1.

Identification

Product Identifier: Substance name Chemical name Chemical family Use Supplier’s name

Lincocide T 2,4,4’-Trichloro-2’-hydroxy diphenylether Chlorophenol Antimicrobial agent Lincoln Manufacturing 50 Industrial Circle Lincoln, RI 02865 Tel: (401) 722-2410 Fax: (401) 727-0752 Email: [email protected]

2. Hazard(s) Identification Classification in accordance with UN GHS/EU Regulation EC 1272/2008 Hazard Class and Category Code(s) Eye irrit.2; Skin irrit.2; Aquatic Acute 1; Aquatic Chronic 1 Hazard statement code(s)

H315: Causes skin irritation H319: Causes serious eye irritation H400: Very toxic to aquatic life H410: Very toxic to aquatic life with long lasting effects.

Precautionary statement(s)

P273: Avoid release into the environment P305+P351+P338; if in eyes: rinse cautiously with water for several min. Remove contact lenses, if present and easy to do, continue rinsing. P501: Dispose of contents/container to an approved waste disposal plant.

Pictogram Signal word

Harmful ‘Warning’

Environmentally toxic

Lincoln Manufacturing, Inc. | 50 Industrial Circle | Lincoln, RI 02865 USA | 1-401-722-2410 | www.LMfgInc.com

3. Composition/information on ingredients

Name

Lincocide T

CAS#

3380-34-5

EC#

222-182-2

GHS Hazard class & categ, code Eye Irrit.2 Skin Irrit.2 Aquatic Acute1 Aquatic Chronic1

Eu Directive 67/548/EEC Classification

Percent (w/w) approx.

Xi; N R36/38 R50-53

97 – 103%

4. First-aid measures General Inhalation

If exposed or concerned, get medical advice/attention. Remove to fresh air, if breathing has ceased give artificial respiration and obtain immediate medical attention. Skin contact Remove contaminated clothing and wash affected area with soap and water Immediately, if irritation or redness occurs obtain immediate medical attention. Eye contact Remove contact lenses, if worn and rinse open eye with at least 15 minutes under Running water and apply sterile protective bandage. Obtain immediate medical Attention. Ingestion Never give anything by mouth if patient is unconscious, do not induce vomiting. Rinse mouth with water and obtain immediate medical attention. Other information Treat symptomatically 5. Fire-Fighting Measures Suitable extinguishing media Exposure hazards

Dry chemical powder; appropriated foam, water spray or carbon dioxide

May release toxic fume of carbon monoxide, carbon dioxide and hydrochloric acid on thermal decomposition. The product is very toxic to aquatic organisms sufficient measures must be taken to retain fire-control water and should not be allowed to enter drains or watercourses. Dispose of contaminated water and according to local regulations.

Lincoln Manufacturing, Inc. | 50 Industrial Circle | Lincoln, RI 02865 USA | 1-401-722-2410 | www.LMfgInc.com

Fire fighting procedures

Wear self-contained breathing apparatus and full protective clothing to Prevent contact with skin and eyes. A self-contained breathing apparatus and suitable protective clothing Should be worn by fire fighters.

Protective equipment

6. Accidental Release Measures Personal precautions

Mark out contaminated area with signs and prevent access to unauthorized Personnel, prevent inhalation or contact with skin or eyes by wearing suitable Protective equipment (see section 8). Eliminate all sources of ignition

Spill response

Be careful to ensure product doesn’t enter drains or surface waters (see section 12 – ecological information).

Disposal Disposal of waste with all applicable federal, state and local laws Methods for cleaning up: Take up mechanically or sweep up carefully and transfer to a suitable Container for recovery or waste disposal (see section 13), avoid Generation of dust, ventilate the area and wash spill site after material Pick-up is complete. 7.

Handling and Storage

Handling

Storage

8.

This substance should only be handled by trained personnel wearing suitable Protective equipment (see section 8), Avoid inhalation, skin, and eye contact. Prevent prolonged or repeated exposure to skin. Provide good ventilation and And keep ignition sources away. To be stored in properly sealed and labeled containers in a clean and dry place With adequate ventilation. Sensitive to heat above temperature of 40°C. Keep Away from chlorinating and oxidizing substances. Keep away from direct Sunlight and heat.

Exposure Controls/Personal Protection

Exposure Limit: No data available Exposure control: Use process enclosure, local exhaust ventilation or other controls to minimize airborne levels of the product, the exposure to the product must be reduced to the lowest level. Wear suitable respirator, safety goggles, suitable gloves & aprons, for extra safety use within fume chambers. Wash thoroughly after handling, do not expose to eyes, or clothing. Avoid prolonged or repeated exposure; be particular about the safety showers & eye bath.

Lincoln Manufacturing, Inc. | 50 Industrial Circle | Lincoln, RI 02865 USA | 1-401-722-2410 | www.LMfgInc.com

Occupational exposure controls: Wear recommended personal protective equipment as details below: Personal protection: Chemical resistant gloves & safety glasses a must Respiratory protection: Seek professional advice prior to respirator selection, atmospheric level should be maintained below the exposure limit; if airborne concentration is high use mask or respirator. Hand protection: Wear chemical resistant gloves Eye protection: Wear safety glasses Skin protection: Wear chemically protective clothing Work practices: Eye wash facilities and safety shower should be easily accessible, before breaks and at the end of work thoroughly wash hands with soap and water. Wash contaminated clothing before reuse, clean footwear before use. Environmental exposures controls: All necessary precautions must be taken to avoid release into the environment, refer to local, state or nationals legislations for environment and pollution control. 9. Physical and Chemical Properties Appearance: White crystalline powder Odor: Faintly aromatic pKa: 7.9 Melting point/freezing point: 57±1°C Boiling point: Not known Flash point: 273°C (433.4°F) Vapor pressure: 4x10¯⁶ mmHg (20°C) Relative molecular mass: 289.5 Solubility: Soluble in methanol, alcohol and acetone Vapor density: Not known Reactivity in water: Not known 10. Stability and Reactivity Stability: Stable and no hazardous Polymeritization. Conditions to avoid: Keep away from direct sunlight, heat and sources of ignition. Usual precautions for handling of chemicals should be observed. Materials to avoid: Avoid contact with chlorinating and oxidizing substances Reactivity: Avoid contact with chlorinating substances 11. Toxicological Information

Lincoln Manufacturing, Inc. | 50 Industrial Circle | Lincoln, RI 02865 USA | 1-401-722-2410 | www.LMfgInc.com

Ingestion: LD50 oral (mouse) 4300 mg/kg Inhalation: LD50 inhalation (rat) 140 mg/m3, Irritating to mucous membranes and upper respiratory tract. Skin contact: LD50 dermal (rabbit) 9300 mg/kg, Irritating to skin Eye contact: Irritant Health-related end-points Sensitization: Not confirmed to be a sensitizer Mutagenicity: Not mutagenic in Ames test 12. Ecological Data

Aquatic toxicity Other data Impact on sewage treatment plants Mobility Abiotic degradation Biological degradation Bioaccumulative potential Other adverse effects

Summary

LC50 96 h Zebra Fish: 0.5 mg/l EC50 48h Daphnia: 0.4 mg/l EC50 72h Algae: 0.2 mg/l IC50 3 hr Bacteria: 20 mg/l Partial elimination in effluent treatment by sludge absorption Nitrification inhibition test, EC50 11.4 mg/l Sparingly soluble in water No information available 10-25% TOC/DOC analysis No information available Very toxic to aquatic organisms if run directly to surface waters Lincocide T is not biodegraded in screening level test due to its antimicrobial properties and the high concentration of test substance in these tests. Partially eliminated by absorption on effluent treatment sludge.

13. Disposal Considerations Product: Waste material is classified as hazardous waste and should be disposed of by incineration or collected by a registered waste disposal company, operating within the hazardous wastes regulations. Contaminated packaging: Contaminated empty containers must be disposed of as chemical waste.

Lincoln Manufacturing, Inc. | 50 Industrial Circle | Lincoln, RI 02865 USA | 1-401-722-2410 | www.LMfgInc.com

14. Transport Information Not classified as dangerous for transport in accordance with CDG, IMDG, ADR, RID, ICAO/IATA UN No.: 3077 Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, Solid, N.O.S. (2,4,4’-trichloro-2’hydroxy-diphenyl ether) Class: 9 Packing group: III 15. Regulatory Information Classification in accordance with UN GHS/EU Regulation EC 1272/2008

Hazard class category code(s)

Hazard statement code(s)

Pictogram Signal word R-Phrases

S-Phrases

Eye Irritation 2 Skin Irritation 2 Aquatic Acute 1 Aquatic Chronic 1 H319: Causes serious eye irritation H315: Causes skin irritation H400: Very toxic to aquatic life H410: Very toxic to aquatic life with long lasting effects.

Harmful

Environmentally toxic

‘Warning’ 36/38 Irritating eyes and skin 50/53 very toxic to aquatic organisms, may cause long term affects in the aquatic environment. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 39 Wear eye/face protection 46 If swallowed, seek medical advice immediately and show this SDS 60 This material and its container must be disposed of as hazardous waste

Lincoln Manufacturing, Inc. | 50 Industrial Circle | Lincoln, RI 02865 USA | 1-401-722-2410 | www.LMfgInc.com

61 Avoid release into the environment, refer to special instructions/safety data sheet.

16. Additional Information Prepared on: 4/29/2015 DISCLAIMER: The information contained herein is based on current knowledge and experience and from tests performed in a controlled environment. No responsibility is accepted that the information is sufficient, complete or correct in all cases. Users should consider the data only as a supplement to other information. Product specifications should be verified by users prior to usage. Users should make independent determination of suitability and completeness of information from all sources to assure proper use of this product and the safety of User’s customers. Users should be aware that results may vary depending on use of and/or mixture of this product with other products. The determination of suitability of the above product for any particular use is solely the responsibility of the user. 7-17-15 NP

Lincoln Manufacturing, Inc. | 50 Industrial Circle | Lincoln, RI 02865 USA | 1-401-722-2410 | www.LMfgInc.com