE

SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard

 

SARA 313 - Threshold Values % 1.0

Yes Yes Yes no no

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U.S. State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals:

     

U.S. State Right-to-Know Regulations

  Chemical Name HEXANE

Massachusetts X

New Jersey X

Pennsylvania X

 

 

 

Rhode Island

 

International Regulations Chemical Name HEXANE

 

Illinois X

Carcinogen Status

 

Exposure Limits Mexico: TWA 50 ppm Mexico: TWA 176 mg/m3

Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

         

16. OTHER INFORMATION

  Prepared By Revision Note

 

Regulatory Affairs No information available.

Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.

End of Material Safety Data Sheet

 

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