Additives for Paints and Coatings
Solvay Novecare Coating Additives SOLVAY Novecare, Global Expert in Additives for Coatings Applications Solvay, a world leader in the development and production of specialty chemicals, supplies performance additives for a variety of paint and coating applications. Solvay additives deliver outstanding benefits to coating formulations, such as enhanced surface wetting, improved coating adhesion to substrate, superior dispersion stability and gloss, enhanced color development and stability, and better foam control. Solvay additives are also effective in minimizing production mixing time and improving manufacturing efficiency. Technical support dedicated With our global technical support network, Solvay provides customers with custom-made solutions and develops formulations adapted to their needs and requirements for the paint and coatings industry. Solvay uses its expertise in safety, toxicology, environmental and regulatory affairs to provide guidance on industrial formulation compounds, thus creating additional value for paint and coatings customers. Global industrial footprint Through its world-class manufacturing operations in Europe, North America, Asia Pacific and Latin America, Solvay shares best practices within zones and benefits from technology transfer. Strengthened by a worldwide R & D and tech-support network, Solvay develops strong partnerships with customers around the world and creates innovative materials focused on next-generation technologies for the paint and coatings market.
Note: T hese products are produced at worldwide locations through the Novecare division of Solvay.
Solvay Novecare offers multiple products w RHODOLINE® series defoamers wR HODOLINE® dispersing agents wR HODOLINE®, IGEPAL® and GEROPON® wetting agents w RHODOLINE® series freeze/ thaw and open time additives wF ENTAMINE® and FENTACARE® specialty amines w RHODIASOLV® coalescent Adapted for paint and coating applications: w Waterborne paints w Aqueous ink systems w Water-based adhesives
Solvay’s Sustainable Portfolio Solvay Novecare works alongside its customers to design products and solutions with reduced impact on health and the environment. As part of corporate social responsibility, Solvay uses procedures that monitor its products throughout their entire life cycles. Solvay supports customers with a broad range of sustainable solutions and services including products optimized around criteria such as biodegradability, eco-toxicity, VOC content, and percentage of renewable materials.
Solvay offers a versatile toolbox for waterborne paint and coatings formulation.
Solvay VOC-free defoamers and APE-free surfactants are examples of its commitment to sustainability and the environment. Solvay recognizes the difficulties in selecting the optimal surfactant system for wetting, dispersing or designing an emulsion polymer system. Formulators require surfactants that perform and are compatible with the entire formula and do not compromise the quality of the coating. Environmental concerns are also key drivers behind the reformulation of well-established systems, leaving formulators with additional challenges to overcome, such as the conversion to APE-free systems or ensuring compatibility with low to VOC-free formulations. Solvay Novecare is developing and expanding its line of industry-leading paint additives to enhance the performance of VOC-free and APE-free water-based formulations while providing additional benefits such as improved freeze-thaw, open time, film appearance, defoaming and wetting characteristics. Solvay consistently develops new sustainable additives that allow formulators to address the performance challenges of newer waterborne formulations, while answering the demand for more sustainable and cost-effective products.
Solvay Coating Additives / 1
Functional Additives RHODOLINE® OTE-500: OPEN-TIME ADDITIVE RHODOLINE® OTE-500 is a novel APE and solvent free open time additive for low to VOC-free waterborne paints, coatings, inks and adhesives.
Sustainable Additives w APE-free and VOC-free additive w Low odor solution w Enables design of low to VOC-free coating formulations w Design sustainable coatings with RHODOLINE® OTE-500 [Green Seal (GS-11) or EU Ecolabel compliant paints]
RHODOLINE® OTE-500 improves open time for low to VOC-free waterborne paints. It could be utilized in various formulations from low to high gloss paints. RHODOLINE® OTE-500 significantly improves open time for paints made with the following resin systems: w All-Acrylic copolymer w Styrene-Acrylic copolymer (S/A) w Vinyl Acetate / Acrylic copolymer (V/AC) w Vinyl Acetate / Ethylene Copolymer (EVA) w Water-based Alkyd Paints RHODOLINE® OTE-500 works in all gloss: high gloss, semi-gloss, satin and flat (matte) systems Key Features w Extends open time w Exhibits excellent dispersion stability w Allows formulation of Eco-label compliant coatings w May reduce/eliminate wetting agents
PAINT SAMPLE
CONTROL
RHODOLINE® OTE-500
2
8
VOC-free ACRYLIC SG PAINT
RHODOLINE® OTE-500
MIN
Visible X shows limits
OPEN TIME
0
2
2
4
4
6
6
8
8
10
10
12
12
14
14
u Listed
2 / Solvay Coating Additives
Flat to semi-gloss paints
High Gloss
Elastomerics / Roof coatings
Traffic Marking Paints
Inks
Adhesives
USA (TSCA)
CANADA (DSL)
EUROPE (EINECS)
AUSTRALIA (AICS)
SOUTH KOREA (KECL)
JAPAN (MITI)
International Inventory Status
VOC-Free
APE-free and VOCfree additive that promotes extended open time
OPEN TIME
APE-Free
RHODOLINE® OTE-500
DESCRIPTION
MIN
0
Application Guideline
PRODUCT NAME
CONTROL
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Low VOC Acrylic Semi-Gloss Paint LOW VOC SEMI-GLOSS PAINT FORMULA Raw Materials
A
B
C
CONTROL PAINT
RHODOLINE® OTE-500 + RHODOLINE® 5520
RHODOLINE® OTE-500
Wt. %
Wt. %
Wt. %
Water
7.75
7.75
7.75
RHODOLINE® 286N – dispersant
0.78
0.78
0.78
RHODOLINE® 643 - defoamer
0.05
0.05
0.05
RHODOLINE® 5520 – wetting agent
0.39
0.39
0.00
RHODOLINE® OTE-500
0.00
0.00
0.39
Amine
0.19
0.19
0.19
Attagel 50
0.48
0.48
0.48
Titanium Dioxide
22.29
22.29
22.29
Water
8.67
8.67
8.67
Acrylic Latex (50%)
46.52
46.52
46.52
RHODOLINE® OTE-500
0.00
1.21
0.82
RHODOLINE® 643
0.19
0.19
0.19
High Shear Builder (ICI)
2.23
1.65
1.94
Water
9.21
8.61
8.56
Low Shear Builder (Ku)
0.85
0.82
0.97
Mildewcide
0.39
0.39
0.39
Total
100
100
100
PVC = 22.2%; Weight Solids = 45.4%; Volume Solids = 32.4%
For optimum results use RHODOLINE® OTE-500 as shown in formulation C above by splitting the quantity in the grind to replace the wetting agent and in the letdown. RHODOLINE® OTE-500 increases the open time with minimal impact on dry film properties. CONTROL PAINT
RHODOLINE® OTE-500 + RHODOLINE® 5520
RHODOLINE® OTE-500
Non-Ionic Surfactant R5520 - %
0.39
0.39
0.00
RHODOLINE OTE-500 - %
0.00
1.21
1.21 (0.39 + 0.82)
21/56/91
27/61/89
23/57/89
Fail-1
16
14
2
8
8
Scrub Resistance ASTM D2486
>1000
555
>1000
Block Resistance ASTM D4946
Control
-
-
0.53
0.79
0.65
-1
4
0
Stain Resistance ASTM D4828
Control
=
=
Surfactant Leaching - O/N Dry
8
9
9
10/10
8/10
PAINT PROPERTIES TESTED
Gloss O/N 20°/60°/85 Freeze/Thaw - 5 Cycles - ΔKu Open Time – Minutes ASTM D7488
Color Rub-up ΔE – BLK (1.6% by volume) Heat Aged – 2 wks @ 50°C – Δ KU
Low Temp FF, 5°C – Sealed/Unsealed
10/10 Rating System: 10 = Best; 0 = Worst
Solvay Coating Additives / 3
Functional Additives RHODOLINE® FT-100: FREEZE-THAW STABILITY ADDITIVE Freeze-Thaw Process
RHODOLINE® FT 100 is a unique APE-free and solvent-free additive utilized to improve freeze-thaw stability primarily for low Tg latex binders as well as waterborne paints formulated with these binders. RHODOLINE® FT 100 also improves gloss, pigment dispersions and stain resistance in these formulations.
Freezing of Latex Polymers (to -18°C)
No FT-100
Key Features w Delivers freeze-thaw stability w Enhances gloss w Boosts stain resistance w APE-free and VOC-free
With FT-100
Easy to use for a wide range of polymers w All Acrylic w Vinyl / Acrylic w Styrene / Acrylic w Ethylene vinyl acetate
u Listed
4 / Solvay Coating Additives
High Gloss
Elastomerics / Roof coatings
Traffic Marking Paints
Inks
Adhesives
USA (TSCA)
CANADA (DSL)
EUROPE (EINECS)
AUSTRALIA (AICS)
SOUTH KOREA (KECL)
JAPAN (MITI)
APE-free and VOC-free additive that promotes freeze-thaw stability
Flat to semi-gloss paints
RHODOLINE® FT-100
DESCRIPTION
VOC-Free
PRODUCT NAME
International Inventory Status
APE-Free
Application Guideline
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Effects of RHODOLINE® FT-100 on Freeze-Thaw Stability of Low VOC Commercial PAINT Commercial all acrylic gloss paint (VOC= 50 g/l/ASTM) RHODOLINE® FT 100 No additive Ethylene Glycol Alkyl Phenol Ethoxylate Linear Alkyl Ethoxylate
Initail Viscosity (KU) 102.4 121.1 103 88 96
1 Cycle
2 Cycle
103.8. gel gel gel gel
104.3
3 Cycle
4 Cycle
5 Usage levels in Cycle paint formulations
104.0 105.4 105.4 paint coagulated paint coagulated paint coagulated paint coagulated
1.0% — 1.0% 1.0% 1.0%
Solvay Coating Additives / 5
Wetting Agents SURFACTANTS RHODOLINE® WA Series w Very fast Wetting w Extremely low foam w Full compatibility with water based paints w APE-Free w VOC-free, flexible for point choice w Low viscosity easy to handle
6 / Solvay Coating Additives
Solvay offers a comprehensive line of wetting and dispersing agents specifically designed for waterborne coatings systems and drives its innovation to deliver new and better performing APE-free and VOC-free solutions. RHODOLINE® and IGEPAL® dispersing and wetting agents provide excellent broad compatibility, improvement of color stability and color acceptance, improved flow and leveling and storage stability in both architectural and industrial paints, inks and adhesive systems. These workhorse additives will reduce the surface tension and improve pigment wetting with minimum foaming. RHODOLINE® 200 and 300 series polymeric dispersants provide exceptional pigment dispersion, improved color acceptance and storage stability. RHODOLINE® 3000 series provides exceptional pigment wetting and color improvement for carbon black and organic pigments. RHODOLINE® 4000 series is designed for inorganic pigments. RHODOLINE® WA APE-free wetting agents provide excellent substrate wetting and low foaming for waterborne paints, coatings, adhesives and inks. RHODOLINE® WA line of products are low viscosity with low pour point for ease of handling.
Rhodoline Rhodoline WA 20 at a1t .0% addition W1A 120 1.0% addition Rhodoline Rhodoline W A 1 20 a t 1 .0% addition WA 120 at 1.0% addition As As is is RHODOLINE Silicone Silicone WA 120 at 1.0% addition Silicone Silicone As iAs sAs isis Silicone ®
RHODOLINE® WA 120
Rhodoline WA 20120 Rhodoline W1A Rhodoline A 120 Rhodoline WA W 120
Benchmark
Benchmark Benchmark Benchmark Benchmark
Solvay Coating Additives / 7
Wetting Agents PRODUCT NAME
DESCRIPTION
HLB Range
APE-Free
VOC
Flat to semigloss paints
High Gloss
Elastomerics / Roof coatings
Traffic Marking Paints
Inks
Adhesives
Application Guideline
RHODASURF® BC-420
TDA Ethoxylate
8
Yes
Yes
u
u
u
u
u
u
RHODASURF® BC-729
TDA Ethoxylate
13.8
Yes
Yes
u
u
u
u
u
u
N/A
Yes
Low
u
u
u
u
u
Yes
No
u
u
u
u
u
u
u
u
RHODOLINE® 5520
Low foam nonionic wetting agent; excellent wetting and color acceptance
RHODOLINE® WA 100
Solvent free surfactant with a good balance of wetting and low foaming properties.
RHODOLINE® WA 120
Low foaming surfactant with excellent wetting properties. Great alternative to silicone wetting agents.
10 - 13
Yes
No
u
u
u
u
RHODOLINE® WA 200
High HLB surfactant with excellent wetting in low to high PVC paint formulations. Excellent alternate for APE, high HLB wetting agents. Improved paint stability.
17 - 19
Yes
No
u
u
u
u
RHODOLINE® 4160
Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.
N/A
Yes
Low
u
u
u
u
RHODOLINE® 4170
Potassium neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.
N/A
Yes
Low
u
u
u
u
u
RHODOLINE® 4188
Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance, color development, color strength and color float resistance.
N/A
Yes
Low
u
u
u
u
u
IGEPAL® CO series
Nonylphenol ethoxylates used as pigment wetters and color stabilizers
4 - 19
N0
No
u
u
u
u
u
IGEPAL® CA series
Octylphenol ethoxylates used as pigment wetters and color stabilizers
4 - 19
No
No
u
u
u
u
u
GEROPON® 99
Low Anionic surfactant for improved adhesion over chaulky and weathered surfaces
N/A
Yes
Low
u
u
u
u
u
u Listed
- Not listed
8 / Solvay Coating Additives
u
CANADA (DSL)
EUROPE (EINECS)
AUSTRALIA (AICS)
SOUTH KOREA (KECL)
CHINA (SEPA)
JAPAN (MITI)
PHILIPPINES (PICCS)
175.105
176.170
176.180
176.200
176.210
FDA Compliance 21 CFR
USA (TSCA)
International Inventory Status
u
u
u
u
u
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u
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-
-
-
-
-
u
u
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u
u
u
-
-
-
-
-
u
u
u
u
u
u
-
-
-
-
-
u
u
u
u
u
u
u
u
u
-
-
u
u
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u
u
u
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-
-
-
-
-
u
u
u
u
u
u
u
u
NE
NE
NE
NE
NE
u
u
u
u
u
u
u
u
NE
NE
NE
NE
NE
u
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Solvay Coating Additives / 9
Dispersants for Waterborne Systems
10 / Solvay Coating Additives
Dispersing Process of Pigment Three steps Wetting w L iquid replaces adsorbed gas on the surface of the pigment w Immersion, adhesion, spreading, and capillary penetration
Pigment
wE xcellent pigment wetting w Improved flow Liquid
Separation wB reaking up of the aggregates and agglomerates wH igh amount energy needed Stabilization w R emaining particle size and its distribution during storage
Key Performance Features
w Improved color acceptance w Improved stability wL ow foaming wB road compatibility
Wetting
Separation
Stabilization
Solvay Coating Additives / 11
Dispersants for Waterborne Systems
APE-Free
VOC
DESCRIPTION HLB Range
PRODUCT NAME
RHODOLINE® 3100
Workhorse dispersant for low to medium HLB organic pigments including medium grade carbon black and lampblack pigments.
11 - 13
Yes
No
RHODOLINE® 3200
Dispersant for low HLB organic pigment including toluidine red, yellow and other organic pigments.
8 - 11
Yes
No
RHODOLINE® 3500
High HLB organic pigment wetting and dispersant agent. Works great with organic pigments as well as industrial grade carbon black pigments.
>16
Yes
No
RHODOLINE® 3700
High HLB pigment wetting and dispersant agent. It works great with high surface area pigments such as conductive carbon blacks.
>16
Yes
No
RHODOLINE® 4100
Anionic; 100 % active. Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents. Improved corrosion resistance.
N/A
Yes
Low
RHODOLINE® 4160
Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.
N/A
Yes
Low
RHODOLINE® 4170
Potassium neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.
N/A
Yes
Low
RHODOLINE® 4188
Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance, color development, color strength and color float resistance.
N/A
Yes
Low
u Listed
- Not listed
NE Not evaluated
12 / Solvay Coating Additives
* Availability based on REACH status
EUROPE (EINECS)
AUSTRALIA (AICS)
SOUTH KOREA (KECL)
CHINA (SEPA)
JAPAN (MITI)
175.105
176.170
176.180
176.200
176.210
u
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—
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NE
NE
NE
NE
NE
u
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u
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u
NE
NE
NE
NE
NE
PHILIPPINES (PICCS)
CANADA (DSL)
FDA Compliance 21 CFR
USA (TSCA)
International Inventory Status
Solvay Coating Additives / 13
Dispersants for Waterborne Systems Percent active (%)
Recommende dosage Levels (wt %)
Flat to semi-gloss paints
High Gloss
10.0
25
0.1 - 0.3
u
u
Na
7.0
45
1.0 - 5.0
u
Na
7.3
35
0.1 - 0.5
u
u
Na
7.9
44
0.1 - 0.5
u
u
u
Na
7.3
44
0.1 - 0.5
Low-foaming, hydrophilic polyacrylate for general pigment dispersions
u
u
Na
7.3
43
Low foaming, ammonia-neutralized copolymer, best for gloss development. Exterior paints
u
u
NH4
7.0
50
APE-Free
VOC-Free
RHODOLINE® 111
Most versatile hydrophobic dispersant for stabilizing TiO2 and other inorganic pigments
u
u
RHODOLINE® 207
Neutralized polyacrylated polymer with excellent chlorine and thermal stability
u
u
RHODOLINE® 226/35
Low-foaming, hydrophobic copolymer for reactive and non-reactive pigments
u
u
RHODOLINE® 230
Hydrophobic dispersant, particularly effective with high calcium carbonate pigment loadings
u
RHODOLINE® 231
Water-soluble anionic dispersant used in pigment slurries and paper coatings. Suited for stabilizing inorganic pigments like TiO2, CaCO3 and MgOH slurries.
RHODOLINE® 270
RHODOLINE® 286N u Listed
- Not listed
NE Not evaluated
14 / Solvay Coating Additives
u
u
* Availability based on REACH status
Inks
pH
Na
DESCRIPTION
Traffic Marking Paints
Salt
u
PRODUCT NAME
Elastomerics / Roof coatings
Hydrophobic
Application Guideline
u
u
u
u
u
u
u
u
u
u
u
u
u
u
0.1 - 0.4
u
u
u
0.1 - 0.4
u
u
u
u
u
u
SOUTH KOREA (KECL)
JAPAN (MITI)
u
u
u
u
u
u
u
u
u
u
u
u
u
u
176.210
AUSTRALIA (AICS)
u
EUROPE * (EINECS)
u
CANADA (DSL)
u
USA (TSCA)
u
FDA Compliance 21 CFR
176.180
176.170
175.320
175.300
175.105
FDA CLEARANCE
u
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—
u
u
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u
u
u
u
u
u
u
u
u
NE
NE
NE
NE
NE
NE
u
u
—
—
—
—
Solvay Coating Additives / 15
RHODOLINE® Defoamers Solvay’s extensive line of RHODOLINE® defoamers is designed to provide optimal foam control in coatings, inks and adhesive formulations. RHODOLINE® defoamers provide excellent deaeration and prevent foam formation during manufacture and application of paints, coatings, emulsion polymerization, inks and adhesives. RHODOLINE® defoamers minimize foam formation during high-shear applications such as paint roll, brush, spray and high-speed ink or coating applications. RHODOLINE® defoamer portfolio includes industry workhorse products for flat to high gloss paint systems as well as printing inks and adhesive systems. The newly developed eco-friendly, APE–free and Zero-VOC defoamers, provide quick foam knockdown and the lasting efficiency. Wide range of use in polymers • All acrylic • Vinyl/Acrylic • Styrene/Acrylic • Vinyl Acetate Ethylene (VAE)
16 / Solvay Coating Additives
Key Features w Quick bubble break and lasting efficiency in Flat to SG Paints w Excellent efficiency in architectural and industrial paints, adhesives and inks w Does not cause fish-eyes or film defects w Excellent foam control in latex manufacturing of vinyl, acrylics and VAE resins w Broad compatibility
300
■ Initial Foam ■ After 1 Minute ■ After 2 Minutes
Foam volume (ml)
250 200 150 100 50 0
No Defoamer
Rhodoline®
Competitor
Solvay Coating Additives / 17
RHODOLINE® Defoamers Adhesives
Traffic Marking Paints
Elastomerics / Roof coatings
High Gloss
Flat to semigloss paints
u
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Inks
VOC-Free
DESCRIPTION
APE-Free
PRODUCT NAME
Silicone Free
Application Guideline
Oil Based RHODOLINE® 622 RHODOLINE® 635 RHODOLINE® 640 RHODOLINE® 643 RHODOLINE® 646 RHODOLINE® 670
Highly recommended for exterior flat to semi-gloss waterborne coatings In-process defoaming of vinyl latexes for coatings, PSA and paints Recommended for flat to semi-gloss coatings Recommended for contractor and consumer latex paints In-process defoaming of latexes for coatings, PSA and inks In-process defoaming of latexes for coatings and PSA
u u
RHODOLINE® 679
Recommended for adhesives and inks
u
u
u
RHODOLINE® 681F
Recommended for flat to semi-gloss coatings
u
u
u
RHODOLINE® 688
Workhorse defoamer for flat to semi-gloss waterborne coatings
u
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u
u
u
u
u
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u u
u
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Glycol Ester RHODOLINE® 990 RHODOLINE® 999* u Listed
A molecular defoamer that provides excellent defoaming efficiency with minimum impact on gloss. A molecular defoamer that provides excellent defoaming efficiency in water-based inks and adhesives with minimum impact on gloss
- Not listed
NE Not evaluated
18 / Solvay Coating Additives
* REACH compliant
u
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u
u
u
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u
CANADA (DSL)
EUROPE (EINECS)
AUSTRALIA (AICS)
SOUTH KOREA (KECL)
JAPAN (MITI)
175.105
176.170
176.180
176.200
176.210
FDA Compliance 21 CFR
USA (TSCA)
International Inventory Status
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u
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NE
NE
NE
NE
NE
u
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—
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NE
NE
NE
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NE
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L
L
L
L
L
Solvay Coating Additives / 19
Coalescent DIB RHODIASOLV® DIB is a new generation of low odor coalescent additive that meets tightening VOC regulations in the paint industry. RHODIASOLV® DIB helps in formulating low VOC paints without the drawbacks of plastisizers. RHODIASOLV® DIB coalescent agent is extremely efficient for architectural, industrial coatings and inks. RHODIASOLV® DIB does not cause film softness and provides films with improved hardness and scrub resistance. Key Features w Enables low VOC formulations w Low odor w Enhanced efficiency w Biodegradability w Hydrolytically stable w Nonflammable w True coalescing agent
Specialty Amines SOLVAY Novecare offers a broad portfolio of fatty and specialty amines for paints and coatings. FENTAMINE and FENTACARE products are based on specialty amines for use in paints and ink systems. FENTAMINE® and FENTACARE® products offer multi-functional performance properties such as improvement of pigment wetting and dispersions, as polyurethane catalysts, epoxy curing agents and used as neutralizing agents. ®
®
Amine Types w Fatty Alky primary amines w Fatty Alkyl Tri & Tetra amines w Alkyl Ethanol/Propanol amines w Specialty amines w Ethoxylated amines w Quaternary amines
20 / Solvay Coating Additives
EUROPE ** (EINECS)
AUSTRALIA (AICS)
SOUTH KOREA (KECL)
JAPAN (MITI)
u
u
u
u
u
NE
FENTAMINE® A-12
Laurylamine
124-22-1
u
u
u
u
u
u
u
FENTAMINE® A-O
Oleyamine
112-90-3
u
u
u
u
u
u
u
FENTAMINE® A-HT
Hydrogenated tallow amine
61788-45-2
u
u
u
u
u
u
FENTAMINE® A-T
Tallow amines
61790-33-8
u
u
u
u
u
u
FENTAMINE® DA-CO
N-Cocoalkyl 1,3-propanediamines
61791-63-7
u
u
u
u
u
u
u
u
u
FENTAMINE® DA-T
N-Tallowalkyl 1,3-propanediamines
61791-55-7
u
u
u
u
u
u
u
u
u
Antistatic
u
Dispersant/ grinding aid
61788-46-3
CAS #
Neutralizer
Coco amine
DESCRIPTION
PU catalys
FENTAMINE® A-CO
PRODUCT NAME
Epoxy curing agent
CANADA (DSL)
International Inventory Status
USA (TSCA)
Recommended Use
Primary Amines
Secondary Amines
Tertiary Amines FENTAMINE® DMA 1295
Dodecyl dimethylamine
112-18-5
u
u
u
u
u
u
u
FENTAMINE® DMA 1695
Hexadecyl dimethylamine
112-69-6
u
u
u
u
u
u
u
FENTAMINE® DMA 1895
Octadecyl dimethylamine
124-28-7
u
u
u
u
u
u
u
FENTAMINE® DMA 0897
Octyl dimethylamine
7378-99-6
u
u
u
u
u
u
u
3-Dimethylamino 1-Propylamine
109-55-7
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Specialty Amines FENTAMINE® DMAPA FENTAMINE® DEAPA
3-Diethylamino 1-Propylamine
104-78-9
FENTAMINE® MDEA
n-methyl diethanol amine
105-59-9
u
u
u
Specialty Amine Ethoxylates FENTACARE® T02
Bis(2-Hydroxyethyl) tallowalkyl amine(2EO)
61791-44-4
u
u
u
u
u
u
u
u
FENTACARE® CO5
Cocoamine 5EO
61791-14-8
u
u
u
u
u
u
u
u
FENTACARE CO2
Cocoamine 2EO
61791-14-8
u
u
u
u
u
u
u
u
u
u
u
u
u
u
—
—
u
u
u
u
u
u
u
u
61791-26-2
u
u
u
u
u
u
u
u
61789-80-8
u
u
u
—
u
u
u
61791-57-9
u
u
NE
u
u
u
NE
®
RHODAMEEN® HT-50 RHODAMEEN® PN-430 RHODAMEEN VP532 ®
Quaternary Amine
FENTACARE® DHT 21 75
Hydrogenated tallow amine ethoxylate Ethoxylated oleyl amine
Ethoxylated tallow amine Di(hydrogenated Tallow) Dimethyl Ammonium Chloride
68783-22-2; 7732-18-5 58253-49-9
Fatty Alkyl Tri and Tetra Amine FENTAMINE® DPTA- T
N1-Tallowalkyl dipropylenetriamines
u Listed
NE Not evaluated
- Not listed
** Availability based on REACH registration
Solvay Coating Additives / 21
The way we do business Solvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is dependent upon the responsible way in which we conduct our current activities — a way that reflects our commitment to each of our
stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People Sphere and the Economic Sphere.
Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self—assessments of their practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable value for all our stakeholders through innovation and partnership.
>R esponsible Care is the chemical industry’s voluntary continuous improvement initiative to promote safe handling of products. (1987) >T he UN’s Global Compact aims to ensure that heads of companies promote and uphold 10 universal principles concerning human rights, Working Conditions, Respect for the environment and anti—corruption. (2003) >T he International Federation of Chemical, Energy, Mine and General Workers’ Unions. (2005)
Europe Solvay Novecare—40, rue de la Haie—Coq-F—93306 Aubervilliers Cedex—France Phone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90 Asia Pacific Solvay Asia Pacific Pte. Ltd.—438B Alexandra Road—#02—09/12 Alexandra Technopark—Singapore 119968 Phone: +65-6291 1921—Fax: +65—6394 3377 Latin America Solvay Novecare—Centro Empresarial—Avenida Maria Coelho Aguiar, 215, Bloco B-1º Andar Cep: 05804-902 —São Paulo—SP Brazil Phone: +55 11 3747-7637—Fax: +55 11 3741-8378 www.solvay.com
Neither Solvay Specialty Polymers nor any of its affiliates makes any warranty, express or implied, including merchantability or fitness for use, or accepts any liability in connection with this product, related information or its use. Some applications of which Solvay’s products may be proposed to be used are regulated or restricted by applicable laws and regulations or by national or international standards and in some cases by Solvay’s recommendation, including applications of food/feed, water treatment, medical, pharmaceuticals, and personal care. Only products designated as part of the Solviva® family of biomaterials may be considered as candidates for use in implantable medical devices. The user alone must finally determine suitability of any information or products for any contemplated use in compliance with applicable law, the manner of use and whether any patents are infringed. The information and the products are for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance or any other process. This is not a license under any patent or other proprietary right.
MARCH
All trademarks and registered trademarks are property of the companies that comprise the Solvay Group or their respective owners. © 2012 Solvay Specialty Polymers USA, LLC. All rights reserved.
NA
Material Safety Data Sheets (MSDS) are available by emailing us or contacting your sales representative. Always consult the appropriate MSDS before using any of our products.
2016
North America Solvay Novecare—504 Carnegie Center Drive, Princeton, NJ 08540—USA Phone: +1-800-973-7873—Fax: +1-609-860-0463—
[email protected]
SOLVAY NOVECARE — DiLeo Graphic Design,
[email protected]
>S olvay Novecare has achieved world—wide ISO—9001 Quality Management System Multi—Site Certification. (2008)
Surfactants and Specialty Monomers
Contents FORMULATED EMULSIFIERS.................................................................................... Page 2 SULFATES ................................................................................................................ Page 6 PHOSPHATE ESTERS................................................................................................ Page 8 SULFONATES............................................................................................................ Page 10 NONIONICS (APE FREE)............................................................................................ Page 12 NONIONICS................................................................................................................ Page 14 SPECIALTY MONOMERS............................................................................................ Page 16 DEFOAMERS ............................................................................................................. Page 20
Solvay Novecare Emulsion Polymerization Working with Solvay
Solvay Novecare is the leading global supplier of emulsifiers, specialty monomers and specialty additives to the Emulsion Polymerization Industry.
wE xtensive portfolio of products
For more than 40 years, we have been committed to providing leading edge solutions to this industry. Our portfolio has evolved into the most comprehensive range of products addressing formulation challenges and more importantly enabling customers to create tomorrow’s performance requirements today.
wS urfactants & Specialty monomers dedicated to Emulsion Polymers manufacturing
Solvay Novecare supports customers with a broad range of sustainable solutions and services including products optimized around criteria such as biodegradability, eco-toxicity, VOC content, and percentage of renewable materials.
w Over 40 years as major supplier to the Emulsion Polymer industry
Our APE-free surfactant portfolio covers all chemistries from nonionics (RHODASURF®), to anionics like alkyl sulfonates (RHODACAL®), alkyl ether sulfates (RHODAPEX®), sulfosuccinates (GEROPON®), phosphate esters (RHODAFAC®) and formulated blends (ABEX®).
wG lobal player with local technical teams to support your developments
Solvay Novecare’s dedicated specialty monomer portfolio (SIPOMER®) brings functionality and boosts binder performance to higher levels. Whether seeking to improve substrate wetting, adhesion to different substrates, emulsion stability or simply demand higher film performance, such as high scrub, stain or water resistance, Solvay has the solution.
Note: These products are produced at worldwide locations through the Novecare division of Solvay.
Solvay Novecare Emulsion Polymerization / 1
Formulated Emulsifiers
Description
APE/ APE-Free
Physical Form
Solids Content (%)
Critical Micelle Concentration (%)
ABEX® 18-S
Proprietary
APE-Free
Liquid
35
0.03
48
®
ABEX 23-S
Proprietary
APE-Free
Liquid
60
0.10
40
®
ABEX 26-S
Proprietary
APE
Liquid
33
0.02
55
ABEX 33-S
Proprietary
APE
Liquid
30
0.12
37
ABEX JKB
Proprietary
APE-Free
Liquid
30
0.13
40
ABEX® VA-50
Proprietary
APE
Liquid
46
0.17
44
ABEX® 2005
Proprietary
APE-Free
Liquid
30
—
—
ABEX® 2020
Proprietary
APE-Free
Liquid
30
0.01
41
®
ABEX 2115-A
Proprietary
APE-Free
Liquid
33
—
—
ABEX 8018
Proprietary
APE-Free
Liquid
31
0.05
37
ABEX® EP-100
Ammonium salt of Sulfated Nonylphenol Ethoxylate; 4 Moles EO
APE
Liquid
30
0.03
33
ABEX® EP-110
Ammonium salt of Sulfated Nonylphenol Ethoxylate; 9 Moles EO
APE
Liquid
30
0.01
37
ABEX® EP-120
Ammonium salt of Sulfated Nonylphenol Ethoxylate; 30 Moles EO
APE
Liquid
30
0.05
42
ABEX® EP-120 NA
Sodium Salt of Sulfated Nonylphenol ethoxylate
APE
Liquid
35
ND
ND
Product
Surface Tension at CMC (dynes/CM)
Formulated Anionics
® ®
®
Formulated Anionics
2 /Surfactants and Specialties
175.300
175.320
176.170
176.180
176.200
176.210
178.3400
181.30
US (TSCA)
Canada (DSL)
Europe (EINECS)
Australia (AICS)
South Korea (KECL)
Japan (MIT)
International Inventory Status
175.105
FDA Status
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—
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—
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—
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—
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—
L
—
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—
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—
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—
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—
—
—
—
—
—
—
—
—
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●
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●
●
●
FDA Listing Status Codes ● Listed with no specific limits
E Extraction L Listed with limitation limitations
International Inventory Status Codes R Referenced with no limitations
RL Referenced with limitations
● Listed
— Not Listed
Formulated Emulsifiers / 3
Formulated Emulsifiers Critical Micelle Concentration (%)
Surface Tension at CMC (dynes/CM)
Description
APE/ APE-Free
HLB
Physical Form
Solids Content (%)
ABEX® 2515
Proprietary
APE-Free
16.3
Liquid
50
0.03
38
®
ABEX 2525/40
Proprietary
APE-Free
17.4
Liquid
40
0.08
44
ABEX® 2535
Proprietary
APE-Free
18.0
Liquid
50
0.09
45
ABEX® 2545
Proprietary
APE-Free
18.3
Liquid
50
0.12
46
Product Nonionics
4 /Surfactants and Specialties
175.300
175.320
176.170
176.180
176.200
176.210
178.3400
181.30
US (TSCA)
Canada (DSL)
Europe (EINECS)
Australia (AICS)
South Korea (KECL)
Japan (MIT)
International Inventory Status
175.105
FDA Status
●
—
—
●
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—
—
—
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R
—
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—
●
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—
●
●
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●
FDA Listing Status Codes ● Listed with no specific limits
E Extraction L Listed with limitation limitations
International Inventory Status Codes R Referenced with no limitations
RL Referenced with limitations
● Listed
— Not Listed
Formulated Emulsifiers / 5
Sulfates
Critical Micelle Concentration (%)
Surface Tension at CMC (dynes/CM)
Description
Ionic Charge
Physical Form
Solids Content (%)
RHODAPON® UB STD
Sodium Lauryl Sulfate
Anionic
Liquid
30
0.06
29
RHODAPON® L-22EP
Ammonium Lauryl Sulfate
Anionic
Liquid
28
0.06
33
Sodium Lauryl Sulfate
Anionic
Liquid
30
0.06
29
RHODAPEX EST-30*
Sodium Tridecyl Ether Sulfate; 3 Moles EO
Anionic
Liquid
30
0.08
33
RHODAPEX® LA-40S
Sodium Salt of Sulfated Linear Alcohol Ethoxylate; 4 Moles EO
Anionic
Liquid
31
0.02
32
RHODAPEX® LA-120S
Sodium Salt of sulfated linear Alcohol Ethoxylate, 12 Moles EO
Anionic
Liquid
30
0.02
34
RHODAPEX® LA-300S
Sodium Salt of sulfated linear alcohol ethoxylate, 30 Moles EO
Anionic
Liquid
30
0.03
44
RHODAPEX® AB-20**
Ammonium Salt of Sulfated Alcohol Ethoxylate; 9 Moles EO
Anionic
Liquid
29
0.03
33
RHODAPEX® OPS-253
Sulfate of Alkyl Phenol Ethoxylate Sodium Salt
Anionic
Liquid
36
0.09
36
RHODAPEX® CO-436
Ammonium Salt of Sulfated Alkylphenol Ethoxylate; 4 Moles EO
Anionic
Liquid
58
0.03
33
Product ALKYL SULFATES
RHODAPON LX-28 AEP ®
ETHER SULFATES
* North America Only, **Europe- Asia
6 /Surfactants and Specialties
175.300
175.320
176.170
176.180
176.200
176.210
178.3400
US (TSCA)
Canada (DSL)
Europe (EINECS)
Australia (AICS)
South Korea (KECL)
Japan (MIT)
New Zeland
Philippines
International Inventory Status
175.105
FDA Status
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FDA Listing Status Codes ● Listed with no specific limits
E Extraction L Listed with limitation limitations
International Inventory Status Codes R Referenced with no limitations
RL Referenced with limitations
● Listed
— Not Listed
Sulfates / 7
Phosphate Esters
Product
Description
Ionic Charge
Physical Form
Solids Content (%)
Critical Micelle Concentration (%)
Surface Tension at CMC (dynes/CM)
PHOSPHATE ESTERS RHODAFAC® RS-410
Aliphatic Phosphate Ester; 3 Moles EO
Anionic
Liquid
100
0.002
—
RHODAFAC® RS-610
Aliphatic Phosphate Ester; 6 Moles EO
Anionic
Liquid
100
0.002
—
Aliphatic Phosphate Ester; 6 Moles EO; Ammonium Salt Solution
Anionic
Liquid
25
0.01
30
RHODAFAC® RS-710
Aliphatic Phosphate Ester; 10 Moles EO
Anionic
Liquid
100
0.002
36
RHODAFAC® RS-710 D
Aliphatic Phosphate Ester; 10 Moles EO
Anionic
Liquid
30
0.002
36
RHODAFAC® RS-960
Aliphatic Phosphate Ester; 50 Moles EO
Anionic
Liquid
80
—
—
RHODAFAC® RE-410
Aromatic Phosphate Ester; 3 EO
Anionic
Liquid
100
—
—
RHODAFAC® RE-610
Aromatic Phosphate Ester; 9 Moles EO
Anionic
Liquid
100
0.01
37
RHODAFAC® RK-500 A
Aliphatic Phosphate Ester; 3.5 Moles EO
Anionic
Liquid
74
—
—
RHODAFAC® RS-610A-25
8 /Surfactants and Specialties
175.300
175.320
176.170
176.180
176.200
176.210
178.3400
US (TSCA)
Canada (DSL)
Europe (EINECS)
Australia (AICS)
South Korea (KECL)
Japan (MIT)
International Inventory Status
175.105
FDA Status
—
—
—
—
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—
—
FDA Listing Status Codes ● Listed with no specific limits
E Extraction L Listed with limitation limitations
International Inventory Status Codes R Referenced with no limitations
RL Referenced with limitations
● Listed
— Not Listed
Phosphates Esters / 9
Sulfonates
Ionic Charge
Physical Form
Solids Content (%)
Critical Micelle Concentration (%)
Sodium Alpha Olefin Sulfonate
Anionic
Liquid
40
0.07
29
RHODACAL® 330
Isopropyl Amine Dodecyl Benzene Sulfonate
Anionic
Liquid
90
0.1
32
RHODACAL® DS-10
Sodium Dodecyl Benzene Sulfonate
Anionic
Flake
98
0.1
32
RHODACAL® DS-4
Sodium Dodecyl Benzene Sulfonate
Anionic
Liquid
23
0.1
32
RHODACAL® DSB
Disodium Alkyl Diphenyloxide Sulfonate
Anionic
Liquid
45
0.08
32
RHODACAL® LDS-22
Sodium Dodecyl (linear) Benzene Sulfonate
Anionic
Liquid
23
0.1
32
GEROPON® SS-OIP
Disodium Salt of Monoalkyl Ether Sulfosuccinate
Anionic
Liquid
40
0.1
30
GEROPON® ACR-4
Disodium Sort 4 Monoalkyl ether Sulfosuccinate
Anionic
Liquid
31
0.01
29
Aqueous Dioctyl Sodium sulfosuccinate
Anionic
Liquid
75
0.35
27
Product
Description
Surface Tension at CMC (dynes/CM)
SULFONATES RHODACAL® A-246/L
SULFOSUCCINATES
Geropon® 99
10 /Surfactants and Specialties
175.300
175.320
176.170
176.180
176.200
176.210
178.3400
US (TSCA)
Canada (DSL)
Europe (EINECS)
Australia (AICS)
South Korea (KECL)
Japan (MIT)
International Inventory Status
175.105
FDA Status
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FDA Listing Status Codes ● Listed with no specific limits
E Extraction L Listed with limitation limitations
International Inventory Status Codes R Referenced with no limitations
RL Referenced with limitations
● Listed
— Not Listed
Sulfonates / 11
Nonionics (APE Free) Critical Surface Micelle Tension Concentration at CMC (%) (dynes/CM)
Description
Moles of Ethylene Oxide
Physical Form
Solids Content (%)
RHODASURF® BC-420
TDA Ethoxylate
3
Liquid
100
—
RHODASURF® BC-610
TDA Ethoxylate
6
Liquid
100
—
—
11.4
RHODASURF® BC-720
TDA Ethoxylate
9-10
Paste
100
—
—
13.8
RHODASURF® BC-729
TDA Ethoxylate
9-10
Liquid
90
—
—
13.8
RHODASURF BC-840
TDA Ethoxylate
15
Paste
100
—
—
15.4
RHODASURF TLA 3040
TDA Ethoxylate
30
Liquid
40
0.08
44
17.4
RHODASURF TLA 4050
TDA Ethoxylate
40
Liquid
50
0.09
45
18
RHODASURF TLA 5050
TDA Ethoxylate
50
Liquid
50
0.12
46
18.3
RHODASURF® TR 4070*
TDA Ethoxylate
40
Liquid
70
—
—
—
RHODASURF® L-4
LA Ethoxylate
4
Liquid
100
—
—
9.7
RHODASURF® LA-9/85
LA Ethoxylate
9
Liquid
85
—
13.1
RHODASURF LA-12/80
LA Ethoxylate
12
Liquid
80
—
14.4
RHODASURF ON-870
OA Ethoxylate
20
Solid
100
0.015
37
15.4
RHODASURF ON-877
OA Ethoxylate
20
Liquid
70
Proprietary
—
Liquid
65
0.08
41
17
RHODASURF® L-7/90
LA Ethoxylate
7
Liquid
90
—
30
12.5
RHODASURF® S25 28
TSP Ethoxylate
25
Liquid
28
—
ANTAROX® L-61
EO/PO
—
Flakes
100
—
Insoluble
3.0
ANTAROX® L-62
EO/PO
Liquid
100
—
Soluble
7.0
ANTAROX® L-64
EO/PO
Liquid
100
—
43.2
15.0
Product
HLB
ALIPHATIC ALCOHOL ETHOXYLATES
® ®
® ®
® ® ®
RHODASURF 6530 ®
8
14.5
BLOCK CO-POLYMERS
*Europe- Asia
12 /Surfactants and Specialties
—
176.170
176.180
176.200
176.210
178.3400
181.30
US (TSCA)
Canada (DSL)
Europe (EINECS)
Australia (AICS)
South Korea (KECL)
Japan (MIT)
International Inventory Status
175.105
FDA Status
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FDA Listing Status Codes ● Listed with no specific limits
E Extraction L Listed with limitation limitations
International Inventory Status Codes R Referenced with no limitations
RL Referenced with limitations
● Listed
— Not Listed
Nonionics (APE Free) / 13
Nonionics
Product
Description
Moles of Ethylene Oxide
Ionic Charge
Physical Form
Solids Content (%)
Critical Micelle Concentration (%)
Surface Tension at CMC (dynes/ CM)
HLB
ALKYLPHENOL ETHOXYLATES IGEPAL® CA-210
Octylphenol Ethoxylate
1.5
Nonionic
Liquid
100
—
Insoluble
4.8
IGEPAL® CA-630
Octylphenol Ethoxylate
9
Nonionic
Liquid
100
0.005
31
13
IGEPAL® CA-877
Octylphenol Ethoxylate
23
Nonionic
Liquid
70
—
—
16.6
IGEPAL® CA-887
Octylphenol Ethoxylate
30
Nonionic
Liquid
70
0.03
38
17.4
IGEPAL® CA-897
Octylphenol Ethoxylate
40
Nonionic
Liquid
70
0.04
44
18
IGEPAL® CA-407
Octylphenol Ethoxylate
40
Nonionic
Liquid
70
0.04
44
18
IGEPAL® CO-210
Nonylphenol Ethoxylate
1.5
Nonionic
Liquid
100
-
IGEPAL®CO-430
Nonylphenol Ethoxylate
4
Nonionic
Liquid
100
-
IGEPAL® CO-530
Nonylphenol Ethoxylate
6
Nonionic
Liquid
100
0.03
32
10.8
IGEPAL® CO-630
Nonylphenol Ethoxylate
9
Nonionic
Liquid
100
0.005
32
13
IGEPAL® CO-720
Nonylphenol Ethoxylate
12
Nonionic
Liquid
100
0.007
36
14.2
IGEPAL® CO-730
Nonylphenol Ethoxylate
15
Nonionic
Liquid
100
0.008
39
15.0
IGEPAL® CO-858
Nonylphenol Ethoxylate
20
Nonionic
Liquid
80
0.01
41
16.0
IGEPAL® CO-887
Nonylphenol Ethoxylate
30
Nonionic
Liquid
70
0.02
45
17.2
IGEPAL® CO-897
Nonylphenol Ethoxylate
40
Nonionic
Liquid
70
0.04
44
17.8
IGEPAL® CO-977
Nonylphenol Ethoxylate
50
Nonionic
Paste
70
0.05
44
18.2
IGEPAL® CO-987
Nonylphenol Ethoxylate
70
Nonionic
Paste
70
0.05
48
18.6
IGEPAL® DM-430
Dinonylphenol Ethoxylate
7
Nonionic
Liquid
100
—
—
9.5
14 /Surfactants and Specialties
175.300
175.320
176.170
176.180
176.200
176.210
178.3400
US (TSCA)
Canada (DSL)
Europe (EINECS)
Australia (AICS)
South Korea (KECL)
Japan (MIT)
International Inventory Status
175.105
FDA Status
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FDA Listing Status Codes ● Listed with no specific limits
E Extraction L Listed with R Referenced limitation limitations with no limitations
RL Referenced with limitations
● Listed
— Not Listed
APE Nonionics / 15
Specialty Monomers
% of Solid
Tg (°C)
% Water
Inhibitor ppm
Specific gravity
SIPOMER® PAM-100
100
-18
Water soluble
> Solventborne (Polyacrylate Polyols…)
UV/EB Cure
UV/EB cure
n Best
n Possible
6 / Specialty Monomers
n Not suitable
The acrylic functionality of SIPOMER® PAM-300 provides a higher reactivity in radiation cure application
Water Soluble
Water Soluble
Thanks to their superior MAP/DAP ratio, SIPOMER® PAM-100 and SIPOMER® PAM-200 are easily incorporated into polyurethane systems with minimum impact on viscosity. SIPOMER® PAM 200 can be used in polyurethane waterborne systems where it provides improved adhesion with system and stabilization features.
Example: Car Refinish: More cars coated with fewer problems Direct-to-metal substrates represent a significant field for innovation yielding process simplification and environmentally friendly solutions such as: w Direct-to-metal priming that consolidates a complex process into one step w Shift from solventborne to waterborne resin systems Standard primers for car refinishing are based on 2K polyurethane solventborne resin systems. Either SIPOMER® PAM-100 or SIPOMER® PAM-200, based on the formulation and technology used, will be effective in improving metal adhesion of such systems.
Adhesion Data in 2K Polyurethane Solventborne Systems SIPOMER® PAM-200 can significantly improve the dry and wet adhesion on both aluminum and cold-rolled steel. SIPOMER® PAM is used to make acrylic polyols. ALUMINUM IMMERSION HOURS
DRY
2
4
Control
1B
0B
0B
1% PAM
3-4B
0B
0B
4% PAM
5B
0B
0B
Adhesion is evaluated according to ASTM D3359 test: OB poor adhesion - 5B perfect adhesion.
COLD-ROLLED STEEL IMMERSION HOURS
DRY
2
4
8
24
48
Control
5B
4-5B
2B
0B
0B
0B
1% PAM
5B
2B
2B
1B
0B
0B
4% PAM
5B
5B
5B
5B
4-5B
4-5B
SIPOMER® PAM / 7
SIPOMER® PAM “Adhesion and Much More” Automotive Refinish: Direct-to-Metal (DTM) Benefits
Ready-to-apply top coat with DTM primer in 30 minutes instead of 12 hours with standard systems
Coating Cost ($) 100%
Clear coat
100%
92%
Clear coat
Top coat
Top coat
Primer
75%
Pre-treatment
Treating Primer
50%
Metal
Metal
25% 0
Standard System
Standard System
Direct to Metal
Example: Coil Coating: Improved efficiency and environmentally friendly
Coil coating is a continuous and highly automated process whereas the metal coil is unwound and both the top and bottom sides are cleaned, chemically treated, primed, oven cured, top coated, oven cured again, and rewound for shipment. Thanks to this process, large coils can be coated at high speed before fabrication. Resins incorporating SIPOMER® PAMs will boost primer adhesion and anti-corrosion properties eliminating the need for pre-treatment step(s) translating into less waste, energy & process time.
Direct to Metal
Benefits : w Process savings: one step vs. two steps w Eliminate waste treatment and reporting/regulation requirements Linked to the use of heavy metals such as chrome and phosphorous.
Coil-Coating Cost ($) 100%
Top coat Top coat
Primer
100%
89%
Standard
Removal of Pre-treatment
75%
Pre-treatment
Treating Primer
50%
Metal
Metal
25% 0
Standard System
8 / Specialty Monomers
Removal of Pre-treatment
Example: Maintenance Coatings: An environmental solution that works!
Organic coatings play an important role in corrosion protection. One of the key challenges to convert solventborne systems to more sustainable, water-based formulation resides in significant loss in adhesion and anticorrosion performances. Thanks to it’s excellence in metal adhesion, SIPOMER® PAM-200 boosts the performance of acrylic waterborne resins enabling matching performance versus solventborne anticorrosion coatings, allowing low VOC coatings formulations and consumers who are demanding new products that meet or exceed the requirements for lower VOC coatings. Good Adhesion Results SIPOMER® PAM-200 was used to modify a waterborne styrene/acrylic resin. An anticorrosion paint was formulated and tested for adhesion and corrosion-resistance properties. Compared with a control paint formulated without SIPOMER® PAM-200, the results are below: PAINT-BASED ON S/A LATEX WITH 1%
PAINT-BASED ON S/A CONTROL LATEX
CROSSHATCH RESULTS AFTER WATER IMMERSION
CROSSHATCH RESULTS AFTER WATER IMMERSION
24 hrs
520 hrs
24 hrs
520 hrs
> Cold-rolled steel
5B
5B
4B
2B
> Iron phosphate steel
5B
5B
1B
1B
> Zinc phosphate steel
3B
3B
0B
0B
S/A: Styrene/Acrylic
Adhesion is evaluated according to ASTM D3359 test: 0B poor adhesion – 5B perfect adhesion. Adhesion is evaluated after 24 hours and after 520 hours of immersion in water.
Good Anti-Corrosion Results
SIPOMER® PAM / 9
SIPOMER® PAM “Adhesion and Much More” Special-Purpose Coatings: Improved performance and efficiency
This segment includes coatings for various metal substrates mainly applied by Original Equipment Manufacturers. This market ranges from coatings for large vehicles, such as trucks, farm tractors and cranes to house appliances. Different technologies compete in this market with the objective of a single, multipurpose coating applied directly to metal. The result is elimination of pre-treatment and fewer steps in the process! Either SIPOMER® PAM-100 or SIPOMER® PAM-200, based on the formulation and technology used, can boost acrylic resin performances in terms of adhesion and corrosion resistance and offer a viable solution for directto-metal applications.
84%
Standard System
Single coat Direct to Metal
100%
Top coat Single coat Direct to Metal
Primer Pre-treatment
Metal
Metal
Coating Cost ($)
100%
75% 50% 25% 0
Standard System
Single coat Direct to Metal
Good results without pre-treated substrate SIPOMER® PAM-100 was used to modify a waterborne styrene/acrylic resin. The resin was formulated in a clearcoat and tested for adhesion on untreated, coldrolled steel. Wet adhesion was evaluated under different test conditions: w Water-spots test w Immersion test w After 24 hours recovery Control 2%
PAM-100
4-hour spot test
0B (0%)
4B (95%)
4-hour immersion test
0B (0%)
3B (92%)
24-hour recovery test
0B (0%)
5B (100%)
Anticorrosion is evaluated according to ASTM D3359 OB: poor adhesion 5B: perfect adhesion
10 / Specialty Monomers
Conclusions SIPOMER® PAM-100 and SIPOMER® PAM-200 specialty monomers enable process simplification and cost savings for the industrial coatings market. Whether your application is automotive refinishing, coil coatings,maintenance or special purpose coatings, the benefits of using the SIPOMER® PAMs include: w Elimination of costly metal pre-treatment step w Reduction of layers in the coating system w Cost saving of labor required for the coating application w A shift from heavy metals-based conversion coatings to organic w A shift from solventborne to waterborne systems
SIPOMER® PAM-4000 – Metal Adhesion Promoter
BLANK SIPOMER PAM 4000 ®
Monomer Ratio (BOTM) MMA
51.5
BA
46.5
MAA
1
SIPOMER PAM-4000
®
Cross-hatched Tape Adhesion Test - Cold Steel
1
Surfactant Charge (BOTM) Rhodapex RS-610 A25
0.5 in Kettle 1.0 in Pre-emulsion
Initiator System: Thermal, Ammonium Persulfate Seed: 20% Initiator Solution / 4% Pre-Emulsion Particle Size : 126 nm Latex Stability : Freeze/Thaw Stability - 5+ cycles Heat Stability (60C) - 30+ days
SIPOMER® PAM / 11
SIPOMER® PAM “Adhesion and Much More” High Scrub for high PVC binders in Architectural coatings with SIPOMER® PAM-5000
Number of cycles DIN scrub resistance at 85 % PVC
Latex Property Results Benchmark
SIPOMER® PAM 5000
119
126
50.30%
50.10%
92
22
Clean
Clean
Viscosity @ 20 rpms (mPa)
548
494
Viscosity @ 50 rpms (mPa)
386
252
Particle size (nm) Solids content (%) Grit / 120mesh (ppm) Coagulum
Matte Paint Application Data Scrub Resistance Results (PVC = 82) Scrub Resistance Measurement ISO test first serial (µ) DIN scrub resistance (cycles)
Benchmark
1 % SIPOMER® PAM 5000
36
17
1050
4000
Improve Scrub Resistance in High PVC Paints
High PVC Vinyl VeoVA paint formulation Ingredients
Initial Reactor Charge
Demineralised water Rhodafac® RS 710-E (10%aq. Sol. At pH 7-8) Potassium persulphate
399 25
393 45
Pre-emulsion
Demineralised water Rhodafac® RS 710-E (10%aq. Sol. At pH 7-8) Sodium bicarbonate Vinyl VeoVA* 2-Ethylhexyl acrylate SIPOMER® COPS-1 (40% aq. Sol.) Acrylic acid Vinyl acetate SIPOMER® PAM 5000 (30% aq. Sol. At pH 5) Silquest A 171
SIPOMER® PAM-5000 – Styrene/Acrylic Starting Point Recipe Monomer Ratio (BOTM) Styrene
49.5
BA
47.5
AA
2
SIPOMER PAM-5000 ®
1.0 (in Kettle Charge)
Surfactant Charge (BOTM)
Parts per weigh
3 200 70 9.4 1.5 730 33.2 2.5
Demineralised water Potassium persulphate
120 1
Line one
Demineralised water Ter-butyl hydroperoxyde (70% aq. Sol.)
20 1.4
Seed: 20% Initiator Solution / 4% Pre-Emulsion
Line two
Particle Size: 120 nm
Demineralised water Bruggolite FF6M
20 1.2
Neutralisation
AMP 95 until pH of 8-8.5
8.3
Latex Stability: 5 cycles of Freeze/Thaw Stability
Biocide
Parmetol K40
Rhodapex® LA-40S
0.1 in Kettle Charge 0.9 in Pre-emulsion
Rhodafac® RS-610A25
1.0 in Pre-emulsion
Initiator System: Thermal, Ammonium Persulfate
12 / Specialty Monomers
Initiator solution
1
Other
2
General Guidance for use of SIPOMER® PAM Monomers
> Storage –Feedings tanks
> High reactivity
DO
DON’T
Do use stainless steel or plastic containers to store solutions of SIPOMER® PAM.
Don’t use iron containers that can be corroded by acidic SIPOMER® PAM releasing metal ions that could trigger the polymerization.
Do follow the order of introduction of our starting recipes. Put SIPOMER® PAM in the kettle when the reaction temperature is met. Do feed separately or in the monomer mixture/pre-emulsion.
Don’t introduce SIPOMER® PAM in the initial charge before heating. Don’t mix with the solution of the initiator. This would rapidly polymerize even without heating.
Do neutralize the polymer before heating at elevated temperature ( > 140° C). > Heat stability of polymer
> Hydrolytic stability
> Corrosion
Copolymers are more stable and can be handled above 200° C. This is strongly dependent on the nature of the polymer and must be checked case by case.
Don’t heat acidic homopolymers to temperatures above 140° C.
Do keep between pH = 5 and pH = 9 for long time storage or when using at temperatures above 60° C.
Don’t use diluted SIPOMER® PAM very acidic (pH < 3) or basic (pH > 10) conditions. This would hydrolyze the ester linkage and the phosphate group.
Do neutralize with a non volatile base and add corrosion inhibitor. Keep the coating at pH > 9 for good anticorrosion properties.
Don’t use SIPOMER® PAM in acidic form when post neutralization is not possible.
SIPOMER® PAM / 13
SIPOMER® Polymerizable Stabilizer Key Features w Improve mechanical stability w Improve thermal stability w Improve salt stability w Decrease need in surfactant w Reduce foaming & water sensitivity
Stabilizers Covalent Bound
Reactive Group Nature of Extender SIPOMER® COPS SIPOMER® AAE10 SIPOMER® AES-100
« Head » group
Allyl ether
Hydrophobic
Sodium Sulfonate
Allyl ether
Hydrophilic
Ethoxylate
Allyl ether
Hydrophilic
Ammonium Sulfate
SIPOMER® COPS-1 is a 40% aqueous solution of sodium 1-allyloxy-2-hydroylpropyl sulfonate:
CH2 = CH - CH2 - O - CH2 - CH(OH) - CH2 - SO3Na Even at levels as low as 0.5 - 1.0% (based on total monomer), SIPOMER® COPS-1 provides latex stability, such as shelf life, freeze/thaw and mechanical and chemical stability. It also provides block resistance for the final polymer. With SIPOMER® COPS-1, the levels of conventional can be reduced significantly. Surfactants are key component in providing stability to latex. However their migration to the interface causes water sensitivity to the dry polymer film. SIPOMER® COPS-1 reacts with other reacts with other comonomers through the chemical (covalent) bond. The sulfonate group will remain at the surface of the particle providing very good stability to the latex. Since the functionality is anchored to the polymer backbone, it will not migrate after film formation and thus cannot modify interfacial properties. As a result of the reduction of conventional surfactant, the foaming tendency of the latex and the water sensitivity of the polymer film are both reduced.
14 / Specialty Monomers
Applications w Use 0.5 Wt% based on total monomer (BOTM) w All acrylic, styrene acrylic, vinyl acrylic, vinyl VeoVA
SIPOMER® COPS-1 Polymerizable Stabilizer Reactivity Ratio Data for SIPOMER® COPS-1 (M1)
The reactivity ratio data show that the r1 values for SIPOMER® COPS-1 are close to 0, suggesting that homopolymerization of this monomer is unlikely. There is no need for adding an inhibitor to this monomer. As shown on the Mayo representation below, the most favorable reactivity ratios were found for SIPOMER® COPS-1 with vinyl acetate and VeoVA 10. However, SIPOMER® COPS-1 can also work very effectively in acrylic and styrene/acrylic systems. Mayo Curves for SIPOMER® COPS-1
SIPOMER® Polymerizable Stabilizer / 15
SIPOMER® COPS-1 Polymerizable Stabilizer Addition of SIPOMER® COPS-1 SIPOMER® COPS-1 improves Freeze/Thaw Stability Latexes
Acrylic control
Acrylic with COPS-1
Styrene/acrylic control
Styrene/acrylic with COPS-1
Surfactant % BOTM
Rhodacal® DS4 1
Rhodacal® DS4 1
Rhodapex® LA40S 1.5
Rhodapex® LA40S 1.5
SIPOMER® COPS-1 % BOTM
0
0.5
0
0.5
Particle size (nm) Solids (%)
17.9 49.8
186 49.9
175 51.1
149 51.1
Freeze thaw cycles
0
5
0
5
Rhodacal DS4: Sodium dodecylbenzene sulfonate (23%) Rhodapex LA40S: Sodium dodecyl ether sulfate; 4 EO (32%) Freeze/thaw test Procedure: Latex was placed in -15C conditions for 12 hours and thawed back to RT for 8 hours. Cycles were repeated 5 times.
SIPOMER® COPS-1 improves mechanical stability Latexes
Acrylic control
Acrylic with SIPOMER® COPS-1
Surfactant % BOTM
Rhodacal® DS4 1
Rhodacal® DS4 1
SIPOMER® COPS-1 % BOTM
0
0.5
Particle size (nm) Solids (%)
179 49.8
186 49.9
Waring blender 5 minutes at 20,000 rpm
Failed
Passed
Mechanical test procedure: Pour 200 mL of latex into a Waring blender. Mix latex at 20,000 rpm under high shear for 5 minutes. If the latex does not completely coagulate after 5 minutes of mixing, it “passes.” If it coagulates within 5 minutes of mixing, it fails.
16 / Specialty Monomers
SIPOMER® COPS-1 improves chemical stability Latexes
Acrylic Control 1
Acrylic Control 2
Acrylic with SIPOMER® COPS-1
Acrylic with nonionic surfactant
Anionic surfactant Rhodapex® LA40S (%BOTM)
1.0
1.5
1.0
1.5
Nonionic surfactant (% BOTM)
0
0
0
1.0
SIPOMER® COPS-1 (% BOTM)
0
0
0.5
0
% CaCl2 added to latex for immediate coagulation
3
6
5
5
Substitution of surfactant by SIPOMER® COPS-1 in a latex formulation Latexes
Acrylic control
Acrylic with SIPOMER® COPS-1
Surfactant % BOTM
Rhodacal® DS4 1.0
Rhodacal® DS4 0.5
SIPOMER® COPS-1 Particle size (nm)
0 179
0.5 196
Solids (%) Wet coagulum (% BOTL)
49.8 0.7
50.6 0.7
Freeze/Thaw cycles Mechanical stability
1 Passed
5 Passed
Foaming height (mL)
200
120
Latex Chemical Stability: The ability of latex to resist coagulation in the presence of salts. (Salt used is Calcium chloride) Procedure: Add CaCl2 at different levels to the latex until immediate coagulation is observed. The data above should be read as follows: CaCl2 was added (in term of weight % compared to total latex -% BOTL): «3%» means that the system was stable at 2% of CaCl2 «6%» means that the system was stable at 5% of CaCl2 Comments: By adding COPS-1, the chemical stability results are improved. To have the same effect in terms of chemical stability, normally non ionic surfactant is used. COPS-1 improves chemical stability without increasing the amount of free surfactant.
Mechanical test procedure: Pour 200 mL of latex into a Waring blender. Mix latex at 20,000 rpm under high shear for 5 minutes. If the latex does not completely coagulate after 5 minutes of mixing, it “passes.” If it coagulates within 5 minutes of mixing, it fails.
SIPOMER® Polymerizable Stabilizer / 17
SIPOMER® COPS-3 Polymerizable Stabilizer Features: w Good pigment binding power w High PVC paints system w Anti-corrosion properties w Improved color acceptance w Good stain and block resistance w Improve adhesion to different inorganic substrate w Applicable to most of monomers systems: SA, FA, VA, VeoVA, etc.
SIPOMER® COPS-3 Product Specifications Appearance
Transparent liquid
Active content
39.0-42.0
Color APHA
200 Max
pH (10% aqueous solution)
6.0 - 9.0
Ionic type
Anionic
Improve Water-Resistance & Corrosion Inhibition 50wt% SA latex: 1% of Rhodapex® LA 40S; 0.5% of BOTM COPS-3 Without COPS-3
With COPS-3
Without COPS-3
• Glass substrate: 100 um film • Soaking into water for 24 hrs
• Substrate: Iron phosphate panel Curing @ room temperature, 60-70% RH
COPS-3 in Vinyl VeoVA System w5 5% Vinyl VeoVA System: VAM/VeoVA-10:70:30 w1 % BOTM of COPS-3 w0 .3% BOTM of RS610-A25 & 2% BOTM of Rhodasurf® 6530
Particle size (nm)
Commercial SA
Without COPS-3
COPS-3
~150
262.2
238.7
405
1168
75 PVC paints Scrub resistance *Only available in China
18 / Specialty Monomers
550
With COPS-3
SIPOMER® AES 100 Copolymerizable Stabilizer Key Benefits w Reduce Grit w Increase stability (mechanical, FT, chemical )
SIPOMER® AES-100 Latex MMA
52
BA
47
MAA
1
Particle Size: 150 nm
Surfactant Type
Rhodapex® LA40S
Amount in Kettle:
0.10%
Amount in Feed:
0.90%
Amount of AES-100
0%
Way of Addition of AES-100
In situ-seeded pre-emulsion
1%
1%
Feed
Kettle
Dry Grit
130 ppm
10 ppm
70 ppm
Mechanical Stability
3'
9'
9'
F/T stability
0
>5
>5
Calcium Stability
2%
5%
6%
Dry Grit: Filtration on 100 micron net Mechanical Stability: Waring Blender 22.000 rpm ( time to coagulation ) Calcium Stability: CaCl2*2H2O/Dry latex ratio ( concentration to coagulate a 30 % diluted latex )
SIPOMER® Polymerizable Stabilizer / 19
SIPOMER® WAM Wet Adhesion Monomers “The 1% that makes the difference” SIPOMER® WAM SIPOMER® WAM II SIPOMER® WAM E W50
Reactive Group
Binders
Allyl Ether
Both acrylic & vinyl copolymers
Methacrylamide
Acrylics
Methacrylate Ester
Acrylics
Superior wet-adhesion properties
SIPOMER® WAM was custom designed to combine the benefits of amine and ureido functionalities in a single monomer. The Table below shows the synergistic effects of this combination. SIPOMER® WAM is incorporated into all-acrylic and vinyl-acrylic polymer systems through its allylic functionality. It provides wet adhesion in two ways: wT he ureido ring promotes interaction with the substrate via its high polarity and hydrogen bonding. w The amine functionality provides an additional site for interaction with substrate and pigment. SIPOMER® WAM modifies the latex binder, enabling it to wet the pigment particles more effectively, due to reduced interfacial tension. Effects of Amine and Ureido Functionalities, Alone and In Combination
20 / Specialty Monomers
SIPOMER® WAM into the polymer backbone greatly improves wet-adhesion of both all-acrylic and vinyl-acrylic latex paint systems for both interior and exterior applications.
Lab tests demonstrate exceptional wet adhesion
Test after test has proven that all-acrylic and vinyl-acrylic polymers containing SIPOMER® WAM provide latex paints with the best and most cost-effective wet-adhesion properties available. In a Wet Pick Adhesion Test, latex with SIPOMER® WAM showed greater wet adhesion as indicated by the substantially smaller area of peeling. And in a Wet Adhesion Abrasion Test, the latex paint containing SIPOMER® WAM demonstrated outstanding wet-scrub performance. Results of Wet Pick Adhesion Test
Results of Abrasion Test
SIPOMER® WAM-based paints compared to commercial products As shown in the Table below, polymers containing SIPOMER® WAM were evaluated against commercial wet adhesion systems. Paints based on SIPOMER® WAM exhibited superior wet-adhesion properties as well as greater shelf stability and improved color stability. When effective use levels were measured, SIPOMER® WAM also proved to be the most cost-effective wet-adhesion promoting system available. Gardner Scrub Test Results with SIPOMER® WAM-Based Paints Versus Commercial Standards
Control
Control
SIPOMER® WAM / 21
SIPOMER® WAM II Wet Adhesion Monomer Innovative chemical structure
With SIPOMER WAM II, emulsion polymerization producers can formulate products with an easy-to-use wet-adhesion monomer which is effectively polymerized in both redox and thermal processes. ®
MAEEU The MAEEU advantage is its ability to easily copolymerize in all-acrylic, vinyl-acrylic and styreneacrylic latex systems.
SIPOMER® WAM II in Latex Blends
22 / Specialty Monomers
SIPOMER® WAM II provides enhanced wet-adhesion, wet-scrub resistance and solvent resistance in a wide range of latex systems. SIPOMER® WAM Il’s improved performance is the result of MAEEU (methacrylamidoethylethyleneurea), an advanced ureido-based adhesion promoting monomer.
Dramatically improved wet-scrub resistance Wet-Scrub Resistance Test
Similar results with SIPOMER® WAM II in semi-gloss paint
When all-acrylic latexes containing SIPOMER® WAM II were formulated into a semi-gloss paint at 23% PVC, improved wet-scrub resistance was demonstrated. The paint formulated without SIPOMER® WAM II began lifting from the substrate at 95 cycles. The paint formulated with SIPOMER® WAM II exhibited outstanding scrub resistance, completely covering the substrate after 2000 cycles.
SIPOMER® WAM II / 23
SIPOMER® WAM Ester Wet Adhesion Monomers SIPOMER® WAM E Technologies
w Wet adhesion monomers for emulsion polymerization • Based on N-(2-Methacryloyloxyethyl) ethylene urea chemistry • Typical usage levels between 0.5 and 2.0 BOTM w Primarily recommended for waterborne acrylic and styrene acrylic binder systems • Improve wet adhesion • Improve scrub resistance w Also used in polymerizations and co-polymerizations in bulk, suspension and solution with polymers for use in plastics, leather, paper and textile industries
SIPOMER® WAM Ester w SIPOMER® WAM E W50 50 % Active in Water
O O
N
NH
O w Methacrylate polymerizable group w Ureido ring functionality for wet adhesion w Choice of activity and diluents
Typical Properties Property Appearance
SIPOMER® WAM E W50 Yellowish Liquid
Gardner Color
5 max
Solids, %
48 – 52
Viscosity, cPs
50 max
Density at 25 ºC, g/mL MMA, %
24 / Specialty Monomers
1.00 – 1.20 2.0 max
Features: w Excellent wet adhesion improvement w Significant scrub resistance improvement w Readily incorporated into most polymer systems w Excellent binder conversion rate
Application Testing
w Evaluated SIPOMER® WAM E W 50 & WAM E MMA 50 products in all-acrylic latex binder system wP aint application test were conducted in a semi gloss all-acrylic paint system wT ested for wet adhesion, scrub, gloss, viscosity, stability and all other paint properties
SIPOMER® WAM Ester / 25
SIPOMER® WAM Ester Wet Adhesion Monomers All-Acrylic Emulsion Polymerization Formula Materials
BOTM
Monomers
Property Resin Solids
Target 50%
MMA*
52
Seed Particle Size
40 max
BA
46
Final Particle Size
130 nm
MAA
1
pH
9.0 – 9.5
Wet Adhesion Monomer**
1
Dried Coagulum, %
0.25 max
Surfactant – Rhodacal DS-4
1
Resin Viscosity, cPs
< 500
Kettle
0.15
Monomer Emulsion
1.25
Initiator System (2 % in water)
Thermal
Ammonium Persulfate 2% Monomer Emulsion
Seed 25 % Initiator Solution Temperature during Monomer Addition
80 ºC
Monomer Addition
3h
Post-Monomer Addition Temperature
85 ºC
Emulsion Polymerization Results Binder Property
No WAM Added
SIPOMER® WAM E W50
Seed Particle Size, nm
37
36
pH before neutralization
2.2
1.9
pH after neutralization
9.2
9.3
Solids, %
49.7
49.8
Conversion, %
100
100
Dried coagulum, %
0.05
0.03
Resin Viscosity, cPs
123
125
Resin Particle Size, nm
133
126
26 / Specialty Monomers
S/G Acrylic Paint Test Formula Materials
PARTS
GRIND
Property
Target
Gloss
45 - 55
Water
6.0
PVC
Propylene Glycol
2.0
KU Viscosity
95 - 97
Rhodoline® 111
1.0
ICI Viscosity
0.8 – 1.3
Rhodoline® 681F
0.2
Rhodoline® WA 100
0.2
Ti-Pure R-826
27.0
25
LETDOWN Latex
40.0
Rhodoline® 681F
0.1
Texanol
2.0
Acrysol RM-8W
0.5
Acrysol 2020 NPR
0.4
Water
20.6
Paint Test Results Property
Blank
SIPOMER® WAM E W50
Viscosity, ON, KU
95.4
96.3
Viscosity, ON, ICI
0.84
1.13
Gloss, 20/60/85 º
13.3/50.9/78.7
11.4/47.6/76.4
97.3
97.9
500
4752
100 %
497 %
Contrast Ratio Scrub Test* # cycles to breakthrough Wet Adhesion Test** * Scrub test results on vinyl scrub panel ** Wet adhesion Scrub Test ASTM D6900-10
SIPOMER® WAM Ester / 27
SIPOMER® Resin Modifiers “Improved peel strength”
SIPOMER® IBOA Radiation curing resins application w Improves toughness, chemical and abrasion resistance w Reactive Diluent w Radcure polymerizable
SIPOMER® ß-CEA Adhesives application w Lowers Tg w Improves adhesion
15
9
6
3
0
28 / Specialty Monomers
180° horizontal peel test
12 Peel strength (N/25mm)
SIPOMER® IBOMA Clear coat application w Improves toughness, chemical and abrasion resistance w Easily incorporated in resins (methacrylate)
100% Acrylic Pressure Sensitive Adhesive
0% B - CEA
0.5 % B-CEA
■ After 3 min, adhesion
6.0
8.5
■ After 1 hr. adhesion
10.0
13.0
SIPOMER® BEM – SIPOMER® SEM – SIPOMER® HPM series
Rheology
By combining its experience in specialty monomers and emulsion polymerization, Solvay extended the available range of specialty methacrylic esters monomer for HASE thickeners. SIPOMER® BEM SIPOMER® BEM delivers low shear efficiency.
PSEUDOPLASTIC
SIPOMER® HPM 400 SIPOMER® HPM 400 delivers low to mid shear efficiency. SIPOMER® HPM 400 allows to easily match cellulosic thickeners profiles. SIPOMER® HPM-100 SIPOMER® HPM 100 delivers mid shear efficiency. SIPOMER® SEM 25 SIPOMER® SEM 25 delivers mid to high shear efficiency. SIPOMER® HPM 200 SIPOMER® HPM 200 delivers high shear efficiency. SIPOMER® HPM 200 allows to easily match Newtonian thickeners profiles.
NEWTONIAN
Solvay SIPOMER® HPMs are 50 Wt% active specialty methacrylic monomers designed to easily access desired rheology profiles. Working with SIPOMER® HPMs provides choice in profile and significant cost saving versus “generic” HASE. Properties Solvay SIPOMER® HPMs were incorporated in standard HASE polymer recipes and benchmarked versus well known “generic” HASE at equal viscosity (95KU) in 30 Wt% solid latex (table 1) as well as at equal use level in flat paints (table 2). While the HPM 200 based thickener presents a very performant solution as Newtonian ICI builder, the HPM 100 based HASE combines KU building and improved ICI viscosity. Whereas cellulosic replacement is targeted, HPM 400 based system offers matching profile with higher efficiency. Active HASE Wt%
Brookfield (cP)
ICI (P)
HPM 200 based hase - A
1.87
1400
2.55
Benchmark 1
3.17
1350
2.25
HPM 100 based hase - B
0.56
6800
0.6
Benchmark 2
0.57
4600
0.5
HPM 400 based hase - C
0.42
7600
0.25
Benchmark 3
0.36
7200
0.22
HEC
0.76
7600
0.25
Table 1: All paint latex system were adjusted to 95 (±2) KU stormer viscosity
HPM 400 based HASE
Benchmark 3
HPM 100 based HASE
Usage ( Wt% Active)
0.5
0.5
0.5
0.5
1.6
1.6
Equilibrium Stormer Viscosity (KU)
78.6
83.5
100.6
94.6
100.3
113.4
Equilibrium ICI (P)
0.7
0.6
1
1
2.05
1.5
1.3/2.4/5.9
1.3/2.3/5.5
1.3/2.4/6.1
1.3/2.5/7.1
1.3/2.6/7.8
1.3/2.5/7.0
Gloss, 20° / 60° / 85°
Used as KU builders
Table 2: SIPOMER® HPMs based HASE bench marked at equal use level in a flat paint formula
HPM 200 Benchmark 2 based HASE Benchmark 1
Used as ICI builders
Rheology / 29
SIPOMER® Product Performance Internati % of Solid
Tg (°C)
% Water
Inhibitor ppm
Specific gravity
US (TSCA)
SIPOMER® PAM-100
100
-18
T he International Federation of Chemical, Energy, Mine and General Workers’ Unions. (2005)
Europe Solvay Novecare—40, rue de la Haie—Coq-F—93306 Aubervilliers Cedex—France Phone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90 Asia Pacific Solvay Asia Pacific Pte. Ltd.—438B Alexandra Road—#02—09/12 Alexandra Technopark—Singapore 119968 Phone: +65-6291 1921—Fax: +65—6394 3377 Latin America Solvay Novecare—Centro Empresarial—Avenida Maria Coelho Aguiar, 215, Bloco B-1º Andar Cep: 05804-902 —São Paulo—SP Brazil Phone: +55 11 3747-7637—Fax: +55 11 3741-8378 www.solvay.com
Neither Solvay Specialty Polymers nor any of its affiliates makes any warranty, express or implied, including merchantability or fitness for use, or accepts any liability in connection with this product, related information or its use. Some applications of which Solvay’s products may be proposed to be used are regulated or restricted by applicable laws and regulations or by national or international standards and in some cases by Solvay’s recommendation, including applications of food/feed, water treatment, medical, pharmaceuticals, and personal care. Only products designated as part of the Solviva® family of biomaterials may be considered as candidates for use in implantable medical devices. The user alone must finally determine suitability of any information or products for any contemplated use in compliance with applicable law, the manner of use and whether any patents are infringed. The information and the products are for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance or any other process. This is not a license under any patent or other proprietary right.
MARCH
All trademarks and registered trademarks are property of the companies that comprise the Solvay Group or their respective owners. © 2012 Solvay Specialty Polymers USA, LLC. All rights reserved.
NA
Material Safety Data Sheets (MSDS) are available by emailing us or contacting your sales representative. Always consult the appropriate MSDS before using any of our products.
2016
North America Solvay Novecare—504 Carnegie Center Drive, Princeton, NJ 08540—USA Phone: +1-800-973-7873—Fax: +1-609-860-0463—
[email protected]
SOLVAY NOVECARE — DiLeo Graphic Design,
[email protected]
>S olvay Novecare has achieved world—wide ISO—9001 Quality Management System Multi—Site Certification. (2008)
Rhodoline® 4188
Specialty Additive for Improved Color Stability
Color Solutions Applications
Key features
w Flat to high gloss architectural paints
w Improved wetting of pigments
w Pigment slurries
w Improved color acceptance/development
w Grind or letdown
w Better general dispersion stability
w Excellent co-dispersant
w Improved resistance to color floating
w Stabilizing agents
w Enhanced gloss
w Wetting agents
w Excellent wetting w Improved adhesion
Committed to your Coatings Success
w Better corrosion inhibition w Improved water resistance w No impact on other paint properties
Control
Rhodoline® 4188
Semi-Gloss Acrylic Paint Formulation
North America Phone: + 1-800-973-7873
Europe, Middle East, Africa Phone: +33 01 53 56 50 00
Asia Pacific Phone: +65 62 91 19 21
Latin America Phone: +55 11 3747-7637
www.solvay.com www.solvay.com
Color Solutions Rhodoline® 3000/4000 Series
Dispersants for Pigment Concentrates
The Solvay Group is committed in sustainably recreating the chemical industry, focusing on innovation and operational excellence
INNOVATIVE SOLUTIONS FOR AN INCREASINGLY DEMANDING MARKET Solvay, a world leader in the development and production of specialty chemicals, supplies performance additives for a variety of paint and coatings pplications. To meet market demands, Solvay’s global technical support network provides customers with custom-made solutions, and develops formulations adapted to their needs and requirements for the paint and coatings industry. These are surface-active solutions and functional monomers for the production of polymers in emulsion, meeting performance and sustainability requirements, such as zero VOC, biodegradability and low ecotoxicity. Solvay coatings also provides paint additives solutions, providing benefits in formulation and application. Solvay shares its best practices throughout its world-class manufacturing operations in North America, Latin America, Europe and the Asia Pacific region and benefits from technology transfer to create innovative materials focused on next-generation technologies for the paint and coatings market.
DISPERSANT MECHANISM Wetting: Liquid that replaces air on the surface of the pigment particle by reducing the interfacial tension Dispersant: Product that maintains fine solid particles in a suspended state and inhibits aggregation or sedimentation in a liquid medium
Electrostatic Stabilisation
Stabilization: Prevents re-agglomeration by electrostatic and/or steric repulsion Steric Stabilisation
PIGMENT STABILIZATION Challenges: • Maintain storage stability of pigment concentrates over longer time periods • Compatibility of these pigment concentrates with different coating systems after enduring longer storage time • Color acceptance/development in tinted systems Performance: • Anchoring of dispersant over the pigment’s surface - Improved compatibility - Improved color acceptance - Preventing flocculation and sedimentation
Pigment Properties: Inorganic vs. Organic Property
Inorganic
Organic
Solubility
Generally insoluble
Slightly soluble
Tint strength
Low
High
Hiding power
High, opaque
Low, more transparent
Fairly easy to disperse
Difficult
Specific gravity
High
Low
Heat resistance
High
Low
Excellent
Poor
Low
High
Ease of dispersion
Weathering Brightness (Intensity)
The Rhodoline® 3000 and Rhodoline® 4000 lines are high efficiency dispersants for water-based pigments concentrates, without VOCs and alkylphenols. RHODOLINE® 3000 SERIES Product
Active %
HLB
Recommendation
Rhodoline® 3100
85
11 - 13
Rhodoline® 3200
90
8 - 11
Rhodoline® 3500
70
> 16
Rhodoline® 3700
97
-
Dosage
Workhorse dispersant for low to medium HLB organic pigments including medium grade carbon black and lampblack pigments. Dispersant for low HLB organic pigment including toluidine red, 5 - 30% yellow and other organic pigments. of the pigment High HLB organic pigment wetting and dispersant agent. weight. Works great with organic pigments as well as industrial grade carbon black pigments.
High HLB pigment wetting and dispersant agent. Works great with high surface area pigments such as conductive carbon blacks.
RHODOLINE® 4000 SERIES Product
Ion Nature
Active %
Recommendation
Dosage
Rhodoline® 4100
Anionic
100
Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents.
Rhodoline® 4160
Anionic (ammonium salt)
25
Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents.
Rhodoline® 4170
Anionic (potassium salt)
25
Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents.
Rhodoline® 4188
Anionic (ammonium salt)
87
Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents.
0.1 - 0.5% (active) as paint wetting agent; 1 - 2% (active) as pigment wetting; 5 - 20% (active) based on total pigment weight as dispersant for concentrates.
Colour Index
Rhodoline®
% of additive on the pigment total
PR 112
3100
8 - 15%
PY 74
3100
11 - 15%
PBK 7
3500
15 - 30%
Improved stability
PB 15:0
3500
15 - 20%
APE and VOC free
PB 15:1
3500
20 - 30%
PG 7
3500
15 - 25%
PO 5
3500
8 - 15%
ATTRIBUTES High performance with less dispersant Exceptional color strength development Exceptional color acceptance upon tinting
The way we do business Solvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is dependent upon the responsible way in which we conduct our current activities — a way that reflects our commitment to each of our stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People Sphere and the Economic Sphere. Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self-assessments of their practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable value for all our stakeholders through innovation and partnership. > Responsible Care is the chemical industry’s voluntary continuous improvement initiative to promote safe handling of products. (1987) > The UN’s Global Compact aims to ensure that heads of companies promote and uphold 10 universal principles concerning human rights, working conditions, respect for the environment and anti-corruption. (2003) >T he International Federation of Chemical, Energy, Mine and General Workers’ Unions. (2005) > Solvay Novecare has achieved world wide ISO-9001 Quality Management System Multi-Site Certification. (2008)
North America Solvay Novecare – 504 Carnegie Center – Princeton, NJ 08540 – USA Phone: +1-800-973-7873 – Fax: +1-609-860-0463 –
[email protected] Europe Solvay Novecare – 40, rue de la Haie-Coq – F-93306 Aubervilliers Cedex – France Phone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90 –
[email protected] Asia Pacific Solvay Novecare – 1, Biopolis Drive – #05-01/06 AMNIOS – Singapore 138 622 Phone: +65 - 6291 1921 – Fax: +65 - 6394 3376 –
[email protected] Latin America Solvay Novecare – Centro Empresarial – Avenida Maria Coelho Aguiar, 215, Bloco B-1º Andar Cep: 05804-902 – São Paulo-SP Brazil Phone: +55 11 3747-7637 – Fax: +55 11 3741-8378 –
[email protected] www.solvay.com While the information herein is believed to be reliable, we do not guarantee its accuracy. Customers (direct and indirect) are urged to make their own tests with products described herein. Various patents owned by Solvay or others may be pertinent to their use and to compositions containing them. Nothing contained herein is intended as a recommendation to use our products so as to infringe any patent. We assume no liability for any intellectual property rights violation by customers (direct or indirect). Customers (direct and indirect) should make their own patent investigation related to the freedom to operate for any specific intended use. If a relevant patent is identified, customers (direct and indirect) should secure a license from the patent owner. Customers (direct and indirect) should evaluate the products to determine notably their strength, performance and safety. All applicable laws and regulations should be consulted. All the names mentioned are registered trademarks of Solvay, its subsidiaries or affiliates.
AEROSOL® Surfactants
Specialty Additives
AEROSOL® Surfactants Biodegradability
Flash Point °F/°C (Pensky Martens Closed Cup)
Solubility (as is) AEROSOL Surfactants
Type & Form (approx. conc.)
Chemical Name
Water @ 25°C g (as is) /100ml
Organic Solvent
Diester Sulfosuccinates
TR-70
Sodium bistridecyl sulfosuccinate
Anionic 70% solution in ethanol and water
0.1
Very Soluble
Not readily Biodegradable2
77 / 25
TR-70 HG
Sodium bistridecyl sulfosuccinate
Anionic 70% solution in hexylene glycol and water
0.1
Very Soluble
Not readily Biodegradable2
>212 / >100
TR-60 I
Sodium bistridecyl sulfosuccinate
Anionic 60% solution in isopropanol and water
0.1
Very Soluble
Not readily Biodegradable2
91 / 33
OT-75
Sodium dioctyl sulfosuccinate
Anionic 75% solution in ethanol and water
2.0
Very Soluble
Readily Biodegradable1
85 / 29
OT-75 E OPV
Sodium dioctyl sulfosuccinate
Anionic 75% solution in ethanol and water
2.0
Very Soluble
Readily Biodegradable1
85 / 29
GPG
Sodium dioctyl sulfosuccinate
Anionic 70% solution in ethanol and water
2.2
Very Soluble
Readily Biodegradable1
81 / 27
OT-70 PG
Sodium dioctyl sulfosuccinate
Anionic 70% solution in propylene glycol and water
2.2
Very Soluble
Readily Biodegradable1
>212 / >100
OT-70 PG OPV
Sodium dioctyl sulfosuccinate
Anionic 70% solution in propylene glycol and water
2.2
Very Soluble
Readily Biodegradable1
>212 / >100
OT-75 PG
Sodium dioctyl sulfosuccinate
Anionic 75% solution in propylene glycol and water
2.0
Very Soluble
Readily Biodegradable#
>212 / >100
OT-100
Sodium dioctyl sulfosuccinate
Anionic 100% waxy solid
1.5
Very Soluble
Readily Biodegradable1
Not Applicable
OT-B
Sodium dioctyl sulfosuccinate
Anionic 85% powder in 15% sodium benzoate
1.0
Partially Soluble
Readily Biodegradable1
Not Applicable
OT-A (ND)
Sodium dioctyl sulfosuccinate
Anionic 70% solution in Solvesso 150****
—
Very Soluble
Readily Biodegradable1
158 / 70
OT-S
Sodium dioctyl sulfosuccinate
Anionic 70% solution in light petroleum distillate
—
Very Soluble
Readily Biodegradable1
131 / 55
OT-SE ULA
Sodium dioctyl sulfosuccinate
Anionic 70% solution in light petroleum distillate
—
Very Soluble
Readily Biodegradable#
169 / 76
OT-85 AE
Proprietary sulfosuccinate blend
Anionic 85% solution in water
2.0
Very Soluble
Readily Biodegradable1
>212 / >100
* AEROSOL 22N is the European version of this product ** KRUSS -K12 *** Calcium Tolerance at 0.05% for AEROSOL TR products and 0.25% for AEROSOL WA-300
**** Aromatic Solvent from Exxon Methods for assessment of biodegradation: 1: 301A DOC (dissolved organic carbon) die-away test 2: 301B Modified Sturm test
3: 301D Closed Bottle test 4: 301E Modified OECD screening 5: 302B: Zahn Wellens Inherent #: Based on evaluation of components
Surface Tension in Water (min. mN/m)**
Ca Tolerance ppm CaCO3 at 0.5%
CMC %/wt**
27
100
LF-4
Proprietary sulfosuccinate blend
Anionic 80% solution in isopropanol and water
10
Soluble
Not readily Biodegradable3
110 / 43
WA-300
Proprietary sulfosuccinate blend
Anionic 75% solution in propylene glycol and water
2.5
Soluble
Readily Biodegradable1
>212 / >100
MA-80
Sodium dihexyl sulfosuccinate
Anionic 80% solution in ethanol and water
34
Soluble
Not readily Biodegradable4
97 / 36
MA-80 I
Sodium dihexyl sulfosuccinate
Anionic 80% solution in isopropanol and water
34
Soluble
Not readily Biodegradable4
101 / 38
A-196 40
Sodium dicyclohexyl sulfosuccinate
Anionic 40% solution in water
25
Soluble warm
Not readily Biodegradable4
>212 / >100
A-196 97
Sodium dicyclohexyl sulfosuccinate
Anionic 97% flaky solid
10
Soluble warm
Not readily Biodegradable4
Not Applicable
AY-65
Sodium diamyl sulfosuccinate
Anionic 65% solution in ethanol and water
62
Insoluble
Readily Biodegradable#
77 / 25
AY-100
Sodium diamyl sulfosuccinate
Anionic 100% waxy solid
40
Soluble
Readily Biodegradable#
Not Applicable
IB-45
Sodium diisobutyl sulfosuccinate
Anionic 45% solution in water
Infinite
Insoluble
Not readily Biodegradable4
>212 / >100
Cationic 70% viscous solution in isopropanol, ethylene glycol and water
Forms Dispersions
Soluble in the presence of alcohol
Not readily Biodegradable3
85 / 29
Alkylamine-Guanidine Ethoxylate
C-61
* ** *** ****
Alkylamine-guanidine polyoxyethanol
AEROSOL 22N is the European version of this product KRUSS -K12 Calcium Tolerance at 0.05% for AEROSOL TR products and 0.25% for AEROSOL WA-300 Aromatic Solvent from Exxon
Methods for assessment of biodegradation: 1: 3 01A DOC (dissolved organic carbon) die-away test
2: 301B Modified Sturm test 3: 301D Closed Bottle test 4: 301E Modified OECD screening
5: 302B: Zahn Wellens Inherent #: Based on evaluation of components
Surface Tension in Water (min. mN/m)**
Ca Tolerance ppm CaCO3 at 0.5%
CMC %/wt**
29
>1000
0.02
Low VOC and high solids version of AEROSOL OT. Same features and benefits as AEROSOL OT-75.
24
>2250
0.02
Wetting, dispersing, levelling, and emulsifying agent specially designed for applications requiring good dynamic wetting with low and unstable foam generation.
24
500***
0.02
Excellent wetting agent designed for use in the production of pressure sensitive adhesives (PSA). Product is functional at low concentrations and has a high flash point.
28
700
1.5
Good dynamic wetting properties with unstable foam generation. Emulsifying, dispersing and solubilizing agent. High electrolyte stability.
28
700
1.5
Good dynamic wetting properties with unstable foam generation. Emulsifying, dispersing and solubilizing agent. High electrolyte stability.
38
>2250
3.0
Imparts high surface tension, high filler loading capacity, good mechanical stability and reduced water sensitivity. Excellent low foaming surfactant. Produces dispersions with excellent electrolytic stability. Liquid at approximately 40°C.
38
>2250
3.0
Flaky solid form of AEROSOL A-196 40 with same features and benefits.
30
>1125
1.8
Wetting and dispersing agent for hydrophilic systems. Imparts good electrolytic and mechanical stability. It has a high tolerance for electrolytes.
30
>1125
1.8
Solid version of AEROSOL AY-65 used in water free systems. Same features and benefits as AEROSOL AY-65.
30
>2250
3.5
Very hydrophilic surfactant which is an extremely efficient wetting agent in high concentrations of electrolytes. Imparts good electrolytic and mechanical stability and reasonably high surface tension.
40
>2250
0.05
Combines cationic and non-ionic features. Good wetting, dispersing and flushing agent. Allows anionic systems to be compatible with cationic systems. Excellent acid and alkali stability.
Features & Benefits
N.B. Not all products may be offered for sale in all regions. Please check with your local Sales Manager. N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe.
AEROSOL® Surfactants Biodegradability
Flash Point °F/°C (Pensky Martens Closed Cup)
Solubility (as is) AEROSOL Surfactants
Chemical Name
Type & Form (approx. conc.)
Water @ 25°C g (as is) /100ml
Organic Solvent
Mono-ester Sulfosuccinates
EF-800
Proprietary sulfosuccinate composition
Anionic 50% solution in water
Infinite
Insoluble
Inherently Biodegradable5
>212 / >100
EF-810
Proprietary sulfosuccinate composition
Anionic 30% solution in water
Infinite
Insoluble
Inherently Biodegradable5
>212 / >100
A-102
Disodium ethoxylated alcohol half ester of Sulfosuccinic acid
Anionic 31% solution in water
Infinite
Sparingly soluble in polar solvents
Readily Biodegradable3
>212 / >100
A-103
Disodium ethoxylated nonyl phenol half ester of Sulfosuccinic acid
Anionic 34% solution in water
Infinite
Partially soluble in polar solvents
Not readily Biodegradable4
>212 / >100
501
Proprietary sulfosuccinate composition
Anionic 50% solution in water
Infinite
Insoluble
Not readily Biodegradable4
>212 / >100
Sulfosuccinamates
18P
Disodium N-octadecyl sulfosuccinamate
Anionic 30% semi-paste in water
18 at 40°C
Insoluble
Readily Biodegradable2
195 / 91
22 / 22N*
Tetra sodium N-(1,2 dicarboxy ethyl)- N-octadecyl sulfosuccinamate
Anionic 35% solution in water with ethanol/ methanol residuals
Infinite
Insoluble
Not readily Biodegradable#
129 / 54 156 / 70
22 Special
Tetra sodium N-(1,2 dicarboxy ethyl)- N-octadec(en)yl sulfosuccinamate
Anionic 35% solution in ethanol and water
Infinite
Insoluble
Not readily Biodegradable#
129 / 54
Nonyl Phenol Ether Sulfates
NPES-458
Ammonium salt of sulfated nonylphenoxy poly (ethyleneoxy) ethanol
Anionic 58% solution in ethanol and water
Infinite
Partially soluble
Not readily Biodegradable
NPES-930 P
Ammonium salt of sulfated nonylphenoxy poly (ethyleneoxy) ethanol
Anionic 30% solution in water
Infinite
Insoluble
Not readily Biodegradable#
>212 / >100
Anionic 75% powder in odium sulfate
>20
Partially soluble
Not readily Biodegradable#
Not Applicable
83 / 28
Alkyl Naphthalene Sulfonate
OS
* ** *** ****
Sodium diisopropyl naphthalene sulfonate
AEROSOL 22N is the European version of this product KRUSS -K12 Calcium Tolerance at 0.05% for AEROSOL TR products and 0.25% for AEROSOL WA-300 Aromatic Solvent from Exxon
Methods for assessment of biodegradation: 1: 3 01A DOC (dissolved organic carbon) die-away test
2: 301B Modified Sturm test 3: 301D Closed Bottle test 4: 301E Modified OECD screening
5: 302B: Zahn Wellens Inherent #: Based on evaluation of components
Surface Tension in Water (min. mN/m)**
Ca Tolerance ppm CaCO3 at 0.5%
CMC %/wt**
Features & Benefits
31
>2250
0.03
Versatile, APE free, primary or sole emulsifier enabling easy design of new latexes while meeting regulatory requirements. Can reduce the number of raw material required, simplifying formulations. Also highly effective, functioning at low concentrations. High tolerance for water-sensitive monomers.
0.03
Versatile, APE free primary or sole emulsifier. Highly effective, functions at low concentrations, making it extremely cost effective. The product imparts outstanding pre-emulsion stability, giving robust reaction kinetics, high conversions and minimizes final latex grit and coagulum in emulsion polymerization reactions. High tolerance for water-sensitive monomers.
0.1
Excellent APE free primary emulsifier for acrylic, styrene acrylic, vinyl acrylic and EVA latexes. Imparts both steric and charge stabilization giving systems with very good electrolytic and mechanical stability. Excellent acid stability and low surface and interfacial tension values make it a useful stabilizer/dispersant in a variety of aqueous systems. Good tolerance for cationic surfactants and polyvalent cations. Non-dermatitic.
31
29
>2250
>2250
34
>2250
0.01
Excellent primary emulsifier for acrylic, styrene acrylic and vinyl acrylic latexes especially high gloss systems. Imparts both steric and charge stabilization giving systems with very good electrolytic and mechanical stability. Outstanding compatibility with divalent and trivalent cations as well as quaternary ammonium surfactants. Non-dermatitic.
28
>2250
0.03
Emulsifier for generation of small particle size acrylic latexes. Also dispersing and wetting agent.
40
102
0.06
Emulsifying, dispersing, and foaming agent exhibiting good stability in acid and alkali solutions. Also has excellent lubricating properties.
36
200
0.04
Surfactant combining high hydrophilic and hydrophobic moieties with excellent acid and alkali compatibility. Emulsifier, dispersant and hydrotrope solubilizer. Non-dermatitic.
36
200
0.04
Same as for AEROSOL 22 but can have some additional grafting properties.
30
>2250
0.02
High foaming surfactant, also used as an emulsifier.
31
>2250
0.02
Emulsifier which is effective at low usage levels.
35
>2250
1.0
Stable wetting and dispersing agent in relatively high concentrations of acid or alkali. Highly effective in the manufacture of wettable powders.
N.B. Not all products may be offered for sale in all regions. Please check with your local Sales Manager. N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe.
Commercial Uses AEROSOL Surfactants
Emulsion Polymer Applications
Other Applications
Diester Sulfosuccinates
TR-70
TR-70 HG
Used as an emulsifier in acrylic, styrene acrylic and vinyl systems. In vinyl systems it modifies surface active properties which can make the finished film water resistant. It has an excellent synergy with primary emulsifiers to generate and stabilize fine latex dispersions as well as improving preemulsion stability in all acrylic and styrene acrylic systems.
Highly hydrophobic wetting agent. Dispersing agent for resins, pigments, polymers and dyes in organic systems. Particularly effective in flushing pigments from aqueous press cakes to solvent media. Used for the preparation of printing inks, rust inhibitors and anti-misting coatings. Dispersing dyes and pigments into plastics.
TR-60 I
A version of AEROSOL TR designed specifically for VCM polymerization. Due to its hydrophobic nature it stabilizes the VCM droplet very well. Offering the opportunity to generate bimodal and high solid latexes by allowing secondary nucleation. Polymer can be easily recovered.
–
OT-75
Used in a wide variety of emulsion and suspension polymerizations as a primary or co-emulsifier. It can produce latexes with low levels of coagulum, very low particle size and narrow distribution. As a post additive it lowers surface tension, improving flow and levelling characteristics.
Wetting and levelling agent for a wide range of industries: inks and OPVs, paint, adhesives, textile, paper, petroleum, rubber, metal, agricultural, mining, detergent compounding. Additionally used as dewatering aid and mould-release agent.
OT-75 E OPV
–
Specifically for OPV applications, ultra low levels of diethyl hexyl maleate (DEHM).
GPG
–
Used by a variety of industries as a wetting agent, e.g. in fire fighting foams, dust control, lubricants and coolants, degreasing, dry cleaning, cleaning solutions for glass etc.
OT-70 PG
OT-70 PG OPV
OT-75 PG
A high flash point version of AEROSOL OT
–
A high flash point version of AEROSOL OT
Same uses as for AEROSOL OT-75 but when a higher flash point is required. Compatible in paint formulations. Used in oil spill dispersants. Specifically for OPV applications, ultra low levels of diethyl hexyl maleate (DEHM). Same uses as for AEROSOL OT-75 but when a higher flash point is required. Compatible in paint formulations. Used in oil spill dispersants.
OT-100
–
Used in solvent and non-aqueous systems. Mould release for poly methyl methacrylate (PMMA). Used in inks, photographic products, dyes, textile, leather, scintillation fluid, agrochemical applications and fibre production. Wetting agent and antistat for polyethylene manufacture. Dispersing aid for dyes and pigments in plastics such as polyethylene and polypropylene.
OT-B
–
Used in agrochemicals for wettable powders and water dispersible granules.
N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe
AEROSOL Surfactants
Emulsion Polymer Applications
Other Applications
Diester Sulfosuccinates (continued)
OT-A (ND)
–
Used in agrochemical formulations, where it wets out active ingredients aiding their spread on to and penetration of the plant structure.
–
Very compatible and effective as a wetting/solubilizing/ dispersing agent in a wide variety of organic/hydrocarbon/ oilbased systems. Designed for instant solubility in all organic systems, such as rust inhibitors, degreasers, lubricants, dry cleaning solvents, pre-wash spot removers. Also used as a wetting and dispersing agent in plastics, lacquers and varnishes. Used in oil spill dispersants. Wetting and antistat agent for polyethylene manufacture.
OT-S
OT-SE
OT-85 AE OT-NV
LF-4
WA-300
MA-80 MA-80 I
A-196 40
A-196 97
AY-65 AY-100
IB-45
Primary or co-emulsifier for a wide variety of latex types for effective small particle generation at low usage levels.
Used in low VOC systems as a wetting agent, emulsifier and dispersant. Low surface tension and rapid dynamic wetting for a range of applications including printing inks, OPVs, paint, coatings, textiles and all types of cleaning formulations.
Co-emulsifier to enhance wetting properties of a dispersion with limited foam generation. Produces low surface tension latexes for adhesives, paints, floor polishes, printing inks, etc. Reduces or eliminates the need for post-addition of wetting agents to latexes.
Post addition wetting agent for OPVs, printing inks, paints, textile, paper, adhesives and coating applications. Gives excellent wetting and low foam. Also gives improved adhesion, gloss and color resolution.
Co-emulsifier providing enhanced stability and wetting properties of latex. Also reduces the need for non-ionic cosurfactants.
Post addition wetting and levelling agent for PSA applications.
Effective in all monomer systems. Yields complete conversion, coagulum-free latexes with good mechanical stability. Imparts good adhesion on porous substrates. Polymer can be easily recovered. Also reduces the need for non-ionic co-surfactants.
Wetting agent for OPVs, PSAs, paints, inks, textiles, battery separators, strong electrolyte solutions, electroplating, leaching operations, etc.
Emulsifier for modified styrene-butadiene and styrene-acrylic latexes. Unsurpassed for manufacturing styrene butadiene latexes. Imparts excellent water resistance and adhesion. Produces high surface tension latexes with good mechanical stability and high filler loading capacity. Imparts good adhesion of deposited film to its substrate.
Excellent low foaming surfactant. Produces dispersions with excellent electrolytic stability.
Surfactant for emulsion polymerization systems, especially where polymer recovery is desirable.
Extremely effective wetting agent in concentrated salt solutions. Used in electroplating as a wetting and dispersing agent. Additive for agricultural chemical applications. Effective dispersant for hydrophilic resins and pigments. Very effective wetting agent for leather coatings.
Used in emulsion polymerization and stabilization of styrene, Extremely stable in concentrated electrolyte solutions for styrene butadiene and other styrene based systems. Imparts leaching, wetting, electroplating and dispersion applications. high surface tension and good mechanical stability to latexes. Highly hydrophilic surfactant.
Commercial Uses AEROSOL Surfactants
Emulsion Polymer Applications
Other Applications
Alkylamine-Guanidine Ethoxylate
C-61
–
Cationic dispersing and fixing agent for pigments, dyes and fillers. Emulsifying agent used alone or with AEROSOL OT. Used in the manufacturing of glass fiber matting. Softening agent for textiles. Used in acid or alkali cleaning formulations.
Mono-ester Sulfosuccinates
EF-800
APE free primary or sole emulsifier for acrylic, vinyl acrylic, styrene acrylic and styrene butadiene latex systems. High tolerance for water-sensitive monomers facilitates easy development of high performance systems. Yields high solids/low viscosity latexes, enabling solids > 60% in final latexes. Yields excellent mechanical, electrolytic and freeze/ thaw stability, low coagulum and grit, hence increasing operational efficiencies. Produces latex films with high optical clarity and excellent heat stability.
APE free surfactant for variety of industries providing excellent emulsification, low surface tension and good stability.
EF-810
APE free primary or sole emulsifier for acrylic, vinyl acrylic, styrene acrylic and styrene butadiene latex systems. High tolerance for water-sensitive monomers facilitates easy development of high performance systems. Yields high solids/low viscosity latexes, enabling solids >60% in final latexes. Excellent pre-emulsion stability giving increased manufacturing flexibility. Also produces latexes with excellent mechanical, electrolytic and freeze/thaw stability, low coagulum and grit hence increasing operational efficiencies. Produces latex films with high optical clarity and excellent heat stability.
APE free surfactant for variety of industries providing excellent emulsification, low surface tension and good stability.
A-102
APE free primary emulsifier for acrylic, vinyl acrylic, styrene acrylic and EVA latexes. Can be used with N-methylolacrylamide without modifying performance requirements. Generates small to intermediate particle size emulsions, effective as a post stabilizer. Provides good adhesion in combination with AEROSOL MA-80 and 22. Gives low-coagulum levels, clear film formation and resistance to yellowing on heating. Films also have good water resistance.
Surfactant or foaming agent for personal care and cleaning applications, suitable for use in shampoos, bath and shower gels as well as germicidal cleaners. Additionally used in foaming cement, wallboard and adhesives. Also a good solubilizer and dispersant for medium HLB resin systems and other aqueous systems.
A-103
Used in emulsion polymerization as either the sole or primary emulsifier for the preparation of high gloss vinyl acetate and acrylic latexes. Produces small particle size emulsions with good film clarity as well as mechanical stability. Can be used with AEROSOL’s 22, MA-80 and A-102 to modify particle size. Gives good water resistance of the latex film and is resistant to yellowing on heating. Effective as a post-additive stabilizer.
Surfactant or foaming agent for personal care and cleaning applications, suitable for use in shampoos, bath and shower gels as well as germicidal cleaners. Additionally used in foaming cement, wallboard and adhesives. Also a good solubilizer and dispersant for medium HLB resin systems.
Used in emulsion polymerization of acrylic systems especially at low surfactant concentrations. High tolerance for water soluble monomers. Yields high solids/low viscosity latexes with freeze/thaw stability, mechanical stability and high optical clarity.
Provides low surface tension and good stability in printing ink, textile and paper applications. Used in the production of fire fighting foams.
501
N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe
AEROSOL Surfactants
Emulsion Polymer Applications
Other Applications
Sulfosuccinamates
18P
Imparts excellent rheological properties to pigmented latexes. Used in emulsion and suspension polymerizations. Foaming agent for latexes especially in carpet backing and textile applications.
Used as a foaming agent in foamed insulation, carpet backing, cement, wallboard and resins. Excellent stability in acid and alkali solutions, therefore also used in cleaning formulations and lubricants.
22/22N
Imparts small particle size for all latexes except vinyl acetate. In combination with AEROSOL’s MA-80 or A-102 produces highly stable high solids latexes. Excellent as a post-additive for mechanical stabilization, especially in paint applications giving high water resistance. Imparts excellent rheological properties in pigmented latexes.
Excellent pigment dispersant. Used in agrochemical formulations, industrial, household and metal cleaners. Excellent solubilizing agent for soaps and other surfactants in soluble salt solutions. Excellent lime soap dispersant.
22 Special
Same as for AEROSOL 22 but can have some additional grafting properties.
–
Nonyl Phenol Ether Sulfates NPES-458
Emulsion polymerization of vinyl acetate, acrylic and styrene acrylic systems giving very small particle size emulsions.
Used in textile scouring agents and detergents. Also used in iodine based germicidal cleaners.
NPES-930 P
Produces very fine particle size vinyl acetate, acrylic and styrene acrylic latexes with low levels of coagulum and good mechanical stability. Latexes also have good freeze/thaw stability. Superior emulsifier for Zn cross-linking latexes for floor finishes. Extremely low surfactant levels needed that result in superior water resistance and high optical clarity.
Used in detergents and rosin dispersions.
Alkyl Naphthalene Sulfonate
OS
Surfactant for emulsion polymerization and additive for latexes.
Dispersant for pigments and dyes in paints and plastics. Used in agrochemical wettable and dispersible powders. Used in metal cleaning, bottle washing, paint strippers, brick and tile cleaning, pickling, acid etching agents and hard surface cleaners due to its excellent acid and alkali stability.
Cytec Solvay Group
5 Garret Mountain Plaza Woodland Park, NJ 07424
[email protected] Tel: +1.973.357.3100 Fax: +1.973.357.3100
www.cytec.com
Disclaimer: Cytec Industries Inc. in its own name and on behalf of its affiliated companies (collectively, “Cytec”) decline any liability with respect to the use made by anyone of the information contained herein. The information contained herein represents Cytec’s best knowledge thereon without constituting any express or implied guarantee or warranty of any kind (including, but not limited to, regarding the accuracy, the completeness or relevance of the data set out herein). Nothing contained herein shall be construed as conferring any license or right under any patent or other intellectual property rights of Cytec or of any third party. The information relating to the products is given for information purposes only. No guarantee or warranty is provided that the product and/or information is adapted for any specific use, performance or result and that product and/or information do not infringe any Cytec and/or third party intellectual property rights. The user should perform its own tests to determine the suitability for a particular purpose. The final choice of use of a product and/or information as well as the investigation of any possible violation of intellectual property rights of Cytec and/ or third parties remains the sole responsibility of the user. All trademarks are the property of their respective owners. © 2015 Cytec Industries Inc. The ® indicates a Registered Trademark in the United States and the ™ indicates a trademark in the United States. The mark may also be registered, subject of an application for registration, or a trademark in other countries.
AEROSOL® Surfactant Selection Guide
Specialty Additives
AEROSOL® Surfactants Diester Sulfosuccinates
OT-85 AE
OT-NV
LF-4
E
E
E
E
E
E
E
E
E
E
D
E
E
D
D
D
D
TR-70
OT-S (E)
E
OT-A (ND)
E
E
OT-B
E
E
OT-100
OT-70/75 PG
E
E
GPG
OT-75 (E)
E
E
TR-60 I
E
S tyrene & Styrene / Acrylics
Polymer
TR-70 HG
A crylics
Applications
Emulsion Polymerization
S tyrene / Butadiene S tyrene / Acrylonitrile V inyl Acetate & Vinyl Acetate / Acrylics
E
E
V inyl Chloride & Vinylidene Chlorides
E
E
E
E
D
D
(micro)Suspension Polymerization
E
D
Latex Post Stabilization Foaming Rubber or Plastic Pigment & Color Dispersing Polymer Processing Aids
D
D
D
D
W
W
W
W
D
D
D
W
Coatings & Inks Pigments Dispersing & Wetting
D
D
D
D
D
D
Color / Tint Development
W
W
W
W
W
W
W
W
Paint & Coating Formulation
X
X
X
X
D
X
X
X
Printing Ink Formulation
X
X
X
X
D
X
X
X
OPV
W
W
W
W
W
W
W
P SA
W
W
W
W
W
W
W
Sealant
W
W
W
W
General Adhesives
W
W
W
W
W
W
W
W
W
W
W
W
W
X
X
X
X
S
S
S
S
S
S
S
S
S
S
W
Adhesives
Construction / Building Materials
W
W
W
W W
Textile / Non Woven
D
D
W
W
W
Agrochemical
X
X
X
X
X
O il Spill Dispersants
S
S
Drilling / Production / Stimulation
S
S
Remedial Cleaning
S
S
W
W
X
Oil Industry S
Mining, Paper & Pulp W
D ust Control Dewatering Aids
W
W
Electronics & Electrical
W
W W
W
W
W
Cleaning A utomotive
X
X
X
Dry Cleaning
S
D
S
Germicidal
W
W
W
W
W
W
Glass & Bottle Metal - Etching, Plating D - Dispersing
W
W
X
E - Emulsification
X
X
X
D
D
W
X
W F - Foaming
S - Deter
(Wetting, Dispersin The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe.
Mono-ester Sulfosuccinates
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E E
E
E
E
E
E
E
D
D
E
E
D
D
W
W
E
E
E E
E
E
E
D
E
E
E
E
C-61
E
E
Others
OS
E
NPES 930 P
E
NPES 458
E
22 Special
E
22 / 22N
E
18P
E
501
AY-100
E
A-103
AY-65
E
A-102
A-196 97 E
E
EF-800
A-196 40 E
E
Nonyl Phenol Ether Sulfates
EF-810
MA-80 (I) E
E
IB-45
WA-300 E
Sulfo Succinamates
E
D E
E
E
E
D
E
E F
F
D
D
D
D
D
D
D
D
D
D
D
X
W D W
D
X
X
X
X
X
D
D
D
W
D
D
D
D
W W
W W
W
X
W Z
W
W
X
X
X
X
W
X
F
E
E
E
X
Z
Z
Z
E
X
E
D
S
X
D W
F
S W W W
W
W
W X
W
W
D
W
W
X
D
D S
D W
rgency
ng, Emulsification)
D W
W W - Wetting
W
D
X
X - Wetting & Emulsification or Dispersing
D
W
D
X
X
D
X
D Z - Wetting & Foaming
X
Cytec Solvay Group
5 Garret Mountain Plaza Woodland Park, NJ 07424
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