FISSORE AGENCY FISSORE Agency Screening&Recycling MachineryBiohazardous&Medical Waste Systems

P2P PLASTIC TO PETROL Waste plastic to Fuel conversion

www.bollegraaf.it www.fissoreagency.com [email protected] [email protected] Tel.: +377.97.70.60.30 Fax: +377.97.70.60.36 Mob.:+377.6.80.86.91.06 6, Impasse de la Fontaine Le Park Palace MC 98000 MONTE-CARLO Principauté de Monaco S.S.E.E. 511 G 09734 Répertoire spécial des Agents Commerciaux No. 01 AC00240 N.ro IDENTIFIANT EUROPEEN: FR 84 000057157

Modular System to convert plastic waste from MSW into hydrocarbon liquid / gas fuel

FISSORE AGENCY

La

P2P PLASTIC TO PETROL

VULCANES Ltd

Environmental Expertise

( www.vulcanes .com ) in partership with

Oil Field Tekniks

Environmental Expertise

and its General Agent

FISSORE Agency already Bollegraaf

6, Impasse de la Fontaine- Monte-Carlo, Principato di Monaco

Recycling Machinery’s General

Agent

are honored to present to the market this fantastic product!

FISSORE AGENCY

P2P PLASTIC TO PETROL Polycrack System:

how to convert Plastic waste into petrol ( and other fuels) The currently abundant existence of waste plastics needs a solution.

Vulcanes Presents a new and innovative technology for the conversion of plastic waste into fuel gases and liquids, using a catalytic conversion method, than innovative to be examined and, with great satisfaction, awarded with the “gold medal for the best invention of 2007 for the waste treatment“ by the University of Texas (IC2), together with the Federation of Indian Chambers of Commerce (FICCI), through the LOCKEED Martin’s “Innovation and Growth Program”.

FISSORE AGENCY

P2P PLASTIC TO PETROL

FISSORE AGENCY

P2P PLASTIC TO PETROL

In the further presentation to the market, held in England on June'07 for a limited number of Customers coming from all the world, were shown, in addition to the widening of the process “ from plastics to fuel with a single catalyst!“, the further features of the P2P System: the now official possibility of dealing with the same plant, without any variation: a) Organic and vegetable waste… (so renewable energy sources!) obtaining ethanol and natural gas; b) Fluff (all plastics) from shredded cars; c) Plastics from electronic and bio-medical waste; d) Green and lopping waste obtaining ethanol . e) Oil and similar from kitchen waste (fried and others!) obtaining fuel; f) Palm Oil and waste (fuel and LPG); g) All kind of vegetable oil (fuel and LPG); h) Waste from treatment of all kind of vegetable oil (fuel and LPG); i) Cellulose and paper factory waste (like Pulper!), obtaining natural gas; j) Fats and animals waste (obtaining fuel and LPG); k) Animals Excrements of any kind and therefore from rabbits, horses, pigs, sheep, cows, chickens and so on (natural gas) l) Slushes of refineries (fuel and LPG); m) Tar and bitumen exhausted (fuel and LPG); n) Much other kind of slush (for example from sewer plants!), obtaining natural gas; Specifically, we have a patented chemical reagent able to separate in less than 1 minute white water from solid waste! o) FLOCK (natural gas); is well to remember here that the flock is the cellulose fiber in which the organic material is transformed as well as paper, cardboard and small pieces of wood, obtained by the AUTOCLAVE treatment … without forgetting that this flock that can be used for the construction of multilayer boards and subsequent manufacture of furniture, or anti-seismic or sound-absorbing panels… or even burned, developing electricity: 5.6 mW/h constant from a 2 autoclaves plant… but in case it is possible to process it the existing plant and without being forced to purchase additional equipment, in fact, you can insert it in P2P plant and obtain abt. 30-35% of methane, while the other part will be turned into "COKE", which finds good use as a "filter" in all LPG plants, and in creating anti-radioactive products such jackets and so on, or even, as mentioned previously, as "blacksmoke" in the manufacture of reconditioned or traditional tires except those for high speed. These processes are increasingly adding to the now famous treatment “fuel from plastics” and are all GUARANTEED in their perfection and performance. Finally, with effect from 20 August'07 is available, in India, a smaller plant and therefore reduced capacity compared to the standard, but fully functional and made available to Customers for any type of test!

ALL our systems are ZERO air e mission

FISSORE AGENCY

P2P PLASTIC TO PETROL

“Demo Polycrack System ” In the further presentation held on 0ctober 2007, in Mumbai, India, world premiere for the Customers who wanted to be present to witness their great interest… in a P2P plant fully functional, it has witnessed to the various processes of transformation of plastics into fuel, and some questions have raised directly to the inventor Ing. T. R. RAO (our Partner and co-shareholder, recently awarded by the gold medal for “The best invention of 2007 for the waste treatment”), and has been demonstrated, with great astonishment of those present, the capacity of the machine to move from one type of work to another one without having to stop the cycle or make whatsoever changes!

T.R. Rao Partner Vulcanes [email protected]

FISSORE AGENCY

P2P PLASTIC TO PETROL

“Demo Polycrack System” MUMBAI , 0tt0bre 2007

We underline, with great pride and enthusiasm that the

P2P system is able to treat also: A) EXHAUST TIRES B) EXHAUST OILS FROM VEHICLES (cars, trucks, moto, etc.) leaving directly to the Customer the possibility to transform them into diesel-gasoline or to PURIFY completely the product for resale as a “base oil" ready to be added! ALL our systems are ZERO air e mission

FISSORE AGENCY

P2P PLASTIC TO PETROL

FISSORE AGENCY

P2P PLASTIC TO PETROL

Following one of the many (really a lot!) press releases published in Spain on March 2008 the 5th, in reference to the agreement signed between the Velez MALAGA Authorities and VULCANES Ltd, about to the FIRST AUTOCLAVE+P2P plant, establishing the plastics transformation into fuel (P2P) as well as the flock use to procreate methane gas and consequently electrical and thermal ENERGY.

FISSORE AGENCY

P2P PLASTIC TO PETROL 1. Company profile

Vulcanes Ltd

Vulcanes Ltd originates from a global network-organisation across the recycling Industry. Vulcanes is a young organisation with expertise in the field of: • WTE (Waste To Energy) • MSW (Municipal Solid Waste) • Biomass • Industrial Waste • C&D (Construction and Demolition) • Muds/Sludges Treatment Vulcanes offers as a System Integrator turnkey solutions bringing together the most advanced and reliable technologies in the market. These custom made turnkey solutions are characterized by high return on investments, high efficiency and are highly innovative. Furthermore Vulcanes offers consultancy, environmental solutions and project management. The scope of work for project management can vary from delivering management services up to the complete staffing and field operations. In order to secure the required customers operational and financial result. Vulcanes employs a dedicated team of engineers, project managers and experts. These professionals have a proven track record in the industry with numerous references of successful installations and showcases in the market. Vulcanes has access tot a worldwide network of expertise in the environmental market. Vulcanes has the exclusive global Oil Field Tekniks dealership for P2P systems. Vulcanes, with FISSORE AGENCY, distribution for the Oil Field Tekniks P2P systems, and Aerothermal English Autoclave systems is worldwide.

ALL our systems are ZERO air e mission

FISSORE AGENCY

P2P PLASTIC TO PETROL

2. Company profile

Oil Field Tekniks

Oil Field Tekniks is a Research and Development organization, specialized in developing technologies for converting Petroleum and Petrochemical wastes into usable value added products. Backed by a team of engineers and developers with years of experience handling hydrocarbon wastes, the company has developed many technologies for the utilization of waste material as useful products. The personnel involved in Oil Field Tekniks have vast experience in the Petroleum industry and understands the petroleum and petrochemical products well to develop technologies that can mitigate the waste problems. Following are some of the technologies developed, commercialized and under commercialization. Bitumen to Furnace Oil Conversion - Desulphurization of Diesel Fuels - Conversion of waxy sludge to fuel oil Conversion of sludge to bio-fertilizer -Development of chemicals for water purification - Development of chemicals for tank cleaning - Aqueous phase tank cleaning systems The strength of the company is its understanding of the basic materials and the knowledge to convert problems into solutions We offer : Innovative solutions Cost effective Environmentally friendly Safe and reliable technology Commitment to quality Global presence Service orientation Problem specific solutions In house designing capability Fully integrated systems for internal and external Any kind of muds Treatment

ALL our systems are ZERO air e mission

FISSORE AGENCY

P2P PLASTIC TO PETROL 5.1 Introduction

Oil Field Tekniks, introduces a new and innovative technology for the conversion of waste plastics into useful fuel oil, using a catalytic conversion method. Il mondo sta affrontando il problema dello smaltimento dei rifiuti in plastica. The world is facing the problem of disposal of waste plastics. The ease of manufacture and the abundant availability of plastics in all wakes of life, have created a situation where the useless and waste plastics from the abandoned electronics, carry bags, automobile accessories etc. Unless, economic disposal methods are found out, world will see the menace of soil degradation, loss of water table and many other problems associated with the non-biodegradable plastics. Even though, the scientists are working on the manufacture of biodegradable plastics, the existence of abundant waste plastics currently, needs a solution. Based on this reasoning, the novel catalytic conversion technique has been developed and successfully tested.

ALL our systems are ZERO air e mission

FISSORE AGENCY

P2P PLASTIC TO PETROL 5.2 Principles involved

Plastics are polymers containing carbon and hydrogen and few other elements like chlorine, nitrogen etc. polymers are a group of monomers combined together to form a single larger molecules called polymers. Polymers are High molecular weight molecules and when they degrade i.e when they break, they form low weight molecules called monomers. This is the reverse reaction of forming polymers from monomers. This process is called Degradation of polymers. In the process of conversion of waste plastic into fuels Degradation of Polymers takes place. The degradation polymers must happen in the absence of oxygen at a high reaction temperatures and in the presence of a Catalyst. The presence of oxygen or absence of catalysts will make the process into a melting of plastic process followed by the plastic getting converted to coke.

ALL our systems are ZERO air e mission

FISSORE AGENCY

P2P PLASTIC TO PETROL 5.3 Waste plastic Yield informatio n

In the process, waste plastic is heated to the reaction temperatures inside a Reaction vessel, in the presence of a catalyst. The plastic then starts degrading into low molecular weight monomers. The monomers re-combine to form petroleum vapours having different chains of hydrocarbons. The vapours are condensed to form light fuels. Here, the catalysts play a vital role and with the tweaking of catalysts we can convert the plastics to either LPG or Liquid fuels similar to Petrol . Input Catalyst Temperature Pressure Batch

Assorted waste plastic about 5% 250-4000°C Atmospheric continuous

The product yields Gas Liquid hydrocarbons Coke

Quantity (wt %) 10-15 70-80 7/10

Typical analysis of the gaseous product is given in the following table: S.No 1 2 3 4 5 6 7 8 9 10 11

Component Methane Ethane + ethylene Propane Propylene so - butane n-Butane C4 (unsaturated) Iso C5-n-C5 C5+higher Hydrogen CO/CO2

Quantity (w/w %) 7.0 11.0 7.5 28.0 2.0 1.0 25.5 0.1 15.3 2.6