CLASSIFICATION AND LABELLING 1. Classification and labelling according to CLP / GHS Name: cadmium (non-pyrophoric) Implementation: EU State/form of th...
CLASSIFICATION AND LABELLING 1. Classification and labelling according to CLP / GHS Name: cadmium (non-pyrophoric) Implementation: EU State/form of the substance: powder Remarks: cadmium is usually manufactured as massive solid; small quantities produced as non-pyrophoric powder Classification and labelling according to CLP / GHS for physicochemical properties Not classified for physico-chemical properties Classification and labelling according to CLP / GHS for health hazards Endpoint
Hazard category
Hazard statement
Acute toxicity inhalation:
Acute Tox. 2
H330: Fatal if inhaled.
Reproductive Toxicity: Repr. 2
H361: Suspected of damaging fertility or the unborn child .
Germ cell mutagenicity:
Muta. 2
H341: Suspected of causing genetic defects .
Carcinogenicity:
Carc. 1B
H350: May cause cancer .
Specific target organ toxicity - repeated:
STOT Rep. Exp. H372: Causes damage to organs through prolonged or repeated exposure . kidney, lung, bone Route of exposure: Inhalation
Classification and labelling according to CLP / GHS for environmental hazards Endpoint
Hazard category
Hazards to the aquatic environment (acute/short-term):
Aquatic Acute 1 H400: Very toxic to aquatic life.
Hazards to the aquatic environment (longterm):
Aquatic Chronic H410: Very toxic to aquatic life with long 1 lasting effects.
M-Factor acute: 10 M-Factor chronic: 10
Hazard statement
Labelling Signal word: Danger Hazard pictogram: GHS06: skull and crossbones
GHS08: health hazard
GHS09: environment
Hazard statements: H350: May cause cancer H341: Suspected of causing genetic defects H361: Suspected of damaging fertility or the unborn child (H361fd is exact statement) H330: Fatal if inhaled. H372: Causes damage to Lung, kidney, bone through prolonged or repeated exposure by inhalation. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. Precautionary statements: P270: Do not eat, drink or smoke when using this product. P273: Avoid release to the environment. P391: Collect spillage. P281: Use personal protective equipment as required. P405: Store locked up. P308+P313: IF exposed or concerned: Get medical advice/attention. P501: Dispose of contents/container to... (According to local/national waste legislation) Name: cadmium (pyrophoric) Implementation: EU State/form of the substance: powder Classification Classification and labelling according to CLP / GHS for physicochemical properties Endpoint
Hazard category Hazard statement
Pyrophoric solids: Pyr. Solid 1
H250: Catches fire spontaneously if exposed to air.
Classification and labelling according to CLP / GHS for health hazards Endpoint
Hazard category
Hazard statement
Acute toxicity inhalation:
Acute Tox. 2
H330: Fatal if inhaled.
Reproductive Toxicity: Repr. 2
H361: Suspected of damaging fertility or the unborn child .
Germ cell mutagenicity:
Muta. 2
H341: Suspected of causing genetic defects .
Carcinogenicity:
Carc. 1B
H350: May cause cancer .
Specific target organ toxicity - repeated:
STOT Rep. Exp. H372: Causes damage to organs through prolonged or repeated exposure . kidney, lung, bone Route of exposure: Inhalation
Classification and labelling according to CLP / GHS for environmental hazards Endpoint
Hazard category
Hazards to the aquatic environment (acute/short-term):
Aquatic Acute 1 H400: Very toxic to aquatic life.
Hazards to the aquatic environment (longterm):
Aquatic Chronic H410: Very toxic to aquatic life with long 1 lasting effects.
Hazard statements: H250: Catches fire spontaneously if exposed to air. H350: May cause cancer. H341: Suspected of causing genetic defects. H361: Suspected of damaging fertility or the unborn child (exact statement is H361fd) H330: Fatal if inhaled. H372: Causes damage to lung, kidney, bone through prolonged or repeated exposure by inhalation. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. Precautionary statements: P273: Avoid release to the environment. P391: Collect spillage. P210: Keep away from heat/sparks/open flames/... /hot surfaces.... No smoking. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P281: Use personal protective equipment as required. P308+P313: IF exposed or concerned: Get medical advice/attention. P405: Store locked up. P501: Dispose of contents/container to... (according to local/national waste legislation) Name: cadmium (massive) Implementation: EU State/form of the substance: solid Classification The substance is classified as follows: Classification and labelling according to CLP / GHS for physicochemical properties Not classified for physic-chemical properties Classification and labelling according to CLP / GHS for health hazards Endpoint
Hazard category Hazard statement Reason for no classification
Reproductive Toxicity:
data lacking
Germ cell mutagenicity:
data lacking
Carcinogenicity:
data lacking
Specific target organ toxicity - repeated:
data lacking
Classification and labelling according to CLP / GHS for environmental hazards Endpoint
Hazard category
Hazard statement
Hazards to the aquatic environment (acute/short-term):
Aquatic Acute 1 H400: Very toxic to aquatic life.
Hazards to the aquatic environment (longterm):
Aquatic Chronic H410: Very toxic to aquatic life with long 1 lasting effects.
Hazard statements: H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. Precautionary statements: P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of contents/container to...
2. Classification and labelling according to DSD / DPD 2.1. Classification and labelling in Annex I of Directive 67/548/EEC Chemical name: cadmium (non-pyrophoric) Classification and labelling in Annex I of Directive 67/548/EEC for physicochemical properties Not classified for physic-chemical properties Classification and labelling in Annex I of Directive 67/548/EEC for health hazards Endpoint
Classification
Acute toxicity:
T+; R26 Very toxic by inhalation.
Repeated dose toxicity:
T; R48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
Carcinogenicity:
Carc. Cat. 2; R45 May cause cancer.
Mutagenicity - Genetic Toxicity:
Muta. Cat. 3; R68 Possible risk of irreversible effects.
Toxicity to reproduction fertility:
Repr. Cat. 3; R62 Possible risk of impaired fertility
Toxicity to reproduction -
Repr. Cat. 3; R63 Possible risk of harm to the unborn child.
Endpoint
Classification
development: Classification and labelling in Annex I of Directive 67/548/EEC for the environment Endpoint
Classification
Environment: N; R50/53 Dangerous for the environment; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Labelling Indication of danger: T+ - very toxic N - dangerous for the environment R-phrases: R45 - May cause cancer R26 - Very toxic by inhalation R48/23/25 - Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed R62 - Possible risk of impaired fertility R63 - Possible risk of harm to the unborn child R68 - Possible risk of irreversible effects R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S-phrases: S53 - avoid exposure - obtain special instructions before use S45 - in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) S60 - this material and its container must be disposed of as hazardous waste S61 - avoid release to the environment. Refer to special instructions/safety data sheets Notes: Note E Chemical name: cadmium (pyrophoric) Classification and labelling in Annex I of Directive 67/548/EEC for physicochemical properties Endpoint
Classification
Flammability:
F; R17 Spontaneously flammable in air.
Classification and labelling in Annex I of Directive 67/548/EEC for health hazards Endpoint
Classification
Acute toxicity:
T+; R26 Very toxic by inhalation.
Repeated dose toxicity:
T; R48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
Carcinogenicity:
Carc. Cat. 2; R45 May cause cancer.
Mutagenicity - Genetic Toxicity:
Muta. Cat. 3; R68 Possible risk of irreversible effects.
Toxicity to reproduction fertility:
Repr. Cat. 3; R62 Possible risk of impaired fertility
Endpoint
Classification
Toxicity to reproduction development:
Repr. Cat. 3; R63 Possible risk of harm to the unborn child.
Classification and labelling in Annex I of Directive 67/548/EEC for the environment Endpoint
Classification
Environment: N; R50/53 Dangerous for the environment; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Labelling Indication of danger: F - Highly flammable T+ - very toxic N - dangerous for the environment R-phrases: R45 - May cause cancer R17 - Spontaneously flammable in air R26 - Very toxic by inhalation R48/23/25 - Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed R62 - Possible risk of impaired fertility R63 - Possible risk of harm to the unborn child R68 - Possible risk of irreversible effects R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S-phrases: S53 - avoid exposure - obtain special instructions before use S45 - in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) S7/8 - keep container tightly closed and dry S43 - in case of fire, use... (Indicate in the space the precise type of fire-fighting equipment. if water increases risk, add 'never use water') S60 - this material and its container must be disposed of as hazardous waste S61 - avoid release to the environment. Refer to special instructions/safety data sheets Notes: Note E
2.2. Self classification(s) Chemical name: cadmium (massive) Self classification according to Directive 67/548/EEC criteria Endpoints
Classification
Reason for no classification
Acute toxicity
data lacking
Repeated dose toxicity
data lacking
Carcinogenicity
data lacking
Mutagenicity - Genetic
data lacking
Endpoints
Classification
Reason for no classification
Toxicity Toxicity to reproduction- fertility
data lacking
Toxicity to reproductiondevelopment
data lacking
Environment
N; R50/53 Dangerous for the environment; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Labelling Indication of danger: N - dangerous for the environment R-phrases: R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S-phrases: S60 - this material and its container must be disposed of as hazardous waste S61 - avoid release to the environment. refer to special instructions/safety data sheets
