2010 Page 1 of 5

Safety Data Sheet in Accordance with regulation 453/2010 Page 1 of 5 Date of issue: 04.05.2015 Replaces Data Sheet of: --"*" alterations as compared...
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Safety Data Sheet in Accordance with regulation 453/2010

Page 1 of 5

Date of issue: 04.05.2015 Replaces Data Sheet of: --"*" alterations as compared to previous version; n.ap. = not applicable; n.av. = not available

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1

1.2 1.3 1.3.1 1.3.2 1.4

Product identifier Trade Name: Dermalux Alcohol Tester II n.av. Article No.: 00000661 Preparation No.: n.ap. Registration No.: Relevant identified uses of the substance or mixture and uses advised against Use: cosmetics Details of the supplier of the safety data sheet Address of the Company / Supplier by order of KBD GmbH D-69469 Weinheim InnoCent International GmbH, Reutackerstraße 22D, D - 79591 Eimeldingen Telephone: +49 – 7621-422 338-0, Telefax: +49 – 7621-422 338-3, E-Mail: n.av. Responsible for the data sheet: CoSiChem AG, Ernst-Lemmer-Straße 27, D - 35041 Marburg, [email protected] Emergency telephone number Emergency - Telephone of Company / Undertaking Information Centre Specialising in Symptoms of Poisoning Telephone: +49 – 7621-422 338-0 (8:30 – 16:30) Telephone: +44 870 600 6266

SECTION 2: Hazards identification 2.1

2.2

Classification of the substance or mixture Classification and labelling according to Directive 1272/2008/EC: Flam. Liq. 2 H225 Classification and labelling according to Directive 1999/45/EC: Highly flammable R 11 Label elements Classification according to 1272/2008/EC: Yes. Applicable Exemptions: No. Signal word(s): Danger Component(s):

Hazard pictogram(s):

H - Phrases: H225: Highly flammable liquid and vapour. P - Phrases: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P262: Do not get in eyes, on skin, or on clothing. P403+P235: Store in a well-ventilated place. Keep cool. P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Additional Markings: None. The above mentioned labelling is valid for distribution to industrial user. 2.3

Other hazards In use, may form flammable/explosive vapour-air mixture. This mixture contains no substances which are assessed to be PBT or vPvB. Solvents may degrease the skin.

SECTION 3: Composition/information on ingredients 3.1 3.2

Substances n. ap. Mixtures Chemical Characterisation: Mixture alcoholic solution Dangerous Ingredients: CAS - No. Index - No. EC - No. 64-17-5

603-002-00-5

200-578-6

Text of R-/H- phrases: see section 16

Material Ethanol REACH_01-2119457610-43-xxxx

m% - range 60 - 75%

Symbol R / H - phrases F GHS02

R 11 H225

Safety Data Sheet in Accordance with regulation 453/2010

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Trade Name: Dermalux Alcohol Tester II Company / Supplier: InnoCent International GmbH, Reutackerstraße 22D, D - 79591 Eimeldingen Telephone: +49 – 7621-422 338-0, Date of issue: 04.05.2015 Replaces Data Sheet of: ---

SECTION 4: First aid measures 4.1 4.1.1 4.1.2 4.1.3 4.1.4 4.2 4.3

Description of first aid measures Inhalation: Move to fresh air in case of accidental inhalation of fumes from overheating or combustion. If symptoms persist, call a physician. Skin Contact: Wash off with soap and plenty of water. Eye Contact: In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Ingestion: Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting. Consult a physician. Show this safety data sheet to the doctor in attendance. Most important symptoms and effects, both acute and delayed Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: Firefighting measures 5.1 5.1.1 5.1.2 5.2 5.3 5.3.1 5.3.2

Extinguishing media Suitable Extinguishing Media: Use dry chemical, CO2, water spray or "alcohol" foam. Extinguishing Media to Avoid: None. Special hazards arising from the substance or mixture In the event of fire the following can be released: Carbon oxides Advice for firefighters Special Protective Equipment: Wear positive pressure self-contained breathing apparatus. Wear full protective clothing. Additional Information: In the event of fire, cool tanks with water spray. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures 6.1 6.2 6.3 6.4

Personal precautions, protective equipment and emergency procedures See chapter 8.2.2 Keep away from sources of ignition - No smoking. Environmental precautions Do not discharge into surface waters / groundwater. Inform responsible authorities in the case of accidental release of larger quantities. Methods and material for containment and cleaning up Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Dispose of wastes in an approved waste disposal facility. Reference to other sections None.

SECTION 7: Handling and storage 7.1 7.1.1

7.1.2

Precautions for safe handling Precautions for Safe Handling: Avoid contact with eyes and skin. Do not inhale vapours. Do not eat, drink or smoke during work. Remove contaminated, saturated clothing immediately. Wash hands before breaks and after work. Precautions in Case of Fire and Explosion: Keep away from sources of ignition, do not smoke. Take measures to prevent the build up of electrostatic charge. Pay attention to flashback.

Safety Data Sheet in Accordance with regulation 453/2010

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Trade Name: Dermalux Alcohol Tester II Company / Supplier: InnoCent International GmbH, Reutackerstraße 22D, D - 79591 Eimeldingen Telephone: +49 – 7621-422 338-0, Date of issue: 04.05.2015 Replaces Data Sheet of: --7.2 7.2.1 7.2.2 7.2.3 7.3

Conditions for safe storage, including any incompatibilities Storage Instructions: Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in an area equipped with solvent resistant flooring. Protect from frost, heat and sunlight. Store away from: Do not store together with strong oxidizing agents. Further Information on Storage Conditions: Provide adequate ventilation. Vapours are heavier than air and may spread along floors. Specific end use(s) n.av.

SECTION 8: Exposure controls/personal protection 8.1

8.2 8.2.1 8.2.2 8.2.2a 8.2.2b

8.2.2c 8.2.2d 8.2.2e 8.2.3

Control parameters Material

Limit Value

Ethanol

500 ppm | 960 mg/m³

Exposure controls Appropriate engineering controls Provide appropriate exhaust ventilation at machinery. Individual protection measures Respiratory Protection: Not required under normal use In case of insufficient ventilation, wear suitable respiratory equipment. Recommended filter type: A Not required under normal use. Hand Protection: Repeated or prolonged exposure: protective gloves complying with EN 374. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. In case of contact through splashing: safety glasses Eye Protection: Long sleeved clothing Skin Protection: Observe wearing time limits: Further Information: Environmental exposure controls: n.av.

SECTION 9: Physical and chemical properties 9.1 9.1.1

Information on basic physical and chemical properties Form: liquid Colour:

Odour: alcoholic Odour threshold: n.av.

9.1.2 9.1.3 9.1.4 9.1.5 9.1.6 9.1.7 9.1.8 9.1.9 9.1.10 9.1.11 9.1.12 9.1.13 9.1.14 9.1.15 9.1.16 9.1.17 9.1.18 9.2

pH-value, undiluted: Boiling point / Boiling - range (°C): Flash point (°C): Flammability (EEC A10/A13): Ignition temperature (°C): Autoflammability (EEC A16): Oxidising properties: Explosion hazard: Explosion limits (Vol.%) lower: Vapour pressure: / Vapour density (Air = 1): Density (g/ml): Solubility (in Water): Partition coefficient, n-Octanol / Water: Viscosity: Solvent content (m %): Thermal decomposition (°C): Evaporation rate: Other information n.av.

7, pH-value, 1% aqueous solution: n.av. n.av., Melting point / Melting range (°C): n.av. 21, closed cup No. n.av. No. No. No. 3,5 (Ethanol), upper: 15 (Ethanol) n.ap. / Vapours are heavier than air n.av. miscible n.av. n.av. 60 – 75 n.av. n.av.

Safety Data Sheet in Accordance with regulation 453/2010

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Trade Name: Dermalux Alcohol Tester II Company / Supplier: InnoCent International GmbH, Reutackerstraße 22D, D - 79591 Eimeldingen Telephone: +49 – 7621-422 338-0, Date of issue: 04.05.2015 Replaces Data Sheet of: ---

SECTION 10: Stability and reactivity 10.1 10.2 10.3 10.4 10.5 10.6

Reactivity None. Chemical stability Stable under normal conditions. Possibility of hazardous reactions In use, may form flammable/explosive vapour-air mixture. Conditions to avoid Extremes of temperature and direct sunlight. Keep away from naked flames, hot surfaces and sources of ignition. Incompatible materials Incompatible with oxidizing agents. Hazardous decomposition products No decomposition if stored and applied as directed. To avoid thermal decomposition, do not overheat.

SECTION 11: Toxicological information 11.1 11.1.1 11.1.2

Information on toxicological effects Substances n. ap. Mixtures Acute Toxicity: Inhalation: Ingestion: Skin Contact: Irritation / corrosion (to skin / eye): Sensitisation: Carcinogenicity: Mutagenicity: Teratogenicity: Narcotic Effects:

n.av. n.av. n.av. Slight None. n.av. n.av. n.av. Inhalation of high vapour concentrations can cause CNSdepression and narcosis.

11.1.3 – Practical Experience 11.1.12 n.av. 11.1.13 Practical Experience Observations relevant for classification: None. Further Observations: Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Classification of the preparation has been done by calculation in accordance with EEC directives.

SECTION 12: Ecological information 12.1 12.2 12.3 12.4 12.5 12.6 12.6.1 12.6.2 12.6.3 12.6.4 12.6.5

Toxicity We have no quantitative data concerning the ecological effects of this product. Persistence and degradability No data is available on the product itself. Ethanol: Readily biodegradable. Bioaccumulative potential n.av. Mobility in soil n.av. Results of PBT and vPvB assessment This mixture contains no substances which are assessed to be PBT or vPvB. Other adverse effects COD-Value, mg/g: n.av. BOD5-Value, mg/g: n.av. AOX-Remarks: Not applicable. Significant Components: None. Other adverse effects: Not applicable.

Safety Data Sheet in Accordance with regulation 453/2010

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Trade Name: Dermalux Alcohol Tester II Company / Supplier: InnoCent International GmbH, Reutackerstraße 22D, D - 79591 Eimeldingen Telephone: +49 – 7621-422 338-0, Date of issue: 04.05.2015 Replaces Data Sheet of: --SECTION 13: Disposal considerations 13.1 Waste treatment methods 13.1.1 Recommendation: D 10

13.2 13.2.1 13.2.2

Waste - Code - No.: The Waste code should be assigned in discussion between the user, the producer and the waste disposal company.

In addition comply with the regional authorities. Contaminated Packaging Recommendation: Wash with suitable cleaner. Otherwise as described under Residues. Safe Handling: As described under Residues.

SECTION 14: Transport information ADR 14.1 14.2 14.3

14.4 14.5 14.6

14.7

UN number 1266 UN proper shipping name UN 1266 Perfumery products Transport hazard class(es) 3

Packing group II Environmental hazards

IMDG

IATA

1266

1266

Perfumery products

Perfumery products

3

3

II

II

No. Special precautions for user Transport category: 2 F-E, S-D Classification Code: F1 Hazard - No.: 33 LQ: 1L Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code n.av.

Packing Instructions (Passenger): 353 Packing Instructions (Cargo): 364

SECTION 15: Regulatory information 15.1 15.2

Safety, health and environmental regulations/legislation specific for the substance or mixture n.av. Chemical safety assessment : A chemical safety assessment has not been carried out.

SECTION 16: Other information Text of R / H phrases mentioned in Section 3 R 11: Highly flammable. H225: Highly flammable liquid and vapour. This datasheet has been compiled in accordance with EU regulation 453/201. The statements in this Material Safety Data Sheet were made to the best of our knowledge and are as accurate as possible. They are given for information only. They do not constitute a contractual guarantee of a product’s properties. They must neither be altered nor transferred to other products. Prepared by: CoSiChem AG, Ernst-Lemmer-Straße 23, D - 35041 Marburg, [email protected], +49-6421-886563 Receipt of Data: 10.04.2015, iig_0056