SAFETY DATA SHEET Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Denmark

SikaCor 6630 HS

SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Product name

: SikaCor 6630 HS

1.2 Relevant identified uses of the substance or mixture and uses advised against At present there is no complete information available on identified uses. When the data becomes available, it will be integrated into the safety data sheet. Product use : Corrosion protection. 1.3 Details of the supplier of the safety data sheet Manufacturer/Distributor

: Sika Danmark A/S Hirsemarken 5 3520 Farum Danmark : (0045) 48 18 85 85 : (0045) 48 18 84 96

Telephone no.: Fax no. e-mail address of person responsible for this SDS Emergency telephone number

: [email protected] : Giftlinjen (Bispebjerg Hospital) telefon 82 12 12 12

1.4 Emergency telephone number Supplier Telephone number : Giftlinjen (Bispebjerg Hospital) telefon 82 12 12 12

SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : Mixture Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Flam. Liq. 3, H226 Eye Irrit. 2, H319 Skin Sens. 1, H317 Repr. 2, H361fd (Fertility and Unborn child) STOT RE 2, H373 Aquatic Chronic 2, H411 The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended. Classification according to Directive 1999/45/EC [DPD] Europe The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification : R10 N; R51/53 Physical/chemical hazards : Flammable. Environmental hazards : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 16 for the full text of the R phrases or H statements declared above. Date of issue

: 15.10.2015.

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SECTION 2: Hazards identification See Section 11 for more detailed information on health effects and symptoms. 2.2 Label elements Hazard pictograms

Signal word Hazard statements

:

: Warning : Flammable liquid and vapor. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of damaging fertility. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects.

Precautionary statements Prevention

Response Hazardous ingredients

Supplemental label elements Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

: Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/ face protection. : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. : hexaboron dizinc undecaoxide Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%) 2-methylpropan-1-ol Pentamethyl piperidylsebacate : Not applicable. : Not applicable.

2.3 Other hazards Other hazards which do not result in classification

: None known.

SECTION 3: Composition/information on ingredients Substance/mixture Chemical family/ Characteristics

: Mixture : Coating of synthetic resin, containing solvent Classification

Product/ingredient name Identifiers naphtha (petroleum), hydrotreated heavy RRN: 01-2119457273-39 EC: 265-150-3 CAS: 64742-48-9 Index: 649-327-00-6 2-methoxy-1-methylethyl acetate RRN: 01-2119475791-29 EC: 203-603-9 CAS: 108-65-6 Date of issue

: 15.10.2015.

%

67/548/EEC

Type

Regulation (EC) No. 1272/2008 [CLP]

>=10 - =1 - =1 - =2.5 - 5.7 mg/l >15000 mg/kg 23.4 mg/l >5000 mg/kg >5000 mg/kg 1100 mg/kg 3680 mg/kg

4 hours 4 hours -

Conclusion/Summary Irritation/Corrosion Conclusion/Summary Sensitization

: Not available.

Conclusion/Summary Mutagenicity

: Not available.

Date of issue

Species

: Not available.

: 15.10.2015.

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SECTION 11: Toxicological information Conclusion/Summary Carcinogenicity Conclusion/Summary Reproductive toxicity Conclusion/Summary Teratogenicity Conclusion/Summary

: Not available. : Not available. : Not available. : Not available.

Specific target organ toxicity (single exposure) Product/ingredient name n-butyl acetate Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%) 2-methylpropan-1-ol

Category

Route of exposure

Target organs

Category 3 Category 3

Not applicable. Not applicable.

Narcotic effects Narcotic effects

Category 3

Not applicable.

Respiratory tract irritation

Specific target organ toxicity (repeated exposure) Product/ingredient name Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)

Category Category 1

Route of exposure Not determined

Target organs Not determined

Aspiration hazard Product/ingredient name naphtha (petroleum), hydrotreated heavy Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%) Information on the likely routes of exposure

Result ASPIRATION HAZARD - Category 1 ASPIRATION HAZARD - Category 1

: Not available.

Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation Skin contact

: No known significant effects or critical hazards. : May cause an allergic skin reaction.

Ingestion

: Irritating to mouth, throat and stomach.

Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects Not available. Conclusion/Summary General

Carcinogenicity Date of issue

: Not available. : May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. : No known significant effects or critical hazards. : 15.10.2015.

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SECTION 11: Toxicological information Mutagenicity Teratogenicity Developmental effects Fertility effects Other information

: : : : :

No known significant effects or critical hazards. Suspected of damaging the unborn child. No known significant effects or critical hazards. Suspected of damaging fertility. Not available.

SECTION 12: Ecological information 12.1 Toxicity Product/ingredient name

Result

Species

Exposure

zinc oxide n-butyl acetate

Acute EC50 0.17 mg/l Acute EC50 647.7 mg/l

Algae Algae

72 hours 72 hours

Conclusion/Summary

: Not available.

12.2 Persistence and degradability Conclusion/Summary

: Not available.

12.3 Bioaccumulative potential Product/ingredient name

LogPow

BCF

Potential

2-methoxy-1-methylethyl acetate n-butyl acetate 2-methylpropan-1-ol 2-butanone oxime

1.2

-

low

2.3 1 0.63

5.011872336

low low low

12.4 Mobility in soil Soil/water partition coefficient (KOC)

: Not available.

Mobility

: Not available.

12.5 Results of PBT and vPvB assessment PBT vPvB

: Not applicable. : Not applicable.

12.6 Other adverse effects

: No known significant effects or critical hazards.

SECTION 13: Disposal considerations 13.1 Waste treatment methods Product Methods of disposal

: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. European waste catalogue (EWC) Waste code 08 01 11*

Date of issue

Waste designation waste paint and varnish containing organic solvents or other dangerous substances : 15.10.2015.

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SECTION 13: Disposal considerations Packaging

: Completely emptied packagings may be given for recycling. Empty packaging may still contain hazardous residues. Empty packaging should be removed by a licensed waste contractor.

European waste catalogue (EWC) (Packaging)

: packaging containing residues of or contaminated by dangerous substances

SECTION 14: Transport information ADR/RID - ADN

IMDG

IATA

14.1 UN number

UN1263

UN1263

UN1263

14.2 UN proper shipping name

Paint Zinc oxide

Paint Zinc oxide

Paint Zinc oxide

14.3 Transport hazard class(es)

3

3

3

14.4 Packing group III

III

III

14.5 Environmental hazards

Yes

Yes

Yes

Additional information

The environmentally hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

The environmentally hazardous substance mark may appear if required by other transportation regulations.

Special provisions 640 (E)

Emergency schedules (EmS) F-E, S-E

Tunnel code (D/E) Classification code F1 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

: Not available.

SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization Annex XIV None of the components are listed. Substances of very high concern None of the components are listed. Annex XVII - Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Date of issue

: 15.10.2015.

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SECTION 15: Regulatory information VOC content (EU)

: VOC (w/w): 23.69%

Other EU regulations REACH Information:

: All substances contained in our Products are - preregistered or registered by our upstream suppliers, and/or - preregistered or registered by us, and/or - excluded from the regulation, and/or - exempted from the registration.

Europe inventory

: All components are listed or exempted.

Product/ingredient name

Carcinogenic effects -

Mutagenic effects

Carc. 2, H351

-

hexaboron dizinc undecaoxide 2-butanone oxime

-

Developmental effects Repr. 2, H361d (Unborn child) -

Fertility effects Repr. 2, H361f (Fertility) -

National regulations

Product/ingredient name 2-butanone oxime

List name Denmark Carcinogenic Chemicals

Name on list 2-butanonoxim

Classification Listed

Notes -

Product registration number

: 533561

Danish fire class Denmark – Cancer risks

: II-1 : National Working Environment Authorities Ordinance on Measures to Prevent Cancer Risks during Work with Substances and Preparations is applicable. : 3-6 : According to the regulations on work involving coded products, the following stipulations apply to the use of personal protective equipment:

MAL-code Protection based on MAL

General: Gloves must be worn for all work that may result in soiling. Apron/coveralls/ protective clothing must be worn when soiling is so great that regular work clothes do not adequately protect skin against contact with the product. A face shield must be worn in work involving spattering if a full mask is not required. In this case, other recommended use of eye protection is not required. In all spraying operations in which there is return spray, the following must be worn: respiratory protection and arm protectors/apron/coveralls/protective clothing as appropriate or as instructed.

MAL-code: 3-6 Application: When spraying in new* booths if the operator is outside the spray zone. When using scraper or knife, brush, roller, etc. for pre- and post-treatments outside a closed facility, spray booth or spray cabin. - Air-supplied half mask and eye protection must be worn. During downtimes, cleaning and repair of closed facilities, spray booths or cabins, if there is a risk of contact with wet paint or organic solvents. When using scraper or knife, brush, roller, etc. for pre- and post-treatments in cabins or booths of the existing* facility type, if the operator is inside the spray zone. - Air-supplied half mask, coveralls and eye protection must be worn. When spraying in existing* spray booths, if the operator is outside the spray zone. Date of issue

: 15.10.2015.

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SECTION 15: Regulatory information - Air-supplied full mask, arm protectors and apron must be worn. During non-atomizing spraying in existing* facilities of the combined-cabin, spraycabin and spray-booth type where the operator is working inside the spray zone. - Air-supplied full mask, arm protectors and apron must be worn. During all spraying where atomization occurs in cabins or spray booths where the operator is inside the spray zone and during spraying outside a closed facility, cabin or booth. - Air-supplied full mask, coveralls and hood must be worn. Drying: Items for drying/drying ovens that are temporarily placed on such things as rack trolleys, etc. must be equipped with a mechanical exhaust system to prevent fumes from wet items from passing through workers' inhalation zone. Polishing: When polishing treated surfaces, a mask with dust filter must be worn. When machine grinding, eye protection must be worn. Work gloves must always be worn. Caution The regulations contain other stipulations in addition to the above.

Restrictions on use

:

Carcinogenic waste

:

Waste group 15.2 Chemical Safety Assessment

: :

*See Regulations. Not to be used by professional users below 18 years of age. See the National Working Environment Authorities Executive Order on young people's dangerous work. Waste containers must be labeled: Contains a substance or substances regulated by Danish working environment legislation on cancer risks. H This product contains substances for which Chemical Safety Assessments are still required.

SECTION 16: Other information Indicates information that has changed from previously issued version. Abbreviations and acronyms : ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number Full text of abbreviated H statements

: H226 H304 H312 H315 H317 H318 H319 H335

Flammable liquid and vapor. May be fatal if swallowed and enters airways. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Causes serious eye irritation. May cause respiratory irritation. (Respiratory tract irritation)

(Respiratory

tract irritation) H336

May cause drowsiness and dizziness. (Narcotic effects)

(Narcotic

effects) Date of issue

: 15.10.2015.

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SECTION 16: Other information

Full text of classifications [CLP/GHS]

Full text of abbreviated R phrases

Full text of classifications [DSD/DPD]

H351 Suspected of causing cancer. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. (Fertility and Unborn child) H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. : Acute Tox. 4, H312 ACUTE TOXICITY (dermal) - Category 4 Aquatic Acute 1, H400 AQUATIC HAZARD (ACUTE) - Category 1 Aquatic Chronic 1, H410 AQUATIC HAZARD (LONG-TERM) - Category 1 Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM) - Category 2 Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1 Carc. 2, H351 CARCINOGENICITY - Category 2 Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3 Repr. 2, H361fd (Fertility TOXIC TO REPRODUCTION (Fertility and Unborn child) and Unborn child) Category 2 Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2 Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1 Skin Sens. 1A, H317 SKIN SENSITIZATION - Category 1A STOT RE 1, H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE (Respiratory tract EXPOSURE) (Respiratory tract irritation) - Category 3 irritation) STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE (Narcotic effects) EXPOSURE) (Narcotic effects) - Category 3 : R10- Flammable. R40- Limited evidence of a carcinogenic effect. R21- Harmful in contact with skin. R48/20- Harmful: danger of serious damage to health by prolonged exposure through inhalation. R65- Harmful: may cause lung damage if swallowed. R41- Risk of serious damage to eyes. R36- Irritating to eyes. R37/38- Irritating to respiratory system and skin. R43- May cause sensitization by skin contact. R66- Repeated exposure may cause skin dryness or cracking. R67- Vapors may cause drowsiness and dizziness. R50- Very toxic to aquatic organisms. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : Carc. Cat. 3 - Carcinogen category 3 Xn - Harmful Xi - Irritant N - Dangerous for the environment

History Date of printing Date of issue Date of issue

: 05.04.2016. : 15.10.2015. : 15.10.2015.

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SECTION 16: Other information Date of previous issue Notice to reader

: 28.06.2012.

The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any use and processing.

Date of issue

: 15.10.2015.

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