BNA08656954 H D M St00014723

LABORATORY REPORT

SMITH-EMIER Y COMPANY CHEMISTS - ENGINEERS 920 SANTEE STREE T

LOS ANGELES 1 3

Date

L4BOR .ITORY No. 305585 Sample WATER Marked Received

March 11, 194 9

" From Well Sampled by Smith -Emery Company"

3

3/3/4 9

Submitted by

North American Aviation, Inc . Los Angeles Municipal Airport Los Angeles, Californi a

Att : R. L . Kaufman, Dept . 90 Plant 'Engineering MILYSIS TART ! N PER MILLIO

ANALYSIS OF DISSOLVED SOLIDS

Silica».». »... .....».»__»(SiO:) . _...»....._.. ..._ .

5 .6

.aluminum Oxide. ._ ... . .(.41:0s) .__._. ... ... . .. »._

Trace 0 .4

Iron

13000

53 .6 Sodium

33.6

(Na)

sulphate...... ...... . ...._(SO~) »..._ Chloran,-..--»..- ....-._...(C!) Carbonares~. »» . _»..» ..-( COs) ..

»,

dluminum Oxide _....._.. Iron Oxide.- .... ......._ .Ft~>".»» »....» -

----_-

Trac e

01 4

Cakium Bicarbonate -----Ca(HCO;)%..-.--.. Calcium Sulphate. .» . .. .

Calcium Chloride --- ..-----_CaCI Magnesium Bicarbonate. '4g(HCO,) s__---

440 None

Magnesium Magnesium Chloride.. ... ... .WgCl4.--»». » Sodium Bicarbonate . ... ... ... ...VaHCO,»_»- .-._ Sodium Carbonate.____-------Na :COs »» -----..._

None

166 . 0 None Non e

None 72- 6

Sodium

......»...

»

786 . 7

Total Hardness as CaCO :............. _. . .._

5855 .3

526 . 5 Non e None

15 . 6

Sodium Total Solids.

Total Non-Volatile

50 6

silica ...». . ._. .. .- -.. . .» .»»._.SiO:».».»._. .» . ..

143 .0

786e7

Total Solids . . .» ._- ...... ... .» . ..... .»....». .._

HYPOTHETICAL COMBINATIONS PARTS PE P MILLION

463, 0

DETER MINr1TIONS Carbon Dioxide ( CO :) uncombined in p .p .m. --.Hydrogen Sulphide (H2S) in p .p .m . _ .».. .. . ..- .. Specific Electrical Conductance (K x 10-•) ..»».».I Hydrogen Ion Concentration (pH) . . ..... .. .._ . ..... .. .. Boron (B) in p.p .m .~_... .»». . . .» . »».».. . ... . .._. _. * Dissolved Oxygen (q.) *

44 .0 None 90 .0 7 .15 Trace _0 .d Do m

Color----- » ._ ... .. ...._ ... .»..». 10 odor-------_. . . _.» _. »». »... ... .»» None Taste.-._»__» _ ....- . . » ._ . .. . __... . Non e Turbidity .- ..»..» ._»..... . .. .». . .. ... ... .~ 10 Suspended

Trace

These items were determined from water

Respectfully submitted;

RI-D21- 065045

BNA0865695 5 HDMSt00014724

4/ I J i // /, P C

WATER ANALYSIS Samvle Identification : W ell hA at Storage Tank Sample ;o1lect?l : September 31, 1955 by R .! .W .

Color - 1 Suspended solids - q ppm Total dissolved solids - 520 ppve Settleable solids less than 0 .01 :al//L Equivalent conductance X106 .1 25C - 92 4

phi-7 .a Total hardness - 409 ppm as Ca CO Ionic constituents .pm as Ca OC 3

PPm Ca mg Na

5 .77 115 287 2 .40 29 120 2 .21 49 .3 10 7

K

.09 3 .5 4 .5

Fe N'H4 0 .0

0 .6 0.0

10 .47

0.0

CC) H

3

6.28

383

31L

2 .86

137

1h2

504 Cl W03 W02 F

1 .15

57 . 5

0. 0 0. 0

.2

P0 4 P03

40.8

0 .0

0 .6

10 .2 9

Free CO2 by calculation - 24 ppm .

-8-

RI-D21-065046 .

BNA0865695 6 H D M St00014725

iv i . ; :\I' :.1'

:~ ~-7r -rnx•

Sample Identification : 'Fell LA at Storage T ank Spectrographic - Se-niquantitative Analysis on 0 .1160 a . residue from evaporation of 200 -,ml sample .

IDq/L Calcium Cower Sodium Potassium Magnesium

25 .0 0 .00072 2 .1 .82

4.4

162 . 0 .004 12 . 2

4. 7 26 . 0 .1 0

Aluminum

0 .019

Iron Manganese

0.14

.8 1

0 .13 3 .1

.7 5 18 .00 .1 9

Silicon Boron

Strontium

0 .033

0 .17

.99

Well 4A - Lime Treatment, probable composition after : Color Clear pH 8 .5 - 9 .0 Calcium 10 - 20 ppm Iron Zero Carbon Dioxide Zero Hardness as Ca CD, 130 pots Total dissolved soli .ds 300 ppm

-9-

RI-D21-06504 7

BNA0865695 7 H D M St00014726

NATIONAL ALUMINATE CORPORATIO N

REPORT OF WATER ANALYSI S From

"" i :Ortj: 1 t :'Cro-h' : c c

Address tii £'-nt

:~':

,

••

I

T n n

,

Attention o f Analy in* No .

~3 00 2

Snn.pling rout.

Phy.ica!Appearenoe

C^ or1Cs? .

floc sJ!, .r-1-,t .

ANALYSIS HYPOTHETICAL COMBINATIONS Results shown in Grains 1.•r U . S . Gallon unless otherwise indicated . To convert to ppm . multiply by 17 . 1

Total Di .sol . ed Solids . . . . . . . . . . . . . . . .

Silica . . . . . . . . . . . . . . . . . .

Suspended Solids . . . . . . . . . . . . . . . . . . . . . .

Alumina . . . . . . . . . . . . . . .

Total Hardness ( as CsCO, ) . . . . . . . . . . .

Ferric Oxide . . . . . . . . . . . .

Non-Carbonate Hardness (as CaCO3) . . .

Calcium Carbonate . . . . . .

Calcium Hardness ( as CaCO3 ) . . . . . . . . .

Magnesium Carbonate . . . .

Magnesium Hardness (as CaCO3) . . . . . .

Calcium Sulphate . . . . . . . .

Phenolphthalein Alk . (as CaCOs) . . . . . .

Magnesium Sulphate . . . . .

P(BaCI2) Alk . (as CaCO3 )

Calcium Chloride . . . . . . . .

Total Alk .(r. ;CJ.) . . . . . . (as CaCO3) . . . .

Magnesium Chloride . . . . .

Free Carbon Dioxide

(as CaCO3) . . . .

Sodium Hydroxide . . . . . . .

Chloride ( as NaCl) . . . . . . . . . . . . . . . . . . .

Sodium Carbonate . . . . . . .

Sulphate ( as Na ,S04) . . . . . . . . . . . . . . . . .

Sodium Chloride . . . . . . . . .

Silica ( as SiOs ) . . . . . . . . . . . . . . . . . . . . . .

Sodium Sulphate . . . . . . . .

Alumina

Sodium Phosphate . . . . . . .

(as A1203) . . . . . . . . . . . . . . . . . .

Iron ( as Fe in ppm.) . . . . . . . . . . . . . . . . .

Phosphate ( as P0 4 in ppm .) ( ie c~ Total Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

BNA0865695 8 H D M St00014727

ALUMINATE CORPORATIO N

.NATIONAL

6216 West 66th Mau CMepe 38, 1 1111nois

REPORT OF WATER ANALYSIS From r .- .

Attention o/

An dre, a

A naly.is No.

Sample Marked

Sursplinp h at • • .' 3 C a7 : •

Phy.i a1 A ppeotrswes i ~.

' . . .j ?OC

C ._

51, .a a

__ANALYSIS HYPOTHETICAL COMBINATION S Result . ,hewn in Griina p, r U . S . Galion unlmu otherwia • indieated . To conve rt to ppm . multiply by 17. 1

Total

I)ivsolved Solids . . . . . . . . . . . . . . . .

3



C`

Silica . . . . . . . . . . . . . . . . . .

Suspended Solids . . . . . . . . . . . . . . . . . . . . . .

Alumina . . . . . . . . . . . . . . .

Total Hardness ( as CaCO3 ) . . . . . . . . . . . ,^ j • r'

Ferric Oxide . . . . . . . . . . . .

Non-Carbonate Hardness (s, CaCO .) . . . } •~ ~

Calcium Carbonate . . . . . .

Callum Hardness ( as CaCO3 ) . . . . . . . . .

Magnesium Carbonate . . . .

Magnesium Hardness (as CaCO .) . . . . . .

Calcium Sulphate . . . . . . . .

Phenolphthalein Alk . (as CaCO3) . . . . . .

Magnesium Sulphate . . . . .

P(BaC12) Alk . (so CaCO5) . . . . . . . . . . . .

Calcium Chloride . . . . . . . .

Total Alk . (. . .^ }. . . . . . (as CaCO,) . . . .

Magnesium Chloride . . . . .

Free Carbon Dioxide

(as CaCO :, ) . . . .

Sodium Hydrezid. . . . . . . .

Chloride ( as NaCl) . . . . . . . . . . . . . . . . . . .

Sodium Carbonate . . . . . . .

Sulphate ( as Na-.SO,) . . . . . . . . . . . . . . . . .

Sodium Chloride . . . . . . . . .

Silic-3 ( as SiOs ) . . . . . . . . . . . . . . . . . . . . . .

Sodium Sulphate . . . . . . . .

Alumina ( as A12Os ) . . . . . . . . . . . . . . . . . .

Sodium Phosphate . . . . . . .

Iran (as Fe in ppm.) . . . . . . . . . . . . . . . . . Phosphate ( as P04 in ppm.) .a e•,ti. . - .,y Total Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

U..,' A •.. 1510 I? .e

BNA0865695 9 H D M St00014728

NATIONAL

ALUMINATE CORPORATIO N

6216 West 66th Place Chkpo 38, Illinois _

REPORT OF WATER ANALYSIS Atfrntim: of

8309 1

Analysis No. Sample Marked :

Sampling 10f .

Physicaj Appe ara4ses

; I '' no cc :

n_ ' 1 •'' C: O^I.C i 13 .

floc

ANALYSISR sults e

a1i,-ht .

HYPOTHETICAL COMBINATIONS , .hnwn in Grains p .•r U . S . Gallon unless otherwise indicated. To convert to ppm . multiply by 17 . 1

Total Dissolved Solids . . . . . . . . . . . . . . . .

Silica

Suspended Solids . . . . . . . . . . . . . . . . . . . . . .

Alumina

Total Hardness (am CaCOj ) . . . . . . . . . . .

. . . . . ........ . . . .. . . . . . . . . . . . .. . .

2 1 .1+- Fer ri c Oxide . . . . . . . . . .

Non-Carbonate Hardness (as CaCOa)

Calcium Carbonate . . . . . .

Calcium Hardness ( as CaCO3) . . . . . . . . .

Magnesium Carbonate . . . .

17

Magnesium Hardness (as CaCO -j ) . . . . . .

Calcium Sulphate . . . . . . . .

Phenolphthalein Alk . (as CaCO1) . . . . . .

r) .0 Magnesium Sulphate . . . . .

P(BaCI 2) Alk . (aa CaCO3 )

Calcium Chloride. . . . . . . .

Total Alk. . . . . . . . . . . . . (as CaCO,) . . . .

Magnesium Chloride . . . . .

Free Carbon Dioxide

(as CaCO?) . . . .

Sodium Hydroxide . . . . . . .

Chloride (as NaCl) . . . . . . . . . . . . . . . . . . .

• f-' Sodium Carbonate : . . . . . .

Sulphate (as Na2SO4) . . . . . . . . . . . . . . Silica

. .

;as Si02) . . . . . . . . . . . . . . . . . . . . . .

Alumina

( as A1 203) . . . . . . . . . . . . . . . .

1



~'

Sodium Chloride . . . . . . . . .

c . 6 Sodium Sulphate . . . . . . . . Sodium Phosphate . . . . . . .

iron ( as re in ppm .) . . . . . . . . . . . . . . . . . Phos p hate ( asppm P04 i n .) .

.-., . . , .-.

Total Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

G-3 -49 Irste

Mn

Fam it A qv 11'/ IT

BNA08656960 HDMSt00014729

c,rLp $ERv r • .r s?~a' 'T * NG CNEMWC -LS FOR ALL NOUSTRWO MVNICS FAUTI& S

tr1( ► `AI_ AU UM', t1[ Cote;r)O (? ATIO N 6716 WES'

66 1 ' PLAC E

CH ICAGO -38-1 LE TtLtINONt PO 7 .7$4 0 'N CAL!rORNIA JAY T . N1CHOISO N g .. A cp

LOO

. q A~:[RCV DgIvE tnq •+

OYt*L .

J 'r'c

20,

AMOtsis

W MNIMOV M

TtRM WHIM . - TRINITY 1144

1 ? 9

; # 33091 d r'rice building 'ct, r . . _ . ^n.•s c~ : Ield Lch)rstor7 . ._ 1 matey l to tie li .'

43 C .4 3

; :C~ ~ ~ r -7

:,

~1 .

:

c;tlrrs t .t h;,ve been ode shows the pretenc e to other r^^^r ± .^. . ter the sar',le nos :. ~i 0;' any drep: i Lh ircn conten t h'

nb c .` ._.

On

_

J . .., e

r? i^

to

tnr.

°rD; 1 th e .sell . _ .' i c _ c 11 =_ : t e r;lart and the orr

reco : :r+e n,dc,

ti ons

and

'ti.' o ; rc. L.'Jr.it c f -^.~ktr s

r e- :estecf t give recorJ-

r

BNA0865696 1 HDMSt00014730

' :AT'( \Al . A1 .1'MINATF CORPOP- .T1ON 0

t .l

'

c

it : C

r

in zeter-In-Ir-c the corrosivier~'r3-

(~ ; LC . :' `^~ (6) Dissol-re .. S^li3s, ~1 rd s'-s free carhor. diCr eoides containin g v =r :! corrosive beca'ase o f ( ) c^rbCn di oxidC Lo n

t : ^ r~cr r.

`

r c : .,: -a t 'S

OS 14 _ .

cv':

c"r

C? :. ~n tnlJ

}ln .^i t

cc:~ n r ccustic soda that this is roi l _il corrosion on all erL'nrs ,

-J C. ~'~o3 a

'.~~

-ocia e

~r 'Oc'on the feed of

. .o : a s

t. .

r = z; c Ic --•o! : Id rot be a s : : : he sin ; lei and 1

^aitiors . :h . cision W2 2

~~ :r ~~rt~ : yrs . .

4

'

V

.v

ol, 'i n

.

I^~~ediatel y

._ tre3t -ont l epends of ^etrl, thereby : or rim ._ . r t^,^ t usually reco .-mended

'n "! .r 1 , S,

cescribe,! rethod .

= c _ ;e . . ar =rP, vsnts, piact ~i iavcrt ii ioas of new dra' : :a~,,e p_p;r,, t„ of conr_ectim~ ' t'' s six! s;i .^.{- j!-4 --t. ' 'stf ed

fixture

units )n existir.;; rr F; . :g prior `.u ti71-: ^:J.)ncect_(Nn

:rt ;'1f1Ct'_I'f`r~3 rr deL

det.-il draw ng snobs .,, =)L ,e, capucit . : a .-.1 _oc• t Or ci° traps, t!1'•"rce,, ar•, '1'lr'+ r'

r ;a .,

-1,

3 t .I .-Id'3rd o r f n i 2 7 (~ ~

sumps, pumps, valves control. , ubst ice

DIM- ux-mt Tin'd ax . ~W`t11tOt)

S.

(24>Uh

► tOO 5

3 0G~ ]., . zC!"I .

fly

fr

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': wesrs :- • '. . "'ou .+. ;• 'titers 41 :

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1 .!i•3t. . ~l~19r9

:'r 't w

L . .: • :'ity 3ewPrs : . : . "Ounty : ; ewer s i.• .' .~I .r . :. ers arm Jr'tins

NO ' L I`_t . 10 . ~3it iiOf1C YOnC

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f Nose 11mits vary Sri .e1 7 with pa. icn1ar c,nditiona . tiearf suzspefded thst . .iil ee ! t_a out ere not %11ox +ed in a'.n tart' s4nfore . Waits for storm drains vary and are shown for : . .1 . City limits into the L .A . liver as typical . Othsr a,erts Ii'_ely to produce odor , taste, toxic, correaive , fllra :,le, ex ;losis~- or r'dlca . :tiie hazarrds ; vis . sulpitidas, phenols, cfanides , f1o':rtd€is , *, e,,to-)es, et-er*, eta ; have sFecific hit's .nd t ohibitiona .

M

J GA L

HOLLADAY 8 WESTCOTT cayineers 8384 HUNTINGTON DRIVE • LOS ANGELES 32 • CAPITOL I•519 3

January 5, 1956

Mr . Hal Wright Department 766 2 North American Aviation, Inc . Santa Susana Facility Chatsworth, Californi a

Re : NAA Purchase Order R65tiD-90328 h Dear Mr . Wright :

Attached hereto are the water analyses for Well #6 and Well 47 . The quantitative chemical analysis shows these two well waters to be similar in character to the waters of Well #5 and sell #ILA . _You will note that el l _ = 7 has 0 . 6 p,-,m of iron similar to Well =LA which gives a reddish precipitate on aeration and standing . The pH of both waters is relatively low, although still on the alkaline side .

The sample taken at the SRE pond does not show any unusual concentrations . The rather high sodium shown in the spectrographic analysis could be accounted for by NaC1 used for softener regeneration . Since this sample was taken right after a rain it may not be indicative of actual ponded water conditions . A minimum check on the sample from the closed system SRE heat exchanger showed pH 9 .5, Hardness 11< .0 ppm as CaCO3, and Fe 5O ppm . This high iron shows that serious corrosion is occurring in this system and confirms visual observations .

Very truly yours , Y & WFSTCOTT

Ralph M . Westcot t r'tMW :mw (3) encls .

RI-D21- 065048

BNA08656985 HDMSt00014754

J c3

HOLLWAY ® WESTCOTr Bnglneera

WATER ANALYSIS Sample Identification : Well #6 Sample collected:

November, 1955

>)

11 ( S

Color - 0

5102 - 20 ppm

.

i Total dissolved solids

1'

-580 ppm

C02 - 2 .0 ppm Equivalent conductance

x106 -A5~5

pH-7 .1.&5 Total . Hardness ;J27 ppm as CaCo 3 Ionic constituents EFM

Ca L25 Mg 2 .29 Na 2 .69 K 0 .09

PPm

85.0 27 .7 61 . 8

t7 . J

ti.

3. 5

.0 5

Fe Total Cations 9 .3 2 Co3

HC03

0 .0

5 .90

0. 0

360

2 .29 110 SO 1 .15 40 . 8 C1 4 0. 6 NO3 0 .01 0. 1 F 0 .0 Total Anions 9 .35

RI-D2 1. -06504 9

BNA08656986 HDMSt00014755

J 2

HOLLADAY 8 WFST_COTT !ingine~ro

Sample I3entif ication : Well T6 Spectrographic - Seaiquantitative analysi s

CalciumNagnes iu't-

27 .0%

!a . 5

Silicon-

5. 1

AluminumCopper Boron-

0.028 0.0003 7 0 .03 9

Sodium-

7. 0

PotassiumIronManganese TinTitaniumNickelStrontium-

0 .96 0 .083 0 .008 1 O .OlII ni l 0.002 ni l 0 .26

Ctsromium-

0 .00065

- Barium-

RI-D21-06505 0

BNA08656987 HDMSt00014756

J Cj c

HOLLADAY 9 :Y/ESTCCTr 8ngsn~~rs

WATER ANALYSIS .Sample Identification : Sample collected :

Well =7

November, 19[ 5

Color - 8 Si02 - 18 ppm Total dissolved solids - 408 ppm C02 - 2 .8 ppm Equivalent conductance

X106 - 67 5

pH - 7 . !t0 Total Hardness L - 278 ppm as CaCO 3

Ionic constituents EPM

ppm

Ca

3 .61i

72 . 8

Mg

1 .92

23 . 2

Na

1 .58

36. h

R Fe

0 .09

Total Cations

7 .23

Cp3 HC03 S0 Cl N03 F

0.0

Total Anions

7 .29

3.5

0.6

5 .38

0 .97 0.91 0.02 0.01

0.0

328

116 . 5 32 . 3 1 .2 0. 2

RI-D21-06505 1

BNA08656988 HDMSt00014757

J 23 2

HOLLADAY ' E$TCC'-I' Bnginfra

Sample Identification : Well 47 Spectrographic - Semiquantitative analysi s

calcium-

27.0 %

MagnesiumSiliconAluminumCopperBoronSodium-

5.2

Potassium-

0 .9 1

IronManganeseTin-

0.35 0.01 7 ni l

Barium-

0 .05

TitaniumNickelStrontiumChromium-

0 .00 2 ni l 0.19

6.0 0 .018 0 .0002 6 0 .060 7. 8

O.0001r

R=-D21 -06505 2

BNA08656989 HDMSt00014758

LOS ANOC~.Ls SAN ANC( CO PORTLAND

DAMES 8 IVIOORE

SEATTLE SALT IAMB CRT

SOIL MECHANICS ENGINEERS

CNICAGO MEW YORK ATLANTA LONDO N

2333 WEST THIRD

STREET • LOS ANGELES 57 . CALIFORNIA

• DUNKIRK S-1327

RESIDENT PARTNER : VERNON A .SMOOTS

February 16, 19 6

Daniel, Mann, Johnson, and Mendenhall 4201 Sunset Boulevard Los Angeles 29, California

Attention :

Mr. Marvin J. Eudrotf

Gentlemen :

Seven copies of our "Report of Foundation Investigation , Proposed Delta Rocket Test Stands and Appurtenant Structures , Rocket Engine Field Laboratory , Santa Susana , California , for North American Aviation, Inc ." are herewith submitted .

The scope of the investigation was planned

in collaboration with lb . Hans W . Meier of your firm . Sandstone bedrock underlies the site and either is exposed at the ground surface or is encountered at shallow depths . All of the structures, with the exception of those subject to large uplift loads, may be supported upon spread foundations . Drilled cast - in-place concrete piles are recommended for support of structures subject to large uplift loads . Yours very truly ,

DAMES & ) 0BE

VAS

CU

cm

Vernon

G

A.

RI-D21-06507 3

BNA08656990 H D M St00014759

t

The site was explored by drilling 12 holes ranging in depths from 20 to 75 feet, utilizing diamond drilling equipment .

Continuous cores of

the sandstone formation were taken with an I IX core barrel .

Rock and over-

burden soil were examined by our engineer on the site . A Log of Borings is presented on Plates A-1 to A-4 . The percentage of recovery obtained during rock coring is noted on the left of the Log of Borings .

The soil samples and rock cores were examined in the field and in laboratory .

Since the soil and rock are similar to that encountered at

the Bravo and Coca areas , and the rock is somewhat more sound, no additional teats were performed .

i

-oOo= The following Plates are attached and complete this Appendix : Plate A-1 - Log of Borings (Borings 1, 2, 3 ) Plate A-2 - Log of Borings (Borings 4, 5, 6) Plate A-3 - Log of Borings (Borings 7, 8, 9, 10 ) Plate A-4 - Lag of Borings (Borings U, 12 ) and Soil Classificatio Chart and Key to Teat Data RI_p21 '065074

i

BNA0865699 1 H D M St00014760

NORTH AMERICA N

PROPULSION FIELD LABORATORY SANTA SUSANA, VENTURA COUNTY, CALIF. MAIN GATE ~i POWL~q

• TEST ; SERVICE " AREA i RESEARCH AREA

BORING ELEVATION 1183 .6

I FEET

BORING

2

BORING

3 OROIYN WEATHERED AND FRACTURED D BROWN NEATNERED AND FRACTURE D SANDSTONE 5 SANDSTONE G BROWN SANDSTONE S OUND AND FRES H BROWII SANDSTONE S OUND AND FRES H WITH FEW JOINTS OR FRACTURES WITH FEW JOINTS OR FRACTURE S FRACTURE

FRACTURE

3

BORING

BROWN WEATHERED AND SANDSTONE

FRACTURED

~ .y .~ .

BROWN SANDSTONE SOUND AND FRESH WITH FEW JOINTS OR FRACTURE S FRACTURE

GRAY SANDSTONE BROWN SANDSTONE

SEAMS OF GRAY SHAL E

GRAY SANDSTONE GRADING TO GRAY GRAY SANDSTONE

SEAN OF GRAY SHALE GRAY SANDSTONE

BROWN SANDSTONE SEAM OF GRAY SHAL E SEAM OF GRAY SHALE 19 0

GRAY SANDSTONE SEAN OF GRAYISH-BROWN SHALE

FRACTURE (WEATHERED ZONE 6 " BROWN SANDSTONE

FRACTURE

INDICATES PERCENT CORE RECOVER Y

LOG OF SEE "REFERENCE" ON PLOT PLAN

FRACTURE

FRACTUR E

SEAM OF BROWN FRACTURED SHAL E

ELEVATION REFERENCE :

3 (CONTINUED)

ELEVATION 1 719 .1 FEET ELEVATION 1770 .7 FEET

BORINGS

7

BORING

T

ELEVATION ITBI .3 FEET BROWN WEATHERED AND FRACTURED SANDSTONE BROWN SANDSTONE SOUND AND FRESH WITH FEW JOINTS OR FRACTURE S

BORING

8

IONHWEATNERED AHB SANDSTONE

BORING 9

BORING 1 0

Flu . MD OVERBURDEN-BROWN NO DARK BROWN SAND AND COBBLES

FRACTURE

BROWN WEATHERED AND FRACTURED 100 FRACTURE

WITH FEW JOINTS OR FRACTURES FRACTURES

SEAM CF BROWN SHALE (FRACTUR E

FRACTURE

BROWN SAND

BRAT SANDSTONE SEAN OF BRAY SILTSTONE BROWN SANOSTOIIE

SEAN OF BROWN SHAL E SEAN OF BRAY SHALE BRAT SANDSTON E

ul41 • S-

SEAM OF BROWN SHALE BRAT SANDSTON E SEAM OF BRAY SHALE BROWN SANDSTON E

BROWN FRACTURED SANDSTONE (LOST WATER CIRCULATtON)

BRAT SANDSTONE

BRAY SANDSTONE

LOG OF

BORINGS

il_li

RI-D2 [email protected]

BNA08656997 HDMSt00014766

HAL W. JOHNSON

vT~as 0-37499

Pacific SpeetroChemical Laboratory CHEMICAL AND SPECTROGRAPHIC ANALYSI S

- RESEARCH 235$ Ov.risnd Ave u. Las Asy.i .s 64 , Cspfomis

September 29, 1956

Report of semiquantitative spectrographic analysis of water residue samples os . 1 thru 7, subritted by 1r . J . S . ordmann fo r

Pacific Chemical Consultants 14203 9es3emer Street

Van :iuys, California

#11 _

Ca1ciumCopperSodium-

Magn esiumA1uminumSiliconIron-

30 .0° 0 .00035 3 .0

7 .8 - 0 .018 7 .8 0 .020

#2 24 .0% 0 .00030 2 .7

4

ir3 28 .0% 0 .00034 4 .3

'30 .0° 0 .00029 3 .0

7 .2

8 .8

12 .0

0 .021 7 .8 0 .016

0 .018 8 .1 0 .018

0 .024 12 .0 0 .016

#5

32 .0' 0 .00027 4 .8

11 .2 0 .019 9 .8

Langanese -

0 .0044

0 .0099

0 .0066

0 .032

0 .017 0 .024

boronStrontiumPotassium-

0 .063 0 .23 0 .91

0 .052 0 . 32 0 .74

0 .068 0 .43 1 ..0

0 .083 0 .17 0 .96

0 .10 0 .23 0 .79

,f 7

#6 32 .0 0 .00022 4 .8

9 .2 0 .023 13 .0 D .016 0 .024 0 .034 0 .28 0 .96

33, 3 0 .0X1 9 3.1 9.4 J .01 8 7.5 3 .01 3

0 .01 » 0 .090 0 .3 8 1.5

Respectfully sulitte d PACIFIC SPLCTROC' LIC .AL L LBORATCaY

FP1 ; J :1

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cL1

. Johns,?/ r

RI-D21-065053

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' •

RI-D21-06505 5

BNA08657000 HDMSt00014769

.ORN .

PICNM .. o 9-3411

16

LABORATORY REPOR T

SMI)ITI-I-EMERY COMPAN Y CHEMISTS - ENGINEERS 7Rt KAMMT 1A -AM111N ( ;Tr1N 11MI TIRYAtt1) Ll)M AN( ;J F .ya 21 . ('ALTFOItNI A .LL R/.OAT . .R . .V .M .T Too . . 1- ro..r .or ..• .n,. f.e ... .rv ni C~ .e S Te- A.,TMO.,TATe.M I'M rU11L~tATION M ASIA Rt10RT.. MIICLAI.'01M. OR . exTRACTS ( ROM OR RI .ARO .MO tnt5 , . Rr,, A VID •r-,we Ou. w*ITTt. . .MAOVAL AS A MUTUAL PROTttt .OM TO CL.tWT .. TMt /IIM.1C AMA O .7R. Et ttt.

Date

Februa ry 13, 195 7

LABORATORY NUMBER 4300,8 9 Sample WATER

Received

iThrrkcd

-T.,Orth 4merican Rocket Dyne Laboratories Installation , Santa Suzana vountain s

February 4, 1957 -- February 4, 1957"

Submitted by

Holladay r ;, '.,'eestcott 5384 Huntin_;ton Driv e Los Angales 32, California

"Silvernale Pzsorvoir Uveri:low 11 :10 A . ::, . " Sampled by Smith-i e ry Company

ANALYSI S PARTS PrR MILLIO N

ANALYSIS OF DISSOLVED SOLID S

Silica . . . . . . . . . . _ . . . . . . . . . . . . . . . . . . (Sio,) . . . . . . . . . -- Aluminum Oxide . . . . . . . . . . . . (AI,O,) . . . . . . . . . . . . . . . . . . . . . . . Iron Oxide . . . . . . . . . . . . . . . . . . . . . . . (Fe,O, ) . . . . . . . . . . . . . . . . . . . Calcium . . . . . . . . . . . . . . . . . _ . . . . . . . . (Ca) . . . . _ . .__--- . . Magnesium .. . . . . . . . . . . . . . . . . . . . . (hip) . . . . . . . . . _ . . . . . . . . . Sodium . . . . . . . . . . . . . . . . . . . . -- . . . . . (Na) --- . . . . . . . . . . . . . . . . . . . . . Sulphate . . . . . . . . . . . . . . . . . . . . . . . . . . . (SO4) . . . . . . . . . . . . . . . . . . . . . . . . . .. . Chloride . . . . . . . . . . . . . . . . . . . . . . . . . . (Cl) . . . . . .---- . . . .-------- -----Carbonate. . . . . . . . . . . . . . . . . . ------- (CO,) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .- . .. . . .. .. -

TTotal o t a l Solids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

15 .2 Trace Trace 50 .5 23 .3 44 .4 77 .8 20 .0 !Ton e

241 . 6 480 . 8

PART$ MR MILLIO N

HYPOTHETICAL COMBINATIONS

Silica. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . SiO, .. . . . . . . . . . . . . . . . . . . . Aluminum Oxide. . . . . . . . . . . . . . . . . . I,O,. . . . . . . .. . . . . . . . . . . Irrn Oxide. . . . . . . . . . . . . . . . . . . . . . . . . . Fe,O,. . . . . . . . . . . . . . . . . . . Calci,;m Bicarbonate . . . . . . . . . . . . . CA(HCO,) :. . . . . . . . . Calcium Sul Dhate. . . . . . . . . . . . . . . . . . CaSOt . . . . . . . . . . . . . . . . . . . Calcium Chl orid e... . . . . . . . . . . . . . ..CaCI,. . . . .. . . . .. . . . . . . . . . Magnesium Bicarbonate. . . . . . . . g(HCO,). . . . . . . .. 21 :gnesium Sul phate . .. . . . . . . . . .MgSO. . . . . . . . . . . . . . . .. . Magnesium Chloride. . . . . . . . .. . . AfgCl, . .. . . . . . . . . .. . . . . . Sodium Bicarbonate. . . . . . . . . . . . . .NaHCO,. . . . . . . .. . . . . . Sodium Carbonate. . . . . . . . . . . . . . . . . a,CO,.. . . . . . . . . . . . . . . Sodium Sulphate .. . . . . . . . . . . . . . . . . . Na, S04 . . . . . . . .. . . . . . . . . Sodium Chloride . . . . . . . . . .. . . . .. . ..NaC1. . . . . . . . . . . . . . .. . . . . .

15 .2 Traoe Trao e

204 .3 None None

105 .4 28 .9 None None None 80 .8 46 . 2

Total Solids . . . . . . .. . . . .. . .. . . . .. . . . .. . . . . . . . . . . . . . . . . . .. .

358 .0

Total Non-Volatile Solidr .

Total Hardness ar CaCO ... .. . .. . . . .. . . . .. . . . . . . .

222 . 0

DETERMINATIONS Specific Conductance (Aficrombos ; cm .) . . . . . . . . .

. .....

Hydrogen Ion Concentration (pH) . . . . . . . . . . . . . . . . . . . . . . . . . . Boron(B) in p . p .m. . . . . . . . . . . . . . . . . . .. . .. . .. .. . . . . . . . . . . . . . . . . . . . . . . Nitrate (NO,) in p .p .m. . . . . . . . . . . . . . . . . . . -------- . ---- _ . .- . . . . Fluoride (F) in p .p.m . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Tr,-(e Color . . . . . . . . . . . . . . . . . . . .. . . . . . . . . .. . . . . . . .. . . . . . . . . . . . . . . .. . . Odor Quality . . . . . . . . . . . . . . . . . . . . . . . .. .. . . . . . . .. .. . . .. .. .. . . . . . . . . Taste.. . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . .. . . . . . . . . .. . . . Turbidity . farkson Candle. . . . . . . . . . . . . .. . . . .. .. . .. ... .. . .. Suspended Residue. . . . . . . . . . . . . . . . .. . .. . . . . .. . . .. . . .. .. . . . . . . .

Analytical methods need are More r per ;; ed in t''e careent e,litinn of the Standard Methods for the Examination of Pater, Sewage and Industrial li-'a ,tes p ;e%I :LcJ k Y the American Public Health Association unless staled otherwise.

11

M

BNA0865700 1 HDMSt00014770

S► %1ITII -E.ME1r COMYAN Y .% C'111r

r•rAnr.r*nen ,,g 11 . 4TS - r.*T( .t .R1t14

%frTALLURGWAL A\f1 Tt4Tf N O RNOIN6RR 9 :A1 E A aT S ARWN t:TO N'

nOvf.RVAR D

LOS ANGELEM 21 CALIFORNI A

LABORATORY

No. 430989-A

"North American Rocket Dyne Laboratories Installation, Santa Suzana Mountains , Holladay & Westcott, Feb . 4 9 195 7 Marked

Huntington Drive , 5384 Los Angeles , 32, California .

REPORT OF QUALITATIVE SPECTROGRAPHIC EXAMINATION Based on Ash of Solids APProsimate Qaealtig Major Constituent

Intermediate Constituents Minor Constituent s Silicon --------Aluminum -------Iron -----------Potassium ------Strontium ------Barium --- -----Boron -- --------Copper ---------Chromium -------Manganese ------Nickel ---------Titanium -------Ccbalt ---------Lead -----------Rare Earths ------

0- %05% 0.05% 0 .05% 0 .05% 0 .01% 0 .005% 0 .005% 0 .001% 0 .001% 0 .001% 0 .001% None foun d None found None found

Respectfully submitted ,

CH :;MIST3 AND E NGINEERS 9. t..< , All repofta are submitted as the confidential pr, .irrrty of 0 ienta. Authorization for publication of our reports, eanelaaona, sr eatractm from or regarding them is reserved per :dirr our xrittrn approval as a mutual protection to elient .i, the public and oussei v f : .-

a••_•z•

• .'d• •r, '.:dilvire I porva rerkie tsamiaaeaa1l

BNA08657002 HDMSt00014771

a

ra

Pear ,

LABORATORY REPORT Si%"

IITH-EMERY COMPANY PRTARLI .NED HM

CIIRMIATR - RNGINSI1II S !RI RAgT WA"111N O TO 1i AOVI.RVARD LOR ANGRI, RM 21, CALIFORNI A ALL PIPONY. APP .1R/M .TTPO ♦ A eup eo..r ( .rr.-. tl PRO►WRTV or ri_sewn• AOTNOWIATtON POP PO.I. .CATON M OOP RIMRT.' CONCLOMON.. M, .RTRACT . PROM OR RVOARD5N0 TN[ rnr--D "PMA'N . WR *01 TTPN APPROVAL A . A MUTUAL PROTACTlON TO Mfg"". TM PYRjC AN. OORORV[. .

LABORATORY No. 434961

May 20, 3,957

Date

Sample

Wate r

R.ereived

5-13-57

Sabmitted by

Holladay & Westcott "Wirth American Rocket Dyne Lab . 5384 Huntington Drive Installation Santa Sazana lets ." Los Angeles 32, California

.irked

"Bowl Reclamtion 9s45 a .a ."

REPORT OF DETF *ffNATIONS

Biocheadcal oxygen demand ----------------Hydrogen sulfide (H23 ) ------ ----....------ .-

960 .6 ppw 0 .45 Pm

Igniti on loss on t otal so lid s ---- -- --

70 . 54

Oil by extracti on

36 pp a

-- ----

REMARKSI This eater was very dark in color due to the presence of substantial amounts of suspended ferrous sulfide e

Respectfully sabsdtted,

CHE1 ST : AND ffiNU~

BNA08657003 H D M St00014772

FORM 3 •

LABO RA'CORY Cl. R'Tll ICAT E

IITII- IENIE R

COM P

NV

CIIFMH .SFS • ENGINEERS 920 SANTEF•

STREET

LOS ANGELE S

Date

l .ABo RATORY No . Sample

IFATLI?

"North American Rocket Dyne Laboratories Installation, Santa Suzana, May 13, 1957 - Reclamation bowl (eff2.ue r

,lfarkcd

6-3-57

Rcccired

Submitted b)'

June 27, 1957

05'.29

to pond) water" .

Holl.ad r & Wssecott 53314 Hsi-zt± .nrton Dri-v 4 Los Anr o-1-a 32, California

Sampled by Smith-Eery Cowpany

ANALYSIS GRAINS U . S . GA l

L .118

Silica . . . . . . . . _ . . . . . . . ._ . Aluminum Oxide . .Iron Oxide . . . . . . . Calcium . . . . . .- . . . ,lfu,; ueritnu . . . Sodium- . . . . . . . . . .

Srd pl:ate . . . . . . . Chlorine . . . . . . . . . Carbonate . . . . Ficarbonate

Trace .(Fe,O .)

(Ca) .___

1 .53

(,lf r) (SO .)- . . . . . (CI) .

1, one None .9 4 o

None

.(CO ;I

(Il c o .

3 .89 7 .19

)

29 .59

Total S„lily . . . . _ . . . .

51.58

Total .\'on-f 'olatrle

36 .54

Total llardners ar CaCO

2s. . 25

Silica . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . S'02. . . . . . . . . . . . . . . . . . Alu-4nu,n Oxide. . . . . . . . . . . . . . . . . .AI,0 .. . . . . . . . . . . . . . . . Iron Oxide . . . ._ . . . . . . . . . . . . . . . . . . . . .Fe20a . . . . . . . . . . . . . . . . Calcium Bicarbonate . . . . . . . . . . . . . Ca(HCO ;, ), . . . . . . Calcium Sul phal. . . . . . . . . . . . . . . . .CaSO . . . . . . . .. . . . . . . Calcium Chloride. . . ---- __ . . . . . . .Cdc/2_ . . . . . . . . . . . . . Magnesium Bicarbonate . . . . . . . .Mg(HC03) . . . . ... . Magnesium Sul pbate. . . . . . . . . . . . .MgSO . . . . . . . . . . . . . . . . Magnesium Chloride. . . . . . . - . . . . MgC1= . . . . . . .. . . . . . . . Sodium Bicarbonate. . . . . . . . . . . . . .'VaHCO, . . . . . . . . . . . Sodium Carbonate. . . . . . . . . . . . . . . .Na,CO, . . . . . . . . . . . . . Sodium Sulphate.. . . . . . . . . . . . . . . . . .Na .S0. . . . . . . . . . . . . . Sodium Chloride.- . . . .. . . . . . . . . . . . .NaCt . . . . . . . . . . _ . . . . .

Ferrous Bicarbonate -------Ferrous Chloride

Total Solids .......... ... .. ............. ... .. ... ..... ....

Trac Trac 29 .r. Nor Nor 9. Nor Not Ncr Nor Nor Nor

p:7 8.; . 51 .

DETERS IINATIOI` S Carbon Dioxide (CO,) ur:co!+;%,+'ed i„ h .p .+ . . . _ . Hydrogen Sulphide (HS) in fi, n . n . . Spce .'ic Elerlriral Conducta +. cc (K x `) . . ._ . . . . . . . . Hydrogen ton C- ,-e wr.ltion (P11) Bare, (B) in, p .p .m . .

Color. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Odor. . . . .. . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . Taste. . . --- . . . . . . . . . . . . _ . . . . . . . . . . . . . . . . . . . . .•. . . . .. . . . . . . .. . Turbidity . . . . . _ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Suspended Maiter. . . . . . . . . . . . .-- . . . . . . . .- . . . . . . . . . . . . . . . .

BNA0865700 4 HDMSt00014773

..r. : .~ ,.r

.1111-

is

't 1

1"

1 4

1

.•il U." 1,

< .`.

s . a-b~ 1,Gy1

. :S

+17~tx •' ?aetClo '.~ujii1 Cy i ,1tx,ttr . • . *1yrlx `7 :PtNtAMtt of '1t r i. . &A•oax .

It

0

Table I

Analysis of Bowl Area P clamat .on Water

May 8 SAmple

May 29 Sample

Sunpended Solids

890 ppm

506 ppm

Herdnes`

360 PPM

342 PPm

Iron

7 .5 pi

6 .8 pi

pfi

6 .4

6.5

Conduc tivity (micronhos/cm) 666

793

d

BNA08657006 HDMSt00014775

itcr L.

:?rc- oe

564 SanSu 28 August 1957

21 6 P'I

583 Cano

1!"~11 Water

Tr^n i tt, ? , h-rc- the is a coup of the lash Laboratory Report on ?FL well water . The analysis was Wade by Smithartery Co . Also enclosed is a co^.v of the Cost Study made in oonjtmetion with the TI ?eel .-nation Justifi cation .

L. S . Breese Utilities Group Industrial Engineering

x~r192t!

BNA08657007 HDMSt00014776

L VY' 2 i ^''T C "TZ71 FI CA : IE

Laboratory No . Sample Received Submi tted by

435999

June 27, 195 7

Wat gr

M^rksd - "North American Rocketdyne laboratories 6-3-57 Installation Santa Susana, )ty 13 1957 HoUi.dr7 .4 Westcot4 Reclamation {n.1 (effluent to pond water" . 5384 Hrmtinr-t•cn Pr -r r Los An£eles 32, Cnlifcrnia Sampled by S ith-Amity Compet e

A'?"LT11S AnaC,"is of Dissolved Solid s silica Alumimm Oxide Iron Oxide Calcitam Ragnesium Sodita n Sulphate chlorine

(Si02) 2o3 ) (Ca) (Na )

(SO )

Oraira per u .S . Gallon

11,1,8 Tr?c3 3, p2 7.19 1.5? do"+

Cilica Si02 4 .48 Aluminum Oxide A12 Treos Iron Oxide Trace Ce1cii t Hiearbonate Cat 03 )2 29 .07 Calcium sulphate CaSt None Calcium Chloride None Marneeitae Bicarb. Mgg (H ) 9 .17 04Magnesium Sulphate Pig None Mapnesitmi Chlorine MgC' None Sodita Bicarbonate NaH None Sodium Carbonate Nao003 None sodium snlpf.,ate Naa'2~ 5O1 None Sodium Chloride NaC1 Nons P rrcns Bicarbonate 0 .10 Ferrous Chloride 8 .76 Total Solids

*Tnn A

(Ci7

Carbonate (C033) Bicarbonate (AC03 )

2° .59

Totel So11ds

51 .58

Total Non-Volatile Solids

36,5 4

Fgpothetieal Coubinatione Ormdns per U.S. Gallon

Total Hardness as CaCO3 22& .25 I ST-7=11 ASST C'7S lerbon Dioxide ( ) m combind is p .o .-i 6 .5 'rgen SnlphidH.S) e( in p .p .m 5 0 .45 9peeifle Electrical t•onduct nee (Kx10-) 995,02 yydro,en Ion Conrentraticn (PH) 7 .3

9oran (B) in p.p.rt

Cole? black Odor sewage E2S Turidity n Turbidity +5000 Su•pend"d Matter 54

F,e eetfully eubedtted m Stith-3mery Company ( signed) C'rrists amd Engineers

r~ A t . ~

BNA0865700 8 HDMSt00014777

To

L.1oyd Cantr''1

DEPARTMENT

6611 Neosho

rr oM

L. S . B reese

DEPARTTME• NT

564

rL7ON

21.6

DATE

31 Ju]y 1957

SanSL

17t .31.CT 7^.t1 ro t^ F . 'yors Dated 19 July 195 7

r Poferenc3 (a) Letter W .

Enclosure (1) Ar,a1ysi8 of C^ci ^n Water Prior to Reclamation or Recycling or' ^oclan t (2) Analysis :+f r' 7de3 C 1a.nt: '.later Two Months After the Activation of a Reeler a',inn F,-stn-i in ..'hick the Coolant Water hai Been Recycled (') Lab . Rap„rt c' acs*^ i'-_n~ ~ .ccculatinr Agents in Removing Turbidity

As requsstc' in the referenced letter , we are transmitting results of recla'r.ed - n- t-!r an'► ';: ses taken in conjunction with the rater treatment stuff; of rec1airr?d Prater at the Bowl Area, PFL . The rF :la^=lien s -sly in this area was activated without treatment of any 'r nd . The re :,cling of the coolant water re sulted in a build-un of stcc.rended solids to a point where treatment is required to restore the -,pater to a good usable condition . For this reason , we are srt,-.i',ting the results of sannles taken be fore and after the activ ;.~. ,n -) -'r rocl~~7ation system .

L . S . Brees e Utilities Group '7 -sercrd. t'l Industrial Engineerin g ' -n

9/" ll,

Su-c--rr - o r

L•',' :' : IS B : an cc : A . A. K . An ;e1o ' f

56

3ir: 31 u

66) L "-~ocho

R . Henley P. K . T. E .

66s e^ sho 5~1 -- :o

W. Swan

661 ' :ecsho

532 C---- r o

BNA08657009 HDMSt00014778

22

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3 .1 C .1 O

325 IN It,

39 . 4

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Sample Collected : Pi' - 7 .3 :,auivalon t

Ppm

Total hardness Ci C'O'; Total dissolrc'' ao?. ~':^ C2 . ^ucspended

solle-

M

•1~^~~i?'~a,'i ^'7111^

Calcium 0 , 00024

Copper

cditr n

`.5 .2 1.

t~'C{ £'.F3SiLa2a

lagnesium

on

6 .2 0,032

Aluminuin Tr.

5

0,046

11anganese 0 .12 Silicon

4 .2

Boron

0 .079

Strontiu.+n

I

0 .29

BNA0865701 2 HDMSt00014781

I_rs,'rFr r 3 ON'1_Y

W P Nano No . 57 .19 8

TO

1.1, 1s, Bream

ADDRESS

564-05

FTota

Materials & Processes Grou p

ADDRESS

596-9 3

rrioriF 564

OATM

3 September 195 7

3UOJTCT Analysis of Reclamation :"a er from Bowl Area

Reference : Research Name 172/9_", "An l.ysis of Rcclanatior. 1•'ater from Bowl Area," dated 28 Jung 1957 .

As previously reported, t .r•e bowl area at Santa Sussna is neing water from the storal a pond located in tic lower test stand arcs . This water is used for a two-fold purpose, i . c, for .ooliri . flare buckets durinC firinJ. s and for test stand fire extinCuuishers . The excessive amount of impurities present in the water render it undesir-~,le for fire. extini,uicher use . A water sample was subrLitted by the Utiliti^s Group cf I-du:.trial Erv.;ineeri.nC for analysis and reco mended treatment . Comparing the results of this latest analysis with previous ones, (see Table I), a 25 to 50 porc- :` in^rease of suspended solids and conductivity is observed . The total hardn"ss and pH have remained unchtenCed . Analysis for hydro,;en sulfide Cas revealed a five : opm concentration, which is considered excessive and highly corrosive . Removal of suspended solids was accomplished in the following manner : two cylinders, both containing; approximately three and one -half fluid ounces of bowl area water, were prepared and one-third of an ounce of filter alum (aluminum sulfate) was added to one . After six hours of standing , the particles in the cylinder containinC filter alum settled to the bottom. An additional 20 hours were required for the water in the untreated cylinder to reach the same transparency as the treated one . The water treatment recorunended in Research Memo 172/93 is considered adeetvtte to remove both dissolved gas3s (e . , hydro[,, rt sulfide ) and suspended solids . If the water r. ''quirenents ar-1 such &at the settling time by natural meano must be reduced . ;h :n a baffled floculating tank with a filter alum chemical feed pump should proceed the settling basin (page 3, RM 172/93) 0 'Fable I .

Analysis of 13cr4l Area Reclamatior, Water

I11ay 8 Sample Susp::rded solid ;

hardness pU Conductivity (micrcmhos,/cn) 1123 ,JZ :AS : ; ,h DC : C, Anselmo , Jr ., 595-63 6 W. J . Cecka , 596-60 S DO J . jr I MM r •) . . T

Lay 27 :ample

890 ppm 360

506 ppm

665

793

5~4

342 6 .5

e July 10 Sam 1110 ppm

349 7 .0 1189

5 !., 3i.itstein r~:~J ✓ .eilber, r, S Vr ' Chemical Uni t IL'it.eri lls and Processe s

BNA0865701 3 HDMSt00014782

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32

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564

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1. : PAR .r!C_ 4T

Yt7iv''• j 7,i

r:. AT • 10 Septn*nb er i 957

San L'.

b;- A . 1, rera-esentativa' at miter Ouali. ty, Y, are

. "I :'.r" prarf Uces to supple-

T. L'

it Yuan Storage Reservoir ( Vs11c 12~ 7 '~r1•: d t`rar ach of ther e -n c- the dcna7K) in the area. At the i D, carabie of a pproxd.•na.teiy 70 G . ra--_ . exceed the nakn-up capa bilities of

draw water from the Area II storage c : ;, a the v ell . At the present tirn th-: .^ o-t 11.3- f7 a^d !* n fraaa Area. II . " ,

oc-„le'"•s -inera1 analysis is run on each in a''utt?. on to this initial 071

e^ c"I

anti --re

veil

a.z r oxii ia'.;ely

~z ? c1.o-;a Cal. teats are conducted on t t the system c .pproxiw_'? ^ :;~rrs az-e - e by Dept . 56!t arrd at UJf' p int3 throe hotr4: ta i ^.. -'i_rte -n a o ori:1e resir'_ttal of

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IIII ,

A . A . rr:ec

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..

..

..

.. -

..

..

..

..

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..

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We will snhn . % -17 ir_fornation regarding changes in treatr.*.cnt 8nd P'L . ,^,o f--'hat this information can be passe d

o, : to A . I . pr,r on '• q

a

A. A . Ameday Geraral Supe visISr Indu3trial Engineering

R

cc : L. S . Areese

56b S'-",Su 13. roster 562 Cc^o 561, Caro P . K . i•iutarpl H . D . Sch ad 5 ;l~. S~tSu

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i'~w tr ' :r•ii G. like t o .. .. : : ?.v .G-. . .•.t . („`(]i',? . ; :i' .: :1'i•~ tS :^•_~ .i _ •,

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BNA0865701 6 HDMSt00014785

RICNMOND 9 .3411

0 LABORATORY REPOR T

Si1IITII_EMERY COMPAN Y CHEMISTS - ENGINEERS

7MI I-AMT M A!Aii~NtiTO~1 IROI.•I . RS•AR11

Chem A,% ;t :IHLR :K 21 . CALIRORNI A

ALt '-WT , A•f .V. . , Tpp AR T1fr CaN"r.r MTIAL pee-v.,, pr CLIf T PACT . IPOrA OR A. .( T., AVtrq*tfAfn, F ry .A Ang TMr.M I$ SY*r .Vtrf ►r MA~N OR IC ATr. . .W aM W /i f" WMTt[M AM.. VAL A. A MVfVAL ~f~~ „QI WNI {.r.wr. . ~MlLYlr.M. .

LABORATORY NUIUBLR all7re S I

Date iii~~ 'mot .; -

WATER A11arkcd

ae, ex.

September 24, 195 7

"North American Rocketdyne Laboratory .eanta Suzana , September 9,1957 Reclamation Bowl "

Received

9_9-57

Submitted by

fiolladay & Weztcott, Sampled by : 538+ Huntington Drive , Los Nogales, 32, California .

SMITH- SXERT COMPANY

ANALYSIS ANALYSIS OF DISSOLVED SOLID S

Silica (SID,

PARTS ►ER MILLION

20,2

)

Aluminum Oxide-------------(A1,0,)---------- -Pon Oxide. . . . . . . . . . . . . . . . . . . . .(Fe,O,) . . . . . . . . . .a Calcium. . . . . . . . . . . . . . . . . Magnesi,nt . . . . . . . . . . . . . . . . . . . . . ( M

Trace

Trac e 36 .8 22 .8 81 .0 172 .0 86 .0

Sodium . . . . . . . . . . . . . . . . . . . . . . . .. (Na) . . . . . . .- . . ._ . .. Sulphate------ . . . . . . . . . . . . . . . . ----(SO,) . . . . . . . . . . . Chloride ---- - . . . . . . . . . . . . . . . •(Cl)----- • Carbonate. . . . . . . . . . . . . . . . . . . . . . . . .(CO,) . . . . . . Birarbonat _ . . . . . . (HCO, ) - .-

_

Total Solids_ . . . . . . . . . . . . . . . . . .

236 .k

745 .7

HYPOTHETICAL COMe,NAT,ON s

Silica. . Al,rminum Oxide . . .. . . . . . . . . . . . . . 41,0,. . . . .. . . . .. . . . .. ... Iron Ox %'te- .. . . .. . . . . . . . . . . . . . .•-- --•-Fe,Or .. . . . .. . . . ... . . . . . Calciu:r Bicarbonate-. .. . . . .. . .. . Ct(HCOJ) . . ... . . .. . Calcirm Calphat e------------------CdSO . ..____ ._ .__----- . . . CaM is Chloride . . . . . . . .. . . . -. . .CaCI,__-_-__._ .___-_____ .. Megaerirem BicArbojaie.. .. . .. Mg(HCO,),_-_____.

Magnesium Sxlpbate . . . . . . . . . . . .AtgSO41 ___•_ . . . . . .. . .. .. Magnesium Chloride _ . .. . . . .. . .. MgClr----._ .._ . . . Sodium Biearbotulte______________NaNCO, . . . .. .... . .. .

Sodium Carbonate_. . . . . .. . . . . .. . . NN,CO,... .. . . . . .. . . . . . Sodium Srl pbale__. . ._• ------ Ne,SO, . . . .. . . .. ... .. . iu m PIT -.-I..... . . . . . . .. ... .. . . Sood ,..,,..,,~~ C~loxide. .. . O~i~i

Total ,~'nn-T 'olatile Solids -

625 .4

ulfate - -----.

FART! Fill MJLL1ON

20 .2 Trace Trac e

149 .2 None None

136 . 8 None None 46 b 175 .4 None

Total Hardn ,,, as CeCO,-•---~ . .. .~

DETERMINATION S Specific Conductanc e Hydrogen ton Concentration (pH) . . . . . . . . . . . . . . . . . . . 13,r,7rr(B) in p .p•m . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . Nitrate (NO,) in p .p .m. . . . . .. . . . . . . . . . . . . . . . . . . . . . ... .. ... . .

F uorid, (F) in p•p .m--- -------------------

1148? 0-4

. ...

True Color--_ . -. .____ . . . . . . . . . . . . . . . . . . .. ..... Odor Quditr_ . ---- .-_ _Tarte ._. . .. ... . . . .

... .. .. .. . ..____.. . .. .. . .

Turbiditj, Jackson Candle-------------_ ._ .___

SArrpe aded Residue------- ----_ ._ ._ .

None

N on e

n.d .

10 10

A "'I,!•c•~l InFlhndr Pred ar., t,',, e :,rrrer,t editin,t of the Standard Methods for A" a!er , Seu•ese and Ind,,r,r .the Exmrtinalioly of ; It -s the Ameriran Public HeabJ, Arroeiation Rulers stared otbrtrise. Dissolved Iron ----------0 .015 ply

Chlorine r-,Dema d A Oil ppm 58 .8 pp m Hydrogen Sulfide -

BNA0865701 7 HDMSt00014786

RICHMOND 9-3411

IowM a

LABORATORY REPOR T

SMITH-EMERY COMPAN Y CHEMISTS - ENGINEERS :NI KART N- A!AII?N ( iTON fO(II .KVAR h

I .( ► ~( AV( : f:l .f•:!i 21 . ('AT.1FOW-11 A AI-L NVPO*TS AMC SVRMI T ITO A% T , . r 470-113-"AL PROPIRTT M CLIENTI . AUTNORIEATION FOR rURUCATION OF OUR NE P ORT♦, CONCUMIONE. •R. CA . TRACTS FROM OR REGARDING THEM IS RFSFRVrD OrlOINO OUR WRITTEN APAROVAL AS A MUTUAL PROTECTION TOCIIO,T ., T IME F••LIC ANOOUMELI,E. .

LAIO I?ATORY NUMBER

4400 J

September 24, 1957

"North American Rodcetdyne Laborator y Santa Suzana, September 9, 195 7

Sample WATER Marked

Received

Date

9-9-57 Alfa Bravo Skim Pond "

Subinittcd by

Holladay & Westcott, Sampled by : SMITH-EMERY CCKPANY 5384 Huntington Dr . , Los Angers, 32 , California . ANALYSIS P MIL RT PER LS

I

ANALYSIS OF DISSOLVED SOLIDS

LL10N

Silica. . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . (Sio,) ...... ... --_ ... ... .. ..... .' 25 .9 Trac e Aluntinurt Oxide . . . . . . . . . . . . .(AI,O,)-- . . . . . - . . . .- . . . . . .- .. Trace . . . . . . . . . . Iron Oxide----------------- ---(Fe,O,)-- _--- --73 .7 Calcium ...... .... .. ... . . ... . .. .. ... (Ca) ... ... ..... . . . . . . . . . . . . ... ... . 26 .8 Magnesium . . . . . . . . . . . . . . . . . . . . . . (Mg) . . . . . . . . . . . . . . . . . . .- .- . . .

Total Non- T %nletile Solid, .

. .. .. .. .. ... .

Aluminum Oxide. . . . . . . . . . .. . .. . .al,Of. . . . . .--. . . . . . . .. ..

Trac e

Iron Oxide. . . . . . . . . . . . . . . . . . . . . . . .. .. Feso ... . . . . . . . . . .. . . . .. . . Calcium Bicarbonate . .. . . . .. . . . .. Ca(HCO,). .. . . . . . . .

Trac e

298 . 2 Non e

70 .6

Calcium Chloride . . . . . . . . . . . . . . . . . . CaCi, . . . . . . . . . . . . . . . ... ......

Non e

109 .9

Magnesium Biearbonate .. . .. . . Mg(HCO,) .. . .. . . . .

93 .6

46 .0

Magnesium Sulphate. . . . . .. . . . . . MgSO . . . . . . . . . . . . . . . . .. Magnesium Chloride . . . . . . . . . . . . MgCI,.. . . . . . . . . .. . . . . . . .

Sulphate . . . . . . . . . . . . . . . . . . . . . . . . .(SO,) . . . . . . - . . . . . . . . . . . . .

12,0 302 . 7 667 . 5

.

Total So/iJr . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Silica........ ..... ... ... ..................

Calcium Sulphate. . . . . . . . . . . . . . . . . . CaSO... . . . . . . . . .. .

Sodium . . . . . . . . . .. . . . . . . . . . . . . . . . . . . (Na) . . . . . . . . . . . . . _ . . . . . . .- . _ . .~ Chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . (Cl) . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . Carbo,rate. . . . . . . . . . . . . . . . . . . . . . . . .(CO,) . . . . . . . . . . . . . ._ . . . .- . . . .-- . . . Bica; borate . . . . . . . . . . . . . . . . . . . . . . (HCO ,) . . . . . . . . . . . . . . . . ._ ------ --

PARTS PE R MILLIO N

HYPOTHETICAL COMBINATIONS

513 .9

. . .-

55 . 4

Sodium Bicarbonate . . . . . . . .. . . . ..NaHCO . .. . . .

Non e None

Sodium Carbonate. . .. . . . .. . . . . . . .. a,CO .. . .. . . . ... .. ...... .. .. .

21 . 2

Sodium Sul hate . . . . . . .. . . . . . . . . ..Na,SO.. . . . . . . . . . . . .. . . Sodium Chloride. . . . . . . . . . . . . . . . . .NaCI. . . . . . . . . . . . . . . . . . . . .

Total Solids .. . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . .. . .. . . . . . . .

791 :9 6679 6

Total Hardness as CaCO,......... . . . . . . . .

294

DETERMINATIONS Specific Conductance (Micromho .r/cm .) . . . . . . . . . . . . . . . . . . . . /Hydrogen Io n Cmtcc ntration (pH) . . . . . . . . . .___ . . . . . . . . . Rornn(B) in p .p .,n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _ . . . . . .

827 .8 8 .4

True Color. . . . . . . . . . . . . . . . . . . . . .. . .. . .. .. . . . . .. .. . . . . . . .. . . . . . . . . . . Odor Quali ty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . .. . . . . . . .

0 .2

Taste . . . . . . . . .. . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . .. . . . .. . . . .

Nitrate (NO3) in p .p .m . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . - Turbidity, Jackson Candle. . . . . . . . . . . . . .. .. . .. . . . ... .. .. . . . . Fluoride (F) in p .p.m----------------- ----- - Suspended Resike ----------------- ----- . . . .. . . . . . . . . . .. . . . ... .

None None

nod * . 10

10

Analytical metbndr tired are these ,perijea in the rtrrre,tl edition of the Standard Methods for the Exam ;nat;on of Water, Sewage and Inducinia! 11--arie .r /u b'li.rbed by the American Public Health Association unless stated otherwise .

Dissolved Iron ------ 0 .015 pp m Chlorine Demand -- - - - 0 .3 P -.7' Oil ----------------- 26 .1 p pm Hydrogen Sulfide ---- none

s~iecttill bmitte

Chemi-rt .r-Et tree . .

BNA0865701 8 HDMSt00014787

RICHMOND 9-3411

.

PORN

0 LABORATORY REPORT

4%' \IITI-I-EMIT RY'COMPAN Y CHEMISTS - ENGINEERS .NI EAMT WAMIIIN ( 1TON ROt•f . R V AR f f .T)M

%N( ; V.I."

21, C .Ar. I R Or tN J

ALL RSPORTS AMC SUMMIT 110 A' twr CO, .rier„-IAL PR-PTV OP CLITNTS . AUT,q*IZATM" /OR PU . ACATTON OP OUR RtPTAlTS . OOMGLO .s.s . M . .X. TRACTS FROM OR R[.APOINO T'11 M IS RP St RVrO Pr YO~MO OUR TTPITTtU APPROVAL AS A MUTUAL PROTNCTIOM TO CLIENT{. TTIE MI.L1C ANOOUR1SLVt ..

Date

LABORATORY NUMBER 440010 Sample WATER el iarkcd Retched

9-9-57

September 24, 1957

"North American Rocketdyne Laboratory ;ianta Suzana September 9, 195 7 Delta Rete nt ion Pond" Sampled by :

Submitted by Holladay & Y;estcott, 5384 Huntington Drive , Los Angeles , 32,'California .

SMITH-EMERY C 0(PANT

ANALYSIS ANALYSIS OF DISSOLVED SOLID S

silica. . .- . . . . . . . . . . . . . . . . . . . . . . . . . . (SiO,) . . . . . . . . . . - . . .- . .- . . Aluminum Oxidt . . . . . . . . (A1,0,) . . . . . . . . . __ Iron Oxide. . . . . . . . . . . . . . . . . . . . . . (Fe, 0,) . . . . . . . . . . . . . . . . . . . . . . . . . ... Calcium------- ---- . .------------Ca Magnesium . . . . .. . . . . . . . . . . . . . . . . (MIg) . . . . . . . . .-- . . .. . _ . .----Sodium . . . . . . . . . . . . . . . . . . .. . . . . . . . . . ( Nit) . . . . . . . . . . . . . _ . . . . . . . . . . . Sulphate . . . . . . . . . . . . . . . . . . . . . . . .(SO,) . . . . . . .. . . . . . . . . . . . . . .- . . Chloride. . . . . . . . . . . . . . . . . . . . . . . . . . . (Cl) . . . . . . . . . . .. . . . . . . . . . . . . . Carbonate . . . . . . . . . . . . . . . . . _ . . .(CO,) . . . . . . . . . _ . . . . . Bicarbonate . . . . . . . . . . . . . . . . . . . . . . (HCO,) . . . . . . . . . .

Total Solids ------- . . . .. . . . . . . . . .. . . . . . . . . . . . .

Total ,\on-I'4latile Solids. . .

PARTS PER MILLIO N

25 .3 Trace Trac e

64 .1 25 .8 78 .4 96 .3 50 . 0 Bone 324 . E

664 . 5

1+.99 .5

PARTS r[R MILLIO N

HYPOTHETICAL COMBINATIONS silica. . . . . . . . . . . . . . . .

. . . . . . . . . . . . . ! . . . . .Siot . . . . . . . . . . . . . . . . . . . .. Aluminum Oxide. . . . . . . . . . . . . . . . . AI,O,. . . . . . . .. . . . . . . . . . . Iron Oxide. . . . . . . . . . . . . . . . . . . . . . . . . . . . Fe,O,. . . . . . . . . . . . . . . . . . . Calcium Bicarbonate . .. . . . . . . . . ..Ca(HCO,) . . . . . . . . . . Calcium Sul phate. . . . . . . . . . . . . . . . . .CaSO. .. . . . . . . .. . .. ... .. Calcium Chloride. . . . .. . . . . . . . . . . . . CaCI, . . . . . . . . . . . . . . . . .. . .

25 .3 Trace Trace 259 .6 None None

Magnesium Bicarbonate . .. . . . . Mg(HCO,) . . . . . . . . . Magnesium Sal phate. . . . . . . . . . . .)MusD . . . . . . . . . . . . . . . . . . Magnesium Chloride. . . . . . . . . . . . MCI, ... . . . . . . . . . . .. . .. Sodium Bicarbonate. . . . . . . . .. . . . .NaHCO . . . . . .. . . . .. _.. Sodium Carbonale... .. . . . .. . . . . . . Na,CO, .. . . . . . .. .. . .. . Sodium Sulphate.. . . . . . . . . .. . . . . . . .Na,SO,. . . . . . . . . . ... .. .. Sodium Chloride . . . . . . .. . . . -------NaCI- .. .. . . . ... . . Total Solids . .. . . . . . . . . .. . . . .. . ... .. . .. . . . .. . . . .. . ............ ....

155 .1 None None None None

Total Hardness or CaCO-_ . . . . . . . . .. .. . . . . . . . .

142 .1 82 . 4 266

DETERMINATIONS Specific Conductance (Micromh„s - cm .).- . . . Hydrogen los Concentration (p,11) . . . . . . . . . . . . . . . . . . Boron ( B) in p . p . m . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Nitrate (NO,) in p. p .m. . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . Fluoride (F) in p . p .m . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

819 .7 °A 2 0 .2

Trite Color . . . . . . . . . . . . . . . _ . . . . . . . . . .. . .. . . . .. . . . . . . . . . . . . . . . __. Odor Quality .. . . . . . . . . . . . . _ . . . .. . .. . .. .. . . . . . . . . . . . .. . . ----° Taste ----------- ---- . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _ . . . .-- . . . . .. . .. .. . . Turbidity. Jackson Cardle. . . . . . . . . .. . . . .. ... .. . ..... .. . . : . . ; Suspended Residue_ .- _ . . . . .. . . . . . . . . . . . . . • .. .. . . . . .

None None n .d e

10 10

Ar:Tlllic .,! mrthodr u'ed are 11--c , -r, nr-rev ; (J,;i, n of the StasJ,nd Methods for the Examination of II"a:er , Sewage and Industrial 11"dr'e : , .'; : -- : .rd l ;he A-verican Public Health Associaiioa inlets stated oliberuyse .

Lissclved Iron ------ 0 .035 ptw Chlorine Ler. &nd ----:I' :: C~ Chlorine Residual --- 0 .1 pYFydrogen Sul-1de ---:c 011

pect f ally saw fitted,

----------------Che+ni.tlq-LF7r1 qe

BNA0865701 9 HDMSt00014788

t -

• •

? i rp`: ;

DtPARrMF n'

56/4 Caro

!"rc'• .

A . i, . 1- ^%, nv

D'-NART r*MT

56

r'N(`Ttf:

576

DP.TF

9 October 195 7

TO

F.

F.

i,

r.;

7

~,

1

/.

SonSu

rr^,h"T `.';r`TzR PT THE SO' L RtiTF2'TION

Ffl.F `Y :711IR

R vyr-' r act "n'~ f r reov('a e coolant water at the Bowl Arr,c wn3 ec•ti- r, ".^'1 4 n nnnth of ttpril . This avatar was pumped directly frcn rett :t.ion reservoir for reuse as coolant water at the Fowl tot stares !rith^ut treatment or filtration of any kind . Within o shor ; tir..c, this recycling operation resulted in 3 build-up of ar ;7rrrw?cd solids are a noticeable hydrogen sulphide odor in tho cr^e . 7'_a ore tcd n very undesirnble working condition for peg err^I in the s~-a, and posed the question of using water that hod e,-teriorntc' to the extent that it would be detrimental to the e ;,sten o Steps were irjnoelintely taken to have a complete analysis trade of the wptcr, c :'tr r which tests were conducted to determine

the not effective gonna of restoring the water to a'usable qualitye St;r±ples hv're been ar^iyze41 by the tf aterials and Processes Grnup of our 'Research Section, anc' by an outsirdo chemical laboratory . The results of the tests shared that the water contained more then 900 PPM suspended eo?Ic'', free hydrogen sulphide , a residual oil content and a PH of 6 .4 . Te'ts p-rtcrae-? at the laboratories showed that with a retention tires of four hours, the application of conditioning and flocculatiiw e^crt.^ v-rld restore the water to a usable quality . It was r;e^~c c-, ' .e initiate a pror_ rem through Dept . 546 for the narma l tre•-t- c r the reclair .Pd water . This progeai would perrlt further ^l ^nr n ti^n tinA er nermal operating eel-tditions, and provide the in"c---^-' ic.n neoeesery try make a cost evaluation of the manual operation .

This prof-^"r'^ l,£ a been in operation for two r^orthe with the f^llocri ng re!7ultr : 1. 2. 3.

Undesirable hydrogen sulphide odor no longer preztent . i'1 ck color completely removed .

5. 6. 7. p.

S?--'.r•c soon: ~t'jlation in the reservoir very mall . Y.~-omen su lphide completely rerioved . TDIe : ol-- d Iron reduced to .035 PPM. Tr-er.t-ort reeuired snprcn!itactely t :'i^e a month . ie treetnent e.Dprf:Tf ^.,nt sly t30 .t~!)

Su^rcnPPA rolide { turbity}s r duced to a neligible asonnt . FH 3.ncrenserl to alkaline side .

BNA0865702 0 H D M St00014789

0

• 9 C_:tol • 19x 7

Pago 2 . st Favl R-n~` ention Reservoir -

-

-

--

-

-

-

-

-

-

-

-

-

-

-

o r.. zr ^ : it . r. .:ee~'+c ~3a'•3o of Dopt . 564-05 to continue c,f 'bo r r 1 E ct ~h r arn~31 npp1ieAticna , since th e n: ~,,,°^r rrc :7;1^cr, .."~{ .: • ~,' , ,~ u-+ tit; for u e as coolant Water at a c r~• Y,r. . : .n~:t cc^, . r t.c.r n tic treatment nyatem , which ban rn^nu,,r+ occur that will justify

ec.a~

A . A . Ameda y General Supervisor InAuatrial Hagineering

A .A mmn

i~:1.-ra S n'u lmsol-m o

% . W . g: amen S . reesc ti . D . Cr :.asl~c' G, r. . i)',nklin C . C£rr~_'c t

lr~~- 52 vin `

Fos `i J .-n3 S-^nS•1 3 /- 5 e

G . LStit :`c< .

^

Fps J

C~ no

T.T . 1. 2e n W . C . Rich rC :!?n Scrcc3

San- 1 r- 5 c . nsu

BNA0865702 1 H D M St00014790

TERMINAL TESTING LABORATORIES, INC .

dnalytlul and Consulting Chemists and Bacteriologis u 4024 BANDINI BLVD., LOS ANGELES 23, C.U.WORNtA

9-2514- 9-162 5

LABORATORY NO.

a 2074, a 2075, a 2076

REPORTED

POH

EOCKTMN

SAMPLED

SAMPLE

WAT.~?S

RECEIVED

>~cAx>w is valley floc a is ii ique rtki - quite umwval ,

RI-D21- 065032 '

BNA08657030 HDMSt00014799

The Creteeeou r c ive en:da+ se is bo d ta the aarttrweet west e:d tia,Ly an the sc ath b7 Z,-*am ACa shales . A 3wrge teat tr=dlnC east- ~~ by VW*. to the South a erentl,4 fars a seal in this d1reattoa . e.

fac

. of the £ t4 SU3C3 3 !'.

On t1

Rasa

t*3nn the port esterl7 dip ct the

.tioas with I tefrbe+ddod tb n t le sac bern E r r8tmtly f---D the bcir_-iar

en each 3tratua to retain the =tar •.rithin the Chi ca st.^nc.-ta a .

The . w--r1.cr

an the ah is zct iefi :3tsly rsmn but It is =t cartalr is th! 'e bee:ue a

ter vell c:2'112 about 7,COO fact nor ttr.«sasterly of the no th3 .a6t

Co,,..er o1 It. i`toerty p ab=t 2p4W feet up Black :►a xy. ?wad Zrt 51=1, V&lley , h s static water level of Z1155.0 feat &bovo seg level , rih11e

i walls bed nta.tic Later l viols frba 1430 to 1630 feat above sm 'Level, It this •aell tha

:ace elevation is 16.25 feet s» n Sea level which l's abacst

=0 feet to-or thoa wets at ::'*. , anr3 t e statle water legal is 7(0 f cat below • et nrrf ace. The Iaroot static vstQr level at P1'f. is SSO fG041 °: e t

the surf4ce. The ge zla a bsrri ar on the ocrth has not on %r=:ad nest in detr.3:.. It is the mit er's opinion that the shsle body in . tits Chico' taarmtieu . which is - found about 1 4.00 north of c ,arty down Mach Con7m- rood, e:o=i1d be the bee=: iar holdin; t water up on that r M property.

Vera is

poesihle fauliting, which could also be e. aoei.otec3 with the berrie .

RI-D21 - 06503 3

BNA0865703 1 H D M St00014800

IT.

VArT IR- T1F.i •

$inns the activatica of t.',.o r?o u1zi Field I.aba:sc+.m7 Faoili ty, sixteen (16) veils have be m dr{iUad . 1:itb the a rtl tion of t ho jrL t veil in Catotsn• 144 .9 water tails s

atn errszcts hrvo boen receded oa a

uaat2 F this. i`cn::. tan ( 10) ys?a.

or oparasriott, the st,_nr: i a,, water

level be crop ed 2e5 feat ( rver{'o of -roduc2.ng wells), ' t no tfra : love the recorded .mtrr !oval mas%z a ans ree'? setai the Lnfl gar o of ro•~ l eaasat frm percolation . in nt r.ani areas vncch bays s,c firer =::iitiars

can cti.r; the au-face with the &ame of sat t .{.On, rep le .:.istmnt of the growx1-4~;cr £lc .y tt:rouGh prrcalatic i r.-= rainf 11 ., cns. ';; 1, s`. r~~~-I• aT and i:aaz:iag t nsina Is re£l sated in a saaaa ml mss of the rtsd sate iab3.o. T e centlrusl d-cp of the mto love t o s the ten (10) yftra at aperatioa at the PC*i•t2I9~iC~ c1s+d :.ab=a+.ory is e'er-ectiy r='oj ztici i to the ==t of tatcr extracted . P..3.1 e.idanee obta ine d th ctzth W - sent4 of the staxing water 1ot,l indicates that t s u=tter bearing fractures and joints csa caaq2cta1y cantaiaed by i pe iavs m=bcrs*

RI-D21 - 06503 4

BNA08657032 H D M St00014801

ITT .--~~rrr•

r"ri

-Z

Sesgloa takcai tray ao tive %.•alla have been subcittod to mzt:.ide 2nbo ntxzien periaiically fcc Cx 1ete " -mer 1 a..3`.3,yaia . another =xi,;.r4 thr 1!h hi ich tsxto?.

:lbi9 }.."cvidr s

can er+, .1rs:'~,s the is f1 wr co of ; cala*.3 : g

:.xz iaatica of these re-em-to sha.s no sable

;a in

miaeral co*n t.-aticra . until ar;.rtacir:btely aim (6) tm ago, there vas 1-41t.1a being added to the is u triza e. fit:ee t that u=] 4 tend to

the 3!.-ml

c= onttetioa of the water . Lutin g the pcst a !x ( 6) rmnthsp hz,aver, .ti i.rcd in t. a large c• cam:.-st ;ons of nItr-etee (N`3) bane beers r baaisus .

Since citrates hm c l i a y a boau low or o -let beet in

preiic'.ss tents

:ratl a=t.les, they aba Id r*ra :ide, a fond im6loatar,

as ware taken 31 October 19 53 In all active walla, the results sshm;od no :it-ato s in all •.-e1Ls m ec;:t Yell 9A vbich h-nd 2.0 17. ".'. (lab results.

Cr. ban

on

t!-.o *al? oving ;oZaa ) .

This coremtration of 2 .0 ? .11

is below p evi ,%m reca dei c tratiana cm volt samples . This indicate* that paroolatiaz £rars thsas rs t.utio boa3- during the at ,rdx ( 6) moths ban net sham a iifnancs in the quality of the gramd-Water.

'well , •eU #5 '1

w6

:e11 &'7

0 .0

0 .0 0 .0

(:" a ("4t3)

2.0 t 3} ::eU ,11 0 0 Well .'.-12 0 .0 ( :~ :3} %aol1 d`13 0 .0 (_i}

RI-D21 -06503 5

BNA08657033 HDMSt00014802

1-

~~-~a-y7

'.JELL #3

3d

:.f 5,n ,4 h ►'~~ v I -13

A.=13- ZqIL

) ireh 1oL_Q

Total Dissolved Solids

786 PPM

697 PPM

Total Ha dneas

585 PP-n

432 PPM

304

143 Th1

DL

44 PPM

3102

Ir%

PH

FPM

-;L-

137 M . 38 Frli 36.2 PPM

M 7 .15 FM 7.9 FP

RI-D21 -06503 6

BNA08657034 HDMSt00014803

WELL #4A ~cber 1q51

t.1%1b€r! 1q55

Total Di~501v 4 Solids

580

PPM

580 Pm

Total Ssrtdavss

3'?0

PPM

409m P 115 FPM

Ca

29 PP

. 56

449 .3 PP

5a

3.5 PPM

x

0.6 PPx

Pf

363 = PPM

~C03 804 Q 503

142

PPM

39

PPM

0.0 FPM

40.8 PPM

0.0 P

0.0

502

FP

.2 PPM

r

0.6 PPM

P04 .7K

137 PPM

7 .6 PPM

7 .4

PPM

RI-D21-06503 7

BNA08657035 HDMSt00014804

met 1953

DA 4 Total Dizeo1vd Zalid3

457

Catcbr' 1956

Duna 195a

435

487

267 71.0

aotc1 Eardaess

271 pc

Ca N$

79.4 17 .6

21 .6

7i 20

~a

53.4

50.2

52

s

Total Cation

2.8

2.8

7.61

7.58

Co.'

32.5

C1 0.2 Anions

Bcxca Silica

3.7 0.2

7.62 :0.043

0

221 99

102

so4

Total

0.0

3 .10 7.72

0.0

38 0

0.27

7.73 0 .2 3

34

20

Sr~ct?OS^b-iO $

C~olCltsl Sliac Altuxin~s

127 .0$

4.5 3 .6 0.092

Cc

0.c0034

Sodiuu

3.2 1.0

Fotsasitss

Iron Tin Bsriua Tit~riim Nickol Stronti m

cbraors:m

m

0 . 045

0.043

24.0%

7. 2 7.8 0 .021 0 .C,03 Q

0.052 2. 7

0.74 0.016

0.029

O.c099

. 24

.32

7.8

7.7

7.6

RI-D21-06503 8

BNA08657036 HDMSt00014805

c)

ovea~r 1555

iZ

Tutc1 ~iaco1 n Tot l &rdaess

Saba,

580 p 32'1

525 nS Caao3

85.0

27.7

x Total Cntio

c so,

661 .8

3.5

5 .32 0 .0

1330

40 .8 F T;,~s? aaioaS

8a:vn

Qato'' ~e 19%

0.6 0,1

9.35

71.2 31.8

t$ , s

3.5

490 1B7 55 2.2 86

3.1

9.25

0.0

336

~3

125

91

40,0 4.3 0.2

9.32 0,1

Si13 ca

Ssa s 19

19

35

0.37 ?.Er3 0 . 20

26

,°~rc~roJrrc:ti~,~ fl s

n1 *iw F~s:;;ncai~t Siiooa

u~ cop .r

27.0%

4.5

5 .1

0 .020 0.Cui)37

Pd'i~i"otl

E.8 8 .1

0,018 C .C0 .34 0 .068

S4clitnt F'at3sSit~► Iron

0.,6

b~n~aaoSa T3a

a.

0 .018 8. 8

0.002 tit 0a6

0.43

7.45

7.5

Titar i i+iG:tsl Stroa 4asa

cra~onina

7.0

0.063

0.014 0.ec 5

4.3 1 .0

7.8

AI-D21-06503 9

BNA0865703 7 HDMSt00014806

/N

~

D.i'1 s

955 Tot Diasalyed 5c1ids i~t41 H. j' C33

Ca

1,L1~ plat 278 pj 72.8

I~

23 .2

I~ 1C

3.5 7.23

Y3ts3. Catioas Co.,

0.0

80,

a,

32.3 1.2

P

0.2 7.29

Total !'nic &araa Silica

Oata19%

35

56.2

96

39 .1 33 6.55

50 3.50

23.8

0.0

25.8

324 97

3 .1

0

0.2

0 . 21 9.53 4. 0

6 .1.7 0.0

27.0% 5.2

6.3

0.028

Co

0.00025

0.3Go

F.SZ'Q!I

Socii:~t P tanaitant

7.8

0.91

lscn

0.35 0.017 nil

Jsme 195B

584

X33

u

esince

~Caaeae Tn i riraa 'IYtortitm II1~eI Sttontii c

.

30 ,

3o.a~

. .0 3

12.0 0 .021, f! .'Yc,2g

3.0

0.96

0 .CQ 6 0.032

0.05

..

0.002 ni l

043

037

7.4

7.C

?.5

RI_D21-06504 0

BNA08657038 H D M St00014807

i

DATSs

0etoba: 1956 Totr.1 Diaaalvcd :o1id~

543

Total Rard.coza

325

Ca

75.a :2.9

x rot . Caboas C^

0.0

K

348

X04 C1

12.2

N~

Tcte1 Anions r-,wxc~A '

Silica

l

E8 .5 1 .9 9.53

45.3 4.3 0.3 9.E1. 0.2

16

)naaiwa Siiii on ~srtL~am Coe?

ll..'.

Sodius rotaeaius Iroa W n anesa Tin D~rita TltAtLiaaa 2ic;cal utrontita Cu`gttiil,®

4.8

dime 1958

592 315 64 26 12

2.40 9.52 15?

42

0 O.40

9 .EO 0.30

21

9.8 0.019

0.0 0.?9 0.017

?S.2

0.23 .

7.2

7.4

RI-D21 -065041 1

BNA08657039 HDMSt00014808

a~. LL . Octotar 1956 Tfltc1 ~.t3 C1YC3 Solids Total. crd.,aa Ca

4g

z ?ot al Cctiona 4 .r

EC rJ4 Cl

3.1 7.26 00.0 317 52 0

fatal . Aaicns ~aa Ji,.ica

C~:ci:s~a ;se, `i .`t3f ua ~• 7rt1

rft r .

rcY,~

iata► aai~t Iran

:~n~ansss Tia «.

440 232 57.4 21.6 55. 3

5.0 0 .5 7.34 0.0 18

Juts ca 250 68 19 62 3 .10 7.76 0 32 64 31$

0

0.40 fi.BS 0 .30 25

32.0% 9.2 13.0 0.0x3 O.Oa022 0.034 4.8 0.96 0.036 9.2

a

23'F.aaictat ia:al t2 csxti~t

Chrcxaino

0.28

PH

T.8

7.75

[email protected] 2

BNA08657040 HDMSt00014809

.tA2E~ Total Dissolved 5 o Total Uardaesa Ca

C tote 19%

June 15 5

473 267

542

59. 8

28 .4 69.? 3.1

I Total Cati xia Co.,

0 .0

345 27 55 3 .10 0.

32 49B.6 35.5 .; .3

0.2

Total :.aioas

8 .46

0 .0 20

SS1ioa S~eetro~rra r' CalcLu?a

~`.~paa3uat SSi3caa Coker Zoz'a $o iza fotat! aunt ZTA3

lgaaess in

Titaztiuat &ickel StrontiI. Ctuoaitas

313 40

0

0.20 0 .21 36

$

33.0% 9.4 ?.8

0.016 O .CCOl9 0.090 8.1

1.5

0 .016 0 .01 2

0.35

fr$

RI-D21-06504 3

BNA0865704 1 HDMSt00014810

:TA t 2? r t : atc:t is p 4z ca .:--~¢sri7u j. a1 a1 ri' t d/

48. 6••

e

.c v l.cd f r twa~i~

w•b.

w^ j'4 t ;r -: b

co

c;u- i

at

tut!

t t

th r;

cr 1

C

rr

W

c.i .c

.

1 .. r .,

o

a

18.r 4

:ttcn si beoir. to tt r `„c : c v:ed or

t t r~r1Q . , io

o

:ba »atEx »crw :t*:a :rd

The

f V~Jt .

r "'ai3` .z1t~

i3 ~

ate. .-i: •

r3

~

~

~v1.+tTid;: i -, ;. .it

! .- ••. Z

~__

"

:. _

16,CCD ..'.re .'=s•t , t r r :a i i ..~.s

. .~ . .. M.t ♦ r~

% r

. •

(

j

r



Let :: rrt'rco t-ea '

: : : Iwo :r . . :.i

!

s1M

• I



.Ch

' ~a

p

3*

l

i

s

.:Y• se to t5 iru :icrta~ no r Lz blz I t2 the • ' -rst~r:tio5i czn:

.

.

.

.

; cs •.rcre t4 to t e fret t cz~t6:'.A3 tre 1C1(1

Lis

U,

::':e?

f,~ra tai ~r:v~~ cv tr.+s 'e:.-tea ecxu ~e: ac+~ic~ :n a .•* e t"~ ~rrulccfrg .:t

:a.

:,>

RI-D21-06504 4

BNA0865704 2 HDMSt00014811