DILUANT ECO

code 3S-5500

Revision: 00 - 30/07/2014

MATERIAL SAFETY DATA SHEET (According to 1907/2006/EC, 453/2010/EC)

Section 1. Chemical Product and Company Identification Product Name

DILUANT ECO

Chemical name CAS EC Index REACH

Ethyl Acetate (C4H8O2) 141-78-6 205-500-4 607-022-00-5 01-2119475103-46-xxxx

Product Use

Solvent for coating - For professional use only

Supplier

ORE ZAC du Bon Puits -B.P.50123 49481 ST SYLVAIN D'ANJOU Cedex -FRANCE

 : 33.02.41.21.14.10  : 33.02.41.21.14.18 Responsible for the MSD: [email protected] Section 2. hazards identification 2.1 Classification :  Directive 67/548/EC or Directive 1999/45/EC. This product was classified in accordance with directive 67/548/EC and Directive 1999/45/EC, adapting the requirements to regulation (EC) 1907/2006 (REACH).  R11: Highly flammable  R36: irritating to eyes  R66: Repeated exposure may cause skin dryness or cracking  R67: Vapours may cause drowsiness and dizziness  CLP Regulation (EC) 1272/2008 Classification of this product has been carried out in accordance with CLP Regulation EC 1272/2008  H225: Flammable liquids. Category 2  H319: Eye irritation. Category 2  H336: Specific toxicity causing drowsiness and dizziness, single exposure, Category 3 2.2 Label elements: LCP Regulation EC 1272/2008

Signal word : Danger Hazard indications : H225 - Highly flammable liquid and vapour H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness Prevention : P210 - Keep away from heat/sparks/open flames/hot surfaces – not smoking P243 -Take precautionary measures against static discharge P261 - Avoid breathing dust/fume/gas/mist/vapours/spray Page 1 sur 7

DILUANT ECO code 3S-5500 Revision: 00 - 30/07/2014 P280 - Wear protective gloves/protective clothing/eye protection/face protection P303+P361+P353 – IF ON SKIN (or hair) : remove/take off immediately all contaminated clothing. Rinse skin with water/shower P305+P351+P338 – IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Supplementary information: EUH066 - Repeated exposure may cause skin dryness or cracking 2.3 Other hazards Non-applicable 2.4- PBT –vPvB substance Not classified as PBT or vPvB

Section 3. composition – information on ingredients SUBSTANCE MIXTURE  in accordance with Annex II of 1907/2006/CE (point 3) the product contains: Identification CAS 141-78-6 CE 205-500-4 Index 607-022-00-5 Reach 01-2119475103-46-xxx

Name

Ethyl acetate

Directive 67/548/EC F - R11 Xi - R36 R66- R67

Regulation 1272/2008/EC Flam. Liq. 2 – H225 Eye Irrit.2 – H319 STOT SE 3 – H336

% weight

100

*For the wording of the listed risk phrases (R-H) refer to section 16

Section 4. First aid measures General information:  Remove immediately the soiled clothes  Remove from the exposure, lie down  The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the product or persistent discomfort, showing the MSDS of this product. Inhalation  Remove to fresh air. If breathing is difficult, seek medical attention  In case of unconsciousness place patient stably in side position for transportation Skin contact  After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non –abrasive soap. If irritation persists, seek medical attention.  Wash contaminated clothing before reusing. Eye Contact  Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek medical attention Ingestion  Do not induce vomiting. Never give anything by mouth to an unconscious person.  Seek immediate medical attention, showing the MSDS of this product

Section 5. Fire- Fighting Measures 5.1- Suitable extinguishing agents  Foam – carbon dioxide – chemical powder- water spray (fog)  It is recommended not to use tap water as an extinguishing agent. 5.2- Special hazards caused by substances, its products of combustion or resulting gases  Formation of toxic gases is possible during heating or in case of fire: CO, CO2, NO, …. 5.3- Protective equipment  Wear protective suit.  Remove all source of ignition  Cool all the containers with water spray

Page 2 sur 7

DILUANT ECO

code 3S-5500

Revision: 00 - 30/07/2014

Section 6. Accidental release measures 6.1- Personal precaution- protective equipment – emergency procedures  Remove the soiled clothes  Do not breathe vapors and smokes - Do not smoke  Avoid contact with skin and eyes – Wear suitable protective equipment: gloves, safety glasses,  Remove source of ignition and ventilate area  Take precautionary measures against static discharges. 6.2- Measures for environmental protection  Prevent seepage into sewage, streams and cellars. Do not allow to enter sewers/ surface or ground water.  Avoid at all cost any type of spillage into an aqueous medium. Contain the product absorbed appropriately in hermetically sealed containers  Notify the relevant authority in case of exposure to the general public or environment. 6.3 Measures for cleaning/ collecting  Absorb with inert material (sand-vermiculite...). Avoid use of sawdust or other combustible absorbents..  Dispose contaminated material as waste according to the local legislation  Ensure adequate ventilation

Section 7. Handling and Storage 7.1- Handling  Avoid contact with skin.  Ensure good ventilation/exhaustion at the workplace  Keep ignition source away – Do not smoke. Fully control sources of ignition (mobil phones, sparks,..) and ventilate during cleaning operations.  Protect against electrostatic charges  Wear suitable gloves  Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods. Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used.  Transfer in well ventilated areas, preferably through localized extraction.  Comply with the essential security requirements for equipment and systems defined in Directive 94/9/EC or/and 1999/92/E C (ATEX) . 7.2 Storage  Storage in a cool and well ventilated place, avoid heat and direct sunshine.  Store only in the original container at a temperature not exceeding 30°C  Keep the container tightly closed

Section 8. Exposure controls – personal protection 8.1- Control parameters Ensure good ventilation at the workplace. Personal, workplace pr environmental monitoring may be necessary to ensure exposures are below recommended and legal limits Limit values Ethyl acetate - VLE = 400 ppm (1400 mg/m3) France/INRS ACGIH : 400 ppm TWA - OSHA (US) = 400 ppm (1400 mg/m3 DNEL (Workers) Substance Ethyl Acetate

Page 3 sur 7

Oral Dermal Inhalation

Short exposure Systemic Local Non applicable Non applicable Non applicable Non applicable 1468 mg/m3 1468 mg/m3

Long exposure Systemic Local Non applicable Non applicable 63 mg/kg Non applicable 734 mg/m3 734 mg/m3

DILUANT ECO DNEL (Population) Substance Ethyl Acetate

PNEC Substance Ethyl Acetate

code 3S-5500

Revision: 00 - 30/07/2014

Oral Dermal Inhalation

Short exposure Systemic Local Non applicable Non applicable Non applicable Non applicable 734 mg/m3 734 mg/m3

STP = 650 mg/l Soil = 0.148 mg/kg Intermittent : 1.65 mg/l

Oral = 200 g/kg Sediment (fresh water) = 1.15 mg/kg Fresh water = 0.24 mg/l Sediment (marine xater) : 0.115 mg/kg Marine water = 0.024 mg/l

Systemic 4.5 mg/kg 37 mg/kg 367 mg/m3

Long exposure Local Non applicable Non applicable 367 mg/m3

8.2- Exposure controls - Personal Protective Equipment - General security and hygiene measures in the work place In accordance with the order of importance to control professional exposure (Directive 98/24/EC) it is recommended to use localized extraction in the work area as a collective protection measure to avoid exceeding the professional exposure limits. In case of using individual protection equipment they should have the ‘CE marking’ in accordance with Directive 89/686/EC. For more information on personal protection Equipment (storage, use, cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. 

Respiratory protection

In case of brief exposure or low pollution use respiratory filter device (A2/P2). In case of intensive or longer exposure: use self-contained respiratory protective device. 

Protection of hands

Wear protective gloves . The glove material has to be impermeable and resistant to the product (Nitril – EN 374 - > 45µ) For each workplace a suitable glove has to be selected. 

Eye Protection

Use safety glasses. (Tightly sealed goggles) 

Skin and body protection

Wear protective clothing covering the body  General protective and hygienic measures Keep away from beverages and food. Wash hands before breaks and at the end of work. Do not smoke during the use of the product.

Section 9. Physical and Chemical properties Form/colour/odour pH Boiling point Auto ignition temperature Flash point Lower flammability limit Page 4 sur 7

Liquid- colorless- characteristic smell Not applicable 77°C 426 °C - 4 °C 2.2% volume

DILUANT ECO Upper flammability limit Vapor pressure Vapor density Evaporation rate Specific gravity

code 3S-5500 11.4% volume < 110 kPa - 50°C 3.04 (air = 1) 6.2 (butyl acetate =1) 0.897 g/cm3

Revision: 00 - 30/07/2014

Section 10. Stability and reactivity 10.1- Reactivity No hazardous reactions are expected under normal storage and use conditions Vapors may form explosive mixture with air 10.2- Stability Chemically stable under normal storage, handling and use conditions 10.3- Hazardous decomposition product None when use as directed 10.4- Conditions to avoid Avoid heat, flames, sparks and other sources of ignition. Avoid inhalation of material or combustion by-products. Keep out of water supplies and sewers. Do not store at elevated temperatures. Avoid contact with material 10.5- Incompatible materials Strong acids, strong bases, strong oxidizers, nitrates

Section 11. Toxicological information Acute Oral Toxicity DL50 value Substance DL50 oral/rat DL50 Dermal /rabbit CL50 Inhalation/ rat Ethyl acetate 4 100 mg/kg 20 000 mg/kg 58 mg/l (8h) Dangerous health implications In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it may result in adverse effects on health depending on the means of exposure. Inhalation High concentration may cause respiratory tract and mucous membrane irritation. May affect central nervous system : fatigue, slow time reaction, drowsiness, dizziness, loss of consciousness. Ingestion May cause gastrointestinal tract irritation with nausea and vomiting Skin contact May cause skin irritation, may be harmful if absorbed through the skin Eye contact Risk of irritation in case of projection in eyes CMR This product contains no CMR substance

Section 12. Ecological information Do not allow product to reach ground water, water course or sewage system 12.1- Toxicity Substance CL50 - Fish CE50 - Daphnia Ethyl acetate (96h) = 230 mg/l (48h) 717 mg/l 12.2-Persistence and degradability Readily biodegradable 100% (OECD Test Guideline 301D, 28 days) 12.3- Bio accumulative potential Not expected (experimental log Pow : 0.73) Page 5 sur 7

CI50 - Algae (48h) > 3 000 mg/l

DILUANT ECO

code 3S-5500

Revision: 00 - 30/07/2014

12.4- Mobility in soil Koc = 59 - Surface tension : 23240 N/m(25°C) 12.5- Results of PBT and vPvB assessment Non applicable

Section 13. Disposal considerations Waste must be treated in agreement with the applicable regulations. Waste must be confided to an approved processing centre. Do not heat or cut the empty can with electric or gas torch.

Section 14. Transport Information UN Number

1173 – ETHYL ACETATE



ADR - RID

Hazard Class 3 – Hazard label 3 – Packaging group II – Tunnel (D/E)- LQ :1L



IMDG

Hazard Class 3 – Hazard label 3 – Packaging group II - Dangerous for environment : No



IATA

Hazard Class 3 – Hazard label 3 – Packaging group II

Section 15. Regulatory information 15.1- Safety, health and environmental regulations/legislation specific for the substance or mixture: Observe the general safety regulations when handling chemicals. The product has been classified and marked in accordance with Regulation CE 1907/2006 (REACH) Candidate substances for authorization under Regulation 1907/2006/EC (REACH): Non- applicable Regulation 1005/2009/EC about substances that deplete the ozone layer: Non-applicable Regulation 689/2008, in relation to the import and export of hazardous chemical products: Non- applicable Regulation EC 649/2012, in relation to import and export of hazardous chemical products: Non-applicable Limitations to commercialization and use of certain dangerous substances and mixtures (REACH-annex XVII) : listed in point 40

Specific provision in terms of protecting people or the environment: It is recommended to use the information included in this safety data sheet as data used in risk evaluation of the local circumstances in order to establish the necessary risk prevention measures for the manipulation, storage and disposal of this product.

Section 16. Other information This Safety Data Sheet has been designed in accordance with Annex II- guide to compilation of Safety Data Sheet of Regulation EC1907/2006 (REACH) [EC 453/2010]. Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and interpretation of this Safety data sheet, as well as the label on the product. Relevant R- H phrases R11 - Highly flammable R36 - Irritating to eyes Page 6 sur 7

DILUANT ECO code 3S-5500 R66 - Repeated exposure may cause skin dryness or cracking R67 - Vapours may cause drowsiness and dizziness H225 - Highly flammable liquid and vapour H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness

Revision: 00 - 30/07/2014

Abbreviations and acronyms ADR = European agreement concerning the international carriage of Dangerous goods by Road IMDG = International Maritime Dangerous Goods code IATA = International Air Transport Association LD50 = Lethal dose 50 CL50 = Lethal concentration 50 EC50 = Effective concentration 50 DNEL = Derived No Effect Level PNEC = Predicted No Effect Concentration OSHA = Occupational Safety and Health Administration ACGIH = American Conference of Industrial Hygienists INRS = Institut National de recherche et de Sécurité (France) VLE = Valeur Limite d’Exposition (VLE)

Department issuing MSDS: Safety. Environment department Contact: Hélène PION [[email protected]] This information is based on our present knowledge based on technical, national and European legislation. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. The product should be only applied for the applications noted in technical data sheet. The user is responsible to comply with the applied legislation. The information on this safety Data Sheet intends to inform the safety product requirements and it is not a total guarantee of the properties of the product.

Page 7 sur 7