MSDS - Chemical Products Safety Information Sheet in accordance with NBR-14725 Page 1 / 7

Savinyl Blue GLS Substance key: KS16030 Version : 2 - 4 / BR

Revision Date: 11.02.2011 Date of printing : 21.06.2011

1. Product and Company Identification Trade name Savinyl Blue GLS

Material number:103330

Material number: 103330 Internal Substance Code: KS16030 Identification of the company Clariant Production (France) Usine de Huningue Avenue de Bâle 68331 Huningue Telephone no. : +33 3 89 89 60 00 Information about the substance/preparation Division Pigments & Additives tel.: +33.3.89.89.63.38 Emergency telephone number : +33 1 45 42 59 59

2. Composition and information on ingredients Substance

Chemical characterization Copper phthalocyanine Dyestuff, C.I. SOLVENT BLUE 44

3. Hazards identification According to the present state of knowledge, provided that this product is handled correctly, there is no known danger to humans.

4. First aid measures General information Seek medical assistance if discomfort continues After inhalation Remove from danger zone. Obtain medical advice. After contact with skin After contact with skin, wash immediately with plenty of water and soap. After contact with eyes Immediately rinse eyes with running water.

MSDS - Chemical Products Safety Information Sheet in accordance with NBR-14725 Savinyl Blue GLS Substance key: KS16030 Version : 2 - 4 / BR

Page 2 / 7

Revision Date: 11.02.2011 Date of printing : 21.06.2011

After ingestion Obtain medical advice. Advice to doctor Symptoms No symptoms known currently. Hazards No hazards known at this time. Treatment Treat symptomatically.

5. Fire-fighting measures Suitable extinguishing media all Extinguishing media that must not be used for safety reasons No restrictions Special hazards from the substance itself, its combustion products or from its vapours carbon oxides copper oxides nitrogen oxides sulfur dioxide Special protective equipment for firefighting Use self-contained breathing apparatus Further information Cool container and metallic parts with a water spray jet

6. Control Measures for Spillage or Spill Personal precautions Wear suitable personal protective equipment. Environmental precautions Do not allow to enter drains or waterways Methods for cleaning up/taking up Take up mechanically Place for disposal in tightly closed containers. Additional information Information regarding Safe handling, see chapter 7.

7. Handling and storage

MSDS - Chemical Products Safety Information Sheet in accordance with NBR-14725 Page 3 / 7

Savinyl Blue GLS Substance key: KS16030 Version : 2 - 4 / BR

Revision Date: 11.02.2011 Date of printing : 21.06.2011

Advice on safe handling Keep container tightly closed. Keep container in a well-ventilated place. Advice on protection against fire and explosion Take precautionary measures against static discharges. Organic products which are intentionally or unintentionally in powdered form have, in principle, the possibility of creating a dust explosion hazard Avoid formation of dust. Keep away from sources of ignition. Dust explosion class :

ST1 Capable of dust explosion

8. Exposure controls and personal protection General protective measures Observe the usual precautions for handling chemicals. Hygiene measures This substance is classified as non-hazardous. However the usual precautions for handling chemicals must be observed to avoid contact with the skin, eyes and respiratory tract. In case of contact with the product, wash the eye immediately with running water and the skin with water and soap. Respiratory protection :

If ventilation insufficient, use a respiratory protection apparatus

Hand protection :

Nitrile rubber gloves.

Eye protection :

safety glasses

Body protection :

working clothes

9. Physical-chemical properties Form : Colour : Odour :

powder blue not specified

Melting point : not applicable Boiling point : not applicable Flash point : not tested. Ignition temperature : not tested.

MSDS - Chemical Products Safety Information Sheet in accordance with NBR-14725 Page 4 / 7

Savinyl Blue GLS Substance key: KS16030 Version : 2 - 4 / BR

Revision Date: 11.02.2011 Date of printing : 21.06.2011

Self-ignition temperature : not tested. Lower explosion limit : not tested. Upper explosion limit : not tested. Evaporation rate :

not tested.

Vapour pressure : not applicable Density :

1,4 g/cm3

Vapour density in relation to air :

not tested.

Solubility in water : insoluble Soluble in ... :

fat not tested.

pH value :

app. 7 (20 °C, 50 g/l) Method : of an aqueous suspension

Octanol/water partition coefficient (log Pow) :

unknown

Viscosity (dynamic) : not tested. Combustion number :

BZ3 Local combustion without spreading ( 20 °C)

Combustion number :

BZ3 Local combustion without spreading ( 100 °C) Source : Clariant

10. Stability and reactivity Thermal decomposition :

220 °C Method : isoperibolic decomposition test Air open cup

Thermal decomposition :

>= 260 °C Method : dynamic decomposition test

MSDS - Chemical Products Safety Information Sheet in accordance with NBR-14725 Page 5 / 7

Savinyl Blue GLS Substance key: KS16030 Version : 2 - 4 / BR

Revision Date: 11.02.2011 Date of printing : 21.06.2011

Hazardous decomposition products When used and handled as intended, none. Conditions to avoid None known. Materials to avoid not known

11. Toxicological information Acute oral toxicity :

LD50 > 2.000 mg/kg (rat) Method : OECD 401

Acute inhalation toxicity : not tested. Acute dermal toxicity : not tested. Irritant effect on skin :

non-irritant (rabbit) Method : OECD 404 * 1981 dermal irritation / corrosion

Irritant effect on eyes :

non-irritant (rabbit) Method : OECD 405 * 1981 eye irritation / corrosion

Sensitization : not tested. Repeated dose toxicity:

not tested.

Mutagenicity :

not tested.

Carcinogenicity :

not tested.

12. Ecological information Biodegradability : Not applicable due to insolubility in water. This product does not come into contact with the effluent when it is used for its purpose, otherwise it can be removed by filtration operations. Behaviour in environmental compartments No known data. Fish toxicity : not tested.

MSDS - Chemical Products Safety Information Sheet in accordance with NBR-14725 Page 6 / 7

Savinyl Blue GLS Substance key: KS16030 Version : 2 - 4 / BR

Revision Date: 11.02.2011 Date of printing : 21.06.2011

Daphnia toxicity : not tested. Algae toxicity : not tested. Bacteria toxicity : not tested. Remarks No data available.

13. Disposal and treatment considerations Product Incineration in an approved, controlled furnace. Observe: fire hazard data, physical and corrosion data. Uncleaned packaging For disposal local regulation is binding. Composition C , O , H , N , Cu , S ,

14. Transport information Road Transport Regulation

not restricted

Air Transport Regulation

not restricted

Maritime Transport Regulation

not restricted

15. Regulations Brazilian Labelling in accordance with Norm 26 of the Ministery of Labour Regulations. Risk phrases According to the present state of knowledge, provided that this product is handled correctly, there is no known danger to humans. In accordance with regulations for special waste, must be taken to an authorised special waste incineration plant. Safety phrases Keep container tightly closed in a cool, well-ventilated place. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with water and soap. When inhaled remove to fresh air and seek medical aid.

MSDS - Chemical Products Safety Information Sheet in accordance with NBR-14725 Savinyl Blue GLS Substance key: KS16030 Version : 2 - 4 / BR

Page 7 / 7

Revision Date: 11.02.2011 Date of printing : 21.06.2011

When swallowed seek medical aid immediately and show the physician the packaging or the label of the packaging.

16. Other information The data are based on the current state of our knowledge, and are intended to describe the product with regard to the requirements of safety. The data should not be taken to imply any guarantee of a particular or general specification. It is the responsibility of the user of the product to ensure to his satisfaction that the product is suitable for the intended purpose and method of use. We do not accept responsibility for any harm caused by the use of this information. In all cases, our general conditions of sale apply.