Chemical Homeland Security System

George R. Thompson, Ph.D. President and CEO

Chemical Compliance Systems, Inc. 706 Route 15 South, Suite 207 • Lake Hopatcong, NJ 07849 • 973-663-2148 • (fax) 973-663-2378 [email protected] • www.chemply.com

The CCS “Core” Database System 2,500

2,125,000

340,000

6,900,000

CHEMICAL COMPOUND DICTIONARY

COMPENDIUM OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

CHEMICAL CROSS REFERENCE DICTIONARY

ITEM INDEX & PRODUCT DESCRIPTIONS

Tabulation of 2,500 specific chemicals within 58 compound categories

A compilation of acute and chronic health effects for 140,000 chemicals

A cross-referencing system of CAS numbers and their associated synonyms

265,000

Unique identifiers for over 75,000 chemical product items

MANUFACTURERS

PRODUCT COMPONENTS

Detailed information for 8,200 manufacturers of chemical products 6,400

CHEMICAL DISPOSAL CODES Disposal and compatible chemical family storage classifications for 3,200 chemicals

Specific descriptors for more than 300,000 product components

350,000

LIST OF LISTS

CCS

Reference listings for 4,650 regulated hazardous chemicals and associated data found on 300 local, state, federal and international lists

CCS 60,000

375,000

MSDS IMAGES

PRODUCT USER DIRECTORY 2,500

80,000

RATING INFORMATION OF CHEMICAL HAZARDS A rating classification covering health, fire, reactivity, environmental, protective equipment, etc., for 3,200 chemicals

CAMEO

Master Chemical Reference Data (2,915,000 References)

Mode 4 TIF multi-page images of manufacturer MSDSs

Dictionary listing of organizations that use each of the 75,000 unique items

Information data for responders to hazardous chemical emergencies (firefighting, health, first aid, etc.)

Master Product Reference Data (10,960,000 References)

413 360,000

GENERIC CATEGORIES

6,400

1,100

1,050

SAFE CHEMICAL STORAGE CODES

CHEMICAL HAZARD RESPONSE INFORMATION SYSTEM

OIL & HAZARDOUS MATERIALS TECHNICAL ASSISTANCE DATA SYSTEM

Chemical hazard and compatible family storage classifications for 3,200 chemicals

3,000,000

Comprehensive source of preventive, precautionary and response data

Information relating to spill response and harmful effects

Product classification codes derived from federal/state commodity lists that categorize similar products

MSDS INDEX Searchable parameters for each of our 60,000 imaged MSDSs 670

PROCESS CODES Dictionary of USN, DA and MD categories used to track HM usage and HW generation

Comprehensive Chemical Hazard Evaluation Criteria

CHRONIC HEALTH

ACUTE HEALTH LD50 (O/D) LC50

S/E Irritation Stench

pH IDLH

Carcinogenicity Reproduction Effects

TLV PEL

REACTIVITY (NFPA)

SPECIAL

FIRE Flash PointBoiling Point

Radioactive Oxidizer

Organ Effects (Neurotoxicity) Bioconcentration Factor

Water-reactive Corrosive

Explosivity Stability

Shock Sensitivity Heat/Pressure Sensitivity

ENVIRONMENTAL (AIR-WATER-SOIL) Vapor Density Odor Index Fish LD50 Specific Gravity

Volatilization Vapor Pressure Water Solubility Adsorptivity

Biological Exposure Index Biological Oxygen Demand (BOD) Chemical Oxygen Demand (COD) Total Oxygen Demand (TOD)

Persistence Hydrolysis Photolysis Biodegradation

Groundwater Mobility Factor Ambient Aquatic Life Advisory Concentration -AALAC Maximum Contaminant Level-MCL Maximum Contaminant Goal-MCLG

Enhanced MIDAS Database Library



Diagrams Drawings Specifications Standards

Munitions [5266]

RRD Inventory [Stockpile]

MCN Library

Components [13,711]

Parts [42,174]

Parts Environmental Disposition

Bulk Item Materials [3062]

PEP Materials [1824]

MilSpec Review

Bulk Compounds [7917]

Inert Materials [2957]

Alloy Metal Content

PEP Compounds [7188]

Compound Elements

Regulatory Database

CAS # and Synonyms Dictionary

Nonmetal Chemical Content

Inert Compounds [19,104]

MACS-1 / MIDAS Munitions Reference Databases Munition Control Number Dictionary

Bulk Material MilSpec Dictionary

Alloy Metal Composition Dictionary

Inert Nonmetal Composition Dictionary

Compound CAS#s & Synonym Dictionary

Compound Physical Property Dictionary Parts Environmental Disposition Dictionary

Compound Thermodynamic Property Dictionary

Regulated Hazardous Chemicals Acute Hazard Orientation

Chemical Agents Neurotoxins Extreme Toxins Radioactives Explosives Shock Sensitives Corrosives Flammable Oxidizers Hazardous Air Pollutants Persistent Bioacccumulative Toxins Priority Pollutants

Chemical Security Risks List

ACGIH DEA DOT EPA OSHA California Iowa Maryland Nevada New Jersey European Community

CPSC Specialty Regulated Substances Canada Export Control Lists DEA Essential Chemicals DEA Precursor Chemicals DOC Export Restrictions EU Black/Gray Lists IATA Air Transport Forbidden IATA Passenger Transport Forbidden IATA Regulated Substances UK The Red List (Water) UN/FAO Prior Informed Consent

Precursor Chemical Security Risks List

Chemical Agents and Simulants

Properties

Toxicology Data

—Structure —Chemical —Physical

—Human —Animal —In Vitro

Hazards —Protection —Decontamination —Persistence —Use

____________________________________ a HSAS = Homeland Security Advisory System

Incompatibilities —Chemical —Conditions —Containers

Storage Recommendations —Container —Conditions —Distances —HSASa Variables

Toxic Industrial Chemicals/Toxic Industrial Materials (TICs/TIMs) Selected Examples

Industrial Feedstocks:

Acrylamide, Chlorine, Hydrogen Chloride, Phosgene

Carbamate Insecticides:

Baygon, Mobam, Temik, Zectran

Organochlorine Insecticides:

Aldrin, Dieldrin, Endrin, Lindane, Heptachlor

Organophosphate Insecticides:

Disulfotan, Mevnphos, Parathion, Methylparathion

Insecticide Synergists:

Piperonyl Butoxide

Fungicides:

Pentachlorophenol, Hexachlorobenzene, Maneb, Naban, Zineb

Fumigants:

Calcium Cyanide, Methyl Bromide, Phosphine

Seed Disinfectants:

Methylmercury Acetate, Methylmercury Cyanide

GOALS: [1] Identify all chemicals with severe to extreme acute toxicity [2] Identify all chemicals in product classes with similar mechanisms of action

Incompatible Chemical Database Chemical Class

Chemical

Incompatible Chemical

I.C. Class

Interaction Hazard

Corrosives

Acetic Acid Nitric Acid Chlorine

Hydrogen Peroxide Acetylene Aluminum Powder

Oxidizer Flammable Metal

Explosion Explosion Spontaneous Fire

Flammables

Acetone Benzene Carbon Disulfide

Chloroform Chlorine Potassium

Carcinogen Corrosive Flammable

Explosion Explosion Violent Explosion

Reactives

Nitrotoluene Nitroethane Acrylonitrile

Sulfuric Acid Hydrocarbons Bromine

Corrosive Combustible Corrosive

Explosion Explosion Explosion

Products

Toilet Bowl Cleaner Bleach Paint Solvent

Metal Powders Ammonia Chloroform

Metals Product Carcinogen

Explosion Poisonous Gas Explosion

Safe Chemical Storage Codes Code # PK26 PR29 PR01 LG22 LG06 RD26 PK26 YL07 LG04 RD27 RD09 LG27 YL11 LG23 GN26 GN01 RD26 RD27 GN22 PK21 RD23 WH20

Chemical Acetaldehyde Acetylene Ammonia Aniline Arsenic Benzene Benzine Bromine Cadmium Camphor Carbon disulfide Chordane Chromic acid Coal tar creosote Cottonseed oil Cupric nitrate Cyclohexane 1,2-Dichlorobenzene Dimethylformamide 2,6-Dinitrotoluene Ethyl alcohol Formic acid

Code # RD26 YL10 YL07 RD23 GN04 LG24 LG07 YL27 RD26 RD26 YL12 WH23 RD06 LG03 GN02 GN08 LG02 RD26 YL11 RD26 RD26 RD26

Chemical n-Hexane Hydrogen chloride Iodine Isopropyl alcohol Lead Malathion Mercuric chloride Methyl chloroform Methyl methacrylate Naphthalene Nitric acid Phenol Phosphorous (yellow) Potassium arsenate Potassium permanganate Soda lime Sodium dichromate Styrene monomer Sulfuric acid Toluene Turpentine Xylenes

Chemical Compliance Analytical System (C-CAS) Product Desc.

Automated Usage Scales

Mfr. Table

NSNs

Local Data Area Inventory Mfr. Date

Date Received

Exp. Date

Location

Container Bar Code

Item Index

Product Comp.

Cont. & Storage Codes

Locations

Process Codes

Procurement Analyses

Quantity

Process Data

Bar Code

Container Data

Prods. Chems.

C-CAS Manufacturing Data Acquisition Module

Components

Unit of Issue

Trade Name

Storage Code

Manufacturer

Physical State

Item Number

Product Transaction & Cumulative Chemical Database with Local, Standardized Materials Management Analyses

C-CAS Site Data Acquisition Module

Master Inventory Reference Data

MSDS Index

MSDS Images

Activity/Tenant Analyses

Master Chemical Reference Data

C-CAS Communication Module

Label Placard

User ID

Location

Type of Generation

Waste Code

NRC Dispose

C-CAS Waste Module

Regulatory Impact Analyses

State Int'l.

Storage Combination Regulations

Health Hazards

Carcin. Terato.

Spill

Neurot. Exting.

Physical Hazards

Physical Data

Waste Profile Generic Dictionaries

Waste Process

Quantity

(multiple locations)

DOT

Specific Hazards

TLVs

Manifest List of Lists

Container Bar Code

OSHA

PPE

Chemical Hazard Rating Synonym/ CAS # Dictionary

Locat. EPA

Specific Regulations

(connects multiple locations) Size

Units Mfrs.

Hierarchical Materials Management Analyses

User Bar Code

Disposal Code

Totals

PELs Environmental Safety & Health Analyses

Acute Chronic

Environ. Hazards

Air, Water, Soil Data

Flam. Combination Hazards

Treated

Energy

Disposed

Recycled

Special Hazards

Oxydizers, Radioactives, H2O-Reacts.

C-CAS Centralized Database Module

Explos. Corros.

Environmentally Preferable Product Analyses

C-CAS Analytical Report Module

Proprietary Capabilities Provided as a Service from CCS

The CCS Approach for Total Systems Customization and Maintenance Analytical Reports

Local User

Unassessed Components Customized Compliance Management Software

Centralized Databases

Data Input Component Assessment Inventories

Research

Turnkey Support Existing/Proven SOPs

Chemical Compliance Analytical System (C-CAS) Derivative Systems

MSDS Images and Index

Client Inventory Input

Product Characterization

C-CAS Hub

Chemical Reference Databases

Final Reports

List of Lists Database

Munitions Analytical Compliance System for Demil (MACS-1) Chemical Release Database

MIDAS Munitions Characterization Database

Reference Databases

Client Module Installations Munitions Usage Inventory

MACS-1 Hub

Final Reports

Regulatory Databases

Munitions Analytical Compliance Systems (MACS) RATS Range Assembly

MACS-2 (Modification) Ranges

Plasma Arc

MACS-3 (Funded) Demil Scheduling

MACS-1 (Implemented) Demil APE 1236 Incinerator

MACS Centralized Databases

–

Munitions Characterization

TRACS (Funded) Hazardous Waste

Risk Module Demil Processes Constituent Chemicals Chemicals Released Green Criteria Insensitive Criteria Green Munitions

Green Energetics

G-MACS (Funded) Green Munitions

Hazardous Waste Forms Regulations I-MACS (Concept) Insensitive Munitions

ARAS (Concept) Ammo Reliability

MLCMT (Concept) Munition Life Cycle

C-HoSS Security Criteria and Standards

• Chemical Security Hazard Rankings (by Hazard Class) • Chemical Hazard Grades (1-4) (within each ranking) Chemical Hazard Factor (CHF) = Ranking H Grade

• Theft Risk Grades (1-4) (per product) Chemical Security Risk Factor (CSRF) = Ranking H Grade H Theft Risk

• Accessibility Factor Levels (Storage Constraint Levels and Descriptors) (0.5 - 4.5) CSRF ) Accessibility Factor (AF) = Vulnerability Factor (VF)

Chemical Security Product Storage Codes h Based Upon CSRF

h Codes = AF Levels a

CSRF = 30, or CHF = 6 b

= AF Level 1

CSRF =

70, or CHF = 12

= AF Level 2

CSRF = 110, or CHF = 18

= AF Level 3

CSRF = 150, or CHF = 24

= AF Level 4

__________________________________________ a AF Levels will be calculated at 1/2 step intervals. b Whichever is lower for a hazardous material.

Chemical Security Criteria and Homeland Security Advisory System (HSAS) Correlation

HOMELAND SECURITY ADVISORY SYSTEM (HSAS)

If CSRF = or CHF = Then AF Increases

SEVERE

HIGH

ELEVATED

GUARDED

LOW

Red

Orange

Yellow

Blue

Green

> 24 or > 12

> 50 or > 20

> 100 or > 28

> 150 or > 32

> 175 or > 40

2 Levels

1.5 Levels

1.0 Levels

0.5 Levels

0 Levels

Centralized Chemical Hazard and Environmental Management System (C-CHEMS) Centralized and Relational Databases

Industrial Industrial Hygiene Hygiene (IH-CAS) (IH-CAS) Locations & Types Processes Test Results

Natural Natural Resources Resources INRM Plan NEPA AR-200-3

Chemical Chemical Tracking Tracking (C-CAS) (C-CAS) or or Existing Existing System System Chemicals/Products MSDS Images/ Index Location

Hazards Incompatibilities Storage

Cultural Cultural Resources Resources Inventory NEPA Mitigation Plans

CCS Core Database

Air Air (A-CAS) (A-CAS)

Commercial Products

Permits Processes Test Results

Munitions

Green Green Products Products (GP-CAS) (GP-CAS)

Chemicals

Health Impact Green Rating Site-Specific

Munitions ) Munitions (MACS) (MACS) MIDAS Characterization Constraints Dispositions

Green Green Munitions Munitions (GM-CAS) (GM-CAS) Health Impact Green Rating Site-Specific

Chemical Agents

Water ) Water (W-CAS) (W-CAS) Permits Treatments Test Results

Agent Simulants

Storage ) Storage Tanks Tanks (ST-CAS) (ST-CAS)

Regulations

Types & History Permits Inspection Criteria

Toxics Toxics (T-CAS) (T-CAS)

Hazardous Hazardous Waste Waste (HW-CAS) (HW-CAS)

Locations & Types Inspections Test Results Wireless Communication Options

Chemical ) Chemical Safety Safety (CS-CAS) (CS-CAS)

Restoration Restoration Program Program

Pesticides Pesticides (P-CAS) (P-CAS) Permits Schedules Inspections

Soil GIS NJAC 7:14 CERCLA

Environmental Environmental Audits Audits (E-CAS) (E-CAS) Permits & Standards Evaluation Criteria Checklists

Locations & Permits Schedules Dispositions

Solid Solid Waste Waste (SW-CAS) (SW-CAS) Locations & Types Schedules Dispositions

Secure Web Access Options

Chemical Homeland Security System (C-HoSS) Centralized and Relational Databases Chemical Tracking (C-CAS) or Existing System Industrial Hygiene (IH-CAS) Locations & Types Processes Test Results

Chemicals/Products MSDS Images/ Index Location

CCS Core Database

Air (A-CAS) Permits Processes Test Results

Commercial Products

Chemical Safety (CS-CAS)) Hazards Incompatibilities Storage

Munitions (MACS)) MIDAS Characterization Constraints Dispositions

Munitions Storage Tanks (ST-CAS))

Water (W-CAS)) Chemicals

Permits Treatments Test Results

Chemical Agents Agent Simulants

Toxics (T-CAS)

Security Factors

Locations & Types Inspections Test Results

Regulations

Pesticides (P-CAS)

Wireless Communication Options

Permits Schedules Inspections

Types & History Permits Inspection Criteria

Hazardous Waste (HW-CAS) Locations & Permits Schedules Dispositions

Solid Waste (SW-CAS) Product Security & Containment (PS-CAS) Chemical Risks Product Storage Codes Security Standards

Locations & Types Schedules Dispositions

Secure Web Access Options

Chemical Homeland Security System (C-HoSS) and Chemical Hazard and Environmental Management System (C-CHEMS) EMS HoS

EMS

Industrial Hygiene (IH-CAS)

HoS

Munitions (MACS)) MIDAS Characterization Constraints Dispositions

Commercial Products

Health Impact Green Rating Site-Specific

Chemicals HoS

EMS

Green Munitions (GM-CAS)

Munitions

Health Impact Green Rating Site-Specific

EMS

Chemical Agents

HoS

Storage Tanks (ST-CAS))

Water (W-CAS))

Agent Simulants

Permits Treatments Test Results

Types & History Permits Inspection Criteria

Security Factors HoS

EMS

Regulations

Toxics (T-CAS) Locations & Types Inspections Test Results

HoS

Pesticides (P-CAS) Permits Schedules Inspections

HoS

Hazardous Waste (HW-CAS) Locations & Permits Schedules Dispositions

HoS

EMS

Wireless Communication Options

Hazards Incompatibilities Storage

CCS Core Database

Green Products (GP-CAS)

EMS

Chemical Safety (CS-CAS))

EMS

Permits Processes Test Results

EMS

HoS

EMS

HoS

Air (A-CAS)

EMS

Chemical Tracking (C-CAS) or Existing System Chemicals/Products MSDS Images/ Index Location

Locations & Types Processes Test Results EMS

HoS

Product Security & Containment (PS-CAS) EMS

Environmental Audits (E-CAS)

EMS

HoS

Solid Waste (SW-CAS) Locations & Types Schedules Dispositions

Secure Web Access Options

C-HoSS Security Risk Assessment Analytical Reports PRODUCT PRODUCT & & CHEMICAL CHEMICAL ANALYSES ANALYSES

PRECURSOR PRECURSOR CHEMICAL CHEMICAL ANALYSES ANALYSES

SPECIALTY SPECIALTY MODULE MODULE ANALYSES ANALYSES

Inventory by Product Type a Product by Location Product by Container Size Product by Weight Product Hazard Classifications Product Hazard Rankings Product Hazard Grades Product Hazard Factors Product Security Risk Factors Product Accessibility Factors Product Accessibility Levels/Storage Codes Chemicals by Product Pure Chemicals by Location Pure Chemicals by Weight

Precursor Chemicals by Location Precursor Chemicals by Container Size Precursor Chemicals by Weight Precursor Chemicals Hazard Classifications b Precursor Chemicals Hazard Rankings Precursor Chemicals Hazard Grades Precursor Chemicals Hazard Factors Precursor Chemicals Security Risk Factors Precursor Chemicals Accessibility Factors Precursor Chemicals Accessibility Levels/Storage Codes

Air Releases Water Contaminants Toxics Pesticides Hazardous Waste Solid Waste Storage Tanks Munitions Chemical Safety Industrial Hygiene

INCOMPATIBILITY INCOMPATIBILITY ANALYSES ANALYSES

SECURITY SECURITY ANALYSES ANALYSES

Prioritized Incompatibility Threats by Product Prioritized Incompatibility Threats by Room Prioritized Incompatibility Threats by Building Prioritized Incompatibility Threats by Facility

Inventory by CHF Inventory by CSRF Inventory by AF Inventory by Storage Levels Inventory (shift) by HSAS

__________________________________________________________________________________________________________________________ a b

Chemical, Precursor Chemical, Munition, Chemical Agent, Simulant. Assigned by their worst classification: (1) inate classification, or (2) reaction product classification.

For more information . . .

contact Dr. George R. Thompson 973-663-2148 [email protected]

706 Route 15 South, Suite 207 • Lake Hopatcong, NJ 07849 • 973-663-2148 • (fax) 973-663-2378 [email protected] • www.chemply.com