6th International Conference on Green and Sustainable Chemistry GSC- 6. University Park Nottingham

    6th  International  Conference     on  Green  and  Sustainable  Chemistry     GSC-­‐6           University  Park   Nottingham       4-­‐7  Au...
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6th  International  Conference     on  Green  and  Sustainable  Chemistry    

GSC-­‐6      

    University  Park   Nottingham       4-­‐7  August  2013       Updated  04/08/2013  12:58  

 

 

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Welcome  to  Nottingham  

 

Welcome  to  GSC-­‐6!    This  meeting  is  the  end  point  of  over  18  months  of  planning  and  hard   work   by   the   local   team,   we   would   lie   to   thank   all   of   our   presenters,   delegates,   sponsors   and   exhibitors  for  their  efforts  and  indeed  time.     The   Organising   Committee   of   the   6th   International   Conference   on   Green   and   Sustainable   Chemistry  (GSC-­‐6)  welcomes  you  to  University  Park  which  is  The  University  of  Nottingham’s   largest   campus   at   330   acres;   it   has   been   part   of   the   University   since   1929   when   it   was   given   to  the  University  as  a  gift  by  The  Lord  Trent,  Sir  Jessie  Boot,  founder  of  Boots  the  Chemist.         In  Nottingham,  that  dismal  town  where  I  went  to  school  and  college,   they've  built  a  new  university  for  a  new  dispensation  of  knowledge.   Built  it  most  grand  and  cakeily  out  of  the  noble  loot   derived  from  shrewd  cash-­‐chemistry  by  good  Sir  Jesse  Boot.      

 

 

 

 

[DH  Lawrence,  1929]

 

  Nottingham   has   a   rich   heritage   and   identity   in   the   development   of   chemistry   both   academically   and   indeed   industrially.     The   famous   “Boots”   brand   was   established   in   1849   with   the   opening   of   a   “druggist”   shop   in   the   city   centre.     Nottingham   is   the   birthplace   of   ibuprofen,   discovered   in   the   1950s   by   researchers   at   Boots;   the   anti-­‐inflammatory   drug   is   still  one  of  the  largest  “over  the  counter”  medicines  produced.    The  post  patent  BHC  route   to  ibuprofen  is  one  of  the  best  examples  of  process  refinement  for  increased  sustainability   and  is  used  globally  as  an  exemplar  of  the  philosophies  that  underpin  green  chemistry.     The   venue   for   GSC-­‐6,   University   Park   campus   is   widely   regarded   as   one   of   the   largest   and   most   attractive   in   the   country.     Set   in   extensive   greenery   and   around   a   lake,   University   Park   is  the  focus  of  life  for  students,  staff  and  visitors.    The  campus  has  been  a  Civic  Trust  Green   Flag  Award  Winner  every  year  since  2003  –  the  only  university  campus  to  achieve  this  status   in   the   UK.     We   hope   you   will   enjoy   the   walks   and   gardens   of   the   University   Park   during   breaks  in  the  programme.         This   is,   thus,   a   unique   opportunity   for   our   community   to   showcase   some   of   the   finest   examples   in   modern   chemistry.     We   hope   that   GSC-­‐6   becomes   a   melting   pot   for   the   presentation   of   new   science,   stimulating   vibrant   discussion   and   knowledge   exchange.     We   hope   that   friendships   and   made,   collaborations   formed   and   above   all   that   progress   is   initiated  in  this  ever  important  field  of  science     With  our  warmest  regards,         The  Executive  Committee  on  July  15th,  2013,  Nottingham.        

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  Thank  you  to  our  Sponsors       The organisers and advisory board of GSC-6 would like to thank their sponsors and exhibitors for supporting this activity. Sponsors

Exhibitors

 

 

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Conference  Programme   6th  International  Conference  on  Green  and  Sustainable  Chemistry    (GSC-­‐6)   th Sunday  4  August  2013   15.30-­‐ Registration   18.00       Conference  Registration  will  be  held  in  the  Main  Foyer  of  the  Engineering  and   Science  Learning  Centre  (ESLC)       (ESLC  is  building  number  54  on  the  attached  campus  map)             18.00-­‐ Welcome  (Prof  Chris  Rudd,  PVC)   18.15   18.15-­‐ Plenary    -­‐-­‐-­‐-­‐    Prof  Barry  Trost      (P1)   19.15     19.15-­‐ Mixer  and  Drinks   21.00       Drinks  and  Buffet  will  be  served  in  the  ESLC  -­‐  Room  A09/B07-­‐8   Posters  will  be  located  in  the  ESLC  –  Rooms  B01,  B02  and  B14.     Exhibition  will  be  in  the  ESLC  Foyer                                                        

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    6th  International  Conference  on  Green  and  Sustainable  Chemistry    (GSC-­‐6)   th Monday  5  August  2013   8.30-­‐ Plenary    Karl  A  Jorgensen  (P2)   9.30        

    60  

  9.40-­‐ 10.10   10.10-­‐ 10.35   10.35-­‐ 11.00   11.00-­‐ 11.30   11.30-­‐ 11.55   11.55-­‐ 12.20   12.20-­‐ 12.45   12.45-­‐ 13.10   13.10-­‐ 14.30     14.30-­‐ 15.00   15.00-­‐ 15.25   15.25-­‐   15.50   15.50-­‐ 16.15   16.15-­‐ 16.35   16.35-­‐ 17.00   17.00-­‐ 17.25   17.25-­‐ 17.50   17.50-­‐ 18.15   18.15-­‐   18.40   18.40-­‐ 21.00  

20-­‐00-­‐   21-­‐00  

10  

Session  1   (Chemistry  –  X1)   Jessop  (K1)     North  (O1)  

Session  2   (Chemistry  –  X2)   Fortunak  (K2)     Voutchkova-­‐Kostal    (O7)  

 

Quadrelli  (O2)  

Williams  (O8)    

25  

Howdle  (Absract  tba)  

Coffee   (Chemistry  Foyer  and  ESLC)   Sheldon  (O9)  

30   25  

30   25  

Pollak      (O4)  

Lee  (O10)  

25  

Zhao    (O5)  

Hutchison  (O11)  

25  

Marriot  (O6)  

Prasad  (O12)  

25  

Session  3   (Chemistry  –  X1)   Lester  (K3)     Adschiri  (O13)  

Lunch   (ESLC  -­‐  Room  A09/B07-­‐8)   Session  4   (Chemistry  –  X2)   Hessel  (K4)     Sans  (O21)  

Session  5   (ESLC  C01)   Subramaniam  (K5)     Turner    (O29)  

 

Bennett  (O14)  

Garcia-­‐Verdugo  (O22)  

Funaoka  (O30)    

25  

Luan  (O15)  

Albini    (O23)  

Heeres  (O31)  

25  

Piccolo  (O16)  

80  

Coffee   (Chemistry  Foyer  and  ESLC)   George  (O24)   Hallet  (O32)  

30   25  

20   25  

Rossi    (O17)  

Casas  (O25)  

Slattery  (O33)  

25  

Li    (O18)  

X  Zhang  (O26)  

Bogel-­‐Łukasik  (O34)  

25  

El  Hiti  (O19)  

Matsukata  (O27)  

Kamimura  (O35)  

25  

Yadav  (O20)  

Tallon  (O28)    

Desai  (O36)  

25  

Posters  &  Buffet   Drinks  and  Buffet  will  be  served  in  the  ESLC  -­‐  Room  A09/B07-­‐8   Posters  will  be  located  in  the  ESLC  –  Rooms  B01,  B02  and  B14.   Exhibition  will  be  in  the  ESLC  Foyer     Business  Meeting  (GSC  Board  Only  –  By  Invitation)      

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Tuesday  6  August  2013  

 

8.30-­‐ 9.30    

Plenary  Lecture  -­‐    Prof  Jairton  DuPont  (P3)  

60  

 

 

 

Session  6   (Chemistry  –  X1)   Kobayashi  (K6)     Clarke  (O37)  

Session  7   (Chemistry  –  X2)   Aguiar-­‐Ricardo  (K7)     Forder    (O50)  

Session  8   (ESLC  C01)   Peter  Dunn  (K8)     Gallou  (O63)  

10  

Hisaeda  (O38)  

T  Liu  (O51)  

Sneddon    (O64)  

25  

9.40-­‐ 10.10   10.10-­‐ 10.35   10.35-­‐ 11.00   11.00-­‐ 11.30   11.30-­‐ 11.55   11.55-­‐ 12.20   12.20-­‐ 12.45   12.45-­‐ 13.10   13.10-­‐ 14.30     14.30-­‐ 15.00   15.00-­‐ 15.25   15.25-­‐   15.50   15.50-­‐ 16.15   16.15-­‐ 16.35   16.35-­‐ 17.00   17.00-­‐ 17.25   17.25-­‐ 17.50   17.50-­‐ 18.15    

Hayes  (O39)  

Coffee   (Chemistry  Foyer  and  ESLC)   Scott  (O52)   Gordon  (O65)  

30   25  

30   25  

Masui  (O40)  

Thielemans  (O53)  

McKechnie  (O66)  

25  

Whiting  (O41)  

Camp  (O54)  

Martin  Luengo  (O67)  

25  

Kumar  (O42)  

Pilkington  (O55)  

Bogel-­‐Łukasik  (O68)  

25  

Session  9   (Chemistry  –  X1)   Wassercheid  (K9)     JG  Liu    (O43)  

Lunch   (ESLC  -­‐  Room  A09/B07-­‐8)   Session  10   (Chemistry  –  X2)   Martin  Matute  (K10)     Thomas  (Abstract  tba)  

Session  11   (ESLC  C01)   Leitner  (K11)     Hou  (O69)  

 

Chuck    (O44)  

Iskra  (O57)  

Prechtl    (O70)  

25  

Hua  (O45)  

Bianco  (O58)  

Marr  (O71)  

25  

Hunt  (O46)  

80  

Coffee   (Chemistry  Foyer  and  ESLC)   Zhu  (O59)   Gathergood  (O72)  

30   25  

20   25  

Titrici  (O47)  

Sánchez-­‐Vicente  (O60)  

Croft  (O73)  

25  

Wang  (O48)  

Hori  (O61)  

Harper  (O74)  

25  

Okuma  (O49)  

Hubertson  Simanjuntak   (O62)  

Neumann  (O75)  

25  

 

19.00-­‐  

  Conference  Banquet  (ticket  required)     Dining  Room,  Hugh  Stewart  Hall  

 

       

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Wednesday  7  August  2013   8.30-­‐ 9.30     9.40-­‐ 10.10   10.10-­‐ 10.35   10.35-­‐ 11.00   11.00-­‐ 11.30   11.30-­‐ 11.55   11.55-­‐ 12.20   12.20-­‐ 12.45   12.45-­‐ 13.10   13.10-­‐ 13.45  

Plenary    Lecture    Prof  Isabel  Arends  (Biocatalysis)   (Chemistry  -­‐  X1)   Session  12   Session  13   Session  14   (Chemistry  –  X1)   (Chemistry  –  X2)   (ESLC  -­‐  C01)   Broxterman  (K12)   Haack  (K13)   Han  (K14)     Glueck  (O76)   Zuin  (O82)   Goto  (O88)     Liese  (O77)   Mitchener  (O83)   Kawanami  (O89)   Coffee   (Chemistry  Foyer  and  ESLC)   Koel  (O84)   M  Zhang  (O90)     Xu  (O85)   Velilla-­‐Perez  (O91)     Roth  (O86)   Joshi  (O92)     (O87)   (O93)  

Z  Liu  (O78)   Wilson  (O79)   Grau  (O80)   (O81)  

Foresight  Lecture  –  Peter  Wassercheid    –  (Forward  looking  )   Chair  Martyn  Poliakoff  –  closing  Remarks     (Chemistry  –  X1)  

60   10   30   25   25   30   25   25   25   15   30   5  

     

 

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List  of  Contributions  –  Plenary  and  Keynote     Abstract  Number  

Details  

PI  Trost   PII  Jørgensen    

Challenge  for  Total  Synthesis:  Atom  Economy     Organocatalysis  –A  new  tool  for  the  synthesis  of  optically  active  molecules  

PIII  DuPont  

Catalysis  in  and  by  ionic  liquids    

PIV  Arends  

Application  of  enzymes  as  sustainable  catalysts  

F1  Wassercheid  

A  look  forwards!  

K1  Jessop  

Switchable  Water:  Aqueous  Smart  Fluids  

K2  Fortunak  

Sustainable  Access  to  Medicines  Utilizing  Green  Chemistry  

K3  Lester  

SHYMAN  –  Sustainable  Hydrothermal  Manufacturing  of  Nanomaterials  

K4  Hessel  

Novel  Process  Windows  in  Flow:  From  Chemical  to  Process-­‐Design  Intensification  -­‐   from  Green  Chemistry  to  Green  Engineering   Renewable  Chemicals:  Opportunities  and  Challenges     Catalytic  Organic  Reactions  in  Water     Greening  Tailor  Made  “Smart”  Biomaterials  for  New  Therapies     Application  of  environmental  metrics  to  evaluate  green  chemistry  improvements   to  the  synthesis  of  (S,S)-­‐reboxetine  succinate   Chemical  energy  storage  systems  and  related,  novel  catalytic  technologies  

K5  Subramaniam     K6  Kobayashi   K7  Aguiar-­‐Ricardo     K8  Dunn   K9  Wasserscheid     K10  Martín-­‐Matute     K11  Leitner   K12  Broxterman   K13  Haack   K14  Han  

Transition  Metal-­‐Catalyzed  Isomerization  and  Halogenation  Reactions  in  Water     “Panta  rhei”  -­‐  An  Integrated  Approach  to  Continuous-­‐Flow   Asymmetric  Catalysis   Towards  The  Bio-­‐based  Economy:  Perspectives  On  Biomass  Use  For  Chemicals   Manufacturing   Green  Chemistry  Education:  Not  Just  for  Chemists  Anymore     Properties  of  Green  Solvents  and  Applications  in  Green  Chemistry    

   

 

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List  of  Contributions  –  Invited  and  Contributed  Orals     Abstract  Number  

Details  

O1  North   O2  Quadrelli     O3  Howdle  

Synthesis  of  Cyclic  carbonates  from  Waste  CO2  And  Their  Use  As  Green  Polar   Aprotic  Solvents   CO2  conversion:  Emerging  Large  Scale  Applications  and  Selected  Recent  Results     TBA  

O4  Pollak  

Capture  of  Carbon  Dioxide  with  Solutions  Based  on  Ionic  Liquids  

O5  Zhao  

O8  Williams  

Effects  of  water  on  the  hydrogenation  of  o-­‐chloronitrobenzene  in  ethanol,  n-­‐ heptane  and  compressed  carbon  dioxide   CO2  Utilisation  in  the  Biorefinery  -­‐  Old  Science  or  New  Opportunities     Catalytic  Dehydrogenation  of  Alcohols  and  using  Ag,  Pd,  Cu  and  Ir  supported  on   Tunable  Hydrotalcites:  Towards  Mild  Dehydrogenation  of  Alkanes   Catalytic  Synthesis  of  Amides  

O9  Sheldon  

Green,  Bio-­‐based  Solutions  for  a  Sustainable  Economy  

O10  Lee  

Clean  Chemical  Synthesis  via  Nanoporous  Palladium  Catalysts     Greener  syntheses  of  ligand-­‐stabilized  metal  oxide  nanocrystals     Green  and  Sustainable  Chemistry:  Chemo-­‐enzymatic  Conversion  of  Glucose  to   Bicyclic  Nucleosides  and  Sugar-­‐PEG  Polymeric  Architectures   Green  Sustainable  Chemistry  Aspects  of  Supercritical  Hydrothermal  Synthesis   -­‐Organic  Modified  Nanoparticles  and  Fabrication  of  Hybrid  Polymers-­‐   Tuning  Catalyst  Selectivity  via  Nanoparticle  Shape  and  Topography  

O6  Marriott   O7  Voutchkova-­‐Kostal  

O11  Hutchison   O12  Prasad     O13  Adschiri     O14  Bennett   O15  Luan     O16  Piccolo     O17  Rossi   O18  Li     O19  El-­‐Hiti   O20  Yadav   O21  Sans   O22  Garcia-­‐Verdugo     O23  Albini   O24  George   O25  Casas  

Air  stable  pyrite  FeS2  nanocrystals:  facile  hydrothermal  synthesis   and  morphology  control   Heterogeneous  Home-­‐made  Catalysts  with  a  Low  Content  of  Precious  Metals   and  their  Application  in  the  Synthesis  of  Fine  Chemicals   Metal  Nanoparticles  for  Designed  Hydrogenation,  Oxidation  and   Hydroformylation  Catalysts   Study  on  the  Catalytic  Performance  of  the  Catalysts  Supported  onto  Mesoporous   Materials  by  Novel  Loading  Strategies   Sustainable  and  Greener  Chemical  Processes:  Regioselective  Aromatic   Substitution  Reactions  Over  Solid  Catalysts   Science  &  engineering  of  pores,  particles  and  interfaces  in  development  of  green   processes   Integrated  flow  systems  employing  3D-­‐printed  reactionware   The  Use  of  Solid  Ionic  Solvents  to  Develop  Catalytic  Continuous  Flow  Processes   Photocatalysis.  A  Green  Synthetic  Tool      An  Example  of  What  Photochemistry  Can  Do  for  Green  Chemistry   Intensification  of  Supercritical  Extraction  (SCE)  with  High-­‐Power  Ultrasound   (HPU)  Technology:  effects  related  to  process  variables  and  treated  material  

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    O26  X  Zhang  

Scale-­‐up  studies  of  the  electroreduction  of  oxalic  acid  to  glyoxylic  acid  

O27  Matsukata   O28  Tallon  

Prospect  of  Large-­‐scale  Energy  Saving  of  Chemical  Processes  with  Membrane   Technology   Green  Solvents  for  Extraction  of  Polar  Lipids  

O29  Turner  

Hot  Water  Extraction  and  Biocatalysis  of  Polyphenols  in  Agricultural  Byproducts  

O30  Funaoka  

Functionality  Control  of  Native  Lignins  by  the  Combination  of  Self-­‐  and  Cross   Condensations   A  Kinetic  Study  on  the  Conversion  of  Sucrose  to  Hydroxymethylfurfural  and   Levulinic  Acid   Low-­‐Cost  Ionic  Liquids  for  the  Delignification  of  Lignocellulosic  Biomass  

O31  Heeres   O32  Hallett   O33  Slattery   O34  Bogel-­‐Łukasik  

Cheap,  readily  available  ionic  liquids  for  the  pre-­‐treatment  of  lignocellulosic   materials   Lignocellulosic  Biomass  Fractionation  with  Ionic  Liquids  

O35  Kamimura    

Use  of  Ionic  liquids  in  Developing  a  New  Method  for  Feedstock  Recycling  

O36  Desai  

Extraction  of  Essential  Oil  from  the  Leaves  of  Lemongrass  using  Novel  Extraction   Techniques   New  Developments  In  Enantioselective  Alkene  Carbonylation  

O37  Clarke   O38  Hisaeda   O39  Hayes   O40  Masui   O41  Whiting     O42  Kumar   O43  J-­‐G  Liu   O44  Chuck  

Bioinspired  Catalysts  with  Cobalt  Complexes  and  Photosensitizers:  Lessons  from   Vitamin  B12-­‐dependent  Enzymes   Green  Activation  of  Carboxylic  Acids  for  Amide  Bond  Formation   Direct  synthesis  of  Dimethyl  Carbonate  from  CO2  and  MeOH  Catalyzed  by     Sn(Ot-­‐Bu)4  with  Acid-­‐Base  Additives,  and  its  Reaction  Mechanism   Catalytic  explorations  involving  boronates  and  boronic  acids   Metal  Phthalocyanines:  Biomimetic  Catalysts  for  Selective  and  Sustainable   Organic  Synthesis   Bio-­‐inspired  Noble-­‐metal-­‐free  Electrocatalysts  for  Oxygen  Reduction  Reaction  

O46  Hunt  

Renewable  Liquid  Fuels  Produced  by  an  Oleaginous  Yeast  Grown  on  Waste   Resources  in  Low-­‐Cost  Non-­‐Sterile  Conditions   Double  Acceptors  without  COOH  as  Conjugating  Anchor  for  Highly  Efficient  Dye-­‐ Sensitized  Solar  Cells   The  Importance  of  Elemental  Sustainability  and  Recovery  

O47  Titrici  

Biomass-­‐derived  Waterborne  Carbons  for  Renewable  Energy  Applications  

O48  Wang     O49  Okuma  

Efficient  production  and  upgrading  of  5-­‐hydroxymethylfurfural  into  liquid   biofuels   Green  synthesis  of  2-­‐aryl-­‐2-­‐oxazolines  

O50  Forder  

Novel  Routes  to  the  Controlled  Production  of  Polylactide  Copolymers  

O51  T  Liu  

CO2-­‐Assisted  Manipulation  of  Isotactic  Poly-­‐1-­‐butente  Crystal  Modification  

O52  Scott  

Sustainable  Functional  Materials  Derived  from  Cellulose  

O53  Thielemans  

Benign  production  of  polysaccharide  aerogels  through  aqueous  nanoparticle   assembly  

O45  Hua  

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    O54  Camp   O55  Pilkington     O56  Thomas   O57  Iskra   O58  Bianco   O59  Zhu   O60  Sánchez-­‐Vicente  

Harnessing  the  Reducing  Potential  of  Renewable  Sugars  to  Power  Catalytic   Processes   Ensuring  the  Sustainability  of  Artemisinin  Production  from  Artemisia  Annua   TBA   HCl-­‐Catalyzed  Oxidative  Iodination  with  Iodine  and  Hydrogen  Peroxide  –   Incidence  of  Iodine(I)  Reagents   Preliminary  Studies  of  CALB-­‐Catalyzed  Acetylation  of  α-­‐Tetralol  in  the  Ionic   Liquid  [OMPyrr][NTf2]  under  Microwave  Irradiation.   Catalytic  Conversion  of  Methanol  to  Aromatics  with  Modified  zeolite  ZSM-­‐5  

O63  Gallou  

Surface  Modification  of  Mesoporous  Silica  SBA-­‐15  with  Aminosilanes  Using   Supercritical  Carbon  Dioxide   Efficient  Decomposition  of  Perfluorinated  Ionic  Liquid  Anions  Using  Hot  Water   with  Iron:  An  Essential  Step  in  Recovery  of  Fluorine  Component  from  the  Ionic   Liquid  Waste   Synthesis  of  Glycerol  Carbonate  From  Glycerol  and  Dimethyl  Carbonate  Using   CaO  :  Identification  of  Active  Catalyst  Form     Early  Process  Research:  An  Opportunity  for  Advances  in  Green  Chemistry  

O64  Sneddon  

Green  &  Sustainable  Chemistry  at  GSK  –  Tools  and  Practice  

O65  Gordon  

A  Methodological  Approach  To  Sustainable  Catalytic  Processes  

O66  McKechnie  

Life  Cycle  Environmental  and  Cost  Assessment  of  Ethanol  as  a  Chemical   Intermediate   Wastes  In  The  Way  Towards  A  Green  Economy  

O61  Hori  

O62  Hubertson   Simanjuntak  

O67  Martin-­‐Luengo   O68  Bogel-­‐Łukasik   O69  Hou   O70  Prechtl     O71  Marr   O72  Gathergood   O73  Croft   O74  Harper   O75  Neumann  

O76  Glueck   O77  Liese   O78  Z  Liu   O79  Wilson  

Green  metrics  of  bio-­‐based  isoprene  and  other  fuel-­‐like  products  from  animal   fats   The  Immobilization  of  Nano-­‐catalysts  in  Alternative  Reaction  Media:  Application   in  Selective  Hydrogenation   C-­‐C-­‐bond  Cleavage  and  C-­‐N-­‐bond  Formation  Reactions  with  Recyclable   Nanoscale  Cu2O-­‐Catalyst  in  Ionic  Liquids   Lowering  the  Activation  Barrier  to  Bio-­‐renewables:  Ionic  liquids  and  Catalytic   Ionogels   The  Search  for  Safer  Chemicals:  Combined  Catalyst  Performance,  Biodegradation   and  (Eco)toxicity  Studies   Getting  the  Picture:  Interactions  and  Entropy  in  Ionic  Liquids   Getting  the  reaction  outcomes  you  want  in  ionic  liquids:  Towards  solvent-­‐ controlled  reactivity   Degradability  of  ionic  liquids  -­‐  Systematic  investigations  on  aerobic  and   anaerobic  biodegradability  and  hydrolytical  stability  of  ionic  liquid  cations  and   anions  -­‐  contributions  to  a  sound  hazard  assessment   Biocatalytic  Carboxylation  and  Asymmetric  Hydration  of  Aromatics  –  Two   'Green'  Strategies  from  the  Biosynthetic  Toolbox   Increase  of  Sustainability  in  (Bio)Chemical  Synthesis  by  Reaction  Engineering   Lewis  Acid-­‐Promoted  Glycerol  Conversion  to  Lactic  Acid  and  Formic  Acid     Tailored  Solid  Acid  Catalysts  for  Biomass  Conversion  

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    O80  Grau  

Hop  for  Green  Polymer  Materials  

O81  

TBA  

O82  Zuin  

Green  Chemistry  in  Teacher  Training:  a  Brazilian  Case  Study  

O83  Mitchener  

New  Product  Development  For  Green  Manufacturing  

O84  Koel  

The  influence  of  green  chemistry  on  analytical  chemistry  

O85  Xu  

Operando  Raman  spectroscopy  and  kinetic  study  of  low-­‐temperature   CO  oxidation  on  an  α-­‐Mn2O3  nanocatalyst   Supercritical  Water  in  Analytical  Chemistry:  A  Green  Solvent  to  Manipulate   Fused-­‐Silica  Capillaries  for  Separation  Methods   TBC  

O86  Roth   O87   O88  Goto   O89  Kawanami   O90  M  Zhang   O91  Velilla-­‐Pérez     O92  Joshi     O93  

Hybrid  Extraction  Process  for  Phytochemicals  Using  Supercritical  CO2  and  Liquid   Water   Simple  C-­‐O  bond  cleavage  of  diaryl  ether  in  scCO2/water  biphasic  medium  with   H2   Synthesis  and  characterization  of  MnOx–CeO2  catalyst  by  supercritical  anti-­‐ solvent  precipitation   Quantitative  Analysis  of  Products  from  Lignin  Depolymerisation  in  High   Temperature  Water   Levulinic  Acid  from  Cellulose  by  Hydrothermal  Treatment  Using  Zirconia  as  a   Solid  Acid  Catalyst   TBC  

                       

 

 

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List  of  Contributions  –  Poster  Presentations     Abstract  Number  

Details  

P1  Park   P2  Pham  

Fabrication  of  Poly(g-­‐glutamic  acid)  Monolith  by  Thermally  Induced  Phase   Separation  and  Salt  Leaching  Technique   Oxidative  N-­‐Demethylation  of  Tropane  Alkaloids  Using  a  FeIII-­‐TAML  Catalyst  

P3  Wagner  

Conversion  of  sterol-­‐rich  microbial  oils  into  transportation  fuels  

P4  Martín  

Microwave-­‐Assisted  Alkali  Pretreatment  and  Saccharification  of  Rice  Hulls  and   Tobacco  Waste   Characterization  of  Silica  Aerogels  Prepared  in  Supercritical  CO2  

P5  Ozcan   P6  Wang  

P10  Antônio  

Manganese  Oxide/Graphene  nanowires  as  Effective  Catalysts  for  Rechargeable   Li-­‐  O2  Battery   20%  Cs-­‐substituted  Dodecatungstophophoric  acid  (Cs-­‐DTP)  supported  on  Silica   Meso  Cellular  Foam  for  acetylation  of  anisyl  alcohol   Electrochemical  regulation  of  bacterial  metabolism  for  developing  novel  energy   conversion  systems   Waste  to  Wealth:  Renewable  lipids  from  Rhodotorula  glutinis  cultured  on  waste   resources   Green  synthesis  of  2-­‐aryl-­‐2-­‐oxazolines  

P11  Giray  

Green  and  Efficient  Synthesis  of  Xanthanes  in  Supercritical  Diethylether  

P12  Whiffin  

Developing  a  palm  oil  substitute  from  yeast  cultivated  on  waste  resources  

P13  Donnelly  

Determination  of  the  Physical  Properties  and  the  Subsequent  Viability  of  a  Host   of  Potential  Alternative  Aviation  Fuels   REACH  and  its  Impact  –  Towards  Greener  Solvents  

P7  Bhadra   P8  Matsuda   P9  Sargeant  

P14  Fisk   P15  Pinazo   P16  Mikami   P17  Sun  

Sustainability  Metrics  of  Fermentative  Succinic  Acid  Production  and  Its  One-­‐Pot   Catalytic  Valorization  into  γ-­‐Butyrolactone  over  Metal  Supported  Catalysts   Reduction  of  Nitrate  with  Formic  Acid  over  Pd-­‐Sn/TiO2  Catalyst  

P23  Choi  

Poly(vinyl  alcohol)/Sodium  Alginate  Blend  Monolith  via  Thermally  Impacted   Non-­‐  Solvent  Induced  Phase  Separation   Two  in  One  -­‐  New  Thiolate  Iron  Porphyrins  That  Catalyze  Both  Photocathodic   Reduction  of  CO2  and  Anodic  Oxidation  of  Hydrocarbons   Hybrid  Acid  Catalyzed  Direct  Methyl  Levulinate  Synthesis  from  Woody  Biomass   Resources   Separation  of  Complex  Mixtures  using  Supercritical  CO2  with  Solid  Adsorbents  –   an  Economic  Large  Scale  Alternative  to  Supercritical  Fluid  Chromatography   Comparison  of  Three  Vegetable  Oils  for  Biodiesel  Production  with  Supercritical   Fluids   Biodiesel  Production  Using  Supercritical  Methanol  in  a  Continuous  Reactor:   Effect  of  Carbon  Dioxide  Cosolvent   Reduction  of  Petrochemical  Waste  through  Nanotechnology  

P24  Yoda  

Polymer  foam-­‐silica  nanocomposites  for  green  thermal  insulating  materials  

P25  Masuda  

Real-­‐time  Analysis  of  Sc(III)-­‐Catalyzed  Hydroxymethylation  Reactions  in  Water   Using  DART®-­‐MS  

P18  Li   P19  Nemoto   P20  Marriott   P21 García-­‐Jarana     P22  Casas  

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    P26  Liu   P27  Fuku   P28  Parker   P29  Mashkovsky  

P30  Riekkola   P31  Morofuji   P32  Niikuni   P33  Norcott   P34  Gök   P35  Rautiainen     P36  Fukuda   P37  Jenkins   P38  Nanayakkara     P39  Shaheen  

A  Novel  Fluidized  Bed  Dryer  for  Biomass  Drying  Based  on  Self-­‐Heat   Recuperation  Technology   Enhanced  Catalysis  by  Localized  Surface  Plasmon  Resonance  of  Size-­‐  and  Color-­‐ controlled  Ag  Prepared  Using  Microwave  and  Mesopore  Structure   Novel  Catalysts  for  the  Controlled  Depolymerization  of  Lignin   Effect  of  Alloying  and  Preparation  Methods  on  the  Performance  of  Pd-­‐ supported  Bimetallic  Catalysts  in  Stereoselective  Semihydrogenation  of   Diphenylacetylene   Microwave  Assisted  Dehydration  of  Sorbitol   C−H  Amination  and  C−H  /  C−H  Cross-­‐Coupling  of  Aromatic  Compounds  using   Electrochemical  Oxidation   A  valuation  of  environmental  cost  reduction  by  employing  EV/HEV  technology   for  regional  CDM(Clean  Development  Mechanism)   Extending  On-­‐Water  Catalysis  in  Organic  Synthesis   Impregnation  of  Benzoic  Acid  onto  Modified  Bentonite  by  Using  Supercritical   CO2   Base-­‐free  Oxidation  of  Glucose  on  Gold  Catalysts   Preparation  of  Layered  Nano  Composites  by  Self  Assembly  Reaction  of  Amino   Acid  and  Metal  Hydroxide   Development  and  testing  of  alternative  fermentation  fuels  for  aviation  and  road   transport   Depolymerization  of  Lignin  Using  Redistribution  Mechanism  in  Green  Solvents  

P44  Kosa  

Zinc  monoglycerolate  (ZMG)-­‐catalyzed,  solvent  free  synthesis  of  cyclic   carbonates  from  1,2-­‐polyols  for  application  in  the  osmotic  protection  of  clays   Hydrothermal  Carbonization  of  Sugars  and  Rice  Straw  in  the  Presence  of  Sulfuric   Acid   Ozonization  of  Olefins  with  High  Purity  Ozone  in  Carbon  Dioxide  and  Study  of   their  Safety   Highly  Efficient  Endo-­‐  and  Enantioselective  [3+2]  Cycloadditions  of  α-­‐Amino   Esters  to  Olefins  Catalyzed  by  Cu(I)  Amide  Complexes   Novel  Green  Reaction  Process  Using  Pulsed  Discharge  Plasma  at  Gas-­‐Liquid   Interface   Preparation  and  surface  characterization  of  CuO  and  Fe2O3  catalyst  

P45  d’Alessandro  

Lignin  stabilised  Pd  and  Pt  nanoparticles  in  catalytic  reduction  reactions  

P46  Agoudjil     P47  Wang  

Synthesis  and  characterization  of  polysaccharide  /  polysiloxane  Biohybrids  and   biocomposites   Composition  of  black  sesame  oil  extracted  by  scCO2  and  its  nutraceutical   applications   A  Comparative  Evaluation  Of  Microwave-­‐Integrated  Soxhlet  And  Conventional   Soxhlet  Extraction  Methods  For  The  Hypoglycemic  And  Hypolipidaemic   Potential  Of  Jordanian  Psidium  guajava  Fruit  Peel  Extracts   Aluminum-­‐Catalyzed  Direct  Substitution  of  Alcohols,  Including  Electron   withdrawing  Group  Substituted  Benzhydrols     Recycling  CO2  into  fuels  with  high-­‐pressure  synthesized  photoelectrocatalysts  

P40  Watanabe   P41  Yoshida   P42  Yoshimoto   P43  Hayashi  

P48  Issa  

P49  Nakahara  

P50  Tostón   P51  Rechak  

Pharmacokinetics  behavior  of  verapamil  after  intravenous  and  oral   administration  of  valproic  acid  in  rats  by  HPLC  

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    P52  Clough   P53  Ohtaka   P54  Yang   P55  Ning  

Decomposition  of  Imidazolium  Carboxylate  Ionic  Liquids:  Trends,  Mechanisms   and  Long-­‐Term  Thermal  Stability   A  Recyclable  “Boomerang”  Linear  Polystyrene-­‐Stabilized  Pd  Nanoparticles  for  C-­‐ C  Coupling  Reaction  in  Water   Efficient  Absorption  of  SO2  by  Functionalized  Ionic  Liquids  

P60  Peng  

Dehydration  of  Carbohydrates  to  5-­‐hydroxymethylfurfural  in  Ionic  Liquids   Catalyzed  by  Tin(IV)  Phosphonate  and  Zirconium  Phosphonate   Efficient  Synthesis  of  Cyclic  Carbonates  from  CO2  and  Epoxides  Catalyzed  by   KI/cucurbit[6]uril   Efficient  Synthesis  of  Quinazoline-­‐2,4(1H,3H)-­‐diones  from  CO2  and  2-­‐   Aminobenzonitriles  in  Water  without  any  Catalyst   Phase  Equilibrium  Calculation  of  Supercritical  Fluid-­‐Solid  Systems  by   Considering  the  Molecular  Clusters  as  a  Phase   Immobilization  of  Ru  Nanoparticles  on  the  Metal-­‐Organic  Framework  with  both   Micropores  and  Mesopores  using  Supercritical  Fluids   n Study  on  the  Fragmentation  Pathway  of  Aconitine  by  ESI-­‐MS  

P61  Lester  

A  Multifaceted  Catalysis  Approach  to  Nitrile  Activation  

P62  Restani  

Multifunctional  PURE-­‐type  dendrimers:  Sustainable  Strategies  to  Improve  Their   Pharmacokinetic  Performance   Chemical  recycling  of  the  foamed  phenol  resin  by  solubilization  in  high  -­‐   temperature  fluids   Applications  of  CO2  in  Novel  Reaction  Work-­‐up  Procedures  

P56  Shi   P57  Ma   P58  Hou   P59  Wu  

P63  Sugeno   P64  Kulik   P65  Bishopp   P66  Atmaca   P67  Seth   P68  Woodward   P69  Matsuda  

Continuous  Conversion  and  Separation  of  Liquid-­‐Liquid  Biphasic  Reaction   Systems   Efficient  Green  Procedures  for  Preparation  of  Novel  Zinc  Phthalocyanines   Containing  Alkynyl  Moieties   Generic  Method  to  Prepare  Ultra-­‐small  Transition  Metal  Nanoparticles  And   Their  Catalytic  Applications   The  Enzymatic  Degradation  of  Lignin  

P72  Ashworth  

Isomerization  of  Glucose  with  Solid  Base  Catalysts  in  Ionic  Liquid  -­‐Water   Solutions   Optimization  of  Biocatalysed  Kinetic  Resolutions  in  the  Synthesis  of  Some   Enantiopure  Hydroxy-­‐N-­‐Heterocycles   Heck  Strategy  to  Neoflavonoid  Synthesis  Using  Solid  Supported  Pd(0)   Nanoparticles  as  Recyclable  Heterogeneous  Catalyst   Interactions  within  the  Choline  Chloride  –  Urea  Deep  Eutectic  Solvent  

P73  Portela  

Supercritical  water  gasification  of  cellulosic  wastes  

P74  Hao  

P76  Starkey  

Carbon  Sequestration  through  Mineralization  Process  by  Using  Magnesium   Chloride  Solution   Sustainable,  Mild  and  Efficient  p-­‐Methoxybenzyl  Ether  Deprotections  Utilising   Catalytic  DDQ   Continuous  Hydrothermal  Synthesis  of  Novel  Nanomaterials  

P77  Wang  

Hydrogen  Transfer  Initiated  Dehydration  of  1,3-­‐propanediol  in  Ionic  Liquids  

P78  Pérez  

Green  Chemistry  at  Addis  Ababa  University  

P79  de  Ory  

Pressured  Alkaline  Peroxide  Pretreatment  For  Enhancing  The  Enzymatic   Hydrolysis  of  Rice  Hulls  

P70  Piccolo   P71  Sharma  

P75  Walsh  

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    P80  Noé   P81  Gammons   P82  Murai  

A  Versatile  Pinner  Preparation  of  Oerthoesters.  The  model  Case  of   Trimethylorthobenzoate   Investigating  Ionic  Liquids  For  The  Pre-­‐Treatment  Of  Lignocellulosic  Materials  

P85  Bayliss  

Multistep  structural  control  of  native  lignins  ~Functionality  control  and   application  of  lignins  by  acylation~   Solid  Acid  Catalyst  Generated  from  Sulfonation  of  Coffee  Residue  Activated   Carbon  for  Esterification  of  Caprylic  Acid   Standardization  of  environmental  designs  input  into  lignocellulosics  -­‐  From   wood  to  universal  and  functional  composites  under  the  basic  environment     Greener  Synthesis  of  Metal  Organic  Frameworks  in  High  Temperature  Water  

P86  Sanchez-­‐Segado  

Concentration  of  Rare-­‐Earth  Oxides  from  Titaniferous  Sands  

P87  Aoyagi  and   Funaoka   P88  Chauhan  

Thermal  Properties  of  Lignophenols  with  Different  Grafting  Phenols  

P89  Foltran  

On  the  chemical  fixation  of  supercritical  carbon  dioxide  with  epoxides  catalyzed   by  ionic  liquids:  A  combined  spectroscopic  and  computational  study.     Supercritical  Fluid-­‐Assisted  Hydrogenation  of  Wastes  to  Fuel-­‐Like  Products  

P83  Ngaosuwan     P84  Yukari  Uehara  

P90  Morais   P91  Uyama   P92  Zhang   P93  Martin-­‐Luengo   P94  Wang   P95  Xi   P96  Clarke   P97  Schmitz   P98  Grignard   P99  Makhijani   P100  Kumar   P101  Bhatt   P102  Quraishi   P103  Vanamudan   P104  Muhamad   P105  Pedotti   P106  Raghasudha   P107  Gimeno-­‐Fabra  

Bioinspired  Biomass-­‐based  Green  Particulates  for  Industrial  Applications  

CO2  Uptake  over  Highly  Porous  N-­‐doped  Activated  Carbon  Monoliths  Prepared   by  Physical  Activation   Effect  of  MoO3  on  the  heat  resistant  performance  of  nickel  based  MCM-­‐41   methanation  catalysts   Advanced  Uses  of  Wastes  Towards  a  Bio  Based  Economy   The  Production  of  Levulinic  Acid  from  Cellulose  Catalyzed  by  Niobium-­‐based   Porous  Solid  Acid  and  its  Upgrading  to  γ-­‐Valerolactone   Catalytic  conversion  of  cellulose  into  isosorbide  over  mesoporous  niobium   phosphate-­‐based  heterogeneous  catalyst  via  a  sequential  process   X-­‐ray  Photoelectron  Spectroscopy  of  Ionic  Liquids  and  Ionic  Liquid  Metal   Solutions   Asymmetric  hydrogenation  of  challenging  substrates  using  SILP/scCO2-­‐Systems   in  continuous-­‐flow   Toward  the  synthesis  of  cyclic  carbonate  by  chemical  fixation  of  carbon  dioxide   onto  epoxides,  a  kinetic  study  by  Raman  spectroscopy  under  pressure   Use  of  Pectin  as  Green  Additive  in  Conversion  of  Non-­‐biodegradable  Polythene   into  Degradable  one   Conversion  of  Non-­‐biodegradable  Polythene  into  degradable  one  by  using   Green  additivies   Removal  Of  Chromium(VI)  From  Aqueous  Solutions  And  Chrome-­‐Plating   Effluents  Using  Zirconium  Phosphate  Impregnated  Chitosan   Development  and  Electrochemical  Investigation  of  Green  Corrosion  Inhibitors   Green  Facile  Synthesis  Of  Guargum  Stabilised  Silver  Nanoparticles  And  Their   Application  in  the  Degradation  Of  Environmental  Pollutants   Kinetic  studies  and  performance  parameter  of  acid  digestion  of  bioethanol   production  from  agricultural  waste   Mild  hydrolytic  cleavage  of  α-­‐  ferrocenylalkyl-­‐O-­‐methyl  ethers   Synthesis  and  Characterization  of  Co-­‐Cr  Nano  ferrites  by  Citrate-­‐Gel  Auto   combustion  Green  method   Instant  MOFs:  continuous  synthesis  of  MOFs  by  rapid  solvent  mixing  

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    P108  Ghafari  

Kinetic  Study  of  Phenol  Biodegradation  by  a  Microalgae-­‐Bacterium  Consortium  

P109  Mortezayikia     P110  Shridharan  

Carbon  Dioxide  Biofixation  using  Microalgae  in  Hollow  Fiber  Membrane  Photo-­‐   Bioreactors  (HFMPB)   Palm  Oil  Mill  Effluent  (POME)  Polishing  Using  Activated  Carbon  and  Novel   Ultrasound  Cavitation  Technology   Synthesis  of  Ionic  Liquids  in  an  Annular  Micro-­‐reactor  -­‐  Experimental  and   Theoretical  Studies  for  1-­‐ethyl-­‐3-­‐methylimidazolium  ethylsulfate   A  General  Continuous  Flow  Hydrothermal  Route  to  Metal  Sulphide   Nanoparticles   Investigating  the  Mechanical  Properties  of  Myglamophae  Spider  Silk  

P111  Lange   P112  Dunne   P113  Hindley   P114  Housley  

P115  Blundell   P116  Bogel-­‐Łukasik   P117  Amara  

P118  Duma   P119  Miazek   P120  Schofield   P121  Bellamy   P122  Skilton   P123  Prechtl  

The  Use  of  Dimensionless  Groups  to  Analyse  the  Mixing  of  Streams  with  Large   Density  Differences  and  the  Application  to  the  Oxidation  of  p-­‐Xylene  in  Sub-­‐  and   Supercritical  Water.   X-­‐ray  Photoelectron  Spectroscopy  of  Phosphonium  Ionic  Liquids   Green  metrics  of  bio-­‐based  isoprene  and  other  fuel-­‐like  products  from  animal   fats   Advances  in  challenging  catalytic  continuous  flow  heterogeneous   hydrogenations        Protic  Amino  Acid-­‐based  Ionic  Liquids:  A  Green  Synthetic  Approach   Growth  of  Chlorella  in  vanillin  enriched  medium     A  Process  for  the  Production  of  Methacrylic  Acid     Cleaner  continuous  photo-­‐oxidation  in  scCO2  using  singlet  oxygen  and  fluorous   biphasic  catalysis   AUTOMATED  RAPID  SELF  OPTIMISING  REACTORS     Opportunities  for  Hydrogen  Storage  Material  Blends:  The  Role  of  Ionic  Liquids  

   

 

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Getting  to  Nottingham     These  notes  are  provided  In  addition  to  the  general  directions  that  may  be  accessed  on  the   webpages  of  the  University  of  Nottingham:     http://www.nottingham.ac.uk/about/visitorinformation/information.aspx  

  Your  destination  is  University  Park,  directions  can  be  found  here:    

http://www.nottingham.ac.uk/about/visitorinformation/mapsanddirections/universityparkcampus.aspx  

  More  information  about  travel  to  Nottingham  and  vacation  activities  that  you  may  consider   can  be  found  on  the  Experience  Nottinghamshire  webpage:     http://www.experiencenottinghamshire.com/  

   

IMPORTANT  TRAVEL  INFORMATION     For  those  travelling  by  car:  It  is  recommended  that  the  University  is  approached  from   junction  25  of  the  M1  not  junction  24,  as  there  are  major  roadworks  on  the  A453  between   the  J24  of  the  M1  and  Nottingham.           For  those  travelling  by  train:  There  is  major  signalling  work  due  to  be  carried  out  at   Nottingham  railway  station  this  summer.    As  a  result,  Nottingham  railway  station  will  be   closed  and  national  rail  services  will  not  service  the  city.    Railway  journeys  will  terminate  as   East  Midlands  Parkway  which  is  nearby.       Tickets  to  Nottingham  will  still  be  valid,  and  a  free  replacement  bus  service  will  be  operating   regularly  between  East  Midlands  Parkway  and  Nottingham  to  ensure  that  there  is  as  little   disruption  to  your  journeys  as  possible.       When  you  arrive  at  Nottingham  railway  station  an  efficient  taxi  service  will  be  available  from   the  signposted  rank,  the  cost  will  be  cost  between  £6  and  £8  depending  on  traffic.         The  address  that  you  will  need  to  give  to  the  taxi  driver  is  as  follows.  

Orchard Hotel, University Park, The University of Nottingham, NG7 2RJ. or Hugh Stewart Hall, University Park, The University of Nottingham, NG7 2QX.     Updated  04/08/2013  12:58  

 

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    From  East  Midlands  Airport  (Local  connections  to  EU  and  the  UK)     From  East  Midlands  Airport  you  can  take  the  Trent  Barton  Indigo  Skylink  bus  to  Nottingham,   which  leaves  every  30  minutes  and  stops  at  Abbey  Street  (Circled  as  B2  on  map),  about   400m  from  the  Chemistry  Department.  Buses  leave  from  outside  the  Airport  Arrivals  hall,   Busses  are  regular  and  a  timetable  may  be  downloaded  at  the  following  link.     https://www.trentbarton.co.uk/services/skylinknottingham  

  You  may  also  wish  to  take  a  taxi  from  the  rank  on  the  terminal  forecourt.    The  cost  of  a  one   way  journey  is  approximately  £20.     The  address  that  you  will  need  to  give  to  the  taxi  driver  is  as  follows:  

Orchard Hotel, University Park, The University of Nottingham, NG7 2RJ. or Hugh Stewart Hall, University Park, The University of Nottingham, NG7 2QX.

 

 

 

   

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