MSDS of 2-(Aminomethyl)piperidine

Page 1 of 6

Jubilant Organosys Limited

Ref. No 0221A00 Div 05 msds 2-(Aminomethyl)piperidine Date of Issue: 14 February 2005 Revision: 00

MATERIAL SAFETY DATA SHEET 1.

CHEMICAL PRODUCT & MANUFACTURER’S DETAILS

PRODUCT NAME : 2-Aminomethylpiperidine MANUFACTURER FACTORY & REGISTERED OFFICE: Jubilant Organosys Limited, Bhartiagram, Gajraula District: Jyotiba Phuley Nagar Uttar Pradesh-244223 , India PHONE NO: +91-5924-252353 upto 60 Contact Department-Safety: Extension 298 FAX NO : 91-5924-252352 EMERGENCY PHONE: +91-5924-268141

2. • • • •

• • • •

3. • • • • •

HEAD OFFICE: Jubilant Organosys Limited Plot 1-A, Sector 16-A, Institutional Area, Noida, Uttar Pradesh-201301 India. PHONE NO: +91-120-2516601 Contact department: EHS FAX NO : +91-120-2516629 Email: [email protected]

CHEMICAL IDENTIFICATION CHEMICAL NAME SYNONYMS SYSTEMATIC NAME LANGUAGE NAMES

CHEMICAL CLASSIFICATION CHEMICAL FORMULA C.A.S. NO EINECS

: 2-Aminomethylpiperidine : 2-(Aminomethyl)piperidine, : Piperidine-2-methylamine De : Piperidin-2-methylamin Es : piperidina-2-metilamina Fr : pipéridine-2-méthylamine : Piperidine derivative : C6H14N2 : 22990-77-8 : 245-371-1

HAZARD IDENTIFICATION & HEALTH HAZARD Overview: Corrosive liquid basic organic amine. Mode of entry skin, inhalation and ingestion. The complete toxicological profile of this chemical is not known. Do not permit direct contact. Do not dispose into environmental bodies. Eye : Causes severe eye burns. Skin : Causes skin burns and irritation. Ingestion : Corrosive liquid causes burns to the gastrointestinal tract. Inhalation : Corrosive liquid and vapour may cause irritation and burns to the respiratory tract.

MSDS of 2-(Aminomethyl)piperidine Ref. No 0221A00 Div 05 msds 2-(Aminomethyl)piperidine Date of Issue: 14 February 2005 Revision: 00

Page 2 of 6

Jubilant Organosys Limited

FIRST AID MEASURES

4.

Effects of exposure may be delayed. Keep victim warm and quiet. Skin Contact: Remove contaminated clothing. Wash exposed area with water for at least 20 minutes. Get immediate medical attention if irritation persists or symptoms of overexposure develop. Show label to the medical personnel. Eye Contact: Wash thoroughly with running water. Get immediate medical attention if irritation persists or symptoms of overexposure develop. Show label to the medical personnel. Ingestion: Never give anything to an unconscious person. Do not induce vomiting, this chemical is corrosive. Get immediate medical attention. Show the label to the medical personnel. Inhalation: Remove to fresh air and get medical attention for any breathing difficulty. Do not use mouth to mouth resuscitation. Administer oxygen if breathing is difficult.

5.

FIRE FIGHTING MEASURES o

o

Flash Point: 75 C TCC (167 F) This product is classified as combustible. Extinguishing media: Dry chemical or carbon dioxide. Extinguish with foam - dry powder, subsequently secure with foam blanket. Special fire fighting procedures: • Keep upwind. Put on protective equipment before entering danger area. • As in any chemical fire wear a self-contained breathing apparatus MSHA/NIOSH (or equivalent approved) and full protective gloves. • Do not permit the chemical/ fire effluent to enter the environment as far as possible. • Water may be used to cool containers in event of a large fire. Do not permit water to get inside containers. • Dike fire control water for later disposal; do not scatter the material. • After the incident ensure no contact is made with the chemical during undressing. Ensure equipment clean-up. Unusual fire and explosion hazard: • During combustion toxic and irritating fumes may be emitted... • Heating of container(s) will cause pressure rise with risk of bursting and subsequent explosion (BLEVE).

MSDS of 2-(Aminomethyl)piperidine Ref. No 0221A00 Div 05 msds 2-(Aminomethyl)piperidine Date of Issue: 14 February 2005 Revision: 00

6.

Page 3 of 6

Jubilant Organosys Limited

ACCIDENTAL RELEASE MEASURES

• General Information : Use proper personal protective equipment as indicated in Section 8 Spills / Leaks : • Eliminate all sources of ignition. • Stop leak if possible, without risk. • Prevent entry into waterways and basements. If the material has entered such areas inform the authorities. • Absorb spill with inert material such as sand or earth, then place in suitable container. • After clean-up ventilate area if there is no risk to personnel or public.

7. • •

8. • •

•

HANDLING AND STORAGE Handling : See section 8 for exposure control and personal protection measures. Restrict to experienced personnel. Wash thoroughly after usage. Storage : Store in a cool, dry place. Store in a tightly closed container. Keep away from acids. Store as per guidelines of aliphatic amines.

EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure controls: Facilities using this material must be equipped with eye-wash facilities and a safety shower. Use appropriate engineering controls such as process enclosures and local exhaust ventilation and fume hoods to keep airborne levels to a minimum. Personal Protection • Skin: Wear suitable protective clothing. • Hands: Wear compatible gloves. • Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.Exposure. • Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary or when exposure controls are not satisfactory. Exposure Limits • Not available. There are no known exposure limits available for this chemical.. No exposure limits have been listed by ACGIH, NIOSH and OSHA.

MSDS of 2-(Aminomethyl)piperidine Ref. No 0221A00 Div 05 msds 2-(Aminomethyl)piperidine Date of Issue: 14 February 2005 Revision: 00

Page 4 of 6

Jubilant Organosys Limited

9. PHYSICOCHEMICAL PROPERTIES & FIRE/ EXPLOSION HAZARD PHYSICAL STATE : Clear liquid APPEARANCE : Colour less to pale yellow liquid ODOUR : Characterstic BOILING POINT : 1200C at 110mmHg MELTING POINT : NA FLASH POINT : 750C TCC VAPOUR PRESSURE : 1.07 Torr DENSITY : 0.941gm/cc at 200C SOLUBILITY IN WATER : 100g/100g water at 250C pH (10%) : 12 FLAMMABILITY LEL : NA UEL : NA AUTO IGNITION TEMPERATURE : NA EXPLOSIVE SENSITIVITY TO IMPACTS : NA EXPLOSIVE SENSITIVITY TO STATIC ELECTRICITY : NA COMBUSTIBLE LIQUID : Yes PYROPHORIC MATERIAL : No EXPLOSIVE MATERIAL : No OXIDISER : No ORGANIC PEROXIDES : Not formed CORROSIVE MATERIAL : Yes MOLECULAR WEIGHT : 114.19

10. • • • • •

STABILITY AND REACTIVITY Stability: The product is stable at normal temperature and pressure. Avoid excess heat. Unnecessary exposure to light may be avoided. Conditions to Avoid: Avoid proximity to ignition sources, flames, heat and incompatible substances. Incompatibilities: Strong oxidizing agents, acids, anhydrides, isocyanates etc. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, ammonia are possible. Hazardous Polymerization: No information available

MSDS of 2-(Aminomethyl)piperidine Ref. No 0221A00 Div 05 msds 2-(Aminomethyl)piperidine Date of Issue: 14 February 2005 Revision: 00

11. •

• • •

12. •

13. •

14.

Page 5 of 6

Jubilant Organosys Limited

TOXICOLOGICAL INFORMATION ACUTE EFFECTS: • The full toxicological profile of this chemical is not known. • The chemical is corrosive to eyes, skin, on inhalation and if swallowed. • The chemical is an aliphatic amines. Routes of entry include dermal and inhalation. CHRONIC EFFECTS: No data available TOXICITY: • RTECS: CAS #22990-77-8 is unlisted • ORL MOUSE LD50 : 1440 mg/kg CARCINOGENICITY: NTP, IARC, OSHA-not listed. The carcinogenicity of this chemical has not been determined to the best of our knowledge.

ECOLOGICAL INFORMATION The ecological profile of this chemical is not known, do not permit entry into environmental bodies.

DISPOSAL CONSIDERATION Dispose of this material in accordance with local and federal laws as applicable.

TRANSPORT INFORMATION

Classification by IATA/IMDG/ADR/RID Proper Shipping Name: Amines Liquid Corrosive NOS (Piperidine-2-methylamine) UN Number: 2735 Hazard Class: 8 Packing Group: III

15.

REGULATORY INFORMATION

European Information: EC#: 245-371-1 Pictogram: Corrosive Indication of danger: C Risk Phrases • R 34 Causes burns. Safety Phrases • S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. • S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. • S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Canada Not found on the DSL or NDSL (update February 9, 2005)

MSDS of 2-(Aminomethyl)piperidine Ref. No 0221A00 Div 05 msds 2-(Aminomethyl)piperidine Date of Issue: 14 February 2005 Revision: 00

16.

Page 6 of 6

Jubilant Organosys Limited

OTHER INFORMATION

Information contained in this MSDS is believed to be correct but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from them. This MSDS shall be used as a guide only. JUBILANT ORGANOSYS LIMITED makes no warranties expressed or implied of the adequacy of this document for any particular purpose. Document Name: 0221A00 Div 05 msds 2-(Aminomethyl)piperidine Date: 14-Feb-05 Revision Number: 00