Autotechnik-Horsch-GmbH & Co.KG.
Safety Data Sheet according to Regulation (EC) No 1907/2006
„number one“ – Auto-Shampoo Print date: 18.04.2016
Page 1 of 12
Product code:
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier „number one“ – Auto-Shampoo 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Automotive care products Uses advised against any non-intended use. 1.3. Details of the supplier of the safety data sheet Company name: Autotechnik-Horsch-GmbH & Co.KG. Street: Teufelsheide 6 Place: D-49086 Osnabrück
Telephone: Responsible Department:
0541-77615 Dr. Gans-Eichler Chemieberatung GmbH Raesfeldstr. 22 D-48149 Münster
Telefax: 0541-77616 e-mail:
[email protected] Tel.: +49 (0)251/924520-60 www.tge-consult.de
0541-77615 (Mo-Fr; 08:00-16:00)
1.4. Emergency telephone number:
SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Regulation (EC) No. 1272/2008 Hazard categories: Skin corrosion/irritation: Skin Irrit. 2 Serious eye damage/eye irritation: Eye Dam. 1 Hazard Statements: Causes skin irritation. Causes serious eye damage. 2.2. Label elements Regulation (EC) No. 1272/2008 Hazard components for labelling Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts Poly(oxy-1,2-ethanediyl), a-sulfo-?-hydroxy-, C11-14-isoalkyl ethers, C13-rich, sodium salts Alcohols, C9-16, ethoxylated Amides, C8-18 (even numbered) and C18-unsatd., N,N-bis(hydroxyethyl) Signal word:
Danger
Pictograms:
Hazard statements H315 H318
Causes skin irritation. Causes serious eye damage.
Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P280 Wear protective gloves and eye/face protection. Revision No: 1,0
GB - EN
Revision date: 18.04.2016
Autotechnik-Horsch-GmbH & Co.KG.
Safety Data Sheet according to Regulation (EC) No 1907/2006
„number one“ – Auto-Shampoo Print date: 18.04.2016 P305+P351+P338 P310
Page 2 of 12
Product code: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
2.3. Other hazards The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
SECTION 3: Composition/information on ingredients 3.2. Mixtures Hazardous components CAS No
Chemical name EC No
Quantity Index No
REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP] 68411-30-3
Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts 270-115-0
10 - < 15 % 01-2119489428-22
Acute Tox. 4, Skin Irrit. 2, Eye Dam. 1, Aquatic Chronic 3; H302 H315 H318 H412 78330-30-0
Poly(oxy-1,2-ethanediyl), a-sulfo-?-hydroxy-, C11-14-isoalkyl ethers, C13-rich, sodium salts
1-= 8 h CR (polychloroprenes, Chloroprene rubber). - Thickness of glove material: 0,5 mm Breakthrough time >= 8 h NBR (Nitrile rubber). - Thickness of glove material: 0,35 mm Breakthrough time >= 8 h PVC (Polyvinyl chloride). - Thickness of glove material: 0,5 mm Breakthrough time >= 8 h The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Check leak tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. Skin protection Suitable protective clothing: Lab apron. Minimum standard for preventive measures while handling with working materials are specified in the TRGS Revision No: 1,0
GB - EN
Revision date: 18.04.2016
Autotechnik-Horsch-GmbH & Co.KG.
Safety Data Sheet according to Regulation (EC) No 1907/2006
„number one“ – Auto-Shampoo Print date: 18.04.2016
Page 6 of 12
Product code:
500 (D). Respiratory protection With correct and proper use, and under normal conditions, breathing protection is not required. Environmental exposure controls No special precautionary measures are necessary.
SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties
Physical state: Colour: Odour:
liquid colourless characteristic Test method
pH-Value:
not determined
Changes in the physical state Melting point:
not determined
Initial boiling point and boiling range:
not determined
Sublimation point:
not determined
Softening point: Pour point:
not determined not determined
Flash point: Sustaining combustion:
not determined Not sustaining combustion
Explosive properties none
Lower explosion limits: Upper explosion limits:
not determined not determined
Ignition temperature:
not determined
Auto-ignition temperature Gas:
not determined
Decomposition temperature:
not determined
Oxidizing properties none
Vapour pressure:
not determined
Density:
not determined
Water solubility:
not determined
Solubility in other solvents not determined
Partition coefficient:
not determined
Viscosity / dynamic:
not determined
Viscosity / kinematic:
not determined
Flow time:
not determined
Vapour density:
not determined
Evaporation rate:
not determined
Solvent separation test:
not determined
Solvent content:
not determined
Revision No: 1,0
GB - EN
Revision date: 18.04.2016
Autotechnik-Horsch-GmbH & Co.KG.
Safety Data Sheet according to Regulation (EC) No 1907/2006
„number one“ – Auto-Shampoo Print date: 18.04.2016
Page 7 of 12
Product code:
9.2. Other information
Solid content:
not determined
SECTION 10: Stability and reactivity 10.1. Reactivity No information available. 10.2. Chemical stability
The product is chemically stable under recommended conditions of storage, use and temperature. 10.3. Possibility of hazardous reactions
No information available. 10.4. Conditions to avoid Protect against: UV-radiation/sunlight. heat. 10.5. Incompatible materials Materials to avoid: Oxidizing agents, strong. Reducing agents, strong. Strong acid 10.6. Hazardous decomposition products In case of fire may be liberated: Carbon monoxide, Carbon dioxide (CO2). Sulphur oxides, Nitrogen oxides (NOx)
SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicocinetics, metabolism and distribution No data available. Acute toxicity Based on available data, the classification criteria are not met. CAS No
Chemical name Exposure route
68411-30-3
97043-91-9
Species
Source
Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts oral
LD50
1080 mg/kg
Rat
ECHA Dossier
dermal
LD50
>2000 mg/kg
Rat
ECHA Dossier
ATE
500 mg/kg
Alcohols, C9-16, ethoxylated oral
68155-07-7
Dose
Amides, C8-18 (even numbered) and C18-unsatd., N,N-bis(hydroxyethyl) oral
LD50
>2000 mg/kg
Rat
ECHA Dossier
dermal
LD50
>2000 mg/kg
Rabbit
ECHA Dossier
Irritation and corrosivity Causes skin irritation. Causes serious eye damage. Sensitising effects Based on available data, the classification criteria are not met. Carcinogenic/mutagenic/toxic effects for reproduction
Revision No: 1,0
GB - EN
Revision date: 18.04.2016
Autotechnik-Horsch-GmbH & Co.KG.
Safety Data Sheet according to Regulation (EC) No 1907/2006
„number one“ – Auto-Shampoo Print date: 18.04.2016
Page 8 of 12
Product code:
Based on available data, the classification criteria are not met. Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts (CAS-No.: 68411-30-3): In vitro mutagenicity/genotoxicity: Method:: EU Method B.13/14 (Mutagenicity - Reverse Mutation Test Using Bacteria) Result: negative. Method:: OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) Result: negative. Method:: OECD Guideline 473 (In vitro Mammalian Chromosome Aberration Test) Result: negative (without metabolic activation). positive (with metabolic activation). In vivo mutagenicity/genotoxicity: No experimental indications of in vivo mutagenicity exist. Developmental toxicity/teratogenicity: Method: species: Rat Exposure duration: 20d Results: NOAEL = 300 mg/kg literature infomation: ECHA Dossier STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts (CAS-No.: 68411-30-3): Subacute oral toxicity: Method: species: Rat Exposure duration: 28d Results: NOAEL = 125 mg/kg(bw)/day literature infomation: ECHA Dossier Aspiration hazard Based on available data, the classification criteria are not met. Specific effects in experiment on an animal No data available.
SECTION 12: Ecological information 12.1. Toxicity CAS No
Chemical name Aquatic toxicity
68411-30-3
68155-07-7
[h] | [d] Species
Dose
Source
Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts Acute fish toxicity
LC50
1,67 mg/l
96 h Lepomis macrochirus
ECHA Dossier
Acute algae toxicity
ErC50
127,9 mg/l
72 h Desmodesmus subspicatus
ECHA Dossier
Acute crustacea toxicity
EC50
3,5 mg/l
48 h Hyalella azteca
ECHA Dossier
Amides, C8-18 (even numbered) and C18-unsatd., N,N-bis(hydroxyethyl) Acute fish toxicity
LC50
2,4 mg/l
96 h Oncorhynchus mykiss
ECHA Dossier
Acute algae toxicity
ErC50
18,6 mg/l
72 h Desmodesmus subspicatus
ECHA Dossier
Acute crustacea toxicity
EC50
3,2 mg/l
48 h Daphnia magna
ECHA Dossier
Acute bacteria toxicity
(6 (16d) mg/l)
Pseudomonas putida
ECHA Dossier
12.2. Persistence and degradability
Revision No: 1,0
GB - EN
Revision date: 18.04.2016
Autotechnik-Horsch-GmbH & Co.KG.
Safety Data Sheet according to Regulation (EC) No 1907/2006
„number one“ – Auto-Shampoo Print date: 18.04.2016 CAS No
Page 9 of 12
Product code:
Chemical name Method
Value
d
Source
85%
29
ECHA Dossier
28
ECHA Dossier
Evaluation 68411-30-3
Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts OECD Guideline 301 B Product is biodegradable.
68155-07-7
Amides, C8-18 (even numbered) and C18-unsatd., N,N-bis(hydroxyethyl) OECD 301B/ ISO 9439/ EEC 92/69/V, C.4-C
92,5%
Readily biodegradable (according to OECD criteria).
12.3. Bioaccumulative potential Partition coefficient n-octanol/water Log Pow
CAS No
Chemical name
68411-30-3
Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts
68155-07-7
Amides, C8-18 (even numbered) and C18-unsatd., N,N-bis(hydroxyethyl)
1,4 1.35
