DGMK International Conference

Catalysis – Novel Aspects in Petrochemistry and Refining September 26 – 28, 2016 Berlin, Germany

German Society for Petroleum and Coal Science and Technology Petrochemistry Division

This international conference provides a forum for chemists and engineers from refinery, petrochemistry and the chemical industry as well as from academia to discuss novel aspects of catalysis in petrochemistry and refining. Eight Keynote Lectures, 17 Lectures and 22 Posters will be presented at the conference. Additional “last minute posters“ are welcome. Authors who intend to present a “last minute poster“ are kindly requested to contact the Scientific Chairmen at or before the conference. The best poster of the conference will be selected by the attendees for the “Best Poster Award“. This international conference is organised by the DGMK German Society for Petroleum and Coal Science and Technology in association with the Società Chimica Italiana (SCI), the Austrian ÖGEW Österreichische Gesellschaft für Erdölwissenschaften, Leibniz-Institut für Katalyse e.V. (LIKAT), Rostock, and German Catalysis Society (GECATS), Frankfurt am Main.

Scientific Chairmen: Prof. Dr. Stefan Ernst, Technische Universität Kaiserslautern Dr. Ulrich Balfanz, BP Europa SE, Bochum Prof. Dr. Matthias Beller, Leibniz-Institut für Katalyse e.V., LIKAT, Rostock Dr. Michael Bender, BASF SE, Ludwigshafen Dr. Harald Häger, Evonik Performance Materials GmbH, Marl Dr. Mario Marchionna, Saipem S.p.A., San Donato Milanese

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Programme Monday, September 26, 2016 13.30

Registration at the Conference Desk

14.00

Opening and Welcome Address Stefan Ernst

Session Chairman: Mario Marchionna 14.15

Keynote Lecture: U. Pfisterer

BP Europa SE, Bochum, Germany

Opportunities and Challenges with Decarbonisation for Fuels in Refineries 15.00

J. Berg, A. Haas, F. Huber, M. Kirchmann, C. Liebold hte GmbH, Heidelberg, Germany

High Throughput Testing of Resid Hydroprocessing & Naphtha Reforming Catalysts

15.30

M. Mukherjee

Exelus Inc, Fairfield, USA

High-Octane Alkylate from Oil & Gas Derived Feedstocks

16.00

Coffee Break

16.30

Keynote Lecture: H.-C. Schwarzer, D. Himsl, R. A. Rakoczy

Clariant Produkte (Deutschland) GmbH, München, Germany

Tailoring Hydrocarbon Product Properties – Simple Solutions, Challenges, Limits – How to Find the Right Tools

17.15

S. Brandt, M. Scherer

Grace Catalyst Technologies, Worms, Germany

Driving FCC Operations and Profitability to Higher Levels 17.45

R. McGuire Jr., G. M. Smith, S. S. Pan, B. Yilmaz BASF SE, Ludwigshafen, Germany

Boron Based Technology for Fluid Catalytic Cracking and its Utilization in Refineries

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Tuesday, September 27, 2016 Session Chairman: Matthias Beller 8.30

Keynote Lecture: C. Gürtler

Covestro Deutschland AG, Leverkusen, Germany

Catalytic Reactions with Carbon Dioxide

9.15

D. Vogt

University of Edinburgh, UK

Catalytic Conversion of Ethene and Carbon Dioxide to Acrylic Acid 9.45

R. Kuhlmann, M. Nowotny, A. Prüllage, A. Behr TU Dortmund, Germany

Selective Hydrogenation of Carbon Dioxide to Formamides – From Flue Gas to Valuable Products 10.15

M. Ouda, G. Yarce, M. Hadrich, R. J. White, A. Schaadt, H. Klein

Fraunhofer-Institut für Solarenergie Systeme ISE, Freiburg APT Lehrstuhl, Technische Universität München, Germany

The Power to Liquid Concept: Hydrogenation of CO2 to Methanol and the Production of Oxymethylene Ethers

10.45

Coffee Break

11.15

Keynote Lecture: P. Wasserscheid, M. Haumann Universität Erlangen-Nürnberg, Germany

Supported Ionic Liquid Phase Catalysis 12.00

B. Etzold

Technische Universität Darmstadt, Germany

Carbon Based Catalysts

12.30

M. Hartmann, M. Fisch, M. Kriesten

Erlangen Catalysis Resource Center, Friedrich-AlexanderUniversität Erlangen-Nürnberg, Germany

Expanding the Horizon of Porous Catalyst: Metal Organic Frameworks for Base-Catalyzed Reactions 13.00

Lunch Break

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Tuesday, September 27, 2016 Session Chairman: Michael Bender 14.00

Keynote Lecture: P. T. Barger

Honeywell UOP, Des Plaines, USA

Recent Advances in the Production of Olefins and Aromatics 14.45

F. Fournier*; E. Wagner*, J.-P. Laugier**, T. Wurzel***, M. Gorny***, S. Haag****

*Technip Stone & Webster Process Technology, Claremont, USA, ** Technip, Paris, France, *** Air Liquide Global E&C Solutions, **** Air Liquide Forschung und Entwicklung GmbH, Frankfurt, Germany

Boost Ethylene and Propylene Production with Air Liquide´s MTP Process and Technip´s Ethylene Technology

15.15

A. Comazzi*, N. Livraghi*, C. Pirola*, C. Bianchi*, A. Di Michele**, F. Demartin*, K.S. Suslick***

*Dipartimento di Chimica, Università degli Studi di Milano, Italy, **Dipartimento di Fisica e Geologia, Università degli Studi di Perugia, Perugia, Italy, ***University of Illinois at Urbana-Champaign, School of Chemical Sciences, Urbana, USA

Ultrasonic Synthesis and Bench Scale Experimental Tests of Fe-Based Catalysts for the Fischer-Tropsch Reaction

French Cathedral (wikimedia)

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Tuesday, September 27, 2016 15.45

Poster Session and Coffee Survey of Posters on Display: Andreas Jess

The Posters are on display during the whole conference.

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M. P. Yunusov, Sh. T. Gulomov, Kh. A. Nasullayev, U. Kh. Saidov

Scientific - Research Chemical - Pharmaceutical Institute, Tashkent, Uzbekistan

Formation of the Active Centers of the Hydrotreating Catalysts

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F. Vogelgsang, O. Y. Gutiérrez, J. A. Lercher

Technische Universität München, Lehrstuhl für Technische Chemie II, Garching, Germany

Hydrogenation of Polyaromatic Compounds over Unsupported Ni-Mo, Ni-W, and Ni-Mo-W Sulfide Catalysts

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S. Albersberger, J. Hein, O. Y. Gutiérrez, J. A. Lercher

Technische Universität München, Department of Chemistry and Catalysis Research Center, Garching, Germany

Simultaneous Hydrodenitrogenation and Hydrodesulfurization of Model Compounds on Unsupported Ni-Mo-W Sulfide Catalysts

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J. Claußnitzer*, W. Korth*, A. Jess*, B. Bertleff**, J. Albert**, P. Wasserscheid**

*Department of Chemical Engineering, Center of Energy Technology (ZET), University of Bayreuth, Germany, **Institute of Chemical Reaction Engineering, University of Erlangen-Nürnberg, Germany

Oxidative Desulphurization with Polyoxometalate (POM)Catalysts

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M. Peroni, I. Lee, O. Y. Gutiérrez, J. A. Lercher

Department of Chemistry and Catalysis Research Center, Technische Universität München, Garching, Germany

Hydrocracking of Paraffins on Transition Metal Phosphide Catalysts

6

P. Rausch, C. Kern, W. Korth, A. Jess

Department of Chemical Engineering, Center of Energy Technology (ZET), University of Bayreuth, Germany

Hydrocracking of Fischer-Tropsch Waxes with Acidic Tungstenvanadophosphoric Polyoxometalates as Catalysts

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S. Rößler, F. Pöhlmann, C. Kern, A. Jess

Department of Chemical Engineering, Center of Energy Technology (ZET), University of Bayreuth, Germany

Accumulation of Liquid Hydrocarbons in Catalyst Pores During the Initial Phase of Cobalt-Catalysed FischerTropsch Synthesis

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Tuesday, September 27, 2016

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J. Thiessen, S. Rößler, A. Jess

Department of Chemical Engineering, Center of Energy Technology (ZET), University of Bayreuth, Germany

Catalyst Composition, Activity and Selectivity Evolution of Fe-based Catalysts during the Formation Phase in Fischer-Tropsch Synthesis

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F. Nadolny*, G. Stochniol**, S. Peitz**, W. Reschetilowski*

*TU Dresden,Germany, **Evonik Performance Materials GmbH, Marl, Germany

Effect of Surface Acidity on the Catalytic Properties of Micro-/ Mesoporous Composite Materials for Cracking of Renewables

10

K. Glowienka, C. Kern, A. Jess

Department of Chemical Engineering, Center of Energy Technology (ZET), University of Bayreuth, Germany

Formic Acid as Flexible Intermediate in Biofuel Production

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M. Seifert, D. Däumer, C. Bischof, T. Junietz, J. J. Weigand, W. Reschetilowski

Technische Universität Dresden, Germany

Deactivation Properties of Multistep Phosphorus Modified ZSM-5 in Ethanol to Hydrocarbons Process – Structure-property Relations and their Limits

12

N. Wilde*, C.Zschiesche*, D. Himsl**, R. Rakoczy**, A. Reitzmann**, J. Freiding**, D. Kubička***, R. Gläser*

*Institute of Chemical Technology, Universität Leipzig, Germany, **Clariant Produkte (Deutschland) GmbH, Bruckmühl/Heufeld, Germany, ***Technopark Kralupy VŠCHT Praha, University of Chemistry and Technology Prague, Czech Republic

Liquid Fuels by Hydroisomerization of Long-Chain Vegetable Oil-Derived n-Alkane Mixtures over Bifunctional Zeolites

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P. Garbis, C. Kern, A. Jess

Department of Chemical Engineering, Center of Energy Technology (ZET), University of Bayreuth, Germany

Selective Methanation of CO from Gas Mixtures Containing COx and H2

14

G. Tauer, C. Kern, A. Jess

Department of Chemical Engineering, Center of Energy Technology (ZET), University of Bayreuth, Germany

Influence of Transient Conditions on the Methanisation of CO2 from Biogas with Regenerative Hydrogen in a WallCooled Fixed Bed Reactor

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Tuesday, September 27, 2016

15

H. Warmeling, N. von Vietinghoff, A. J. Vorholt, A. Behr

Technical University of Dortmund, Germany

Comparison of Different Reactor Types for the AdditiveFree Aqueous Biphasic Hydroformylation of Midchain Olefin 1-Octene

16

T. A. Faßbach, R. Kirchmann, A. Behr, A. J. Vorholt

Lehrstuhl Technische Chemie, Technische Universität Dortmund, Germany

Telomerization of 1,3-Butadiene Using Pd/NHC Catalysts – Structure-Reactivity-Relationship of the Employed Alcohol

17

T. Gaide, J. Dreimann, A. Behr, A. J. Vorholt

Lehrstuhl Technische Chemie, Technische Universität Dortmund, Germany

Catalytic Functionalisation of Fatty Compounds in Aqueous Thermomorphic Solvent Systems

18

D. Vogelsang, K. A. Ostrowski, A. J. Vorholt

Lehrstuhl für Technische Chemie, TU Dortmund, Germany

Tandem-Catalytic Conversions of 2,7-Octadienol – Easy Direction of Reaction Pathway by Changing Catalytic Conditions

19

M. Schulz, S. Follmann, S. Ernst

Chemical Technology, Department of Chemistry, University of Kaiserslautern, Germany

Propene from Selective Conversion of Ethene over Hierarchical Zeolites ZSM-5, ZSM-22 and ZSM-23

20

N. Paluch, O. Malter, A. Schüßler, S. Ernst

Chemical Technology, Department of Chemistry, University of Kaiserslautern, Germany

Catalytic Activity of Novel Ternary Intermetallic Compounds in Base-Catalyzed Reactions

21

E.M. Movsumzade*, G.Yu. Kolchina**, A.Yu. Bakhtina*

*Ufa State Petroleum Technological University, Ufa, Russia, **Sterlitamak branch of the Bashkir State University, Sterlitamak, Russia

Assessment of the Reactivity of Combustion Catalysts and Investigation the Mechanism Catalysis in Combustion Methods of High-Level Quantum Chemistry

22

E.M. Movsumzade, E.Kh. Karimov, O.Kh. Karimov, O.Yu. Poletaeva

Ufa State Petroleum Technological University, Ufa, Russia

Modern Ion-Exchange Catalyst

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Tuesday, September 27, 2016 Session Chairman: Michael Bender 16.45

Keynote Lecture: G. Hutchings

Cardiff Catalysis Institute, Cardiff University, UK

Supported Gold Catalysts for the Hydrochlorination of Acetylene

17.30

A. Reinsdorf*, W. Korth*, A. Jess*, F. Klasovsky**

*Lehrstuhl für Chemische Verfahrenstechnik, Universität Bayreuth, Germany; **Evonik Technology & Infrastructure GmbH, Marl, Germany

Investigation of Deactivation Mechanism for Heterogeneous Industrial Hydrogenation Catalyst: Accelerated Aging and Catalyst Characterization

20.00

C onferenc e Dinner Restaurant „12 Apostel“ Georgenstr. 2 / S-Bahn-Bögen 177-180 10117 Berlin

German Cathedral and Concert Hall (Andre Huppertz, wikimedia)

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Wednesday, September 28, 2016 Session Chairman: Harald Häger 8.30

Keynote Lecture: J. Velasquez Ochia, C. Bandinelli, A. Chieregato, O. Vozniuk, A. Malmusi, C. Recchi, F. Cavani

Dipartimento di Chimica Industriale, Università di Bologna, Italy

Synthesis of Olefins from Renewables: The Case of Butadiene

9.15

C. Walsdorff

BASF SE, Ludwigshafen, Germany

Challenges in Selective Gas-Phase Oxidation Catalysis

9.45

D. Weber*, P. Weidler**, B. Kraushaar-Czarnetzki*

*Institute of Chemical Process Engineering (CVT), Karlsruhe Institute of Technology, Karlsruhe, Germany, **Institute of Functional Interfaces IFG, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen, Germany

Novel Structured Mixed Oxide Catalyst with Enhanced Catalytic Properties in the Selective Oxidation of Isobutene to Methacrolein 10.15

U.A. Kerimova, S.N. Osmanova, E.H. Ismailov

Institute of Petrochemical Processes, Azerbaijan National Academy of Sciences,Baku, Azerbaijan

Oxidative Dehydrocyclization of Methane over Rhenium Compounds/Alumina Catalysts

10.45

Coffee Break

Session Chairman: Ulrich Balfanz 11.15

Keynote Lecture: A. Behr

Technical University Dortmund, Germany

New Trends in the Catalytic Functionalisation of Petrochemical 1,3-Dienes

12.00

B. H. Müller*, U. Rosenthal*, N. Peulecke*, A. Wöhl**, W. Müller**, M. H. Al-Hazmi***, A. M. Alqahtani***

*Leibniz Institute for Catalysis at the University of Rostock e.V., LIKAT, Rostock, Germany, **Linde AG, Linde Engineering Division, Pullach, Germany, ***Saudi Basic Industries Corporation, Riyadh, Saudi Arabia

Comparative Study of New Chromium-Based Catalysts for the Selective Tri- and Tetramerization of Ethylene

12.30

M. Beller

Leibniz-Institute for Catalysis at the University of Rostock e.V., LIKAT, Rostock, Germany

Challenges and Novel Trends in Catalytic Carbonylation Reactions 13.00

Concluding Remarks and Conference Summary Stefan Ernst Lunch

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General Information Venue:

Berlin-Brandenburgische Akademie der Wissenschaften Markgrafenstraße 38 / Gendarmenmarkt D-10117 Berlin Phone: +49 30 203 70 200, Fax: +49 30 203 70 666 Venue: Leibniz-Saal

Conference Secretary: Christa Jenke DGMK Überseering 40 D-22297 Hamburg

Phone: Telefax: email:

+49 40 639004 12 +49 40 639004 50 [email protected]

On-Site Conference Secretariat at the

Berlin-Brandenburgische Akademie der Wissenschaften Monday, September 26, 2016 Tuesday, September 27, 2016 Wednesday, September 28, 2016

13.30 – 18.30 8.00 – 18.30 8.00 – 14.00

Phone: +49 (0) 176 51211298

Conference Language: English Hotel Reservation: Participants are requested to make their own hotel reservation. There will be no hotel reservation by DGMK. Special DGMK-rate are offered at: Winters Hotel Berlin Mitte am Gendarmenmarkt Charlottenstr. 66, D-10117 Berlin Phone: +49 30 20 60 50 0 Email: [email protected] Rate: Single room € 82,00/night incl. breakfast. Make room reservation not later than September 1, 2016. Motel One Prinzenstraße 40 / Moritzplatz, D-10969 Berlin +49 30 695 671 74-0 Phone: [email protected] Email: Rate: Single room € 59,00/night + € 9,50 breakfast Make room reservation not later than August 26, 2016. Park Plaza Wallstreet Berlin Mitte and art´otel Wallstr. 23-24 and Wallstr. 70-73 both D-10179 Berlin Phone: +49 30 400 557 700 [email protected] Email: (Park Plaza Wallstreet Berlin Mitte)

[email protected] (art ´otel) Email: Rate: Single room € 109,00/night incl. breakfast Make room reservation not later than August 1st, 2016.

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The conference is jointly organized by DGMK and

Società Chimica Italiana

Entrance of Berlin-Brandenburgische Akademie der Wissenschaften

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Registration: Please fill in the enclosed registration form and return it to the Conference Secretary. One registration form is requested for each participant. Registration should be done by

September 12, 2016 Registration Fee: Individual Members of DGMK, SCI or ÖGEW (Industry)

registration by after 12.09.16 12.09.16 € 550,00

€ 590,00

€ 290,00

€ 320,00

free

€ 100,00

Non-Members (Industry)

€ 580,00

€ 620,00

Non-Members (University)

€ 320,00

€ 350,00

€ 130,00

€ 160,00

Individual Members of DGMK, SCI or ÖGEW (University) Students - Individual Members of DGMK, SCI or ÖGEW (copy of student card requested)

Students - Non-Members

(up to the age of 30; copy of student card requested)

The registration fee includes: -

participation in the conference conference preprints (DGMK-Tagungsbericht) coffee/tea/cold drinks during the coffee breaks Lunch on Tuesday, September 27, 2016 Conference dinner on Tuesday, September 27, 2016 Lunch on Wednesday, September 28, 2016

Payment:

Payment is requested after receipt of the invoice.

Refunds:

Refunds will be made for cancellation received in writing until September 12, 2016. Substitutions may be made at any time for registered participants unable to attend.

Conference Preprints:

Lectures and posters presented at the DGMK-Conference are published in full length in the DGMK-Tagungsbericht. These publications are registered under ISBN-Numbers and ISSNNumber and are sold on the book market after the conference. The book will be given to each conference participant upon registration at the conference desk to be the basis for efficient discussions.

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How to reach the Venue The venue is located in the city center (Berlin Mitte) close to the station Friedrichstraße (one station from Berlin Hauptbahnhof)

Conference Dinner Restaurant 12 Apostel Georgenstr. 2

Station Friedrichstrasse

Conference Venue Berlin Brandenburgische Akademie der Wissenschaften Markgrafenstraße 38 / Gendarmenmarkt

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Registration

Fax: +49 40 639004 50

for the DGMK / SCI / ÖGEW- Conference “Catalysis – Novel Aspects in Petrochemistry and Refining” September 26 – 28, 2016 in Berlin

Title, First Name, Name Company/Institution Address

Telefon email

I register for the conference as a member of DGMK SCI / ÖGEW GeCatS as a non-member I am employed in the Industry Academia I am a Student under the age of 30 years I shall pay after confirmation of the registration form and receipt of an invoice

Date / Signature

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Please return to:

DGMK

Deutsche Wissenschaftliche Gesellschaft für Erdöl, Erdgas und Kohle e.V

Mrs. Christa Jenke Überseering 40

D-22297 Hamburg