@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
Revisedl：
2006-12
Page 1 of 13
Lithium-Manganese Dioxide Coin Type Battery Section Ⅰ
Manufacturer‵s name: Shun Wo New Power Electronics (Shenzhen) Co., ltd Address: No.7 1st Zone, Xiakeng, Tongle Village, Longgang Town, Shenzhen China Emergency Telephone Number: (86-755)84294768 or 13602651050 Telephone Number for information: (86-755)83435470 Contact: Vice- Mgr.: Congfa Xu Email:
[email protected]
SectionⅡ – Physical/Chemical Characteristics Specifications: Specifications of batteries shall be as shown in the parenthesis table1. Appearance: Battery shall have no deformation, dent,stain, leakage and camber or burr on their sealing members, which may adversely affect their appearance, performance and commercial value.There shall be no coatings or other foreign objects on the surface of terminals which may adversely affect actual use or perform of batteries.
Merits Lightweight Long Storing Period Smart Volume High Comparison Energy Wide Temperature Range(-20℃~+60℃) Stable Discharged Voltage No Poison (Green Environment-protected Battery) Safety
υ υ
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
2006-12
Revisedl：
Page 2 of 13
ELECTROLYTE Propylene Carbonate (PC)
Dimethoxyethane (DME)
Lithium Perchlorate (LiClO4)
Appearance
Viscosity,Colorless Liquid
Colorless Liquid
Colorless Crystal Particulate
Odor
irritation
Aether Odor
Odorless
Material Item
Specific Gravity
1.143 g/cm （20℃）
0.8664 g/cm （20℃）
2.428 g/cm3（20℃）
Melting Point
-4℃
-58℃
236℃
Boiling Point
161℃
85.2℃
N/A
Flash Point
177℃ 9.00 mPa·s（20℃）
4.5℃ 1.10 mPa·s（20℃）
N/A
Viscosity
3
3
Toxicity LD50 (mg/kg)
----
----
Solubility in
Ethanol、Aether
Ethanol、Aether
υ
Note:
N/A Smart rat Celiac Injection 770 Ethanol、Aether、Water
N/A=Not Applicable
SectionⅢ –Hazardous Components* / Specific Chemical Identity
conpoments
model
Manganese
Graphite
Teflon
dioxide
(C)
(PTFE)
(MnO2)
%
%
%
Plastic (pp)
%
Stainless
Metal *
Propylene
Dimethoxye-
Lithium
*
Perchlorate
Steel
Lithium
Carbonate
%
%
(PC) %
Thane (DME)
%
(LiClO4)
CR1025
24.1
1.1
1.7
5.1
57.9
1.4
2.7
1.0
0.7
CR1216
14.5
0.6
1.0
3.6
72.0
1.1
2.3
0.8
0.6
CR1220
21.0
0.9
1.5
3.9
63.6
1.5
2.1
0.8
0.6
CR1225
22.8
1.0
1.6
4.8
56.9
1.7
3.7
1.4
0.8
CR1530
31.8
1.4
2.2
4.7
49.0
2.1
2.5
0.9
0.7
CR1616
16.7
0.7
1.2
3.5
68.8
1.4
2.4
0.9
0.6
CR1620
20.6
0.9
1.4
4.0
63.1
1.7
2.5
0.9
0.7
CR1632
28.5
1.2
2.0
4.8
52.8
2.1
2.6
0.9
0.7
υ υ
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
%
@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
Revisedl：
2006-12
Page 3 of 13
CR2016
19.0
0.8
1.3
3.6
66.9
1.2
2.1
0.8
0.6
CR2025
22.4
1.0
1.6
3.1
61.6
1.9
2.6
0.9
0.7
CR2032
27.7
1.2
1.9
3.6
53.8
2.2
2.9
1.1
0.8
CR2320
18.0
0.8
1.3
3.7
68.0
1.5
2.1
0.8
0.6
CR2325
24.0
1.1
1.7
2.9
59.9
1.9
2.7
1.0
0.7
CR2330
26.0
1.1
1.8
3.9
56.8
1.9
2.6
1.0
0.7
CR2335
30.0
1.3
2.1
3.3
52.1
2.2
2.6
1.0
0.7
CR2354
33.5
1.5
2.3
2.3
46.4
2.4
3.7
1.3
0.8
CR2412
18.0
0.8
1.3
3.7
69.8
1.0
2.0
0.8
0.6
CR2430
25.8
1.1
1.8
3.9
55.4
2.0
3.2
1.2
0.7
CR2450
33.9
1.5
2.4
3.9
46.0
2.4
2.9
1.2
0.8
CR2450C
32.1
1.4
2.2
2.7
47.5
2.6
3.7
1.3
0.8
CR2477
39.0
1.7
2.7
3.4
39.8
3.2
2.9
1.1
0.8
CR3032
30.2
1.3
2.1
2.8
51.3
2.4
3.1
1.1
0.8
Section Ⅳ – Fire and Explosion Hazard Date Flash Point：PC 177℃；DME 4.5℃；Other Material Non-Flammable Flammable Limits: Hydrogen Gas Extinguishing Media: Portable ABC Dry Powder Fire Extinguisher, sand。 Unusual Fire and Explosion: Do not deposit of battery in fire may explode: Do not short-circuit battery may arose burn: υ υ
υ υ
No No No
Note: Few gas(H2) may be generated during the battery storing,but won‵t arose burning or explosion. Warning : Never recharge/short-circuit/disassemble.Never dispose in fire or expose close to a heat generating area.Never expose battery to strong impact because there is a danger of combustion or explosion.
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
Revisedl：
2006-12
Page 4 of 13
Section Ⅴ – Reactivity Data Stability: Stable Incompatibility (Material to Avoid): Lithium Metal---Contact with water will occur to reaction ,reacts violently then release flammable hydrogen gas and quantity of heat , that may cause fire and explosion; Contact with air also lead to lithium metal metamorphosed. Electrolyte---Contact with air will increase the percentage value of water ,that will reduce the battery‵s storaged-life and inpact on discharge performance.
Section Ⅵ – Health Hazard Data Route(s) of Entry: Not Applicable under normal use Carcinogenicity: ¬ Electrolyte: No ¬ Lithium Metal / Manganese Dioxide : No Signs and Symptoms of Exposure: ¬ Electrolyte:Contact with eyes、nose or skin will not cause irritation and skin burns,also electrolyte is not corrosive; Emergency and First Aid Procedures: ¬ ¬
Contact with Electrolyte: just wipe up with dry cloth then wash it with water; If swallowed: To prevent to be swallowed by children accidentally,if so ,contact a physician immediately.
Section Ⅶ – Precautions For Safe Handling and Use
This battery can be used reliably under normal using condition , but if it is mishandled by any possibility . violent explosion、burnning or electrolyte leakage may happen.Therefore , when using this battery , bear in mind the following points:
υ υ
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
2006-12
Revisedl：
Page 5 of 13
1. Precautions when using Coin type Manganese Dioxide Lithium batteries A. Coin type Manganese Dioxide Lithium battery is a primary battery and cannot be charged. 1)
When used in memory back up circuit , to avoid a current flow from the main power source to the battery circuit , a blocking diode which prevents reverse current flow should be used . (Refer to the following figure)
2)
Low current leakage type diodes should be used . When choosing a diode , the total electric charge by reverse current leakage should be kept at 1~2% of the nominal capacity.
3)
When using batteries , if you have any questions about detailed matters , including power backup specification , please contact Shun Wo New Power Electronics (Shenzhen)Co.Ltd .
Example:
D3
Power source
D1
CMOS etc.
D2
Explanation of symbols D1 , D2 , D3 , - - - - - -Diode
υ υ
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
2006-12
Revisedl：
Page 6 of 13
B. Under condition where normal current flow through the battery will increase , the
battery should not be connected in series with the power supply. C. When connecting a lead wire to the battery . direct soldering or direct spot welding to the battery should be avoided. D. In the case of soldering , practice it at the following condition ; temperature of solder ; 270℃ and less , soldering time : 5 sec . and less. E. In the case of automated soldering , dip only the battery terminal in solder bath and be sure that the battery is not stopped , nor fallen in the bath. F. When the battery is used in apparatus which heats , set the battery away from the heating part or if the battery is near the heat source , isolate them and design the insertion so that the temperature at the battery is 60℃ and less. 2.Prohibitive matters when handing Coin type Manganese Dioxide Lithium batteries ¬
The voltage of Coin type Manganese Dioxide Lithium batteries(3.0V) is different from the voltage of the following batteries, so use Coin type Manganese Dioxide Lithium batteries only in apparatus specially designed for them.
¬
Conventional batteries with different voltage: Manganese dry batteries(1.5V), Alkaline manganese
button
batteries(1.5V);Sliveroxide
batteries(1.5V),Mercury
batteries
(1.4V),Lithium/Thionyl Chloride batteries(3.6V),etc. ¬
Do not use different types of batteries together, nor mix partially used batteries with new ones.
υ υ
¬
Do not use short-circuit （+）（-） of batteries.
¬
Do not reversely connect（+）（-） of batteries.
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
Revisedl：
2006-12
Page 7 of 13
¬
The batteries should be used at normal temperature, never exceeding 60℃.
¬
Do not dismantle the batteries ,put them into a fire, heat them or throw them into water because there is a fear of ignition, explosion or burning.
¬
Do not give unreasonable shocks to batteries, such as hard hits.
3.Precautions when storing Coin type Manganese Dioxide Lithium batteries ¬
To store batteries, keep out of high temperature and high humidity, and avoid dew condensation.
¬
Keep away from direct sunlight and rain water.
¬
Pay attention to avoid short-circuit of batteries by collapse of packages.
¬
During transportation, avoid rough handing which cause dent or deformation.
¬
When piling up the outer packages of batteries, the number of tiers should be limited to the amount indicated on the outer package.
4.Waste Disposal Method: Do as the government regulations.The more importance is that all Newsun lithium-manganese batteries are pollution-free clean power . As a non-hazardous waste and are safe for disposal in the normal municipal waste stream.
Section Ⅷ – Control Measures
λ λ λ λ λ λ
υ υ
Respiratory: N/A Ventilation: Must be provide Protective Gloves: Recommended Eye Protection: N/A Other Protective Clothing or Equipment: Recommended Work Hygienic Practices: Good Personal hygiene and work practices are recommended
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
2006-12
Revisedl：
Page 8 of 13
Section Ⅸ – Accidental Release or Leakage
Leakage characteristics: Batteries when tested in accordance with the storage conditions as below shall not release or leakage :
Table 1.
Items. Storage period
N
Items. Storage conditions Leakage resistance
High temperature , High humidity
υ
Temperature 45℃, humidity 93%RH Temperature 60℃, humidity 93%RH
0
50
0
Temperature -30℃~+60℃ (5h/1cycle)(42times)
High temperature
60℃
45
0
Low temperature
-30℃
45
0
60
0
20±5℃，65±20%RH (1year)
Remarks
30days
Temperature cycle
Room temperature
υ
Rate of occurrence of leakage(%)
By visual means (×10)
0
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
Over discharge Do not permit:
2006-12
Revisedl：
After discharging at room temperature until 0.1V
9
Page 9 of 13
0
cross extrusion or direct extrusion; Deposited in fire or expose close to a heat generating area.
Section Ⅹ– Transportation Information
1.According to the《UN Recommendations on the Transport of Dangerous Goods 》 “Special Provision ”188： “If lithium batteries,during the transportation,avoiding to short with each other, packings of which haved been protected properly and of which the content of the lithium element is below 1.0 gramme are considered as the safety merchandises. “ Newsun ” lithium-manganese dioxide batteries meet all the technical requirements items of the 《UN Recommendations on the Transport of Dangerous Goods 》completely. 2.All newsun lithium batteries are now subject to various transportation regulations for all modes ( truck, rail, ocean and air)of transportation both around the world and domestric. υ
Warning：
(1)The battery must be securely packaged in such a way to prevent the possibility of short-circuiting. (2)The battery and the outer most packaging must be labeled "NONSPILLABLE" or "NONSPILLABLE BATTERY". (3)Visual inspection shows no obvious defect or damage.
Section Ⅺ – Other Information 1.
υ υ
UL Test
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
@
Newsun —Material Safety Data Sheet— Document Number:
MSDS-SWT - CR / 05E1
Revisedl：
2006-12
Page 10 of 13
Table2. Items
Conditions
Requirements
Heat endurance test
Cells are kept stored for 24hrs. at : temperature 80±2℃, humidity 70%RH and less.
Open-circuit voltage is to be kept same as initial value . No abnormal appearance and no substandard dimensions are to be abserved.
Vibration endurance test
Entire amplitud : 1.0mm Frequency : 10~55~10Hz Sweep : 1minute Period : 2h×2(Direction X,Y)
Ditto
Falling endurance test
Cells are fallen 10 times from the height of 75cm onto solid wood with thickness of 3cm without fixing falling angle.
Ditto
Weighing endurance test
Weight of 2kg is laid for 1hour and 1kg for 24hour respectively on all over negative side of cells.
Ditto
Short-circuit test
Cells are Short-circuited for 48hours.
No burst and firing will occur.
2、SGS Test Test Method: (1)With reference to standard analytical method by European Battery Association (EPBA).Battery Association of Japan(BAJ )and National Electrical Manufacturers Association (NEMA ,USA )-April 1998.Samples were digested in concentrated nitric acid and hydrogen peroxide.Analysis was performed by atomic absorption or inductively coupled argon plasma spectrometry.(2)As specified in EPA method 3060A & 7196A .The smple was alkaline digested by using EPA method 3060A ,and then analyzed ny using colorimetric method 7196A . With reference to SGS in-house method . Analysis was performed by GC /MS Test Result : Table3.
υ υ
Datas and dimensions are just reference values.For further details,please contact us through the phone or email above. Contents are subject to change without notice.
@
Newsun —Material Safety Data Sheet— Document Number:
υ
MSDS-SWT - CR / 05E1
2006-12
Revisedl：
Element
Button cell Battery
Limit(button cell)
Lead(Pb)
