Compounds & Chemical Bonds. Compounds & Chemical Bonds. Electrons, Configurations, & Bonds Noble Gases and The Rule of Eight

Compounds & Chemical Bonds View: How atoms bond 
 George Zaidan and Charles Morton! https://www.youtube.com/watch?v=NgD9yHSJ29I! Electrons, Config...
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Compounds & Chemical Bonds

View: How atoms bond 
 George Zaidan and Charles Morton!

https://www.youtube.com/watch?v=NgD9yHSJ29I!

Electrons, Configurations, & Bonds  Noble Gases and The Rule of Eight

! When a nonmetal and a metal combine, they form an ionic bond: Valence electrons of the metal are lost and the nonmetal gains these electrons to achieve a Noble gas electron configuration.! ð  When two nonmetals combine, they form a covalent bond: They share electrons to achieve a Noble gas electron configuration.! ð 

Ionic vs. Covalent Bonding

Compounds & Chemical Bonds

!Atoms in a compound (molecule) are in ratios of whole numbers with specific 3 -dimensional arrangements due to attractive inter-atomic forces (Bonds). These provide favorable energy states & spatial positions (lower energy & farther apart are better), which result in molecules having new chemical, physical, and biological properties.!

Compounds & Chemical Bonds

View: Types of Chemical Bonds! Hank Green / Crash Course!

https://www.youtube.com/watch?v=QXT4OVM4vXI!

Electronegativity

Periodic Table Properties & Organization

http://chemconnections.org/general/movies/html-swf/periodictrends.htm!

Periodic Table Properties & Organization

QUESTION

Periodic Table Properties & Organization

http://chemconnections.org/general/movies/html-swf/periodictrends.htm!

QUESTION

Number of Valence Electrons for Elements in the “A” lettered Vertical Columns Equal the Column Number!

Ionic Bonds

 

Result from electrostatic attractions of closely packed, oppositely charged ions.


 

Form when an atom, which can easily lose electrons reacts with one which has a high electronegativity, that is, it can easily gain electrons. The vertical A column number (# of valence electrons) in the Periodic Table indicates the ion that forms and the number of electrons gained or lost.! Eg. Na (-1e-) and Cl (7e-; +1 e-); Mg (-2e-) and Br (7e-; +1 e-) ; K (-1e-) and O (6e-; +2 e-)!

 

Ionic Compounds

Neutrally Charged! Eg. Salt: NaCl → 1 Na+ and 1 Cl - ! ð  What is the proportion of ions for a compound formed from Mg ion and chlorine?! ð  Mg2+ and Cl-

ð  1 Mg2+ combines with 2 Cl-

ð  ð 

Electron Configurations!

QUESTION

!Predict the formula for the binary ionic compound formed 
 by aluminum and oxygen.! A) Al2O3

!B) Al3O2

!C) Al2O

!D) AlO2

Ionic vs. Molecular (Covalent)  Compounds

Salt (ionic) vs. Water (covalent)!

http://chemconnections.org/general/movies/html-swf/comp_molec_ionic_co.htm!

Covalent Chemical Bonds Molecular Compounds

View: Hank Green! Crash Course!

https://www.youtube.com/watch?v=bD-SH1ASbjw!

Lewis Structures  (Named after Prof. G. N. Lewis UC Berkeley)

  Show

how valence electrons are arranged among atoms and in a molecule; particularly useful for covalent molecules.


  Reflects

central tenet that stability of a compound relates to noble gas electron configuration.


  Shows

bonds and relates to 3-dimensional shapes in molecular structures.!

G.N. Lewis

Photo Bancroft Library, University of California/LBNL Image Library

Footnote:

G.N. Lewis, despite his insight and contributions to chemistry, was never awarded the Nobel prize.

Lewis Electron-Dot Drawings Periods 2 & 3 http://chemconnections.org/general/movies/LewisDotStructures.swf!

Shapes of Molecules

View: What is the shape of a molecule?
 George Zaidan and Charles Morton!

Eg. Ammonia:! https://www.youtube.com/watch?v=Jq_Ca-HKh1g!

Lewis Structures / VSEPR  Molecular Models for C, H, N, O

 

Fundamental repeating shapes found in every biological molecule!

Lewis Structures / VSEPR  Molecular Models for C, H, N, O

 

Fundamental repeating shapes found in every biological molecule!

C =black! H = gray! N = blue! O = oxygen!

http://chemconnections.org/general/movies/html-swf /vsepr_four_electron.htm!

C =black! H = gray! N = blue! O = oxygen!

pink = generic atom!

Polyatomic Ions Discrete units of covalently bonded atoms that behave as ions

pink = generic atom!

QUESTION

Which formula containing polyatomic ions is correct?! !A) MgNO3

!B) NH4CO3

!C) Na(PO4)3 !D) Al2(SO4)3 !

http://chemconnections.org/general/chem120/polyatomics.html

Chemical Formulas & Molecular Representations

How many hydrogens, oxygens, and carbons are there in:! ethanol?! ethylene glycol?! aspirin?!

Red spheres are oxygen, the white/gray are hydrogen, and black carbon.!

Structural Representations of Quinine!

Proteins & Small Molecules

Structure-Odor Relationships

Karen J. Rossiter, Chem. Rev., 1996, 96, 3201-3240

http://dvcchem.org/COT/chemical-communication/ChemComm.html!

Shapes & Interactions: Mirror Images & Smell

http://ep.llnl.gov/msds/orgchem/Chem226/Smell-Stereochem.html

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